smart textile

智能纺织品
  • 文章类型: Journal Article
    可充电纤维Zn离子电池(FZIB)中机械电化学稳定性不足的挑战已成为其广泛应用的关键挑战。传统的刚性Zn线在受到外部机械应力时难以保持稳定的电化学界面。为了解决这个问题,已经开发了一种湿法纺丝技术来制造Zn粉末基纤维阳极,同时引入碳纳米管(CNTs)以增强Zn粉末的可纺性分散。已经进行了随后的退火处理以重新设计具有CNT辅助的表面张力调节的Zn结晶织构,以重定向(002)结晶织构形成。由此得到的退火Zn@CNT纤维在长期弯曲和电化学过程后表现出良好的机械电化学稳定性。制造的FZIB展示了非凡的耐用性,在1mAcm-2和1mAhcm-2下超过800h,即使在180度扭曲角度下进行100次扭曲循环后,边际电压滞后也增加了21.7mV。组装的FZIB全电池即使经过一系列弯曲的长周期,也显示出88.6%的容量保持率,打结,和矫直变形。它还被编织成200cm2大小的纺织品,以证明其集成到智能纺织品中的能力。
    The challenge of inadequate mechano-electrochemical stability in rechargeable fibrous Zn-ion batteries (FZIBs) has emerged as a critical challenge for their broad applications. Traditional rigid Zn wires struggle to maintain a stable electrochemical interface when subjected to external mechanical stress. To address this issue, a wet-spinning technique has been developed to fabricate Zn powder based fibrous anode, while carbon nanotubes (CNTs) introduced to enhance the spinnability of Zn powder dispersion. The followed annealing treatment has been conducted to reengineer the Zn crystalline texture with CNTs assisted surface tension regulation to redirect (002) crystallographic textural formation. The thus-derived annealed Zn@CNTs fiber demonstrates great mechano-electrochemical stability after a long-term bending and electrochemical process. The fabricated FZIB demonstrates a remarkable durability, surpassing 800 h at 1 mA cm-2 and 1 mAh cm-2, with a marginal voltage hysteresis increase of 21.7 mV even after 100 twisting cycles under 180 degree twisting angle. The assembled FZIB full cell displays an 88.6% capacity retention even after a long cycle of a series of bending, knotting, and straightening deformation. It has been also woven into a 200 cm2 size textile to demonstrate its capability to integrate into smart textiles.
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  • 文章类型: Journal Article
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  • 文章类型: Journal Article
    背景:功能性电刺激(FES)是一种康复技术,可以改善患有运动控制障碍的患者的功能。这项研究提出了一种用于FES应用的智能套筒的原始设计和原型设计方法。该文章解释了如何将碳基干电极集成到纺织结构中,并确保电极和刺激器之间的电连接,以有效地输送FES。它还描述了材料和逐步制造过程。
    结果:通过在刺绣的导电基质上进行热压缩成型工艺,将基于碳的干电极集成到纺织品基材中。该基质由纺织镀银导电纱线组成,并与刺激器相连。除了确保电气连接,基质改善了纺织品基底和电极之间的固定。刺激强度,将感知的舒适度和由智能FES套管产生的肌肉扭矩与水凝胶电极进行比较。结果表明,使用智能FES套管具有更好的平均舒适度和更高的平均刺激强度,而产生的肌肉扭矩没有显着差异。
    结论:将所提出的干电极集成到纺织品中是可行的解决方案。可穿戴FES系统不会对电极性能产生负面影响,并倾向于改进它。此外,所提出的原型方法适用于整件服装,以便针对所有肌肉。此外,该方法对于工业生产和商业化是可行的,因为所使用的所有材料和方法已经在市场上可用。
    BACKGROUND: Functional electrical stimulation (FES) is a rehabilitation technique that enables functional improvements in patients with motor control impairments. This study presents an original design and prototyping method for a smart sleeve for FES applications. The article explains how to integrate a carbon-based dry electrode into a textile structure and ensure an electrical connection between the electrodes and the stimulator for effective delivery of the FES. It also describes the materials and the step-by-step manufacturing processes.
    RESULTS: The carbon-based dry electrode is integrated into the textile substrate by a thermal compression molding process on an embroidered conductive matrix. This matrix is composed of textile silver-plated conductive yarns and is linked to the stimulator. Besides ensuring the electrical connection, the matrix improves the fixation between the textile substrate and the electrode. The stimulation intensity, the perceived comfort and the muscle torque generated by the smart FES sleeve were compared to hydrogel electrodes. The results show a better average comfort and a higher average stimulation intensity with the smart FES sleeve, while there were no significant differences for the muscle torque generated.
    CONCLUSIONS: The integration of the proposed dry electrodes into a textile is a viable solution. The wearable FES system does not negatively impact the electrodes\' performance, and tends to improve it. Additionally, the proposed prototyping method is applicable to an entire garment in order to target all muscles. Moreover, the process is feasible for industrial production and commercialization since all materials and processes used are already available on the market.
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  • 文章类型: Journal Article
    脑震荡,在美国普遍存在的公共卫生问题,通常由轻度创伤性脑损伤(mTBI)引起,尤其是在像美式足球这样的运动中。用于测量与运动和娱乐活动中的脑震荡相关的头部撞击的基于智能纺织品的传感器的探索有限。在本文中,我们描述了智能纺织品冲击传感器(STIS)的开发和构建,并在大冲击下验证STIS功能。该STIS可以插入头盔缓冲中以确定头部冲击力。设计的2×2STIS矩阵由许多材料分层结构组成,具有由半导体聚合物复合材料(SPC)制成的传感表面。在设计迭代中修改了SPC尺寸,以增加传感器范围,响应性、响应性和线性。这适用于高影响情况。带有偏置电路的微控制器板用于连接STIS并读取传感器的响应。构造了摆锤测试装置,以评估各种带有冲击力的STIS。使用相机和跟踪器软件来监视摆锤摆动。通过测量摆锤的速度和加速度来计算冲击力。各种STIS的性能是根据冲击力引起的电压来测量的,力从180到722N不等。通过数据分析,确定了线性范围内的阈值冲击力。通过线性回归分析,对传感器的灵敏度进行了评估。此外,建立了一个简化模型,以根据测得的电压测量2×2STIS区域的力分布。结果表明,改善SPC厚度可以获得改善的传感器行为。然而,对于超过阈值的影响,建议的传感器没有反映实际的冲击力,但是它提供了有关传感器上的影响分布的有用信息,而与准确的预期线性响应无关。结果表明,拟议的STIS在一定范围内表现令人满意,并有可能用于开发具有大型STIS矩阵的电子头盔,该矩阵可以覆盖电子头盔内的整个头部。这项工作也鼓励未来的研究,特别是在传感器的结构上,可以承受冲击,这反过来可以提高整体范围和性能,并将准确地测量在引起脑震荡的冲击范围内的冲击。
    Concussions, a prevalent public health concern in the United States, often result from mild traumatic brain injuries (mTBI), notably in sports such as American football. There is limited exploration of smart-textile-based sensors for measuring the head impacts associated with concussions in sports and recreational activities. In this paper, we describe the development and construction of a smart textile impact sensor (STIS) and validate STIS functionality under high magnitude impacts. This STIS can be inserted into helmet cushioning to determine head impact force. The designed 2 × 2 STIS matrix is composed of a number of material layered structures, with a sensing surface made of semiconducting polymer composite (SPC). The SPC dimension was modified in the design iteration to increase sensor range, responsiveness, and linearity. This was to be applicable in high impact situations. A microcontroller board with a biasing circuit was used to interface the STIS and read the sensor\'s response. A pendulum test setup was constructed to evaluate various STISs with impact forces. A camera and Tracker software were used to monitor the pendulum swing. The impact forces were calculated by measuring the pendulum bob\'s velocity and acceleration. The performance of the various STISs was measured in terms of voltage due to impact force, with forces varying from 180 to 722 N. Through data analysis, the threshold impact forces in the linear range were determined. Through an analysis of linear regression, the sensors\' sensitivity was assessed. Also, a simplified model was developed to measure the force distribution in the 2 × 2 STIS areas from the measured voltages. The results showed that improving the SPC thickness could obtain improved sensor behavior. However, for impacts that exceeded the threshold, the suggested sensor did not respond by reflecting the actual impact forces, but it gave helpful information about the impact distribution on the sensor regardless of the accurate expected linear response. Results showed that the proposed STIS performs satisfactorily within a range and has the potential to be used in the development of an e-helmet with a large STIS matrix that could cover the whole head within the e-helmet. This work also encourages future research, especially on the structure of the sensor that could withstand impacts which in turn could improve the overall range and performance and would accurately measure the impact in concussion-causing impact ranges.
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  • 文章类型: Journal Article
    不再使用的蚕丝纺织品产生的各种废物越来越多,造成了相当大的浪费和污染。这个问题在大量使用丝绸的国家引起了广泛的关注。因此,提高再生丝素蛋白(RSF)的力学性能和丰富蚕丝的功能是扩大蚕丝产品综合利用的重要方向。在本文中,报道了通过湿法纺丝制备不同Al2O3NPs含量的RSF/Al2O3纳米粒子(NPs)杂化纤维及其新性能。发现RSF/Al2O3NPs混杂纤维是一种具有隔热和抗紫外线的多功能纤维材料。自然光测试表明,RSF/Al2O3NPs混杂纤维的温升速率比RSF纤维慢,平均温度在15分钟内从29.1°C上升到约35.4°C,而RSF纤维可以上升到约40.1°C。紫外吸收测试表明,该杂化纤维具有抗紫外辐射性能。此外,Al2O3NP的添加可以改善混合纤维的机械性能。这是因为Al2O3NP的混合以剂量依赖的方式促进了RSF反应混合物中β-折叠的自组装,这表现为RSF/Al2O3NPs混杂纤维具有更多的β-折叠,结晶度和较小的晶体尺寸。此外,RSF/Al2O3NPs混杂纤维在微碱性汗液环境中具有良好的生物相容性和耐久性。上述性能使RSF/Al2O3NPs混合纤维有希望候选应用于隔热和抗紫外线织物以及军用服装。
    The various wastes generated by silkworm silk textiles that are no longer in use are increasing, which is causing considerable waste and contamination. This issue has attracted widespread attention in countries that use a lot of silk. Therefore, enhancing the mechanical properties of regenerated silk fibroin (RSF) and enriching the function of silk are important directions to expand the comprehensive utilization of silk products. In this paper, the preparation of RSF/Al2O3 nanoparticles (NPs) hybrid fiber with different Al2O3 NPs contents by wet spinning and its novel performance are reported. It was found that the RSF/Al2O3 NPs hybrid fiber was a multifunctional fiber material with thermal insulation and UV resistance. Natural light tests showed that the temperature rise rate of RSF/Al2O3 NPs hybrid fibers was slower than that of RSF fibers, and the average temperature rose from 29.1 °C to about 35.4 °C in 15 min, while RSF fibers could rise to about 40.1 °C. UV absorption tests showed that the hybrid fiber was resistant to UV radiation. Furthermore, the addition of Al2O3 NPs may improve the mechanical properties of the hybrid fibers. This was because the blending of Al2O3 NPs promoted the self-assembly of β-sheets in the RSF reaction mixture in a dose-dependent manner, which was manifested as the RSF/Al2O3 NPs hybrid fibers had more β-sheets, crystallinity, and a smaller crystal size. In addition, RSF/Al2O3 NPs hybrid fibers had good biocompatibility and durability in micro-alkaline sweat environments. The above performance makes the RSF/Al2O3 NPs hybrid fibers promising candidates for application in heat-insulating and UV-resistant fabrics as well as military clothing.
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  • 文章类型: Journal Article
    这项研究展示了一种新颖的方法,可通过混合溶剂染色在再生织物上使用聚集诱导发射(AIE)染料来开发基于纺织品的吸附传感器。使用H2O和有机溶剂的共溶剂混合物,使用混合溶剂染色方法将AIE染料掺入织物中。这种方法赋予织物独特的荧光特性,基于AIE染料分子在织物上是处于分离状态还是聚集状态来改变荧光强度或波长。染色过程中对有机溶剂中H2O含量的精确控制对于影响荧光强度和传感特性至关重要。这些染色织物表现出反应性热变色和汽化变色性能,与荧光强度的变化对应的温度和暴露于挥发性有机溶剂(VOC)的变化。其优越的特点,包括重复的荧光转换特性和耐光漂白,增强其在各种应用中的实用性。因此,用AIE染料染色的智能织物不仅在服装和时装设计中找到应用,而且在各个领域都表现出多功能性,延伸到感测温度,湿度,湿度和危险化学品。
    This study demonstrates a novel methodology for developing a textile-based adsorption sensor via mixed solvent dyeing with aggregation-induced emission (AIE) dyes on recycled fabrics. AIE dyes were incorporated into the fabrics using a mixed solvent dyeing method with a co-solvent mixture of H2O and organic solvents. This method imparted unique fluorescence properties to fabrics, altering fluorescence intensity or wavelength based on whether the AIE dye molecules were in an isolated or aggregated state on the fabrics. The precise control of the H2O fraction to organic solvent during dyeing was crucial for influencing fluorescence intensity and sensing characteristics. These dyed fabrics exhibited reactive thermochromic and vaporchromic properties, with changes in fluorescence intensity corresponding to variations in temperature and exposure to volatile organic solvents (VOCs). Their superior characteristics, including a repetitive fluorescence switching property and resistance to photo-bleaching, enhance their practicality across various applications. Consequently, the smart fabrics dyed with AIE dye not only find applications in clothing and fashion design but demonstrate versatility in various fields, extending to sensing temperature, humidity, and hazardous chemicals.
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  • 文章类型: Journal Article
    基于纤维的人造肌肉有望用于能够感知的智能纺织品,互动,适应环境刺激。然而,由于变形有限,目前人工肌肉纺织品在可穿戴和工程领域的应用在很大程度上仍然受到限制,限制性刺激,和不舒服。这里,通过掺入很小的部分(<1wt。%)的Ti3C2TxMXene/纤维素纳米纤维(CNF)复合材料制成自合股和加捻羊毛纱线。当受到水分和光热刺激时,它们可以提升和降低超过自身重量3400倍的负荷。此外,纱线肌肉同旋或异旋盘绕以产生弹簧状肌肉,在光热刺激下产生超过550%的伸长或83%的收缩。致动机构,涉及光热/水分-机械能转换,通过实验和有限元模拟的结合来阐明。具体来说,MXene/CNF复合材料可用作光热和吸湿剂,以加速近红外(NIR)光下的水分蒸发和环境空气中的水分吸收。由于其低成本,易于制造,大的可缩放尺寸,强大的力量加上双重响应能力,这些软致动器对智能纺织品和自适应纺织品等设备很有吸引力,软机器人,和可穿戴信息加密。
    Fiber-based artificial muscles are promising for smart textiles capable of sensing, interacting, and adapting to environmental stimuli. However, the application of current artificial muscle-based textiles in wearable and engineering fields has largely remained a constraint due to the limited deformation, restrictive stimulation, and uncomfortable. Here, dual-responsive yarn muscles with high contractile actuation force are fabricated by incorporating a very small fraction (<1 wt.%) of Ti3C2Tx MXene/cellulose nanofibers (CNF) composites into self-plied and twisted wool yarns. They can lift and lower a load exceeding 3400 times their own weight when stimulated by moisture and photothermal. Furthermore, the yarn muscles are coiled homochirally or heterochirally to produce spring-like muscles, which generated over 550% elongation or 83% contraction under the photothermal stimulation. The actuation mechanism, involving photothermal/moisture-mechanical energy conversion, is clarified by a combination of experiments and finite element simulations. Specifically, MXene/CNF composites serve as both photothermal and hygroscopic agents to accelerate water evaporation under near-infrared (NIR) light and moisture absorption from ambient air. Due to their low-cost facile fabrication, large scalable dimensions, and robust strength coupled with dual responsiveness, these soft actuators are attractive for intelligent textiles and devices such as self-adaptive textiles, soft robotics, and wearable information encryption.
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  • 文章类型: Journal Article
    新型冠状病毒病(COVID-19)在世界各地引起了极大的混乱,影响人们的生活,并产生大量的死亡。便携式和可穿戴设备的开发在诸如定点医疗应用和环境监测之类的多个领域中非常重要。具有收集各种类型的生理记录的能力的可穿戴设备正逐渐并入人们的日常生活中。生理指标是必不可少的健康指标,其监测可以有效地早期发现疾病。这也将有助于减少额外严重的健康问题的数量,在避免疾病方面,降低公共部门的整体医疗成本。如今,防护服是纺织品的主要组成部分,被归类为技术或工业纺织品。防护服旨在保护穿着者免受可能导致伤害或死亡的恶劣环境影响。考虑到由于病毒攻击而造成的预期灾难,还认真对待为普通人群提供保护。这篇评论重点介绍了可穿戴式医疗保健设备和医疗纺织品中使用的材料的性能。
    The novel coronavirus disease (COVID-19) has generated great confusion around the world, affecting people\'s lives and producing a large number of deaths. The development of portable and wearable devices is of great importance in several fields such as point-of-care medical applications and environmental monitoring. Wearable devices with an ability to collect various types of physiological records are progressively becoming incorporated into everyday life of people. Physiological indicators are essential health indicators and their monitoring could efficiently enable early discovery of disease. This would also help decrease the number of extra severe health problems, in disease avoidance, and lower the overall public sector health cost. Protective clothing is nowadays a main part of textiles classified as technical or industrial textiles. Protective clothing aims to protect its wearer from the harsh environmental impacts that may result in injury or death. Providing protection for the common population has also been taken seriously considering the anticipated disaster due to virus attacks. This review highlights the properties of the materials that are used in wearable health care device and medical textiles.
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  • 文章类型: Journal Article
    光纤太阳能电池作为有前景的可穿戴电源近年来受到越来越多的关注,尽管在其功率转换效率(PCE)和实现多色外观方面的进一步突破仍然是迫切的需求,特别是在现实世界的应用中。这里,设计了一种纤维染料敏化太阳能电池(FDSSC),该电池在最外面的封装管上集成了由氧化铝/聚氨酯膜组成的光扩散层,并且在内部对电极上集成了由磷光体/TiO2/聚(偏二氟乙烯-共-六氟丙烯)膜制成的光转换层。入射光扩散到更多的纤维电极表面,然后在对电极上转换并反射到相邻的光电阳极,因此,FDSSC有效地利用光纤形状显着增强的光捕获,产生13.11%的创纪录的PCE。这些高效的FDSC还实现了颜色可调的外观,提高其可设计性和与纺织品的兼容性。它们进一步与纤维电池集成作为动力系统,为可穿戴设备和新兴智能纺织品提供电源解决方案。
    Fiber solar cells as promising wearable power supplies have attracted increasing attentions recently, while further breakthrough on their power conversion efficiency (PCE) and realization of multicolored appearances remain urgent needs particularly in real-world applications. Here, a fiber-dye-sensitized solar cell (FDSSC) integrated with a light diffusion layer composed of alumina/polyurethane film on the outmost encapsulating tube and a light conversion layer made from phosphors/TiO2/poly(vinylidene fluoride-co-hexafluoropropylene) film on the inner counter electrode is designed. The incident light is diffused to more surfaces of fiber electrodes, then converted on counter electrode and reflected to neighboring photoanode, so the FDSSC efficiently takes advantage of the fiber shape for remarkably enhanced light harvesting, producing a record PCE of 13.11%. These efficient FDSSCs also realize color-tunable appearances, improving their designability and compatibility with textiles. They are further integrated with fiber batteries as power systems, providing a power solution for wearables and emerging smart textiles.
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  • 文章类型: Journal Article
    而可穿戴系统本质上需要长期佩戴时的热舒适性和医疗保健管理,同时实现它们仍然是挑战。在这里,开发了一种用于个人医疗保健和热管理的高度舒适和透气的智能纺织品,通过组装刺激响应型芯鞘双网络,使银纳米线(AgNWs)芯互锁MXene诱导的石墨烯鞘。根据“类似溶解类似”理论,提出了具有丰富基团的小MXene纳米片作为石墨烯的新型“分散剂”。同时充当AgNW和石墨烯网络之间的“交联剂”,通过填充它们之间的空隙。由MXene“交联”诱导的芯鞘异质互锁导电纤维对各种机械/电/光刺激表现出可靠的响应,即使在大的机械变形(100%)。芯护套导电纤维智能纺织品可无缝适应人体运动,并将这些机械变形转换为字符信号,以快速响应(440毫秒)进行准确的医疗监测。此外,具有出色焦耳加热和光热效应的智能纺织品在刺激响应过程中表现出即时的热能收集/存储,与相变和热变色层集成时,可以开发为自供电热管理和动态伪装。具有芯鞘异质互锁结构的智能纤维/纺织品在个性化医疗保健和热管理方面具有广阔的前景。
    Whereas thermal comfort and healthcare management during long-term wear are essentially required for wearable system, simultaneously achieving them remains challenge. Herein, a highly comfortable and breathable smart textile for personal healthcare and thermal management is developed, via assembling stimuli-responsive core-sheath dual network that silver nanowires(AgNWs) core interlocked graphene sheath induced by MXene. Small MXene nanosheets with abundant groups is proposed as a novel \"dispersant\" to graphene according to \"like dissolves like\" theory, while simultaneously acting as \"cross-linker\" between AgNWs and graphene networks by filling the voids between them. The core-sheath heterogeneous interlocked conductive fiber induced by MXene \"cross-linking\" exhibits a reliable response to various mechanical/electrical/light stimuli, even under large mechanical deformations(100%). The core-sheath conductive fiber-enabled smart textile can adapt to movements of human body seamlessly, and convert these mechanical deformations into character signals for accurate healthcare monitoring with rapid response(440 ms). Moreover, smart textile with excellent Joule heating and photothermal effect exhibits instant thermal energy harvesting/storage during the stimuli-response process, which can be developed as self-powered thermal management and dynamic camouflage when integrated with phase change and thermochromic layer. The smart fibers/textiles with core-sheath heterogeneous interlocked structures hold great promise in personalized healthcare and thermal management.
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