Multifunctional, flexible, and robust thin films capable of operating in demanding harsh temperature environments are crucial for various cutting-edge applications. This study presents a multifunctional Janus film integrating highly-crystalline Ti3C2Tx MXene and mechanically-robust carbon nanotube (CNT) film through strong hydrogen bonding. The hybrid film not only exhibits high electrical conductivity (4250 S cm-1), but also demonstrates robust mechanical strength and durability in both extremely low and high temperature environments, showing exceptional resistance to thermal shock. This hybrid Janus film of 15 μm thickness reveals remarkable multifunctionality, including efficient electromagnetic shielding effectiveness of 72 dB in X band frequency range, excellent infrared (IR) shielding capability with an average emissivity of 0.09 (a minimal value of 0.02), superior thermal camouflage performance over a wide temperature range (- 1 to 300 °C) achieving a notable reduction in the radiated temperature by 243 °C against a background temperature of 300 °C, and outstanding IR detection capability characterized by a 44% increase in resistance when exposed to 250 W IR radiation. This multifunctional MXene/CNT Janus film offers a feasible solution for electromagnetic shielding and IR shielding/detection under challenging conditions.

Electrochromic devices (ECDs), which are capable of modulating optical properties in the visible and long-wave infrared (LWIR) spectra under applied voltage, are of great significance for military camouflage. However, there are a few materials that can modulate dual frequency bands. In addition, the complex and specialized structural design of dual-band ECDs poses significant challenges. Here, we propose a novel approach for a bendable ECD capable of modulating LWIR radiation and displaying multiple colors. Notably, it eliminates the need for a porous electrode or a grid electrode, thereby improving both the response speed and fabrication feasibility. The device employs multiwalled carbon nanotubes (MWCNTs) as both the transparent electrode and the LWIR modulator, polyaniline (PANI) as the electrochromic layer, and ionic liquids (HMIM[TFSI]) as the electrolyte. The ECD is able to reduce its infrared emissivity (Δε = 0.23) in a short time (resulting in a drop in infrared temperature from 50 to 44 °C) within a mere duration of 0.78 ± 0.07 s while changing its color from green to yellow within 3 s when a positive voltage of 4 V is applied. In addition, it exhibits excellent flexibility, even under bending conditions. This simplified structure provides opportunities for applications such as wearable adaptive camouflage and multispectral displays.

The integration of ultraflexible and mechanically robust films with electric heaters and camouflage technology provides a promising platform for the development of wearable devices, especially for aerospace and military applications. Herein, we present a facile and efficient one-step vacuum-assisted filtration method for fabricating Janus films based on aramid nanofibers (ANF) and Ti3C2Tx (MXene). The ANF/MXene nanocomposite film exhibits remarkable properties, including high conductivity (23809.5 S/m), excellent mechanical strength (102.54 MPa), and outstanding thermal stability (575 °C). Most notably, the Janus ANF/MXene composite film demonstrates superior Joule heating performance with a low driving voltage (1-5 V), high heating temperature (30-276 °C), and rapid response time (within 5 s). Additionally, the film exhibits effective thermal camouflage (72 °C for objects with temperatures above 163 °C) and excellent electromagnetic interference shielding properties (SSE/t = 32475.6 dB cm2/g). These results demonstrate that Janus ANF/MXene films possess a unique combination of thermal camouflage, Joule heating, and electromagnetic interference shielding properties, making them highly promising for wearable devices, high-performance electrical heating, infrared stealth, and security protection applications.

Robust, ultrathin, and environmental-friendliness papers that synergize high-efficiency electromagnetic interference (EMI) shielding, personal thermal management, and wearable heaters are essential for next-generation smart wearable devices. Herein, MXene nanocomposite paper with a nacre-like structure for EMI shielding and electrothermal/photothermal conversion is fabricated by vacuum filtration of Ti3 C2 Tx MXene and modified sawdust. The hydrogen bonding and highly oriented structure enhance the mechanical properties of the modified sawdust/MXene composite paper (SM paper). The SM paper with 50 wt% MXene content shows a strength of 23 MPa and a toughness of 13 MJ·M-3 . The conductivity of the SM paper is 10 195 S·m-1 , resulting in an EMI shielding effectiveness (SE) of 67.9 dB and a specific SE value (SSE/t) of 8486 dB·cm2 ·g-1 . In addition, the SM paper exhibits excellent thermal management performance including high light/electro-to-thermal conversion, rapid Joule heating and photothermal response, and sufficient heating stability. Notably, the SM paper exhibits low infrared emissivity and distinguished infrared stealth performance, camouflaging a high-temperature heater surface of 147-81 °C. The SM-based e-skin achieves visualization of Joule heating and realizes human motions monitoring. This work presents a new strategy for designing MXene-based wearable devices with great EMI shielding, artificial intelligence, and thermal management applications.

Dynamic control of a material\'s thermal emission could enable many emerging applications, such as thermal camouflage and infrared (IR) display. Low-dimensional carbon nanomaterials have shown great potential in these applications because of their tuneability in charge density via static gating or ionic intercalation. Herein, a thermal emission modulator based on single-walled carbon nanotubes (SWCNTs) is realized by ionic gating. The Fermi energy of the SWCNTs is shifted via the adsorption of ions on the surface, and the highest emissivity is observed at the neutral state while both P-type and N-type SWCNTs have a reduced emissivity. An emissivity modulation range is achieved approximately from 0.45 to 0.95 within the electrochemical window of the used ionic liquid. Thermal camouflage and IR display applications are then demonstrated by utilizing the tuneable thermal emissivity of the fabricated SWNCT films. More importantly, a single-layer structure allows effective dynamic control purely by static gating, without involving any ion interaction process that may cause structural damage, as observed in graphene and multi-walled nanotubes. Therefore, the SWCNT-based IR modulators exhibit long-term stability, with nearly identical modulation range and response time after 6000 dynamic tuning cycles, indicating great potential for practical applications.

The infinite effective thermal conductivity (IETC) can be considered to be an equivalence of the effective zero index in photonics. A recent highly rotating metadevice has been discovered to approach near IETC, subsequently demonstrating a cloaking effect. However, this near IETC, related to a rotating radius, is quite inhomogeneous, and the high-speed rotating motor also needs a high energy input, limiting its further applications. Herein, we propose and realize an evolution of this homogeneous zero-index thermal metadevice for robust camouflaging and super-expanding through out-of-plane modulations rather than high-speed rotation. Both the theoretical simulations and experiments verify a homogeneous IETC and the corresponding thermal functionalities beyond cloaking. The recipe for our homogeneous zero-index thermal metadevice involves an external thermostat, which can be easily adjusted for various thermal applications. Our study may provide meaningful insights into the design of powerful thermal metadevices with IETCs in a more flexible way.

Translucent Au/graphene hybrid films are shown to be effective in reducing thermal emission from the underlying surfaces when the deposition thickness of Au is close to the percolation threshold. The critical Au deposition thickness for an abrupt change in emissivity is reduced from 15 nm (Si substrate) to a percolation-threshold-limited thickness of 8.5 nm (graphene/Si substrate) because of the chemical inertness of graphene leading to the deposited Au atoms forming a thin, crystalline layer. The effect of the graphene layer on the optical properties of the hybrid film is highlighted by a drastic increase in infrared absorptivity, whereas the visible absorptivity is marginally affected by the presence of a graphene layer. The level of thermal emission from the Au/graphene hybrid films with the percolation-threshold-limited Au thickness is stable even with high background temperatures of up to 300 °C and mechanical strains of ≈4%. As an example of a thermal management application, an anti-counterfeiting device is demonstrated; thermal-camouflage-masked text fabricated with an Au/graphene hybrid film is discernible only using a thermographic camera. Ultrathin metal film assisted by a graphene layer will provide a facile platform for thermal management with semi-transparency, flexibility, and transferability to arbitrary surfaces.

Emerging metamaterials have served as an efficient strategy for the realization of unconventional heat control and management using structural thermal properties, and many functional thermal metadevices have been investigated. However, thermal functions are usually fixed or limited in the switching range. Thus far, real-time thermal regulation is elusive for thermal metamaterials because of deterministic artificial metastructures and uncontrollable phase transitions, coupled with the absence of dynamic adaptability. Here, a self-adaptive metasurface platform to implement programmable thermal functions via the automatic evolution of thermoelectric heat sources and real-time control of the driven voltage is reported. The proof-of-concept smart platform experimentally demonstrates arbitrary switching between elaborate thermal patterns consolidated into an active thermoelectric element matrix. Further, thermal pixels and feedback control systems are integrated into printed circuit boards, resulting in self-adaptability to any thermal requirements. This study sets up a new paradigm for arbitrary transitions between exquisite thermal patterns and is expected to pave the way for real-time thermal management in a programming formation.

Camouflage refers to a creature\'s behavior to protect itself from predators by assimilating its signature with the environment. In particular, thermal camouflage materials in the infrared (IR) wave are attracting interest for energy, military, and space applications. To date, several types of camouflage materials such as photonic crystals and metal-dielectric-metal structures have been developed. However, flexible camouflage materials still face challenging issues because of the material\'s brittleness and anomalous dispersion. Herein, we propose flexible thermocamouflage materials (FTCM) for IR camouflage on an arbitrary surface without mechanical failure. Without using a polymer as a dielectric layer, we realized FTCM by changing the unit cell structure discretely. By imaging methods, we verified their flexibility, machinability, and IR camouflage performance. We also measured and calculated the spectral emissivity of FTCM; they showed electromagnetic behavior similar to a conventional emitter. We quantified the IR camouflage performance of FTCM that the emissivity in the undetected band (5-8 μm) is 0.27 and the emissivity values in detected bands are 0.12 (3-5 μm) and 0.16 (8-14 μm) in the detected bands, respectively. Finally, we confirmed the IR camouflage performance on an arbitrary surface in a supersonic flowfield. FTCM are expected to help to improve our basic understanding of metamaterials and find widespread application as IR camouflage materials.

This paper reports on a new approach to the creation process in fashion design as a result of the exploitation of thermal camouflage in the conceptualization of clothing. The thermal images\' main variation factors were obtained through the analysis of their color behavior in a (diurnal and nocturnal) outdoor beach environment, with the presence and absence of a dressed human body (through the use of a thermal imaging camera), such as the analysis of textile materials in a laboratory (simulating the captured outdoor atmospheric temperatures and those of the model\'s skin using the climatic chamber and the thermal manikin). The combination of different patternmaking, sewing and printing techniques in textile materials, along with the study of the camouflage environment and the human body\'s variation factors, as well as the introduction of biomimetic-inspired elements (chameleon\'s skin), enabled the creation of a clothing design process with innovative de-sign elements which allow us to thermally camouflage the human body and take clothing beyond the visible spectrum in a functional and artistic way.