removal effect

  • 文章类型: Journal Article
    为了减少砂石资源的消耗,利用黄土可以降低运输成本,实现黄土资源丰富地区海绵的原位施工。但黄土的湿陷性和低渗透性使其无法直接用作生物滞留细胞的填料。在这项研究中,硫铝酸盐水泥(SAC)掺有少量玄武岩纤维,综合评价了SAC改性黄土作为生物滞留细胞填料的理化性质和养分去除效果。结果表明,当SAC用量为15%,玄武岩纤维添加量为0%(S15B0)和0.6%(S15B6),固化时间为14天,可以表现出稳定性和适当的渗透性,能初步满足生物滞留细胞的要求。SAC使S15B0和S15B6对氨氮(NH4+-N)和磷酸盐的最大吸附量比沙子高10.96%-31.51%和45.92%-76.72%,分别。SAC改性黄土中的水化产物可以填充黄土颗粒的内部孔隙,并提供结构支撑,并最终减少积聚的毛孔,介孔孔径(20%)和表面均匀性。S15B0和S15B6对NH4+-N和COD均有较好的去除效果。TP去除效率稳定在95.43%~99.95%。前干燥天数和淹没区都对生物滞留细胞中的氮去除有影响,其中较长的前期干燥天数不利于氮的去除,和一个淹没区的安装提高了氮的去除。玄武岩纤维可以增强生物滞留细胞中硝酸盐氮向亚硝酸盐氮的转化过程。因此,SAC的改性可以为黄土作为生物滞留细胞填料的原位利用提供一定的思路。
    In order to reduce the consumption of sand and gravel resources, the use of loess can reduce transportation costs and realize the in-situ construction of spongy in areas with rich loess resources. But the collapsibility and low permeability of loess make it unable to be directly used as the filler of bioretention cells. In this study, sulfoaluminate cement (SAC) mixed with a small amount of basalt fiber was considered to be used for loess modification, and the physicochemical properties and nutrient removal effect of SAC-modified loess as filler in bioretention cells were comprehensively evaluated. The results showed that when the SAC dosage was 15% and the basalt fiber addition was 0% (S15B0) and 0.6% (S15B6) and the curing time was 14 days, the stability and appropriate permeability can be exhibited, which can preliminarily satisfy the requirements of bioretention cell. SAC made the maximum adsorption capacity of S15B0 and S15B6 for ammonia nitrogen (NH4+-N) and phosphate higher than that of sand by 10.96%-31.51% and 45.92%-76.72%, respectively. The hydration products in SAC modified loess can fill the internal pores of loess particles and provide structural support, and ultimately reduce the accumulated pores, mesoporous pore size (20%) and surface homogeneity. Both S15B0 and S15B6 showed good removal effects of NH4+-N and COD. The TP removal efficiency was stable at 95.43%∼99.95%. Both the antecedent drying days and the submerged zone have an effect on the nitrogen removal in the bioretention cells, where a longer antecedent drying days is detrimental to the nitrogen removal, and the installation of a submerged zone improves the nitrogen removal. The basalt fiber can enhance the transformation process from nitrate-nitrogen to nitrite-nitrogen in the bioretention cell. Therefore, the modification of SAC can provide a certain idea for the in-situ use of loess as the filler of the bioretention cell.
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  • 文章类型: English Abstract
    微塑料是污水处理厂中最难去除的新污染物之一。为了探究其发生形式,大小分布,composition,去除效率,移民法,以及污水处理厂中微塑料颗粒的命运行为特征,以呼和浩特市的污水处理厂为例,总共设立了17个采样点。LASX软件计算了形状,丰度,和微塑料的尺寸,并进行了全过程分析。结果表明:纤维状微塑料丰度最高、分布最广,是其主要存在形式,占总丰度的61.8%;微塑料的大小主要在0到1.00mm之间,在四种尺寸中,中国微塑料的丰度为0.25至0.50毫米,占32.9%。在检测到的八种塑料成分中,聚酯物质(PET,PBT),纤维素,聚丙烯(PP)是主要成分,占25%,21%,17%,分别。污水厂进水丰度为(73±5)n·L-1,出水丰度为(14±2)n·L-1,总去除率为(80.8±12.1)%。在污水处理厂的三个处理阶段中,只有初级治疗起了去除的作用,在二次处理中,大量的微塑料激增。不同结构在微塑料去除中起主要作用的是细格(49.2±7.4)%和二级沉淀池(92.4±13.9)%。微塑料主要以纤维的形式存在,碎片,和电影。纤维的比例约为70%,碎片大小主要集中在0.50~5.00mm之间。大多数碎片在5.00毫米的范围内,占50%,使它们成为除了纤维以外的主要形式。膜状尺寸大多集中在小于0.50mm的范围内,占10%以上。因此,提高对小尺寸纤维状和膜状微塑料和大尺寸破碎微塑料颗粒的去除,可以有效降低污水厂排水对环境中微塑料的污染风险。
    Microplastics are among the most difficult new pollutants to remove in wastewater treatment plants. In order to explore the occurrence form, size distribution, composition, removal efficiency, migration law, and fate behavior characteristics of microplastic particles in sewage plants, taking a sewage treatment plant in Hohhot as an example, a total of 17 sampling sites were set up. The LAS X software counted the shape, abundance, and size of microplastics and conducted a full-process analysis. The results showed that: fibrous microplastics had the highest abundance and widest distribution and were the main form of existence, accounting for 61.8% of the total abundance; the size of microplastics ranged mainly between 0 and 1.00 mm, and among the four sizes, the abundance of microplastics 0.25 to 0.50 mm in China was the highest, accounting for 32.9%. Among the eight types of plastic components detected, polyester substances (PET, PBT), cellulose, and polypropylene (PP) were the main components, accounting for 25%, 21%, and 17%, respectively. The influent abundance of the sewage plant was (73 ±5) n·L-1, the effluent abundance was (14 ±2) n·L-1, and the overall removal rate was (80.8 ±12.1)%. Among the three treatment stages of the sewage plant, only the primary treatment played a role in removal, and the abundance of microplastics surged in the secondary treatment. Different structures playing a major role in the removal of microplastics were fine grids (49.2 ±7.4)% and secondary sedimentation tanks (92.4 ±13.9)%. Microplastics mainly existed in the form of fibers, fragments, and films. The proportion of fibers was approximately 70%, and the size of fragments was mainly concentrated between 0.50 and 5.00 mm. Most fragments were in the range of 5.00 mm, accounting for 50%, making them the main form apart from fibrous. The film-like size was mostly concentrated in the range of less than 0.50 mm, accounting for more than 10%. Therefore, improving the removal of small-sized fibrous and film-like microplastics and large-sized fragmented microplastic particles can effectively reduce the pollution risk of microplastics in the environment caused by sewage plant drainage.
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  • 文章类型: Journal Article
    铜绿微囊藻产生的微囊藻毒素(MCs)对动物和人体健康有害,目前没有有效的去除方法。因此,需要开发抑制蓝细菌和去除MC的生物方法。我们鉴定了MB1菌株,确认为羊肚菌,使用形态学和痣进化方法。为了评估菌株MB1对铜绿假单胞菌的影响,我们进行了一项实验,其中我们用羊肚菌MB1接种了铜绿分枝杆菌。在他们共同培养了4张后,接种0.9696ngMB1完全抑制并去除铜绿假单胞菌,同时去除高达95%的MC含量。此外,在他们共同种植的3周内,MB1从铜绿分枝杆菌溶液中去除超过50%的氮和磷。因此,开发有效的MC去除生物技术对于保护环境和人类福祉至关重要。我们在此成功地从其自然栖息地中分离出MB1。该菌株有效地抑制和去除铜绿假单胞菌,并降低铜绿假单胞菌溶液中的氮和磷含量。最重要的是,它表现出强大的消除MC的能力。本研究结果为减轻有害藻华提供了新的方法和技术参考。
    Microcystins (MCs) produced by Microcystis aeruginosa are harmful to animal and human health, and there is currently no effective method for their removal. Therefore, the development of biological approaches that inhibit cyanobacteria and remove MCs is needed. We identified strain MB1, confirmed as Morchella, using morphological and mole-cular evolution methods. To assess the impact of strain MB1 on M. aeruginosa, we conducted an experiment in which we inoculated M. aeruginosa with Morchella strain MB1. After their co-cultivation for 4‍ ‍d, the inoculation with 0.9696‍ ‍g MB1 completely inhibited and removed M. aeruginosa while concurrently removing up to 95% of the MC content. Moreover, within 3‍ ‍d of their co-cultivation, MB1 removed more than 50% of nitrogen and phosphorus from the M. aeruginosa solution. Therefore, the development of effective biological techniques for MC removal is paramount in safeguarding both the environment and human well-being. We herein successfully isolated MB1 from its natural habitat. This strain effectively inhibited and removed M. aeruginosa and also reduced the content of nitrogen and phosphorus in the M. aeruginosa solution. Most importantly, it exhibited a robust capability to eliminate MCs. The present results offer a new method and technical reference for mitigating harmful algal blooms.
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  • 文章类型: Journal Article
    各种研究已经调查了食品中微塑料(MPs)的存在及其对人类健康的潜在危险影响。人类接触国会议员的频率,特别是通过消耗人造食品和饮用水,正在增加。然而,有关用于泡菜生产的盐水和盐水白菜中MP污染的数据有限。这里,我们量化了盐水白菜生产过程中盐水中的MPs。通过进行过滤步骤对盐水工艺用水进行预处理导致98.7-100%的MP去除效率;在未过滤的盐水工艺水中观察到3671±174MP颗粒。一个玻璃过滤器,STS过滤器,Si过滤器显示出显着的MP去除效率,将盐水中的MP颗粒数量分别减少到2,361、2,775和3,490(p<0.05)。我们的结果提供了有关盐水过滤如何有效保护泡菜免受MP污染和生产e的数据。然而,为了克服我们实验室规模研究的局限性,其他技术应在未来用于大规模过滤过程。
    Various studies have investigated the presence of microplastics (MPs) in food and their potential hazardous impact on human health. The frequency of human exposure to MPs, particularly through the consumption of manufactured food and drinking water, is increasing. However, data regarding MP contamination in brine and brined cabbage used for the production of kimchi are limited. Here, we quantified MPs in brine process water during the production of brined cabbage. Pretreatment of the brine process water by performing a filtration step resulted in an MP-removal efficiency of 98.7-100%; 3671 ± 174 MP particles were observed in brining process water that was not filtered. A glass filter, STS filter, and Si Filter showed significant MP-removal efficiency, decreasing the number of MP particles in brining process water to 2,361, 2,775, and 3,490, respectively (p < 0.05). Our results provide data on how filtering of brine can effectively safeguard kimchi from MP contamination and e can be produced. However, to overcome the limitations of our laboratory-scale study, additional technologies should be used in the future for large-scale filtration processes.
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  • 文章类型: Journal Article
    以农村分散污水为研究对象,研究了生物滤池(BF)反应器的处理效果和微生物群落结构特征。在固定的时间和地点,研究了常见污染物的去除效率。通过采用高通量测序的方法,分析了填料和植物根系中微生物群落结构的异质性。结果表明,CODCr的年平均去除率,NH3-N,TN,高炉的TP为83.10%,65.67%,60.25%,和80.32%,出水可达到《农村污水处理设施水污染物排放标准》(DB51/2626-2019)一级。在污水处理过程中,Scindapsus能有效建立复杂稳定的微生物群落,可以更好地降解污染物,尤其是脱氮。优势微生物群落超过11个门类和19个类别。在属一级,优势细菌包括硝基螺旋体,节杆菌,Rhodoplanes,等。
    Taking rural dispersed sewage for research objects, the treatment effect and microbial community structure characteristics of a bio filter (BF) reactor was studied. At fixed time and location, the removal efficiencies of common pollutants were investigated. By using high-throughput sequencing method, the heterogeneities of microbial community structure in fillers and plant roots were analyzed. The results showed that the average annual removal rates of CODCr, NH3-N, TN, and TP by the BF were 83.10 %, 65.67 %, 60.25 %, and 80.32 % respectively, and the effluent could reach the first grade of the water pollutant discharge standard of rural sewage treatment facility (DB51/2626-2019). During the sewage treatment process, Scindapsus could effectively establish complex and stable microbial communities, and could better degrade pollutants, especially nitrogen removal. The dominant microbial communities were more than 11 phyla and 19 classes. At the genus level, the dominant bacteria included Nitrospira, Arthrobacter, Rhodoplanes, etc.
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  • 文章类型: Journal Article
    土霉素(OTC)在临床医学和畜牧业中有着普遍的运用。残留的OTC会影响微生物的正常生命活动,动物,和植物,影响人类健康。微生物修复已成为环境领域的研究热点。锰氧化细菌(MnOB)存在于自然界,并且它们生产的生物锰氧化物(BMO)具有高效的特点,低成本,和环境友好。然而,BMO去除OTC的作用和机制尚不清楚。在这项研究中,获得了MnOB的苏云金芽孢杆菌H38菌株,并对其BMO生产条件进行了优化。最佳条件确定如下:最佳温度=35°C,最佳pH=7.5,最佳Mn(Ⅱ)初始浓度=10mmol/L结果表明,BMO不规则或块状,主要含有MnCO3、Mn2O3和MnO2,具有丰富的官能团和化学键。它们具有粒径小、比表面积大的特点。当BMO剂量为75μmol/L且溶液pH为5.0时,去除OTC(2.5mg/L)。在35°C和150r/min下培养12h后,去除率接近100%。BMO可以吸附和催化OTC的氧化,并可以产生·O2-,·OH,1O2和Mn(Ⅲ)中间体.确定了15种产物和降解途径,与OTC相比,大多数中间体的毒性降低。初步阐明了去除机理。本研究结果便于BMO在水体OTC污染中的实际应用和解决抗生素污染造成的危害。
    Oxytetracycline (OTC) is widely used in clinical medicine and animal husbandry. Residual OTC can affect the normal life activities of microorganisms, animals, and plants and affect human health. Microbial remediation has become a research hotspot in the environmental field. Manganese oxidizing bacteria (MnOB) exist in nature, and the biological manganese oxides (BMO) produced by them have the characteristics of high efficiency, low cost, and environmental friendliness. However, the effect and mechanism of BMO in removing OTC are still unclear. In this study, Bacillus thuringiensis strain H38 of MnOB was obtained, and the conditions for its BMO production were optimized. The optimal conditions were determined as follows: optimal temperature = 35 °C, optimal pH = 7.5, optimal Mn(Ⅱ) initial concentration = 10 mmol/L. The results show that BMO are irregular or massive, mainly containing MnCO3, Mn2O3, and MnO2, with rich functional groups and chemical bonds. They have the characteristics of small particle size and large specific surface area. OTC (2.5 mg/L) was removed when the BMO dosage was 75 μmol/L and the solution pH was 5.0. The removal ratio was close to 100 % after 12 h of culture at 35 °C and 150 r/min. BMO can adsorb and catalyze the oxidation of OTC and can produce ·O2-, ·OH, 1O2, and Mn(Ⅲ) intermediate. Fifteen products and degradation pathways were identified, and the toxicity of most intermediates is reduced compared to OTC. The removal mechanism was preliminarily clarified. The results of this study are convenient for the practical application of BMO in OTC pollution in water and for solving the harm caused by antibiotic pollution.
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  • 文章类型: English Abstract
    目前,微米和纳米塑料是最令人担忧的污染物,已被证实存在于饮用水处理过程的每个阶段。饮用水中的微米和纳米塑料具有很大的比表面积,可以吸附无机物,有机物,和微生物,从而增加其对人类健康的风险。微米和纳米塑料对典型污染物的吸附和团聚行为称为“胶体泵效应”。“专注于饮用水中的微米和纳米塑料,事件,胶体泵效果,和对人体的毒性作用以及胶体泵对微米和纳米塑料的去除效果进行了总结和描述。结果表明,微塑料和纳米塑料广泛存在于水源水中,处理过的水,管网水,和自来水。微米和纳米塑料的胶体泵效应促进了它们与无机物的团聚,有机物,和微生物,这不仅加剧了微米和纳米塑料的毒性作用,而且影响了去除效果。关于混凝沉淀对微米和纳米塑料去除的影响有不同的观点,砂滤器的去除效果有限。深度处理是去除粒径小于5μm的微米和纳米塑料的有效方法。通过探索胶体泵效应的机理及其引发条件,可以有效提高微塑料和纳米塑料的去除率。最后,从饮用水处理工艺和胶体泵效果来看,对饮用水中微米和纳米塑料的控制进行了展望,以期为降低饮用水中微米和纳米塑料的发生和毒性提供参考,确保饮用水质量安全和人体健康。
    Currently, micro- and nanoplastics are the most concerning pollutants, which have been confirmed to exist in every stage of drinking water treatment process. Micro- and nanoplastics in drinking water have large specific surface areas, which could adsorb inorganic matter, organic matter, and microorganisms, thereby increasing their risk to human health. The adsorption and agglomeration behavior of micro- and nanoplastics on typical pollutants is called the \"colloid pump effect.\" Focused on the micro- and nanoplastics in drinking water, the occurrence, colloid pump effect, and toxic effect on the human body and the effect of colloid pumps on the removal of micro- and nanoplastics were summarized and described. The results revealed that micro- and nanoplastics existed widely in source water, treated water, pipe network water, and tap water. The colloid pump effect of micro- and nanoplastics promoted their agglomeration with inorganic matter, organic matter, and microorganisms, which not only intensified the toxic effect of micro- and nanoplastics but also affected the removal effect. There were different viewpoints on the effect of coagulation and sedimentation on the removal of micro- and nanoplastics, and the removal effect of sand filters was limited. The advanced treatment was an efficient process to remove micro- and nanoplastics with a particle size smaller than 5 μm. The removal rate of micro- and nanoplastics could be effectively improved by exploring the mechanism of the colloid pump effect and its initiation conditions. Finally, from the perspective of the drinking water treatment process and colloid pump effect, the control of micro- and nanoplastics in drinking water was prospected in order to provide reference for reducing the occurrence and toxicity of micro- and nanoplastics in drinking water, ensuring drinking water quality safety and human health.
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  • 文章类型: Journal Article
    背景:盐水冲洗分离粘液的能力以及鼻瓣的流量限制作用尚未得到很好的研究。这项研究的目的是比较带有扩展喷嘴的新型冲洗装置与经典冲洗瓶的去除效率。
    方法:通过3D打印制作未手术的鼻腔透明铸模。用酸奶模拟粘液。将装有5毫升酸奶的铸件固定在六个头部位置,并用120毫升灌溉,175毫升,和240毫升染色水通过新颖的装置和冲洗瓶。灌溉效率是洗掉的酸奶的重量除以酸奶的总重量的比率。
    结果:带有侧面开口的长喷嘴的冲洗流与鼻前庭内出口的冲洗流不同。新颖的装置具有连续的水流,直接向上到达嗅裂的前部。根据不同的头部位置,当铸件用120毫升或175毫升水灌溉时,新型装置很容易达到100%的灌溉效率。当在冲洗瓶的每个头部位置下用240毫升水灌溉铸模时,嗅觉裂缝中仍有少量酸奶。灌溉效率取决于体积,240毫升冲洗瓶的平均冲洗效率仅为69.1%。
    结论:新型冲洗装置具有优于经典冲洗瓶的鼻腔冲洗效率。直接向上到达嗅裂前部的连续水流与克服鼻阀的流量限制作用的延长喷嘴相结合,可提高鼻腔冲洗效率。
    BACKGROUND: The ability of saline irrigation to detach the mucous and the flow-limiting effect of the nasal valve has not been well explored. The objective of this study was to compare the removal efficiency of a novel irrigation device with an extended nozzle versus a classic rinse bottle.
    METHODS: Transparent casts of the unoperated sinonasal cavity were made by 3D printing. Yogurt was used to simulate mucous. The cast filled with 5 ml yogurt was fixed in six head positions and irrigated with 120 ml, 175 ml, and 240 ml dyed water through the novel device and the rinse bottle. The irrigation efficiency was the ratio of the weight of yogurt washed away divided by the total weight of yogurt.
    RESULTS: The irrigation stream of a long nozzle with a side opening was different from the irrigation stream of the outlet within the nasal vestibule. The novel devices presented with continuous water stream directly upwards to the anterior part of the olfactory cleft. Depending on different head positions, it was easy for the novel devices to achieve an irrigation efficiency of 100% when the cast was irrigated with 120 ml or 175 ml water. There was still a tiny amount of yogurt left in the olfactory cleft when the cast was irrigated with 240 ml water under each head position for the rinse bottle. The irrigation efficiency was volume-dependent, and the average irrigation efficiency of the rinse bottle at 240 ml only reached 69.1%.
    CONCLUSIONS: The novel irrigation device presented with superior nasal irrigation efficiency to the classic rinse bottle. A continuous water stream directly upwards to the anterior part of the olfactory cleft combined with an extended nozzle overcoming the flow-limiting effect of the nasal valve promotes nasal irrigation efficiency.
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  • 文章类型: Journal Article
    内分泌干扰化合物(EDC),如双酚A(BPA)和17α-乙炔雌二醇(EE2),对人类和野生动物健康的负面影响越来越大。在这项研究中,由芽孢杆菌属产生的生物Mn氧化物(BMO)。WH4的特点是,以及不同pH值下BMOs对BPA和EE2的去除效果和反应动力学,初始有机浓度,并讨论了BMO的剂量。结果表明,BMO的形成是细胞外过程,Mn(II)分别以23.56%和76.44%氧化为Mn(III)和Mn(IV),分别。BMO对BPA和EE2的降解过程遵循一级反应动力学,去除效果随着BPA/EE2初始浓度的增加而降低,随着BMO剂量的增加而增加。然而,BMO对BPA的去除效果随着pH值的升高而降低,而BMOs对EE2的去除效果随着pH的增加而降低。在最优条件下,BPA和EE2的去除率分别超过98.2%和94.3%,分别。此外,这项研究表明,BMO通过偶联降解BPA,氧化缩合,替换,和消除反应得到16个中间产物和EE2通过取代和消除反应得到7个中间产物。
    Endocrine disrupting compounds (EDCs), such as bisphenol A (BPA) and 17α-ethynylestradiol (EE2), have increasingly negative effects on human and wildlife health. In this study, the biogenic Mn oxides (BMOs) generated by Bacillus sp. WH4 were characterized, and the removal effects and reaction kinetics of BPA and EE2 by BMOs under different pH values, initial organic concentrations, and dosages of BMOs were discussed. The results showed that the formation of BMOs was extracellular process, and Mn(II) was oxidized to Mn(III) and Mn(IV) with 23.56% and 76.44%, respectively. The degradation processes of BPA and EE2 by BMOs followed first-order reaction kinetics, and the removal effect decreased with increasing initial BPA/EE2 concentrations and increased with increasing dosages of BMOs. However, the removal effect of BPA by BMOs decreased and then increased with increasing pH, while the removal effect of EE2 by BMOs decreased with increasing pH. Under optimal conditions, the removal efficiency of BPA and EE2 exceeded 98.2% and 94.3%, respectively. Additionally, this study showed that BMOs degraded BPA by coupling, oxidative condensation, substitution, and elimination reactions to obtain sixteen intermediate products and EE2 by substitution and elimination reactions to obtain seven intermediate products.
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  • 文章类型: Journal Article
    In order to improve the utilization efficiency of road runoff and the remove effects of heavy metals, porous asphalt pavements have been used as an effective measure to deal with heavy metals in road runoff. However, the removal effect on dissolved heavy metal is weak. In this paper, basic oxygen furnace (BOF) slag was used as aggregate in porous asphalt concrete to improve the removal capacity of heavy metal. Road runoff solution with a copper concentration of 0.533 mg/L and a zinc concentration of 0.865 mg/L was artificially synthesized. The removal effect of BOF slag porous asphalt concrete on cooper and zinc in runoff was evaluated by removal tests. The influence of rainfall intensity and time on the removal effect was discussed. The results obtained indicated that BOF slag porous asphalt concrete has a better removal effect on copper. The removal rate of copper is 57-79% at the rainfall intensity of 5-40 mm/h. The removal rate of zinc is more susceptible to the changes of rainfall intensity than copper. The removal rate of zinc in heavy rain conditions (40 mm/h) is only 25%. But in light rain conditions (5 mm/h), BOF slag porous asphalt concrete maintains favorable removal rates of both copper and zinc, which are more than 60%. The heavy metal content of runoff infiltrating through the BOF slag porous asphalt concrete meets the requirements for irrigation water and wastewater discharge. The results of this study provide evidence for the environmentally friendly reuse of BOF slag as a road material and the improvement of the removal of heavy metal by porous asphalt concrete.
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