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  • 文章类型: Journal Article
    运动员接触可能是受伤的危险因素。理事机构应提供防止过度接触的准则。
    描述男性和女性橄榄球联盟中当前的接触负荷实践和对接触负荷要求的看法,以允许橄榄球橄榄球联盟(RFL)制定接触负荷指南。
    参与者(n=450名玩家,n=46教练组,n=32名绩效人员,n=23名医务人员)完成了27个项目的在线调查,评估当前接触负荷实践和四个类别的看法:“当前接触负荷实践”(n=12项),“对所需接触载荷的感知”(n=6项),“接触负荷监测”(n=3项),和“触点负载与恢复之间的关系”(n=6项)。
    在男子超级联赛季前赛期间,全面接触和受控接触训练通常每周进行15-30分钟,每周15-45分钟的摔跤训练。在季节里,这三种训练类型通常每周进行15-30分钟.在女子超级联赛中,在赛季前和赛季中,所有训练方式每周最多进行30分钟.男女超级联赛的球员和工作人员都认为,每周进行15-30分钟的全面接触训练足以使球员为橄榄球联赛的身体需求做好准备,但可能需要更长的时间来准备技术联系需求。
    男女超级联赛俱乐部目前在季前赛中进行的接触训练比在赛季中更多,这是教练计划的,被认为足以让球员为橄榄球联盟的需求做好准备。这项研究提供数据来制定接触负荷指南,以提高球员福利,同时不影响表现。
    UNASSIGNED: Athlete exposure to contact could be a risk factor for injury. Governing bodies should provide guidelines preventing overexposure to contact.
    UNASSIGNED: Describe the current contact load practices and perceptions of contact load requirements within men\'s and women\'s rugby league to allow the Rugby Football League (RFL) to develop contact load guidelines.
    UNASSIGNED: Participants (n=450 players, n=46 coaching staff, n=32 performance staff, n=23 medical staff) completed an online survey of 27 items, assessing the current contact load practices and perceptions within four categories: \"current contact load practices\" (n=12 items), \"perceptions of required contact load\" (n = 6 items), \"monitoring of contact load\" (n=3 items), and \"the relationship between contact load and recovery\" (n=6 items).
    UNASSIGNED: During men\'s Super League pre-season, full contact and controlled contact training was typically undertaken for 15-30 minutes per week, and wrestling training for 15-45 minutes per week. During the in-season, these three training types were all typically undertaken for 15-30 mins per week. In women\'s Super League, all training modalities were undertaken for up to 30 minutes per week in the pre- and in-season periods. Both men\'s and women\'s Super League players and staff perceived 15-30 minutes of full contact training per week was enough to prepare players for the physical demands of rugby league, but a higher duration may be required to prepare for the technical contact demands.
    UNASSIGNED: Men\'s and women\'s Super League clubs currently undertake more contact training during pre-season than in-season, which was planned by coaches and is deemed adequate to prepare players for the demands of rugby league. This study provides data to develop contact load guidelines to improve player welfare whilst not impacting performance.
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  • 文章类型: Journal Article
    针对含铬废水带来的问题,如环境污染,生物毒性,和人类健康风险。基于粉煤灰吸附和纳米FeS还原特性,采用矿物负载改性技术和超声沉淀法合成了粉煤灰负载纳米FeS复合材料(nFeS-FA)。吸附剂用量的影响,初始pH值,接触时间,研究了溶液初始浓度对nFeS-FA吸附Cr(VI)和总Cr的影响。利用吸附等温线研究了nFeS-FA对Cr(VI)和总Cr的吸附特性,吸附动力学原理,以及XRD,TEM,SEM-EDS,和BET分析。结果表明,在nFeS-FA为8g/L的条件下,初始pH为4,接触时间为150分钟,溶液的初始浓度为100mg/L,nFeS-FA对Cr(VI)的去除率为87.85%,对总Cr的去除率为71.77%。nFeS-FA对Cr(VI)和总Cr的吸附遵循Langmuir模型和拟二级动力学模型,表明单层吸附以化学吸附为主导机制。XRD,TEM,SEM-EDS,BET表明片状纳米FeS均匀分布在粉煤灰表面,表现出良好的分散性,从而增加比表面积。在吸附实验中,nFeS-FA与Cr(VI)反应,生成的Fe3+主要以FeOOH沉淀的形式存在,而S2-与Cr(III)反应产生Cr2S3沉淀。因此,nFeS-FA对Cr(VI)和总Cr具有优异的吸附性能。可作为水处理领域重金属铬污染修复的技术参考。
    In view of the problems caused by chromium-containing wastewater, such as environmental pollution, biological toxicity, and human health risks. Based on fly ash adsorption and nano-FeS reduction characteristics, fly ash loaded nano-FeS composite (nFeS-FA) was synthesized using mineral supported modification technology and ultrasonic precipitation method. The effect of adsorbent dosage, initial pH, contact time, and initial concentration of the solution on the adsorption of Cr(VI) and total Cr by nFeS-FA was investigated. The characteristics of Cr(VI) and total Cr adsorption by nFeS-FA were studied using adsorption isotherms, adsorption kinetics principles, as well as XRD, TEM, SEM-EDS, and BET analysis. The results demonstrated that under the conditions of nFeS-FA of 8 g/L, initial pH of 4, contact time of 150 min, and initial concentration of the solution at 100 mg/L, nFeS-FA achieved removal efficiency of 87.85 % for Cr(VI) and 71.77 % for total Cr. The adsorption of Cr(VI) and total Cr by nFeS-FA followed the Langmuir model and pseudo-second-order kinetic model, indicating monolayer adsorption with chemical adsorption as the dominant mechanism. XRD, TEM, SEM-EDS, and BET revealed that the flaky nano-FeS was uniformly distributed on the surface of fly ash, exhibiting good dispersion and thereby increasing the specific surface area. During the adsorption experiments, nFeS-FA reacted with Cr(VI), and the generated Fe3+ mainly existed as FeOOH precipitation, while S2- reacted with Cr(III) to produce Cr2S3 precipitation. Therefore, nFeS-FA exhibited excellent adsorption performance towards Cr(VI) and total Cr. It can serve as a technological reference for the remediation of heavy metal chromium pollution in the field of water treatment.
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  • 文章类型: Journal Article
    记住完成的目标-称为前瞻记忆(PM)-对于日常生活中的成功至关重要,然而,很少的实证工作致力于研究教育环境中的前瞻性记忆。这项研究的主要目标是调查学生完成许多面向未来的学术意图(PM任务)的能力,同时关注讲座,看看工作记忆容量(WM)和添加微妙的上下文信息是否会支持学生完成PM任务的可能性。参与者参加了为期2小时的大学课程类活动。在整个会议期间,偶尔有机会完成几个自然PM任务之一。以下发现是基于我们的贝叶斯模型的结果。发现提供有关何时可以完成PM任务的微妙上下文线索可能会提高性能。要记住的PM意图的数量(即,负载)对正在进行的任务性能或PM性能没有明显的影响。此外,WM容量的个体差异可能预测PM性能的近零变化。目前的发现对教育工作者有意义的意义,其中提供上下文,即使在微妙的层面上,可以增强学生完成任务的记忆能力,而不改变他们专注于手头任务的能力。此外,似乎要求学生记住完成多个,预期的课堂任务不太可能阻碍任务完成或他们专注于其他正在进行的任务的能力。
    Remembering to complete goals-termed prospective memory (PM)-is critical for success in everyday life, yet minimal empirical work has been dedicated to examining PM within an educational setting. The main goal of this study was to investigate students\' ability to complete numerous future-oriented academic intentions (PM tasks) while simultaneously paying attention to a lecture and to see if working memory (WM) capacity and adding subtle contextual information would support the students\' likelihood of completing their PM tasks. Participants took part in a 2-hr session of college course-like activities. Throughout the session, there was occasionally the opportunity to complete one of several naturalistic PM tasks. The following findings are based on the results of our Bayesian models. Providing subtle contextual clues about when PM tasks could be completed was found to likely increase performance. The number of PM intentions to be remembered (i.e., load) produced no discernable effect on ongoing task performance or PM performance. Furthermore, individual differences in WM capacity were likely to be predictive of a near-zero change in PM performance. The current findings hold meaningful implications for educators, wherein providing context, even at a subtle level, can enhance students\' ability to remember to complete tasks, without altering their ability to focus on the tasks at hand. Moreover, it appears that asking students to remember to complete multiple, prospective in-class tasks is not likely to hinder task completion or their ability to focus on other ongoing tasks.
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  • 文章类型: Journal Article
    在NH3-SCR中用乙酸乙酯代替氨提供了同时去除VOC和NO的新策略。在这项研究中,通过在700°C下的热解制造了三种不同类型的生物炭。通过水热法将MnOx和TiO2依次加载到这些生物炭基材上,产生具有优化剂量的生物炭基催化剂家族。暴露在240°C的氙灯照射下,生物炭催化剂被指定为700-12-3GN,源自银杏壳,与由毛竹和丝瓜制备的同类物相比,表现出最高的催化活性。NO和乙酸乙酯(EA)的转化效率分别为73.66%和62.09%。分别,在300mg的催化剂负载下。表征结果表明,700-12-3GN催化剂具有优越的活性,这可以归因于更高浓度的Mn4+和Ti4+物种,以及其优越的氧化还原性能和合适的元素分布。值得注意的是,700-12-3GN催化剂具有最小的比表面积,但最大的孔体积和平均BJH孔径,表明比表面积不是影响催化剂性能的主要因素。相反,孔体积和平均BJH孔径似乎是更有影响的参数。该研究为生物炭的资源化利用以及低成本开发光热催化乙酸乙酯和NO提供了参考和展望。
    The substitution of ethyl acetate for ammonia in NH3-SCR provides a novel strategy for the simultaneous removal of VOCs and NO. In this study, three distinct types of biochar were fabricated through pyrolysis at 700 °C. MnOx and TiO2 were sequentially loaded onto these biochar substrates via a hydrothermal process, yielding a family of biochar-based catalysts with optimized dosages. Upon exposure to xenon lamp irradiation at 240 °C, the biochar catalyst designated as 700-12-3GN, derived from Ginkgo shells, demonstrated the highest catalytic activity when contrasted with its counterparts prepared from moso bamboo and loofah. The conversion efficiencies for NO and ethyl acetate (EA) peaked at 73.66% and 62.09%, respectively, at a catalyst loading of 300 mg. The characterization results indicate that the 700-12-3GN catalyst exhibits superior activity, which can be attributed to the higher concentration of Mn4+ and Ti4+ species, along with its superior redox properties and suitable elemental distribution. Notably, the 700-12-3GN catalyst has the smallest specific surface area but the largest pore volume and average BJH pore size, indicating that the specific surface area is not the predominant factor affecting catalyst performance. Instead, pore volume and average BJH pore diameter appear to be the more influential parameters. This research provides a reference and prospect for the resource utilization of biochar and the development of photothermal co-catalytic ethyl acetate and NO at low cost.
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  • 文章类型: Journal Article
    本研究比较了最常见的绝对冲刺阈值(>25.2km/h)与相对和个性化阈值(>70%,>75%,>80%,>85%和>90%的峰值匹配速度)。二十名精英足球运动员,参加葡萄牙联赛的甲级联赛,在三十四场正式比赛中使用GNSS设备进行了监测。作为在整个季节中达到的个人最大速度,检索了峰值匹配速度。当速度超过绝对和相对阈值时,记录距离。计算峰值速度和覆盖距离的平均值±SD,和Pearson相关(r)和平均配对差异分析阈值之间的关系和差异。峰值匹配速度为32.9±1.4km/h。使用绝对阈值和相对阈值覆盖的距离之间的相关性非常强(>70%:r=0.84,p<.001;>75%:r=0.89,p<.001;和>80%:r=0.88,p<.001),强(>85%:r=0.79,p<.001),至中度(>90%:r=0.59,p<.001)。总的来说,>75%(ES:0.23[95%CI:0.16,0.31])和>90%(ES:-1.65[95CI:-1.85,-1.48])相对阈值呈现最小和最大差异,分别,绝对阈值。在考虑比赛位置时也发现了差异。虽然中央中场球员覆盖的距离在绝对阈值和>80%阈值之间相似(-0.03[-0.16,0.10]),在绝对阈值中,后卫覆盖的距离-1.88[-2.42-1.50])比在>80%阈值中更多。玩家覆盖的距离根据选定的阈值而变化,影响不同比赛位置所覆盖的距离。作为位移阈值内的最高速度阈值,绝对冲刺阈值与较低而不是较高的相对阈值显示出更大的相似性。
    This study compared the most common absolute sprint threshold (> 25.2 km/h) with relative and individualized thresholds (> 70%, > 75%, > 80%, > 85% and > 90% of peak match speed). Twenty elite soccer players, competing in the first division of the Portuguese League, were monitored using GNSS equipment during thirty-four official matches. Peak match speed was retrieved as the individual maximal speed reached during the full season. Distances were registered when speed overcame the absolute and the relative thresholds. Mean ± SD of peak speeds and distances covered were calculated, and Pearson correlation (r) and mean paired differences were performed to analyze relationships and differences between thresholds. The peak match speed was 32.9 ± 1.4 km/h. Correlations between distances covered using the absolute and relative thresholds varied from very strong (> 70%: r = 0.84, p < .001; > 75%: r = 0.89, p < .001; and > 80%: r = 0.88, p < .001), strong (> 85%: r = 0.79, p < .001), to moderate (> 90%: r = 0.59, p < .001). Overall, the > 75% (ES: 0.23 [95% CI: 0.16, 0.31]) and the > 90% (ES: -1.65 [95%CI: -1.85, -1.48]) relative thresholds presented the smallest and largest differences, respectively, with the absolute threshold. Differences were also found when considering the playing positions. While the distances covered by central midfielders were similar between the absolute and > 80% thresholds (-0.03 [-0.16, 0.10]), fullbacks covered largely more distance -1.88 [-2.42 -1.50]) in the absolute threshold than in the > 80% threshold. The distances covered by players varied based on the selected threshold, affecting the distances covered by different playing positions. Being the highest speed threshold within displacements thresholds, the absolute sprint threshold showed greater similarity to lower rather than higher relative thresholds.
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  • 文章类型: Journal Article
    在微潮Hyeongsan河口(HRE)研究了水文条件对Hg物种分布和负荷的潜在影响。在台风后期间,接收工业废物的小河中溶解的汞(DHg)和溶解的甲基汞(DMeHg)有效地沉淀为沉积物,而在干燥期间观察到汞污染小河的持续输入而没有沉降。基于事件的均值方法用于探索对汞年通量的水文影响。在汞污染的小河中发现了最大的DHg和颗粒物Hg(PHg)输入,干旱期的汞输入高于湿期,而湿期的PHg输入高于干期。在沉积物中,台风过后汞和甲基汞浓度下降,归因于表面沉积物的侵蚀。总的来说,HRE是汞的有效汇,可减少沿海水域中汞的污染程度。
    The potential effect of hydrological conditions on distribution and loadings of Hg species was investigated in the microtidal Hyeongsan River Estuary (HRE). Dissolved Hg (DHg) and dissolved methylmercury (DMeHg) from the creek receiving industrial wastes were effectively settled to sediment during the post-typhoon period, while persistent input from the Hg-contaminated creek without settling was observed during the dry periods. The event-based mean approach was applied to explore the hydrological effects on the annual flux of Hg. The largest inputs of DHg and particulate Hg (PHg) were found in the Hg-contaminated creek, and DHg input was higher in the dry than wet periods whereas PHg input was higher in the wet than dry periods. In sediment, Hg and MeHg concentrations decreased after the typhoon, attributed to erosion of surface sediments. Overall, the HRE serves as an effective sink of Hg that reduces the degree of Hg contamination in coastal water.
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  • 文章类型: Journal Article
    步行是日常生活的主要活动之一,步态分析可以为许多领域的生物力学计算提供关键数据。在多个应用程序中,有参考数据,包括各种步态条件可能是有用的评估步行性能。然而,有限的广泛的参考数据是可用的,因为许多条件不容易进行实验测试。出于这个原因,使用OpenSim中的肌肉骨骼模型以及步态数据(在七个不同的速度下)来模拟七个负载以及两个参数之间的所有组合。用扭矩测量对下肢生物力学的影响,电源,机械工作。结果表明,生物力学受速度和载荷的影响。我们的结果扩展了以前的文献:在以前的大部分工作中,仅研究了所提出条件的一个子集.此外,我们的模拟方法提供了全面的数据,这些数据可能对许多领域的应用有用,比如康复,骨科,医疗保健,和体育。
    Walking is one of the main activities of daily life and gait analysis can provide crucial data for the computation of biomechanics in many fields. In multiple applications, having reference data that include a variety of gait conditions could be useful for assessing walking performance. However, limited extensive reference data are available as many conditions cannot be easily tested experimentally. For this reason, a musculoskeletal model in OpenSim coupled with gait data (at seven different velocities) was used to simulate seven carried loads and all the combinations between the two parameters. The effects on lower limb biomechanics were measured with torque, power, and mechanical work. The results demonstrated that biomechanics was influenced by both speed and load. Our results expand the previous literature: in the majority of previous work, only a subset of the presented conditions was investigated. Moreover, our simulation approach provides comprehensive data that could be useful for applications in many areas, such as rehabilitation, orthopedics, medical care, and sports.
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  • 文章类型: Journal Article
    该研究旨在确定和解释农村和城市年轻女学生在主要肌肉群体的低强度高容量阻力训练(LIHV-RT)表现的典型差异,以建立相关的定量和定性阻力训练参数集。研究样本包括布拉索夫Transilvania大学的46名休闲活跃女学生,(平均±SD年龄,20±1年;体重,60±3kg;高度,160±4cm)分组城市与农村。这项研究使用了改良的阻力锻炼机,用于the肌和四头肌,配有测力计和传感器,用于识别发展的力和加速度。进行了368次测试,代表每个主题的两次尝试,用于膝盖屈曲和膝盖伸展练习,有两个不同的负载。对于性能分析,考虑了一些变量:直到故障的最大重复次数,产生的最大力,最大加速度,集合的持续时间和每次重复的平均时间。在膝关节屈曲的情况下(对于负载1(L1),d=0.98[0.32,1.54],对于负载2(L2),d=0.65[0.03,1.21])和在膝关节伸展的情况下(对于L1,d=1.89[1.11,2.48],对于L2,d=1.67[0.92,2.25]),农村的最大重复失败次数显示出明显高于城市的值。在膝关节屈曲的情况下(对于L2,d=0.84[0.19,1.39])和在膝关节伸展的情况下(对于L1,d=1.46[0.74,2.03]和对于L2,d=1.56[0.98,2.14]),这些集合的总持续时间在农村显示出比城市高得多的值。此外,我们发现相关重复执行的质量以及在LIHV-MNRF设置期间产生的冲动存在差异。该研究的主要发现是LIHV-RT表现膝关节屈曲和膝关节伸展对抗运动存在差异,农村和城市女学生之间。我们得出的结论是,所获得的结果使教师能够了解针对不同参与者组的RT计划的最佳设计,为了适应他们的教学技术,以实现他们的最终目标,坚持理论或实践内容的特定方面。
    The study aimed to identify and explain the typical differences in low-intensity high-volume resistance training (LIHV-RT) performances for major muscle groups between rural versus urban young female students to establish the relevant set of quantitative and qualitative resistance training parameters. The study sample included 46 recreational active female students at the Transilvania University of Brașov, (mean ± SD age, 20 ± 1 year; body mass, 60 ± 3 kg; height, 160 ± 4 cm) grouped urban vs. rural. The study used modified resistance exercise machines for the hamstring- and quadricep-group muscles, equipped with a dynamometer and sensors for identifying developed forces and accelerations. A number of 368 tests were performed, representing two attempts for each subject, for knee flexion and knee extension exercises, with two different loads. For the performance analysis some variables were considered: the maximum number of repetition until failure, maximum force developed, maximum acceleration, the duration of the set and the mean time per repetition. The maximum number of repetition to failure shows a significant higher value for rural than urban in case of knee flexion (d = 0.98 [0.32, 1.54] for load 1(L1) and d = 0.65 [0.03, 1.21] for load 2(L2)) and in case of knee extension (d = 1.89 [1.11, 2.48] for L1 and d = 1.67 [0.92, 2.25] for L2). The total duration of the sets shows a significant higher value for rural than urban in case of knee flexion (d = 0.84 [0.19, 1.39] for L2) and in case of knee extension (d = 1.46 [0.74, 2.03] for L1 and d = 1.56 [0.98, 2.14] for L2). Additionally we found differences in the quality of the relevant repetitions execution and in the impulse developed during the LIHV- MNRF sets. The study\'s main finding was that there are differences in LIHV-RT performances knee flexion and knee extension antagonistic exercises, between rural and urban female students. We concluded that the obtained results allow teachers to understand the optimal design of RT programs for the different groups of participants, in order to adapt their teaching techniques so that their final objectives are achieved, insisting on particular aspects of the theoretical or practical contents.
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  • 文章类型: Journal Article
    背景:MODEL-AD(晚期阿尔茨海默病的模型生物体开发和评估)正在创建和分发具有人源化的新型小鼠模型,临床相关的遗传危险因素,以更准确地捕获晚发性阿尔茨海默病(LOAD)的轨迹和进展。
    方法:我们通过结合载脂蛋白E4(APOE4)创建了LOAD2模型,Trem2*R47H,和人源化淀粉样蛋白-β(Aβ)。对小鼠进行对照饮食或高脂肪/高糖饮食(LOAD2+HFD)。我们评估了血浆和大脑中疾病相关的结局指标,包括神经炎症,Aβ,神经变性,神经影像学,和多元组学。
    结果:到18个月,LOAD2+HFD小鼠表现出性别特异性神经元丢失,不溶性脑Aβ42升高,血浆神经丝轻链(NfL)增加,以及与脂质代谢和突触功能相关的基因/蛋白质表达改变。影像学显示脑容量和神经血管解偶联减少。观察到在获取基于触摸屏的认知任务方面的缺陷。
    结论:LOAD2+HFD小鼠的综合特征表明,该模型对于寻求了解LOAD在淀粉样蛋白斑和tau缠结之前或独立于淀粉样蛋白斑和tau缠结之前的疾病轨迹和进展的临床前研究非常重要。
    结论:到18个月,与对照小鼠不同(例如,LOAD2小鼠饲喂对照饮食,CD),LOAD2+HFD小鼠在皮质中表现出微妙但显著的神经元损失,大脑中不溶性Ab42的水平升高,和增加的血浆神经丝轻链(NfL)。转录组学和蛋白质组学显示了与多种疾病相关过程(包括脂质代谢和突触功能)相关的基因/蛋白质的变化。体内成像显示大脑区域体积(MRI)和神经血管解耦(PET/CT)的年龄依赖性减少。LOAD2+HFD小鼠在获取基于触摸屏的认知任务方面也表现出缺陷。
    MODEL-AD (Model Organism Development and Evaluation for Late-Onset Alzheimer\'s Disease) is creating and distributing novel mouse models with humanized, clinically relevant genetic risk factors to capture the trajectory and progression of late-onset Alzheimer\'s disease (LOAD) more accurately.
    We created the LOAD2 model by combining apolipoprotein E4 (APOE4), Trem2*R47H, and humanized amyloid-beta (Aβ). Mice were subjected to a control diet or a high-fat/high-sugar diet (LOAD2+HFD). We assessed disease-relevant outcome measures in plasma and brain including neuroinflammation, Aβ, neurodegeneration, neuroimaging, and multi-omics.
    By 18 months, LOAD2+HFD mice exhibited sex-specific neuron loss, elevated insoluble brain Aβ42, increased plasma neurofilament light chain (NfL), and altered gene/protein expression related to lipid metabolism and synaptic function. Imaging showed reductions in brain volume and neurovascular uncoupling. Deficits in acquiring touchscreen-based cognitive tasks were observed.
    The comprehensive characterization of LOAD2+HFD mice reveals that this model is important for preclinical studies seeking to understand disease trajectory and progression of LOAD prior to or independent of amyloid plaques and tau tangles.
    By 18 months, unlike control mice (e.g., LOAD2 mice fed a control diet, CD), LOAD2+HFD mice presented subtle but significant loss of neurons in the cortex, elevated levels of insoluble Ab42 in the brain, and increased plasma neurofilament light chain (NfL). Transcriptomics and proteomics showed changes in gene/proteins relating to a variety of disease-relevant processes including lipid metabolism and synaptic function. In vivo imaging revealed an age-dependent reduction in brain region volume (MRI) and neurovascular uncoupling (PET/CT). LOAD2+HFD mice also demonstrated deficits in acquisition of touchscreen-based cognitive tasks.
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  • 文章类型: Journal Article
    针对锌中的酸性矿山排水(AMD),铜和其他重金属处理困难,严重的水土环境污染等问题。通过超声波沉淀法,本研究制备了载粉煤灰纳米FeS复合材料(nFeS-F)。nFeS-F用量的影响,pH值,搅拌速率,考察了反应时间和溶液初始浓度对Zn(Ⅱ)和Cu(Ⅱ)吸附的影响。数据由拉格伦一阶和二阶动力学方程拟合,内扩散方程,Langmuir和Freundlich等温线模型,并结合SEM,TEM,FTIR,TGA,和XPS分析揭示了nFeS-F吸附Zn(II)和Cu(II)的机理。结果表明:nFeS-F对Zn(II)和Cu(II)的去除率分别达到83.36%和70.40%,分别(用量为8g/L,pH为4,时间为150min,浓度为100mg/L)。吸附过程,主要是化学吸附,符合Lagergren二阶动力学方程(R2=0.9952和0.9932)。吸附等温线与Langmuir模型具有较高的拟合度(R2=0.9964和0.9966),吸附是单层吸附过程。该研究可为酸性矿山排水中重金属的处理及粉煤灰的资源化利用提供参考。
    Aiming at the acid mine drainage (AMD) in zinc, copper and other heavy metals treatment difficulties, severe pollution of soil and water environment and other problems. Through the ultrasonic precipitation method, this study prepared fly ash-loaded nano-FeS composites (nFeS-F). The effects of nFeS-F dosage, pH, stirring rate, reaction time and initial concentration of the solution on the adsorption of Zn(II) and Cu(II) were investigated. The data were fitted by Lagergren first and second-order kinetic equations, Internal diffusion equation, Langmuir and Freundlich isotherm models, and combined with SEM, TEM, FTIR, TGA, and XPS assays to reveal the mechanism of nFeS-F adsorption of Zn(II) and Cu(II). The results demonstrated that: The removal of Zn(II) and Cu(II) by nFeS-F could reach 83.36% and 70.40%, respectively (The dosage was 8 g/L, pH was 4, time was 150 min, and concentration was 100 mg/L). The adsorption process, mainly chemical adsorption, conforms to the Lagergren second-order kinetic equation (R2 = 0.9952 and 0.9932). The adsorption isotherms have a higher fitting degree with the Langmuir model (R2 = 0.9964 and 0.9966), and the adsorption is a monolayer adsorption process. This study can provide a reference for treating heavy metals in acid mine drainage and resource utilization of fly ash.
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