kinetic roughening

  • 文章类型: Journal Article
    使用针对结构因子给出的广泛接受的“通用缩放ansatz”分类框架,分析了通过气相沉积聚合生长的聚合物薄膜的动力学粗糙化。在过去的二十年里,这种方法在分类各种形式的动态缩放和理解驱动界面粗糙化的机制方面发挥了关键作用。聚合物膜的粗糙度指数一致地确定为α=1.25±0.09,αloc=0.73±0.02,和αs=0.99±0.06。然而,无法明确地将这些粗糙度指数值分配给特定的缩放子类,从而提出了一种实用的替代方案。该报告说明了如何基于在实际空间中测量的两个时间缩放指数之间的关系来一致地识别和分类所有潜在的动态缩放:界面的平均局部斜率和全局斜率。固有的异常粗糙化类最终被分配给以异常\“天然(去除背景斜率)局部高度波动\”为特征的聚合物膜生长。此外,新的分析表明,界面表现出异常的缩放,以前被归类为固有异常粗糙,可能属于超级粗糙阶层,特别是当光谱粗糙度指数αs等于1时。
    The kinetic roughening of polymer films grown by vapor deposition polymerization was analyzed using the widely accepted classification framework of \"generic scaling ansatz\" given for the structure factor. Over the past two decades, this method has played a pivotal role in classifying diverse forms of dynamic scaling and understanding the mechanisms driving interface roughening. The roughness exponents of the polymer films were consistently determined as α=1.25±0.09, αloc=0.73±0.02, and αs=0.99±0.06. However, the inability to unambiguously assign these roughness exponent values to a specific scaling subclass prompts the proposal of a practical alternative. This report illustrates how all potential dynamic scaling can be consistently identified and classified based on the relationship between two temporal scaling exponents measured in real space: the average local slope and the global slope of the interface. The intrinsic anomalous roughening class is conclusively assigned to polymer film growth characterized by anomalous \"native (background slope-removed) local height fluctuations\". Moreover, the new analysis reveals that interfaces exhibiting anomalous scaling, previously classified as intrinsic anomalous roughening, could potentially belong to the super-rough class, particularly when the spectral roughness exponent αs is equal to 1.
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  • 文章类型: Journal Article
    随着新媒体艺术的到来,艺术家利用流体动力学来创造迷人的视觉叙事。一种名为树枝状绘画的引人注目的技术是在油漆上使用墨水和异丙醇的混合物,产生复杂的树状图案。为了解开这种技术的复杂性,我们检查了油墨/酒精液滴在具有不同流变特性的液体基材上的扩散。在牛顿基底上,液滴尺寸演变表现出两个幂律,暗示着粘性和马兰戈尼力量之间潜在的相互作用。液滴的前缘以3/8的指数作为前体膜扩散,而其主体以1/4的指数扩散。对于弱剪切稀化的丙烯酸树脂基材,同样的幂律仍然存在,但是树枝状结构出现了,和前体膜的纹理粗糙。观察到的粗糙度和生长指数(3/4和3/5)表明与淬火的Kardar-Parisi-Zhang普遍性类有关,暗示液体基质中存在淬火无序。混合树脂与丙烯酸涂料使其更粘稠和剪切稀化,细化枝晶边缘并进一步粗糙化前体膜。在较大的油漆浓度下,底物变成幂律流体。然后粗糙度和生长指数分别接近1/2和3/4,偏离已知的普遍性类别。随后的结构具有1.68的分形维数,这是扩散限制聚集的特征。这些发现强调了液体底物的非线性流变特性,再加上马兰戈尼传播的拉普拉斯性质,可以掩盖液滴界面的局部动力学粗糙化。
    With the advent of new media art, artists have harnessed fluid dynamics to create captivating visual narratives. A striking technique known as dendritic painting employs mixtures of ink and isopropanol atop paint, yielding intricate tree-like patterns. To unravel the intricacies of that technique, we examine the spread of ink/alcohol droplets over liquid substrates with diverse rheological properties. On Newtonian substrates, the droplet size evolution exhibits two power laws, suggesting an underlying interplay between viscous and Marangoni forces. The leading edge of the droplet spreads as a precursor film with an exponent of 3/8, while its main body spreads with an exponent of 1/4. For a weakly shear-thinning acrylic resin substrate, the same power laws persist, but dendritic structures emerge, and the texture of the precursor film roughens. The observed roughness and growth exponents (3/4 and 3/5) suggest a connection to the quenched Kardar-Parisi-Zhang universality class, hinting at the existence of quenched disorder in the liquid substrate. Mixing the resin with acrylic paint renders it more viscous and shear-thinning, refining the dendrite edges and further roughening the precursor film. At larger paint concentrations, the substrate becomes a power-law fluid. The roughness and growth exponents then approach 1/2 and 3/4, respectively, deviating from known universality classes. The ensuing structures have a fractal dimension of 1.68, characteristic of diffusion-limited aggregation. These findings underscore how the nonlinear rheological properties of the liquid substrate, coupled with the Laplacian nature of Marangoni spreading, can overshadow the local kinetic roughening of the droplet interface.
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  • 文章类型: Journal Article
    A general feature of mature biofilms is their highly heterogeneous architecture that partitions the microbial city into sectors with specific micro-environments. To understand how this heterogeneity arises, we have investigated the formation of a microbial community of the model organism Bacillus subtilis. We first show that the growth of macroscopic colonies is inhibited by the accumulation of ammoniacal by-products. By constraining biofilms to grow approximately as two-dimensional layers, we then find that the bacteria which differentiate to produce extracellular polymeric substances form tightly packed bacterial chains. In addition to the process of cellular chaining, the biomass stickiness also strongly hinders the reorganization of cells within the biofilm. Based on these observations, we then write a biomechanical model for the growth of the biofilm where the cell density is constant and the physical mechanism responsible for the spreading of the biomass is the pressure generated by the division of the bacteria. Besides reproducing the velocity field of the biomass across the biofilm, the model predicts that, although bacteria divide everywhere in the biofilm, fluctuations in the growth rates of the bacteria lead to a coarsening of the growing bacterial layer. This process of kinetic roughening ultimately leads to the formation of a rough biofilm surface exhibiting self-similar properties. Experimental measurements of the biofilm texture confirm these predictions.
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  • 文章类型: Journal Article
    使用原子力显微镜技术在SiO2上溅射Au膜的室温生长过程中观察到了动态缩放行为。通过对粗糙度依赖性的分析,σ,表面粗糙度的能力,P(f),以及相关长度,ζ,在薄膜厚度上,h,粗糙度指数,α=0.9±0.1,增长指数,β=0.3±0.1,动态缩放指数,独立获得z=3.0±0.1。这些值表明,在室温下在SiO2上溅射沉积Au属于保守的生长过程,其中Au晶界扩散起主导作用。
    Dynamic scaling behavior has been observed during the room-temperature growth of sputtered Au films on SiO2using the atomic force microscopy technique. By the analyses of the dependence of the roughness, σ, of the surface roughness power,P(f), and of the correlation length,ξ, on the film thickness,h, the roughness exponent,α = 0.9 ± 0.1, the growth exponent,β = 0.3 ± 0.1, and the dynamic scaling exponent,z = 3.0 ± 0.1 were independently obtained. These values suggest that the sputtering deposition of Au on SiO2at room temperature belongs to a conservative growth process in which the Au grain boundary diffusion plays a dominant role.
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