thermal

  • 文章类型: Journal Article
    我们提出了一种带通/带阻可切换频率选择超表面(FSM),专为飞行过程中产生高温的高速车辆而设计,基于耐高温介电基板和液态金属(LM)。我们通过引入LM,利用耐高温的电介质衬底形成金属FSM元件来制造空腔结构,实现特定的电磁功能。可以控制LM的流动状态以实现FSM的带通/带阻性能的切换。带阻特性的谐振频率为6.1GHz,带通间隔为5.53-6.51GHz。带通特性的谐振频率为5.41GHz,带阻间隔为5.30-5.76GHz,实现5.53-5.76GHz的带通/带阻开关范围。LM流动性可以帮助高温散热。当LM达到一定流速时,FSM结构的平均温度可以降低一个数量级,从一千到不到一百度。FSM表现出低RCS,带阻和带通特性降低22.35dB和36.79dB,分别,与钣金相比。开发并测试了一个原型,验证耐高温FSM结构的设计,带通/带阻开关,和低RCS特性,并有望应用于高速飞机。
    We propose a bandpass/bandstop-switchable frequency-selective metasurface (FSM) designed for high-speed vehicles that generate high temperatures during flight, based on a high-temperature-resistant dielectric substrate and liquid metal (LM). We fabricated a cavity structure by utilizing a high-temperature-resistant dielectric substrate to form a metal FSM element by introducing LM, enabling specific electromagnetic functions. The flow state of the LM can be controlled to achieve the switching of the FSM\'s bandpass/bandstop performance. The bandstop characteristic has a resonance frequency of 6.1 GHz and the bandpass interval is 5.53-6.51 GHz. The bandpass characteristic has a resonance frequency of 5.41 GHz and the bandstop interval is 5.30-5.76 GHz, achieving a bandpass/bandstop switching range of 5.53-5.76 GHz. LM fluidity can aid in high-temperature heat dissipation. When the LM reaches a certain flow rate, the FSM structure\'s average temperature can be reduced by an order of magnitude from a thousand to less than a hundred degrees. The FSM exhibits low RCS, with 22.35 dB and 36.79 dB reductions in bandstop and bandpass properties, respectively, compared with that of sheet metal. A prototype was developed and tested, validating the design of the FSM structure with high-temperature resistance, bandpass/bandstop switchability, and low RCS characteristics, and is expected to be applied in high-speed aircraft.
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  • 文章类型: Journal Article
    单增李斯特菌生物膜在设备表面的持久性构成了交叉污染的重大风险,需要有效的表面去污策略。这项研究评估了结合过氧乙酸(PAA)和饱和蒸汽的跨栏治疗对不锈钢(SS)上7天大的无害乳杆菌(单核细胞增生乳杆菌的非致病性替代品)生物膜的有效性,聚酯(PET),和橡胶表面。结果表明,PAA后SS和PET表面的无毒性减少>6log10CFU/coupleL.1分钟),然后进行蒸汽处理(100°C,6s).在橡胶表面,PAA(80ppm,1分钟),然后进行蒸汽处理(100°C,6s)导致〜5log10CFU/优惠券L.innocua减少。苹果汁土壤的存在降低了障碍处理的功效,PAA(40ppm,1分钟)和蒸汽暴露(6s),导致SS上的L.innocua减少5.6、5.8和4.2log10CFU/试样,PET,橡胶,分别。这种抗微生物组合的功效因表面缺陷而进一步降低,尤其是在有机物的存在下.然而,Thetreatmentstillachieved>5log10CFU/couplereductionsofL.innocuaonwornSSandPETsoiledwithapplejuiceand~4.5log10CFU/couplereductiononworld,弄脏的橡胶表面。这些发现强调了PAA处理后短暂的蒸汽暴露是控制食物接触表面上的李斯特菌的有效策略。
    The persistence of Listeria monocytogenes biofilms on equipment surfaces poses a significant risk of cross-contamination, necessitating effective surface decontamination strategies. This study assessed the effectiveness of hurdle treatments combining peroxyacetic acid (PAA) and saturated steam against 7-day-old L. innocua (a non-pathogenic surrogate for L. monocytogenes) biofilms on stainless steel (SS), polyester (PET), and rubber surfaces. Results demonstrated >6 log10 CFU/coupon L. innocua reductions on SS and PET surfaces after PAA (40 ppm, 1 min) followed by steam treatment (100 °C, 6 s). On rubber surfaces, PAA (80 ppm, 1 min) followed by steam treatment (100 °C, 6 s) resulted in ~5 log10 CFU/coupon L. innocua reduction. The presence of apple juice soil reduced the efficacy of hurdle treatments, with PAA (40 ppm, 1 min) and steam exposure (6 s) resulting in 5.6, 5.8, and 4.2 log10 CFU/coupon reductions of L. innocua on SS, PET, and rubber, respectively. The efficacy of this antimicrobial combination was further reduced by surface defects, especially in the presence of organic matter. Nevertheless, the treatment still achieved >5 log10 CFU/coupon reductions of L. innocua on worn SS and PET soiled with apple juice and ~4.5 log10 CFU/coupon reduction on worn, soiled rubber surfaces. These findings highlight that PAA treatments followed by a brief steam exposure are effective strategies for controlling Listeria on food-contact surfaces.
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  • 文章类型: Journal Article
    尽管最近已转向用于钙钛矿太阳能电池的无甲铵(MA)卤化铅钙钛矿,高效的甲脒盐碘化铅(FAPbI3)设备仍然经常需要甲基氯化铵(MACl)作为添加剂,在退火过程中蒸发。在这篇文章中,结果表明,残差MA+,然而,触发热不稳定性。为了研究MA+的最佳浓度,可以提高热稳定性的可能性,纯FA的固有热稳定性,FA丰富,MA-rich,研究了纯MA钙钛矿薄膜(FA1-xMAxPbI3,FAMA)。结果表明,随着MA+的增加,FAMA钙钛矿的热稳定性降低,在隔离材料固有热稳定性的降解条件下(即,没有水分和氧气的影响)。X射线衍射(XRD)质子转移反应飞行时间质谱(PTR-ToF-MS),光致发光(PL)和紫外可见光谱,和深度剖析X射线光电子能谱(XPS)用于表明,观察到的趋势主要是由于MA阳离子的分解,与其他影响例如前体溶剂和膜形态相反。还发现这些FAMA薄膜的表面富含MA,虽然这种现象似乎不会影响热稳定性。最后,事实证明,这种趋势不受电影顶部Spiro-OMeTAD的存在的影响,因此,太阳能电池设备应该保持这一趋势。
    Despite a recent shift toward methylammonium (MA)-free lead-halide perovskites for perovskite solar cells, high-efficiency formamidinium lead iodide (FAPbI3) devices still often require methylammonium chloride (MACl) as an additive, which evaporates away during the annealing process. In this article, it is shown that the residual MA+, however, triggers thermal instability. To investigate the possibility of an optimal concentration of MA+ that may improve thermal stability, the intrinsic thermal stability of pure FA, FA-rich, MA-rich, and pure MA perovskite films (FA1-xMAxPbI3, FAMA) is studied. The results show that the thermal stability of FAMA perovskites decreases with more MA+, under degradation conditions that isolate the intrinsic thermal stability of the material (i.e., without moisture and oxygen effects). X-ray diffraction (XRD), proton-transfer-reaction time-of-flight mass spectrometry (PTR-ToF-MS), photoluminescence (PL) and UV-visible spectroscopy, and depth-profiling X-ray Photoelectron Spectroscopy (XPS) are employed to show that the observed trend is mainly due to the decomposition of the MA+ cation, as opposed to other effects such as the precursor solvent and film morphologies. It is also found that the surfaces of these FAMA films are MA+ rich, although this phenomenon does not appear to affect thermal stability. Finally, it is demonstrated that this trend is unaffected by the presence of Spiro-OMeTAD atop the film, and thus solar cell devices should preserve this trend.
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  • 文章类型: Journal Article
    许多临床前结果已经得到证实,和临床结果验证了调制电热疗(mEHT)的优势。该方法除了利用热能吸收之外还利用电场的非热效应。调节有助于精确靶向和免疫原性破坏恶性细胞,这可能会产生类似疫苗接种的副作用。新的附加调制(高功率脉冲)进一步发展了mEHT的能力。我的目标是介绍脉冲治疗的优势以及它如何适应mEHT治疗。脉冲治疗增加了破坏选定肿瘤细胞的功效;它在体内更深处活跃,至少是能量传递的三倍。由于脉冲幅度恒定,吸收能量的剂量是更可控的。用于复氧和药物递送的诱导血流足够高,但没有增加恶性细胞扩散的风险那么高。短脉冲减少了表面吸收,使治疗更安全,并且脉冲中增加的功率允许减少提供必要剂量所需的治疗时间。
    Numerous preclinical results have been verified, and clinical results have validated the advantages of modulated electro-hyperthermia (mEHT). This method uses the nonthermal effects of the electric field in addition to thermal energy absorption. Modulation helps with precisely targeting and immunogenically destroying malignant cells, which could have a vaccination-like abscopal effect. A new additional modulation (high-power pulsing) further develops the abilities of the mEHT. My objective is to present the advantages of pulsed treatment and how it fits into the mEHT therapy. Pulsed treatment increases the efficacy of destroying the selected tumor cells; it is active deeper in the body, at least tripling the penetration of the energy delivery. Due to the constant pulse amplitude, the dosing of the absorbed energy is more controllable. The induced blood flow for reoxygenation and drug delivery is high enough but not as high as increasing the risk of the dissemination of malignant cells. The short pulses have reduced surface absorption, making the treatment safer, and the increased power in the pulses allows the reduction of the treatment time needed to provide the necessary dose.
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  • 文章类型: Journal Article
    不可逆吸附,或者脚跟堆积,负面影响活性炭的性能和缩短其寿命。这项研究阐明了流量与解吸吹扫气体的氧杂质之间的相互关系,并在串珠活性炭(BAC)上积累了尾随。探索了九种热解吸方案,变化的氮气吹扫气体氧杂质水平(<5ppmv,10,000ppmv,210,000ppm(21%))和流量(0.1、1、10SLPM或1%,10%,吸附流量的100%)在热解吸过程中。结果表明,增加吹扫气体流量可以提高吸附容量回收率,并减轻吹扫气体氧杂质的不利影响。累积尾随随更高的吹扫气体氧杂质和更低的流速而增加。在最不有效的再生情况下(0.1SLPMN2,21%O2),五个循环后在BAC上形成32.8重量%的累积鞋跟,而最佳情况下(10SLPMN2,<5ppmvO2)仅导致0.3wt%。比较原始和使用过的BAC的孔径分布表明,鞋跟最初形成在狭窄的微孔(<8.5A)中,后来与中孔接合。热重分析(TGA)表明,氧杂质会产生高沸点和/或强结合的鞋跟物质。TGA证实,较高的吹扫气体流量减少了鞋跟量,但在氧气存在下促进了化学吸附鞋跟形成。这些发现可以指导再生条件的优化,提高活性炭在循环吸附过程中的长期性能。
    Irreversible adsorption, or heel buildup, negatively impacts activated carbon performance and shortens its lifetime. This study elucidates the interconnections between flow rate and the oxygen impurity of desorption purge gas with heel buildup on beaded activated carbon (BAC). Nine thermal desorption scenarios were explored, varying nitrogen purge gas oxygen impurity levels (<5 ppmv, 10,000 ppmv, 210,000 ppm (21 %)) and flow rates (0.1, 1, 10 SLPM or 1 %, 10 %, 100 % of adsorption flow rate) during thermal desorption. Results reveal that increasing purge gas flow rate improves adsorption capacity recovery and mitigates adverse effects of purge gas oxygen impurity. Cumulative heel increased with higher purge gas oxygen impurity and lower flow rates. In the least effective regeneration scenario (0.1 SLPM N2, 21 % O2), a 32.8 wt% cumulative heel formed on BAC after five cycles, while the best-case scenario (10 SLPM N2, <5 ppmv O2) resulted in only 0.3 wt%. Comparing the pore size distributions of virgin and used BAC shows that heel initially forms in narrow micropores (<8.5Å) and later engages mesopores. Thermogravimetric analysis (TGA) showed that oxygen impurity creates high boiling point and/or strongly bound heel species. TGA confirmed that higher purge gas flow rates reduce heel amounts but encourage chemisorbed heel formation in oxygen\'s presence. These findings can guide optimization of regeneration conditions, enhancing activated carbon\'s long-term performance in cyclic adsorption processes.
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  • 文章类型: Journal Article
    废活性污泥(WAS)成分复杂,含有大量有害物质,对环境和人类健康构成威胁。污泥的减量化和资源化已成为污泥处理和处置的发展需求。基于直接厌氧消化技术在实际应用中的技术瓶颈,本研究采用了两种不同的热和热碱水解技术对污泥进行预处理。进行了中试规模实验,以研究实验条件,参数,以及两种水解技术的影响。这项研究表明,最佳水解温度为70℃,水解效果与pH值达到平衡,水解停留时间为4-8h,最佳碱浓度范围为0.0125-0.015kgNaOH/kg干污泥。热碱组合处理大大提高了产甲烷性能,NaOH的添加比70°C热水解的甲烷产率提高了31.2%。实验过程中污泥的平均能耗为75kWh/m3,含水量为80%。本研究为探索适合南方特色污水污泥的高效厌氧消化处理技术提供了更好的预处理策略。
    The composition of waste-activated sludge (WAS) is complex, containing a large amount of harmful substances, which pose a threat to the environment and human health. The reduction and resource utilization of sludge has become a development demand in sludge treatment and disposal. Based on the technical bottlenecks in the practical application of direct anaerobic digestion technology, this study adopted two different thermal and thermal-alkali hydrolysis technologies to pretreat sludge. A pilot-scale experiment was conducted to investigate the experimental conditions, parameters, and effects of two hydrolysis technologies. This study showed that the optimal hydrolysis temperature was 70 °C, the hydrolysis effect and pH can reach equilibrium with the hydrolysis retention time was 4-8 h, and the optimal alkali concentration range was 0.0125-0.015 kg NaOH/kg dry-sludge. Thermal-alkali combination treatment greatly improved the performance of methane production, the addition of NaOH increased methane yield by 31.2% than that of 70 °C thermal hydrolysis. The average energy consumption is 75 kWh/m3 80% water-content sludge during the experiment. This study provides a better pretreatment strategy for exploring efficient anaerobic digestion treatment technologies suitable for southern characteristic sewage sludge.
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  • 文章类型: Journal Article
    改性淀粉可以改善其特性,以改善其在食品基质中的用途,生物塑料,和包封剂。在这项研究中,通过酸处理对四个品种的本地马铃薯淀粉进行了改性,酶处理,和乙醇沉淀,和它们的物理化学,结构,热,并对技术功能特性进行了分析。根据FT-IR分析,未观察到改性淀粉对化学基团的影响,并通过扫描电子显微镜(SEM),在酸和酶处理中观察到球形和椭圆形,颗粒尺寸在27和36μm之间。特别是,乙醇沉淀处理产生不同的形态,粒径在10.9和476.3nm之间,导致糊化温度(DSC)和更明显的微晶(XRD)显着降低。另一方面,酶处理显示较高的z电位(ζ)值,酸处理显示出较低的质量损失(TGA)。与天然淀粉相比,酸和乙醇处理会影响面团的性质。技术功能性能显示吸水指数下降,水溶性指数的增加,和不同的膨胀力行为。总之,通过酸改性马铃薯淀粉,酶,和乙醇沉淀处理改变了它们的物理化学性质,如膨胀能力,粘度,和热稳定性。这反过来又影响了它们的分子结构,改变形态和形成凝胶的能力,这扩大了他们在食品工业中的应用,以改善质地,稳定乳液,和加厚产品。此外,这些改性还通过改善淀粉基塑料材料的生物降解性和机械性能为生物塑料的发展开辟了新的机遇。
    Modifying starch allows for improvements in its properties to enable improved uses in food matrices, bioplastics, and encapsulating agents. In this research, four varieties of native potato starch were modified by acid treatment, enzymatic treatment, and ethanol precipitation, and their physicochemical, structural, thermal, and techno-functional characteristics were analyzed. According to FT-IR analysis, no influence of the modified starches on the chemical groups was observed, and by scanning electron microscopy (SEM), spherical and oval shapes were observed in the acid and enzymatic treatments, with particle sizes between 27 and 36 μm. In particular, the ethanolic precipitation treatment yielded a different morphology with a particle size between 10.9 and 476.3 nm, resulting in a significant decrease in gelatinization temperature (DSC) and more pronounced crystallites (XRD). On the other hand, the enzymatic treatment showed higher values for z-potential (ζ), and the acid treatment showed lower mass loss (TGA). Acid and ethanolic treatments affected the dough properties compared to native starches. The techno-functional properties showed a decrease in the water absorption index, an increase in the water solubility index, and varied swelling power behaviors. In conclusion, the modification of potato starches through acid, enzymatic, and ethanolic precipitation treatments alters their physicochemical properties, such as swelling capacity, viscosity, and thermal stability. This in turn affects their molecular structure, modifying morphology and the ability to form gels, which expands their applications in the food industry to improve textures, stabilize emulsions, and thicken products. Furthermore, these modifications also open new opportunities for the development of bioplastics by improving the biodegradability and mechanical properties of starch-based plastic materials.
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  • 文章类型: Journal Article
    血管化复合同种异体移植物(VCA)在移植医学中提出了独特的挑战,由于其复杂的结构和易缺血性损伤。创新的保存技术对于延长这些移植物的生存能力至关重要,从采购到移植。本研究通过整合冷冻保护剂(CPA)优化来解决这些挑战,先进的热跟踪,和离体啮齿动物模型中的逐步CPA加载策略。CPA优化侧重于各种组合,鉴定那些有效抑制冰核形成同时减轻细胞毒性的物质。使用侵入式热电偶和非侵入式FLIR成像监测热动力学,产生详细的温度曲线对于管理热缺血时间和优化冷却速率至关重要。逐步CPA负荷与常规冲洗方案的有效性表明,逐步(非)负荷显着改善了动脉阻力和体重变化的结果。总之,这项研究提出了VCA保存策略的全面改进,结合CPA优化,精确的热监测,和逐步加载技术。这些发现对完善移植方案和改善VCA移植中的移植物活力具有潜在意义。
    Vascularized composite allografts (VCAs) present unique challenges in transplant medicine, owing to their complex structure and vulnerability to ischemic injury. Innovative preservation techniques are crucial for extending the viability of these grafts, from procurement to transplantation. This study addresses these challenges by integrating cryoprotectant agent (CPA) optimization, advanced thermal tracking, and stepwise CPA loading strategies within an ex vivo rodent model. CPA optimization focused on various combinations, identifying those that effectively suppress ice nucleation while mitigating cytotoxicity. Thermal dynamics were monitored using invasive thermocouples and non-invasive FLIR imaging, yielding detailed temperature profiles crucial for managing warm ischemia time and optimizing cooling rates. The efficacy of stepwise CPA loading versus conventional flush protocols demonstrated that stepwise (un)loading significantly improved arterial resistance and weight change outcomes. In summary, this study presents comprehensive advancements in VCA preservation strategies, combining CPA optimization, precise thermal monitoring, and stepwise loading techniques. These findings hold potential implications for refining transplantation protocols and improving graft viability in VCA transplantation.
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  • 文章类型: Journal Article
    职业压力源对整体健康和牙齿健康有影响。口腔健康是一般健康的重要方面。进行当前研究以评估印度南部热电站工人的牙周炎。对52名煤矿工人进行了初步研究,并根据其中的牙周病患病率,样本量为603名受试者.数据收集是使用世卫组织1997年形式进行的。在整个研究人群中,约92(30%)热电站1名工人和83(28.1%)热电站2名工人有4-5毫米的口袋,一个(0.2%)火力发电厂,2名工人有口袋6毫米或更多的热电站工人,和23(7.8%)火力发电厂2工人有6-8毫米的附件损失。只有1个(0.3%)火力发电厂的工人有9-11毫米的附件损失。在目前的研究中,近70%的矿工有微积分,近30%的人有4-5毫米的口袋,只有0.2%的第二矿工人有6毫米或更多的口袋。
    The occupational stressors has an effect on overall health and dental health. Oral health is a vital aspect of general health. The current study was performed to assess the periodontitis among thermal power station workers in South India. Pilot study was done for 52 mine workers and based on the periodontal disease prevalence among them, the sample size was calculated as 603 subjects. The data collection was done using WHO 1997 proforma. Among the total study population, about 92 (30%) thermal power station 1 workers and 83 (28.1%) thermal power station 2 workers had pocket 4-5 mm, one (0.2%) thermal power station, 2 worker had pocket 6 mm or more thermal power station I workers, and 23 (7.8%) thermal power station 2 workers had 6 - 8 mm attachment loss. Only 1 (0.3%) thermal power station I worker had 9 - 11 mm attachment loss. In the current study, nearly 70% mine workers had calculus, nearly 30% had pocket 4-5 mm, and only 0.2% Mine II workers had pocket measuring 6 mm or more.
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  • 文章类型: Editorial
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