A complete framework of predicting the attributes of sea clutter under different operational conditions, specified by wind speed, wind direction, grazing angle, and polarization, is proposed for the first time. This framework is composed of empirical spectra to characterize sea-surface profiles under different wind speeds, the Monte Carlo method to generate realizations of sea-surface profiles, the physical-optics method to compute the normalized radar cross-sections (NRCSs) from individual sea-surface realizations, and regression of NRCS data (sea clutter) with an empirical probability density function (PDF) characterized by a few statistical parameters. JONSWAP and Hwang ocean-wave spectra are adopted to generate realizations of sea-surface profiles at low and high wind speeds, respectively. The probability density functions of NRCSs are regressed with K and Weibull distributions, each characterized by two parameters. The probability density functions in the outlier regions of weak and strong signals are regressed with a power-law distribution, each characterized by an index. The statistical parameters and power-law indices of the K and Weibull distributions are derived for the first time under different operational conditions. The study reveals succinct information of sea clutter that can be used to improve the radar performance in a wide variety of complicated ocean environments. The proposed framework can be used as a reference or guidelines for designing future measurement tasks to enhance the existing empirical models on ocean-wave spectra, normalized radar cross-sections, and so on.

In the fields of Security and Defense, explosive traces must be analyzed at the sites of the terrorist events. The persistence on surfaces of these traces depends on the sublimation processes and the interactions with the surfaces. This study presents evidence that the sublimation process of these traces on stainless steel (SS) surfaces is very different than in bulk quantities. The enthalpies of sublimation of traces of four highly energetic materials: triacetone triperoxide (TATP), 2,4-dinitrotoluene (DNT), 2,4,6-trinitrotoluene (TNT), and 1,3,5- trinitrohexahydro-s-triazine (RDX) deposited on SS substrates were determined by optical fiber coupled-grazing angle probe Fourier Transform Infrared (FTIR) Spectroscopy. These were compared with enthalpies of sublimation determined by thermal gravimetric analysis for bulk amounts and differences between them were found. The sublimation enthalpy of RDX was very different for traces than for bulk quantities, attributed to two main factors. First, the beta-RDX phase was present at trace levels, unlike the case of bulk amounts which consisted only of the alpha-RDX phase. Second, an interaction between the RDX and SS was found. This interaction energy was determined using grazing angle FTIR microscopy. In the case of DNT and TNT, bulk and traces enthalpies were statistically similar, but it is evidenced that at the level of traces a metastable phase was observed. Finally, for TATP the enthalpies were statistically identical, but a non-linear behavior and a change of heat capacity values different from zero was found for both trace and bulk phases.