greenhouse gases

温室气体
  • 文章类型: Journal Article
    中国原铝工业(PAI)的蓬勃发展带来了大量有害空气污染物(HAP)和温室气体(GHGs)的排放。通过使用生命周期评估和自下而上的方法,首次开发和探索了1990-2021年中国PAI中多种典型HAP和温室气体的综合排放清单。我们的结果表明,中国PAI的HAP和GHGs的时空排放趋势差异显著。常规大气污染物(包括SO2、NOx和颗粒物(PM)),自2007年以来,由于各种环境政策的实施,氟化物和全氟化合物(PFCs)得到了有效抑制;CO的排放,VOCs,CH4、重金属和CO2以出乎意料的不同速率增加。从空间分布的角度来看,河南,山西,贵州,广西和山东主导了中国PAI的排放,但是随着消费扩张和环境约束,PAI工厂开始向西北和西南地区扩展,这些地区拥有充足和廉价的电力资源,从而带来了显著的排放增加,特别是西北地区的常规大气污染物和西南地区的CO和VOCs。通过PAI排放的潜在驱动力,结果表明,不同阶段的管端控制措施对各阶段相关物种的减排起到了不同的作用,但其还原效果逐渐减弱。未来的减排应寻求生产技术和能源系统的潜在变化。在环境规制和资源禀赋的约束下,促进PAI的循环经济发展将是同时减少PAI中的HAP和GHGs排放的关键战略。
    The booming of China\'s primary aluminum industry (PAI) brought substantial emissions of hazardous air pollutants (HAPs) and greenhouse gases (GHGs). By using life cycle assessment and bottom-up method, a comprehensive emission inventory for multiple typical HAPs and GHGs from China\'s PAI during 1990-2021 was developed and explored for the first time. Our results show that spatial-temporal emissions trends of HAPs and GHGs from PAI in China diverse significantly. The conventional atmospheric pollutants (including SO2, NOx and particulate matter (PM)), fluoride and per fluorinated compound (PFCs) had been effectively suppressed since 2007 due to the implementation of various environmental policies; while, emissions of CO, VOCs, CH4, heavy metals and CO2 had increased at different rates unexpectedly. From the spatial distribution perspective, Henan, Shanxi, Guizhou, Guangxi and Shandong dominated the emissions of PAI in China, but with consumption expansion and environmental constrains, PAI plants start to expand to northwest and southwest areas where are richer in sufficient and cheaper power resources, thus bring significant emission increasing there, particular for conventional atmospheric pollutants in northwest and CO and VOCs in southwest China. By underlying driving forces of PAI emissions, results show that end-of-pipe control measures at various stages have played different roles to reduce emissions of the concerned species at each period, but its reduction effect diminished gradually. Future reduction should seek underlying changes in production technology and energy system. Under constrains of environmental regulation and resource endowment, promoting circular economic development for PAI would be a key strategy to reduce HAPs and GHGs emissions simultaneously in PAI.
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  • 文章类型: Journal Article
    背景:干燥的非洲森林通过隔离和储存碳,在缓解气候变化方面发挥着至关重要的作用,以及减少温室气体排放。尽管先前的研究强调了碳储量在这些生态系统中的重要性,几乎没有评估冠层覆盖和环境因素对非洲干森林碳储量的影响。本研究通过调查环境因素和植被覆盖对Desa森林碳储量的影响来解决这一知识差距,埃塞俄比亚北部独特且受威胁的非洲干旱森林生态系统。木本植被数据,死垃圾,草生物量,从57个地块收集土壤样本。在95%的置信水平(α=0.05)下进行了单向方差分析(ANOVA),以检查冠层覆盖和环境因素对各种池的碳储量的影响。
    结果:在确定的35种木本物种中,JuniperusProcera是最主要的,而CarissaedulisVahl和桉树是最不占优势的。平均总碳储量为92.89Mgha-1,贡献来自地上碳,地下碳,垃圾碳,草碳,和土壤有机碳。在碳库中,土壤有机碳的碳储量最高,占总数的76.8%,其次是地上生物量碳为17.7%。在海拔等级和冠层水平上发现了碳储量的显着变化,但在坡度和纵横因子上没有发现。
    结论:总之,发现海拔和冠层水平显着影响Desa森林的碳储量,为非洲干旱森林的保护和气候变化缓解工作提供有价值的见解。森林干预规划和管理策略应考虑不同环境变量和树冠水平的影响。
    BACKGROUND: Dry Afromontane forests play a vital role in mitigating climate change by sequestering and storing carbon, as well as reducing greenhouse gas emissions. Despite previous research highlighting the importance of carbon stocks in these ecosystems, the influence of canopy cover and environmental factors on carbon storage in dry Afromontane forests has been barely assessed. This study addresses this knowledge gap by investigating the effects of environmental factors and vegetation cover on carbon stocks in Desa\'a forest, a unique and threatened Afromontane dry forest ecosystem in northern Ethiopia. Data on woody vegetation, dead litter, grass biomass, and soil samples were collected from 57 plots. A one-way analysis of variance (ANOVA) was performed at a 95% confidence level (α = 0.05) to examine the influence of canopy cover and environmental factors on the carbon stocks of various pools.
    RESULTS: Among the 35 woody species identified, Juniperus procera was the most dominant, while Carissa edulis Vahl and Eucalyptus globulus were the least dominant. The average total carbon stock was 92.89 Mg ha-1, with contributions from aboveground carbon, below-ground carbon, litter carbon, grass carbon, and soil organic carbon. Among the carbon pools, soil organic carbon had the highest carbon stock, accounting for 76.8% of the total, followed by above-ground biomass carbon at 17.7%. Significant variations in carbon stocks were found across altitude class and canopy level but not slope and aspect factors.
    CONCLUSIONS: In summary, altitude and canopy level were found to significantly influence carbon stocks in Desa\'a forest, providing valuable insights for conservation and climate change mitigation efforts in dry Afromontane forests. Forest intervention planning and management strategies should consider the influence of different environmental variables and tree canopy levels.
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  • 文章类型: Journal Article
    人们普遍预计农业对全球环境的影响将继续扩大,受人口和经济增长以及饮食变化的驱动。这篇评论强调了气候变化是农业环境影响的另一个放大器,通过降低农业生产力,降低农用化学品的功效,土壤侵蚀加剧,加快作物病虫害的生长和扩大范围,增加土地清理。我们确定了气候变化加剧农业温室气体排放的多种途径,创造一个潜在的强大的气候变化强化反馈循环。气候变化带来的挑战强调了向可持续发展过渡的迫切需要,适应气候的农业系统。这需要投资,以加速采用提供多种好处的成熟解决方案,发现并扩大新的有益工艺和食品。
    Agriculture\'s global environmental impacts are widely expected to continue expanding, driven by population and economic growth and dietary changes. This Review highlights climate change as an additional amplifier of agriculture\'s environmental impacts, by reducing agricultural productivity, reducing the efficacy of agrochemicals, increasing soil erosion, accelerating the growth and expanding the range of crop diseases and pests, and increasing land clearing. We identify multiple pathways through which climate change intensifies agricultural greenhouse gas emissions, creating a potentially powerful climate change-reinforcing feedback loop. The challenges raised by climate change underscore the urgent need to transition to sustainable, climate-resilient agricultural systems. This requires investments that both accelerate adoption of proven solutions that provide multiple benefits, and that discover and scale new beneficial processes and food products.
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  • 文章类型: Journal Article
    甲烷(CH4)是一种有效的温室气体(GHG),其大气浓度自工业化前以来几乎增加了两倍。湿地占全球CH4排放量的很大一部分,然而,控制潮汐湿地CH4通量的大小和因素仍不确定。我们合成了来自美国周边潮汐沼泽的100个室和9个涡流协方差(EC)站点的CH4通量数据,以评估控制因素并改善对CH4排放的预测。这项工作包括创建一个基于温室气体通量的开源数据库(https://doi.org/10.25573/serc.14227085)。整个腔室和EC站点的年通量平均为26±53gCH4m-2year-1,中位数为3.9gCH4m-2year-1,只有25%的站点超过18gCH4m-2year-1。在每日最高温度正常值(MATmax)高于25.6°C的新鲜低聚盐碱位点观察到最高通量。紧随其后的是MATmax≤25.6°C的经常被淹没的低中新鲜低卤沼泽,和MATmax>19°C的中盐碱位点。配对室CH4通量和孔隙水生物地球化学的分位数回归表明,在硫酸盐浓度>4.7±0.6mM时,通量的第90百分位下降到5±3nmolm-2s-1以下,孔隙水盐度>21±2psu,或地表水盐度>15±3psu。跨站点,盐度是年度CH4通量的主要预测因子,在网站内,温度,毛初级生产力(3GPP),潮汐高度控制了diel和季节尺度的变异性。在迪尔尺度上,在预测CH4通量变化的重要性方面,3GPP先于温度,而在季节性尺度上观察到相反的情况。水位影响dielCH4通量的时间和途径,储存的CH4在低至涨潮时脉冲释放。本研究提供了改善潮汐沼泽CH4排放估算的数据和方法,支持蓝碳评估,完善国家和全球温室气体清单。
    Methane (CH4) is a potent greenhouse gas (GHG) with atmospheric concentrations that have nearly tripled since pre-industrial times. Wetlands account for a large share of global CH4 emissions, yet the magnitude and factors controlling CH4 fluxes in tidal wetlands remain uncertain. We synthesized CH4 flux data from 100 chamber and 9 eddy covariance (EC) sites across tidal marshes in the conterminous United States to assess controlling factors and improve predictions of CH4 emissions. This effort included creating an open-source database of chamber-based GHG fluxes (https://doi.org/10.25573/serc.14227085). Annual fluxes across chamber and EC sites averaged 26 ± 53 g CH4 m-2 year-1, with a median of 3.9 g CH4 m-2 year-1, and only 25% of sites exceeding 18 g CH4 m-2 year-1. The highest fluxes were observed at fresh-oligohaline sites with daily maximum temperature normals (MATmax) above 25.6°C. These were followed by frequently inundated low and mid-fresh-oligohaline marshes with MATmax ≤25.6°C, and mesohaline sites with MATmax >19°C. Quantile regressions of paired chamber CH4 flux and porewater biogeochemistry revealed that the 90th percentile of fluxes fell below 5 ± 3 nmol m-2 s-1 at sulfate concentrations >4.7 ± 0.6 mM, porewater salinity >21 ± 2 psu, or surface water salinity >15 ± 3 psu. Across sites, salinity was the dominant predictor of annual CH4 fluxes, while within sites, temperature, gross primary productivity (GPP), and tidal height controlled variability at diel and seasonal scales. At the diel scale, GPP preceded temperature in importance for predicting CH4 flux changes, while the opposite was observed at the seasonal scale. Water levels influenced the timing and pathway of diel CH4 fluxes, with pulsed releases of stored CH4 at low to rising tide. This study provides data and methods to improve tidal marsh CH4 emission estimates, support blue carbon assessments, and refine national and global GHG inventories.
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  • 文章类型: Journal Article
    医疗保健是温室气体的主要来源,因此,对这种对气候变化的贡献的考虑需要以能够为护理模式提供信息的方式进行量化。鉴于基于活动的财务数据的可用性,环境扩展投入产出(EEIO)分析可用于计算医疗保健活动的系统碳足迹,允许比较不同的患者护理途径。因此,我们量化并比较了两种常见护理路径对稳定型冠状动脉疾病患者的碳足迹,具有相似的临床结果:冠状动脉支架置入术和冠状动脉搭桥手术(CABG)。对这两种途径的医疗保健成本数据进行了分类,并通过将经济中的资金流与为支持所有相关活动而排放的温室气体联系起来来计算与该支出相关的碳足迹。与平均稳定患者CABG途径相关的全身碳足迹,在悉尼一家大型三级转诊医院,澳大利亚在2021-22年,二氧化碳排放量为11.5吨,比平均可比支架植入途径的2.4吨CO2-e足迹高4.9倍。这些数据表明,出于环境原因,应首选稳定冠状动脉疾病的支架置入途径,并引入EEIO分析作为一种实用工具,以协助医疗保健相关的碳足迹。
    Healthcare is a major generator of greenhouse gases, so consideration of this contribution to climate change needs to be quantified in ways that can inform models of care. Given the availability of activity-based financial data, environmentally-extended input-output (EEIO) analysis can be employed to calculate systemic carbon footprints for healthcare activities, allowing comparison of different patient care pathways. We thus quantified and compared the carbon footprint of two common care pathways for patients with stable coronary artery disease, with similar clinical outcomes: coronary stenting and coronary artery bypass surgery (CABG). Healthcare cost data for these two pathways were disaggregated and the carbon footprint associated with this expenditure was calculated by connecting the flow of money within the economy to the greenhouse gases emitted to support the full range of associated activities. The systemic carbon footprint associated with an average stable patient CABG pathway, at a large tertiary referral hospital in Sydney, Australia in 2021-22, was 11.5 tonnes CO2-e, 4.9 times greater than the 2.4 tonnes CO2-e footprint of an average comparable stenting pathway. These data suggest that a stenting pathway for stable coronary disease should be preferred on environmental grounds and introduces EEIO analysis as a practical tool to assist in health-care related carbon footprinting.
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  • 文章类型: Journal Article
    This consensus document addresses the reduction of the environmental impact of inhalers in Portugal. It was prepared by the Portuguese Council for Health and the Environment and the societies representing the specialties that account for these drugs\' largest volume of prescriptions, namely the Portuguese Society of Pulmonology, the Portuguese Society of Allergology and Clinical Immunology, the Portuguese Society of Pediatrics, the Portuguese Society of Internal Medicine, the Portuguese Association of General and Family Medicine and also a patient association, the Respira Association. The document acknowledges the significant impact of pressurized metered-dose inhalers on greenhouse gas emissions and highlights the need to transition to more sustainable alternatives. The carbon footprint of pressurized metered-dose inhalers and dry powder inhalers in Portugal was calculated, and the level of awareness among prescribing physicians on this topic was also estimated. Finally, recommendations were developed to accelerate the reduction of the ecological footprint of inhalers.
    Este documento de consenso aborda a redução do impacto ambiental dos inaladores em Portugal. Foi elaborado pelo Conselho Português para a Saúde e Ambiente e pelas sociedades que representam as especialidades com maior volume de prescrição destes medicamentos, nomeadamente a Sociedade Portuguesa de Pneumologia, a Sociedade Portuguesa de Alergologia e Imunologia Clínica, a Sociedade Portuguesa de Pediatria, a Sociedade Portuguesa de Medicina Interna e a Associação Portuguesa de Medicina Geral e Familiar em conjunto com uma associação de doentes, a Associação Respira. Reconhece-se o impacto significativo dos inaladores pressurizados doseáveis nas emissões de gases com efeito de estufa e a necessidade de transição para alternativas mais sustentáveis. Calculou-se a pegada de carbono dos inaladores pressurizados doseáveis e dos inaladores de pó seco em Portugal e estimou-se o nível de literacia dos médicos prescritores relativamente a este tema. Finalmente, foram elaboradas recomendações com o objetivo de acelerar a redução da pegada ecológica dos inaladores.
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  • 文章类型: Journal Article
    该研究表征了2020年12月至2021年11月之间温室气体(GHG)通量(CO2,CH4和N2O)的时空变化及其在印度喜马拉雅山麓亚热带湿地中的调节驱动因素。五个不同的栖息地(沼泽森林的M1草皮表面,M2-沼泽森林的平原表面,M3-带有小草的沼泽表面,M4-沼泽土地,拥有密集的大型植物,和具有稀疏植物的M5沼泽土地)进行了研究。我们进行了温室气体通量的原位测量,小气候(AT,ST,和SMC(v/v)),和土壤特性(pH,EC,N,P,K,和SOC)在所有栖息地类型中重复三次。在整个栖息地,CO2,CH4和N2O通量的范围分别为125至536mgm-2h-1,0.32至28.4mgm-2h-1和0.16至3.14mgm-2h-1。生境(M3和M5)表现出比其他生境更高的GHG通量。CH4通量遵循夏季>秋季>春季>冬季的层次结构。然而,CO2和N2O通量跟随夏季>春季>秋季>冬季。CO2通量主要受ST和SOC控制。然而,CH4和N2O通量主要受生境中ST和SMC(v/v)调节。在N2O通量的情况下,土壤P和EC在整个生境中也起着至关重要的作用。AT是控制整个栖息地所有温室气体通量的通用驱动器。结果强调,亚热带喜马拉雅湿地的长期温室气体通量监测对于准确预测近期的温室气体通量及其随气候变化而变化的性质已成为当务之急。
    The study characterized the temporal and spatial variability in greenhouse gas (GHG) fluxes (CO2, CH4, and N2O) between December 2020 and November 2021 and their regulating drivers in the subtropical wetland of the Indian Himalayan foothill. Five distinct habitats (M1-sloppy surface at swamp forest, M2-plain surface at swamp forest, M3-swamp surface with small grasses, M4-marshy land with dense macrophytes, and M5-marshy land with sparse macrophytes) were studied. We conducted in situ measurements of GHG fluxes, microclimate (AT, ST, and SMC(v/v)), and soil properties (pH, EC, N, P, K, and SOC) in triplicates in all the habitat types. Across the habitats, CO2, CH4, and N2O fluxes ranged from 125 to 536 mg m-2 h-1, 0.32 to 28.4 mg m-2 h-1, and 0.16 to 3.14 mg m-2 h-1, respectively. The habitats (M3 and M5) exhibited higher GHG fluxes than the others. The CH4 flux followed the summer > autumn > spring > winter hierarchy. However, CO2 and N2O fluxes followed the summer > spring > autumn > winter. CO2 fluxes were primarily governed by ST and SOC. However, CH4 and N2O fluxes were mainly regulated by ST and SMC(v/v) across the habitats. In the case of N2O fluxes, soil P and EC also played a crucial role across the habitats. AT was a universal driver controlling all GHG fluxes across the habitats. The results emphasize that long-term GHG flux monitoring in sub-tropical Himalayan Wetlands has become imperative to accurately predict the near-future GHG fluxes and their changing nature with the ongoing climate change.
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  • 文章类型: Journal Article
    背景:医生和患者都越来越意识到药物治疗对环境的影响。哮喘治疗模式向MART治疗(维持和缓解治疗)的转变会影响治疗相关的排放。吸入药物的碳足迹也与所用设备的类型有关。如今,最常用的含推进剂的加压计量吸入器(pMDI)的碳足迹通常比不含推进剂的干粉吸入器(DPI)和软雾吸入器高20-40倍。
    方法:我们使用已发布的市场吸入器生命周期分析和全面的2020年欧洲销售数据,分析了欧洲吸入药物的碳足迹。此外,我们对全球哮喘倡议(GINA)第2步的不同治疗方案的治疗相关排放进行了估算.
    结果:如果DPI优于pMDI,则有可能将吸入药物的碳足迹减少85%。欧盟pMDI的排放量估计为4.0兆吨二氧化碳当量(MTCO2e),如果使用DPI,则可以减少到0.6MTCO2e。在用DPI治疗中度哮喘时,在单一吸入器中按需联合使用吸入型皮质类固醇和长效β-激动剂,其年度碳足迹(0.8kgCO2e)明显低于传统的维持治疗,即单独使用吸入型皮质类固醇和按需短效β-激动剂(2.9kgCO2e).
    结论:人们已紧急呼吁医疗保健部门减少哮喘和慢性阻塞性肺疾病(COPD)患者的碳足迹,改用非推进剂吸入器可以将其治疗的碳足迹减少近20倍。
    BACKGROUND: Both physicians and patients are increasingly aware of the environmental impacts of medication. The shift of treatment paradigm towards MART-treatment (Maintenance and Reliever Therapy) in asthma affects the treatment-related emissions. The carbon footprint of inhaled medication is also tied to the type of the device used. Today the most commonly used propellant-containing pressurised metered-dose inhalers (pMDIs) have a carbon footprint typically 20-40-fold higher than propellant-free dry powder inhalers (DPIs) and soft mist inhalers.
    METHODS: We analysed the carbon footprint of inhaled medications in Europe using published life cycle analyses of marketed inhalers and comprehensive 2020 European sales data. In addition, we give an estimate on treatment-related emissions of different treatment regimens on Global Initiative for Asthma (GINA) step 2.
    RESULTS: There is potential to reduce the carbon footprint of inhaled medications by 85% if DPIs are preferred over pMDIs. Emissions from pMDIs in the EU were estimated to be 4.0 megatons of carbon dioxide equivalent (MT CO2e) and this could be reduced to 0.6 MT CO2e if DPIs were used instead. In the treatment of moderate asthma with DPI, an as-needed combination of inhaled corticosteroid and long-acting beta-agonist in a single inhaler had a substantially lower annual carbon footprint (0.8 kg CO2e) than the more traditional maintenance therapy with an inhaled corticosteroid alone with as-needed short-acting beta-agonist (2.9 kg CO2e).
    CONCLUSIONS: There has been an urgent call for healthcare to reduce its carbon footprint for appropriate patients with asthma and chronic obstructive pulmonary disease (COPD), changing to non-propellant inhalers can reduce the carbon footprint of their treatment by almost 20-fold.
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  • 文章类型: Journal Article
    预测未来气候需要整合来自广泛学科的知识和专业知识。预测必须考虑到可能取决于气候预测的气候变化缓解政策。这种相互依赖,或“圆形”,这意味着气候预测必须以温室气体(GHG)的排放为条件。长期预测也受到信息不对称的影响,因为用户无法使用跟踪记录来判断提供者的技能。聚合的问题,循环性,信息不对称可以使用具有联合结果空间的预测市场来解决,允许同时预测温室气体浓度和温度。具有高度细粒度的预测市场的可行性,联合结果空间在英国每月降雨量和温度的市场上进行了测试。实验表明,这些市场可以汇总具有相关专业知识的专家的判断,并建议类似结构的市场,视野更长,可以提供一种机制,为决策提供可靠的气候相关风险预测,规划,和风险披露。
    Predicting future climate requires the integration of knowledge and expertise from a wide range of disciplines. Predictions must account for climate-change mitigation policies which may depend on climate predictions. This interdependency, or \"circularity\", means that climate predictions must be conditioned on emissions of greenhouse gases (GHGs). Long-range forecasts also suffer from information asymmetry because users cannot use track records to judge the skill of providers. The problems of aggregation, circularity, and information asymmetry can be addressed using prediction markets with joint-outcome spaces, allowing simultaneous forecasts of GHG concentrations and temperature. The viability of prediction markets with highly granular, joint-outcome spaces was tested with markets for monthly UK rainfall and temperature. The experiments demonstrate these markets can aggregate the judgments of experts with relevant expertise, and suggest similarly structured markets, with longer horizons, could provide a mechanism to produce credible forecasts of climate-related risks for policy making, planning, and risk disclosure.
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  • 文章类型: Journal Article
    青藏高原特别容易受到气候变化的影响和人类活动造成的干扰。为了更好地了解高原土壤氮和硫循环与人类活动之间的相互作用,研究了0~20cm深度麦钦县3个土层土壤氮、硫密度分布特征及其影响因素,0-100厘米,本文讨论了0-180cm。结果表明,在0-180厘米的深度,Machin县的土壤氮密度在1.36至16.85kg/m2之间,而硫密度在0.37至4.61kg/m2之间。三个因素的影响-地质背景,土地利用现状,土壤类型对土壤氮和硫密度均极显著(p<0.01)。具体来说,土壤类型和地质背景等自然因素,连同人为因素,包括土地利用方式和放牧强度,被认为是导致土壤氮和硫密度空间变化的决定性因素。青藏高原的马钦县展示了天然的氮和硫汇;然而,监测外部氮和硫输入高、肥力保持能力低的地区向大气中排放的N2O和SO2至关重要,比如光秃秃的土地。在此基础上,土壤中氮和硫循环的时空变化及其源汇关系仍是未来研究的重点。
    The Qinghai-Tibet Plateau is particularly vulnerable to the effects of climate change and disturbances caused by human activity. To better understand the interactions between soil nitrogen and sulfur cycles and human activities on the plateau, the distribution characteristics of soil nitrogen and sulfur density and their influencing factors for three soil layers in Machin County at depths of 0-20 cm, 0-100 cm, and 0-180 cm are discussed in this paper. The results indicated that at depths of 0-180 cm, soil nitrogen density in Machin County varied between 1.36 and 16.85 kg/m2, while sulfur density ranged from 0.37 to 4.61 kg/m2. The effects of three factors-geological background, land use status, and soil type-on soil nitrogen and sulfur density were all highly significant (p < 0.01). Specifically, natural factors such as soil type and geological background, along with anthropogenic factors including land use practices and grazing intensity, were identified as decisive in causing spatial variations in soil nitrogen and sulfur density. Machin County on the Tibetan Plateau exhibits natural nitrogen and sulfur sinks; However, it is crucial to monitor the emissions of N2O and SO2 into the atmosphere from areas with high external nitrogen and sulfur inputs and low fertility retention capacities, such as bare land. On this basis, changes in the spatial and temporal scales of the nitrogen and sulfur cycles in soils and their source-sink relationships remain the focus of future research.
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