stainless steel

不锈钢
  • 文章类型: Journal Article
    不锈钢焊工暴露于重金属。我们评估了这些金属在全血和尿液中的浓度,以及与总染色体畸变(CA)相关的相关生化参数,染色单体型(CTA型,CTA)和染色体类型(CSA类型,CSA),在117名焊工和控制个人中。从统计学上看,总Cr的浓度较高,在焊工的全血和尿液中观察到Ni和Mn,吸烟的焊工的浓度更高。相反,在对照组中,经肌酐调整的尿重金属Cr和Mn的浓度显着升高。在整个焊工组中观察到总CA的统计频率较高,在无烟焊工中,与对照组相比。总CAs的频率与Cr浓度显著相关,全血中的Ni和Mn(分别为R=0.61,P=0.0001,R=0.33,P=0.0001和R=0.66,P=0.0001),尿中Ni和Mn的浓度(分别为R=0.27,P=0.003和R=0.28,P=0.003)以及尿中Cr的浓度,根据肌酐调整Ni和Mn(分别为R=0.22,P=0.029,R=0.26,P=0.005和R=0.20,P=0.030)。同样,CTA类型的频率与全血中Cr和Mn的浓度显着相关(R=0.31,P=0.0007和R=0.34,P=0.0002)。CSA类型的频率与Cr的浓度显着相关,全血中的Ni和Mn(分别为R=0.43,P=0.0001,R=0.38,P=0.0001和R=0.46,P=0.0001)。在所有焊工中检测到的血清肌酐和总胆红素的统计学值均较高,与相应的对照组相比,吸烟者也是如此。焊工接触重金属增加了CA的频率,并改变了重金属尿液排泄与其可能积累之间的平衡。
    Stainless steel welders are exposed to heavy filler metals. We evaluated the concentration of these metals in whole blood and urine, and the relevant biochemical parameters in relation to the total chromosomal aberrations (CAs), chromatid-type (CTA-type, CTAs) and chromosome-type (CSA-type, CSAs), in 117 welders and control individuals. Statistically higher concentrations of the total Cr, Ni and Mn were observed in whole blood and urine of welders, and the concentrations were higher in welders who smoked. On the contrary, concentrations of urinary heavy metals Cr and Mn adjusted for creatinine were significantly higher in the control groups. A statistically higher frequency of total CAs was observed in the whole group of welders, and also in the non-smoking welders, as compared to controls. The frequency of total CAs significantly correlated with the concentration of Cr, Ni and Mn in whole blood (R=0.61, P˂0.0001, R=0.33, P˂0.0001 and R=0.66, P˂0.0001, respectively), with urinary concentrations of Ni and Mn (R=0.27, P=0.003 and R=0.28, P=0.003, respectively) and with urinary concentrations of Cr, Ni and Mn adjusted for creatinine (R=0.22, P=0.029, R=0.26, P=0.005 and R=0.20, P=0.030, respectively). Likewise, the frequency of CTA-types significantly correlated with the concentration of Cr and Mn in whole blood (R=0.31, P=0.0007 and R=0.34, P=0.0002). The frequency of CSA-types significantly correlated with concentrations of Cr, Ni and Mn in whole blood (R=0.43, P˂0.0001, R=0.38, P˂0.0001 and R=0.46, P˂0.0001, respectively). The statistically higher values of serum creatinine and total bilirubin were detected in all welders, as well as in smokers when compared to the corresponding controls. The exposure to heavy metals in welders increased the frequencies of CAs and altered the balance between urinary excretion of heavy metals and their possible accumulation.
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  • 文章类型: Journal Article
    多次重复使用对由不同材料(不锈钢(SS),铝(Al),钛(Ti),和氧化锆(Zr)通过利用两种模具材料在不同的持续时间是感兴趣的牙医。使用为植入物类似物的内部螺纹创建的印模测量螺纹之间的间距。或通过立体显微镜在0时设置为x50的副本,3rd,6th,9th,和第12个间隔。观察到,随着在所有植入物类似物中以增加的时间间隔增加的重复使用,线1-2之间的距离减小。然而,在钛植入物类似物中,线之间距离的减小较低,其次是氧化锆植入物类似物,并且在铝植入物类似物中,减小最大,其次是SS植入物类似物。当评估线3-4之间的距离时,观察到与所有植入物类似物中的线1-2相比,线3-4之间的距离减小。类似地,与螺纹1-2和螺纹3-4相比,螺纹5-6之间的距离减小较小。随着在所有植入物类似物中以增加的时间间隔增加的重复使用,线1-2之间的距离减小。然而,在钛植入物类似物中,丝线之间距离的减少程度最低,其次是锆植入物类似物.
    The impact of multiple reuse on the alterations in internal threads of four different implant analogous composed of different materials (stainless steel (SS), aluminum (Al), titanium (Ti), and zirconia (Zr) by utilizing two die materials at different time durations is of interest to dentists. The spacing between the threads was measured using the impressions created for the interior threads of implant analogs, or replicas by stereomicroscope set to x50 at 0th, 3rd, 6th, 9th, and 12th interval. It was observed that there was decrease in distance between threads 1-2 as the increasing reuse at increasing time intervals in all implants analogs. However the decrease in distance between threads was low in Titanium implants analogs followed by Zircona implant analogs and the decrease was maximum in aluminum implants analogs followed by SS implant analogs. When there was evaluation of distance between threads 3-4 then it was observed that there was reduced decrease in distance between threads 3-4 as compared to threads 1-2 n all implant analogs. Similarly the reduction in distance between threads 5-6 was lesser as compared to threads 1-2 and threads 3-4. There was decrease in distance between threads 1-2 as the increasing reuse at increasing time intervals in all implants analogs. However, the reduction in distance between threads was lowest in Titanium implants analogs followed by Zircona implant analogs.
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  • 文章类型: Journal Article
    通过适当的修复来修复被切除的原发性磨牙对于恢复功能和维护治疗的持久性至关重要。本研究旨在评估和比较不锈钢(ST)冠的表面粗糙度,氧化锆(ZR)冠,玻璃纤维(FG)冠,和二硅酸锂(LD)内牙冠作为牙髓切除的初级磨牙的修复,评估其拮抗剂的表面粗糙度。对60颗下颌第一磨牙进行定性表面粗糙度评估,并根据牙冠类型分为四组(n=15/组)(ST组,组-ZR,group-FG,group-LD)。而其他六十个声音,未准备的上颌第一磨牙用于评估其相对于测试牙冠的表面粗糙度。根据每种牙冠类型和制造商的说明进行样品制备和胶结。使用两体磨损测试进行表面粗糙度。对数据进行统计学分析。所有测试的牙冠显示表面粗糙度变化增加,除了组-ZR,机械磨损后表面粗糙度变化最小,差异无统计学意义(P=0.681)。所有牙冠类型在机械磨损后都显着增加了其对手的表面粗糙度,除ST组无明显影响外(p≥0.05)。与其他组相比,氧化锆冠和二硅酸锂内冠的表面粗糙度变化最小,而SSC在拮抗剂釉质中的牙齿损失最小。
    Rehabilitation of pulpotomized primary molars with an appropriate restoration is essential for recovering function and safeguarding the durability of the treatment. This study aimed to assess and compare the surface roughness of stainless steel (ST) crowns, zirconia (ZR) crowns, fiberglass (FG) crowns, and lithium disilicate (LD) endo-crowns as a restoration for pulpotomized primary molars also, evaluating the surface roughness of their antagonists. Sixty pulpotomized primary mandibular first molars were used for qualitative surface roughness evaluation and divided into four groups (n = 15/group) according to the crown type (group-ST, group-ZR, group-FG, group-LD). While the other sixty sound, unprepared primary maxillary first molars were used for evaluation of their surface roughness against the tested crowns. Specimens\' preparation and cementation were carried out according to each crown type and manufacturer\'s instructions. The surface roughness was done using a two-body wear test. The data were statistically analyzed. All tested crowns showed an increased change in surface roughness, except group-ZR, which had the least change in surface roughness after mechanical wear with no statistically significant difference(P = 0.681). All crown types significantly increased the surface roughness of their antagonists after mechanical wear, except group-ST which showed insignificant affection (p ≥ 0.05). Zirconia crowns and lithium disilicate endo-crowns had the least change in surface roughness compared to other groups while SSCs showed the least tooth loss in the antagonist enamel.
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  • 文章类型: Journal Article
    为了便于水下激光焊接技术在核电站原位修复中的应用,本研究在304NG氮控不锈钢上进行了局部干水下激光焊接和空气激光焊接的对比实验。目的是探索其在水下环境中的微观结构演变和机械性能。结果发现,在空气中激光焊接的熔合线附近,柱状枝晶向焊缝中心逐渐演变为细胞枝晶,最终消失,导致骨架铁素体和锯齿状奥氏体结构。水下激光焊接接头表现出相似的特性,但在柱状和细胞枝晶之间具有更明显的交替。此外,细胞树突的大小显著减小,在焊缝中心观察到针状铁素体。水下激光焊接接头的硬度略高于空中激光焊接接头。与空气中的激光焊接相比,水下激光焊接接头的强度从443MPa增加到471MPa,位移从2.95毫米增加到3.45毫米,两种类型的焊接接头均表现出塑性和脆性的混合模式断裂。
    In order to facilitate the application of underwater laser welding technology in in situ repairs of nuclear power plants, this study conducted comparative experiments between local dry underwater laser welding and laser welding in air on 304NG nitrogen-controlled stainless steel. The aim was to explore its microstructural evolution and mechanical properties in underwater environments. It was found that, near the fusion line of laser welding in air, columnar dendrites gradually evolved into cellular dendrites toward the weld center, eventually disappearing, resulting in a skeletal ferrite and serrated austenite structure. The underwater laser welding joints exhibited similar characteristics yet with more pronounced alternation between columnar and cellular dendrites. Additionally, the size of cellular dendrites decreased significantly, and needle-like ferrite was observed at the weld center. The hardness of underwater laser welded joints was slightly higher than that of in-air laser welded joints. Compared to laser welding in air, the strength of underwater laser welding joints increased from 443 MPa to 471 MPa, and the displacement increased from 2.95 mm to 3.45 mm, both types of welded joints exhibited a mixed mode fracture characterized by plasticity and brittleness.
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  • 文章类型: Journal Article
    在这项研究中,我们优化了多层不锈钢316L和430叠层的扩散连接参数。扩散键合的制备工艺至关重要,因为粘合表面需要抛光和精心清洁,以确保光滑的粘合过程。我们制造了由55mm×55mm×3mm和100mm×50mm×3mm尺寸组成的12层板,并通过评估不同粘结条件下粘结区的拉伸强度来研究粘结响应,粘接温度范围为1000至1048°C,粘结时间从15到60分钟不等,压力范围从10到25.3MPa,在真空环境下。SS430的压缩蠕变速率明显高于SS316L。扩散焊接材料的可压缩性不影响扩散结合强度。多轴拉伸强度测试证实了在各个轴上的强粘合接头强度。平行测试的单片和扩散结合(DB)试样的拉伸强度基本相同。优化的扩散结合参数(条件G2C:1048°C/25.3MPa/15分钟)非常适合在紧凑型热交换器中生产SS316L不锈钢芯,提供卓越的粘接质量和降低成本。这些发现对紧凑型热交换器中不锈钢芯的生产具有实际意义,证明了我们研究的相关性和适用性。
    In this study, we optimized the parameters of diffusion bonding on multi-layered stainless steel 316L and 430 stacks. The preparation process for diffusion bonding is crucial, as the bonding surfaces need to be polished and meticulously cleaned to ensure a smooth bonding process. We fabricated twelve-layer plates consisting of 55 mm × 55 mm × 3 mm and 100 mm × 50 mm × 3 mm dimensions, and the bonding response was investigated by evaluating the tensile strength of the bonding zone under varying bonding conditions, with a bonding temperature ranging from 1000 to 1048 °C, a bond time ranging from 15 to 60 min, pressure ranging from 10 to 25.3 MPa, and under a vacuum environment. SS430 exhibits a significantly higher compression creep rate than SS316L. The compressibility of diffusion welding materials does not impact the diffusion bonding strength. Multi-axial tensile strength tests confirmed strong bonding joint strength in various axes. The tensile strengths of monolithic and Diffusion bonding (DB) specimens tested in parallel are essentially identical. The optimized diffusion bonding parameters (Condition G2C: 1048 °C/25.3 MPa/15 min) are ideal for producing SS316L stainless steel cores in compact heat exchangers, offering a superior bonding quality and reduced costs. These findings have practical implications for the production of stainless steel cores in compact heat exchangers, demonstrating the relevance and applicability of our research.
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  • 文章类型: Journal Article
    OBJECTIVE: To identify the characteristics of patients and femur fractures treated with a stainless steel intramedullary nail (ESIN) in children under 15 years of age. Know the results of using the ESIN of related steel in the service.
    METHODS: Retrospective study with review of hospital records and organization of data in spreadsheets.
    RESULTS: 24 cases were identified, 17 male cases and 7 female cases. A minimum age of 4 years and a maximum of 11 years were observed (average of 7 years). The 3 most common trauma mechanisms were being run over (n:8, 33%) and falling from a height (n:8, 3%). The most common location of the fractures was in the mid-diaphyseal region (n: 20, 88%), only one case presented a bilateral femur fracture. The most common associated trauma was traumatic brain injury. The observation period observed several months between 2 and 5. With regard to complications, 3 cases were observed (12.5%) being bursitis, vicious construction and loss of reduction.
    CONCLUSIONS: Steel HIF shows similar good results. As the study includes the retrospective profile, the absence of a group and the small sample size. Level of Evidence IV, Case series.
    OBJECTIVE: Identificar as características dos pacientes e das fraturas de fêmur tratadas com haste intramedular flexível (HIF) de aço inoxidável em menores de 15 anos. A partir disso, conhecer os resultados relacionados ao uso da HIF de aço inoxidável no serviço. Métodos: Estudo retrospectivo, com revisão de prontuários hospitalares e organização dos dados em planilhas.
    RESULTS: Identificados 24 casos, sendo 17 do gênero masculino e sete do gênero feminino. Foram observadas idade mínima de 4 anos e máxima de 11 anos (média de 7 anos). Os mecanismos de trauma mais comuns foram atropelamento (n: 8, 33%) e queda de altura (n: 8, 33%). A localização mais comum das fraturas foi na região médio diafisária (n: 20, 88%), apenas um caso apresentou fratura de fêmur bilateral. O trauma associado mais comum foi traumatismo crânio-encefálico. O período de consolidação observado variou entre 2 e 5 meses. No que se refere a complicações, foram observados três casos (12,5%), sendo estes: bursite, consolidação viciosa e perda de redução. Conclusão: A HIF de aço apresenta bons resultados, semelhantes aos das hastes de titânio. As limitações do estudo incluem o perfil retrospectivo, a ausência de grupo controle e o número pequeno da amostra. Nível de evidência IV, Série de casos.
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  • 文章类型: Journal Article
    放射治疗(RT)是最广泛使用和最有效的癌症治疗方法之一。随着器官重建需求的增加和材料技术的进步,越来越多的癌症患者使用金属植入物。这些植入物可以影响RT剂量和临床结果,值得肿瘤学家仔细考虑。本综述讨论了不同类型的金属植入物影响RT过程各个阶段的机制,在治疗期间检查减轻这些影响的方法,并讨论了金属植入物对RT结果的临床意义。总之,当RT场内存在金属植入物时,肿瘤学家应仔细评估其对治疗的影响.
    Radiotherapy (RT) is one of the most widely used and effective cancer treatments. With the increasing need for organ reconstruction and advancements in material technology, an increasing number of patients with cancer have metallic implants. These implants can affect RT dosage and clinical outcomes, warranting careful consideration by oncologists. The present review discussed the mechanisms by which different types of metallic implants impact various stages of the RT process, examined methods to mitigate these effects during treatment, and discussed the clinical implications of metallic implants on RT outcomes. In summary, when metallic implants are present within the RT field, oncologists should carefully assess their impact on the treatment.
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  • 文章类型: Journal Article
    在现代医学中越来越多地使用外源性材料作为留置医疗器械,为病原体进入人体提供了新的途径,在某些情况下,威胁生命的感染。此类材料与细菌或真菌的生物污染是手术期间的主要问题。因为这通常与生物膜形成有关并且难以治疗,顽固性感染。因此,激烈的研究工作已经开发了几种策略来保护医疗设备表面免受病原微生物的定植。这里,我们使用多巴胺作为偶联剂来涂覆四种不同的医学材料(塑料聚醚醚酮(PEEK),不锈钢,钛和硅胶导管)与细菌素,肠霉素EJ97短和硫肽微球菌P1。使用水接触角测量和X射线光电子能谱来验证材料的有效涂层。通过针对生物膜的抗微生物试验(BOAT)和电子扫描显微镜研究了在这些材料上涂覆的细菌素对万古霉素抗性屎肠球菌(VRE)菌株生物膜形成的影响。在培养的人细胞上测试了细菌素修饰的生物材料的体外生物相容性。结果表明,实现了细菌素与植入物表面的结合,两种细菌素的组合可以抑制屎肠球菌在所有四种材料上的生物膜形成。修饰的植入物对测试的人细胞没有细胞毒性。因此,用两种细菌素进行表面改性可以提供一种新颖有效的方法来防止在多种植入材料上形成生物膜。
    The ever-increasing use of exogenous materials as indwelling medical devices in modern medicine offers to pathogens new ways to gain access to human body and begin, in some cases, life threatening infections. Biofouling of such materials with bacteria or fungi is a major concern during surgeries, since this is often associated with biofilm formation and difficult to treat, recalcitrant infections. Intense research efforts have therefore developed several strategies to shield the medical devices\' surface from colonization by pathogenic microorganisms. Here, we used dopamine as a coupling agent to coat four different materials of medical interest (plastic polyetheretherketone (PEEK), stainless steel, titanium and silicone catheter) with the bacteriocins, enterocin EJ97-short and the thiopeptide micrococcin P1. Water contact angle measurements and x-ray photoelectron spectroscopy were used to verify the effective coating of the materials. The effect of bacteriocins coated on these materials on the biofilm formation by a vancomycin resistant Enterococcus faecium (VRE) strain was studied by biofilm-oriented antimicrobial test (BOAT) and electron scanning microscopy. The in vitro biocompatibility of bacteriocin-modified biomaterials was tested on cultured human cells. The results demonstrated that the binding of the bacteriocins to the implant surfaces is achieved, and the two bacteriocins in combination could inhibit biofilm formation by E. faecium on all four materials. The modified implant showed no cytotoxicity to the human cells tested. Therefore, surface modification with the two bacteriocins may offer a novel and effective way to prevent biofilm formation on a wide range of implant materials.
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  • 文章类型: Journal Article
    含铜材料作为自消毒表面引起了人们的注意,适用于帮助医疗机构减少医疗保健相关感染。然而,反复暴露于生物清洁方案中经常使用的消毒剂对其抗菌活性的影响仍未得到充分表征。本研究旨在评估铜(阳性对照)的抗菌效率,黄铜合金(AB+®)和不锈钢(阴性对照)在反复暴露于季铵化合物和/或过乙酸/过氧化氢的混合物后,常用于医疗机构。选择一组6种抗生素抗性菌株(临床分离株)用于该评估。在短时间(5分钟)暴露后,铜和黄铜材料比不锈钢保留了明显更好的抗菌效率,无论考虑的细菌菌株或消毒剂处理。此外,两种消毒剂产品的后处理,含铜材料仍达到与处理前相似的抗菌效率水平。抗生素耐药机制,如外排泵过度表达并没有削弱含铜材料的抗菌效率,与铜稳态/抗性相关的一个或几个基因的存在也没有。鉴于这些结果,由铜和黄铜制成的表面仍然是对抗可能导致医疗保健相关感染的抗生素抗性菌株传播的有趣工具。
    Copper-containing materials are attracting attention as self-disinfecting surfaces, suitable for helping healthcare settings in reducing healthcare-associated infections. However, the impact of repeated exposure to disinfectants frequently used in biocleaning protocols on their antibacterial activity remains insufficiently characterized. This study aimed at evaluating the antibacterial efficiency of copper (positive control), a brass alloy (AB+®) and stainless steel (negative control) after repeated exposure to a quaternary ammonium compound and/or a mix of peracetic acid/hydrogen peroxide routinely used in healthcare settings. A panel of six antibiotic-resistant strains (clinical isolates) was selected for this assessment. After a short (5 min) exposure time, the copper and brass materials retained significantly better antibacterial efficiencies than stainless steel, regardless of the bacterial strain or disinfectant treatment considered. Moreover, post treatment with both disinfectant products, copper-containing materials still reached similar levels of antibacterial efficiency to those obtained before treatment. Antibiotic resistance mechanisms such as efflux pump overexpression did not impair the antibacterial efficiency of copper-containing materials, nor did the presence of one or several genes related to copper homeostasis/resistance. In light of these results, surfaces made out of copper and brass remain interesting tools in the fight against the dissemination of antibiotic-resistant strains that might cause healthcare-associated infections.
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  • 文章类型: Journal Article
    在700至1000°C的温度范围内研究了铁基316L不锈钢的氧化行为。通过选择性激光熔化生产板状的试样。制作后,将样品喷砂,然后在空气中退火不同的时间(0.5、2、8、32小时)。在温度和时间的影响下,不锈钢倾向于形成氧化层。扫描电子显微镜,能量色散分析,和X射线衍射用于分析该层的组成。值得注意的是,主要由(Fe-Cr)组成的薄氧化物层由于温度的影响而形成在表面上。此外,随着温度的升高(高达1000°C),主要合金元素的氧化物,具体地,Mn2(Fe-Cr)O4与Fe-Cr氧化物一起出现。此外,对样品进行转换X射线(CXMS)和转换电子(CEMS)穆斯堡尔谱。基于表面金属氧化物的厚度,CXMS显示出具有降低的穆斯堡尔效应的单重态。CEMS显示在表面层(0.3μm)中存在Fe3+。此外,在较高的温度水平下发生了一个有趣的现象,这是由于表面金属氧化物层厚度不均匀以及穆斯堡尔辐射朝向电子探测器的切线方向。
    The oxidation behaviour of iron-based 316L stainless steel was investigated in the temperature range of 700 to 1000 °C. The test specimens in the shape of plates were produced by selective laser melting. After fabrication, the samples were sandblasted and then annealed in air for different periods of time (0.5, 2, 8, 32 h). Under the influence of temperature and time, stainless steels tend to form an oxide layer. Scanning electron microscopy, energy dispersive analysis, and X-ray diffraction were employed to analyse the composition of this layer. Notably, a thin oxide layer primarily composed of (Fe-Cr) formed on the surface due to temperature effects. In addition, with increasing temperature (up to 1000 °C), the oxide of the main alloying elements, specifically Mn2(Fe-Cr)O4, appeared alongside the Fe-Cr oxide. Furthermore, the samples were subjected to conversion X-ray (CXMS) and conversion electron (CEMS) Mössbauer spectroscopy. CXMS revealed a singlet with a decreasing Mössbauer effect based on the surface metal oxide thickness. CEMS revealed the presence of Fe3+ in the surface layer (0.3 µm). Moreover, an interesting phenomenon occurred at higher temperature levels due to the inhomogeneously thick surface metal oxide layer and the tangential direction of the Mössbauer radiation towards the electron detector.
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