fibers

纤维
  • 文章类型: Journal Article
    阿尼氏微塑料(MPs)被认为是对人类的重要暴露危害,尤其是在室内环境中。使用ExDoM2剂量学模型研究了人呼吸道(HRT)中MP的沉积和清除,改性以纳入MP纤维的沉积和清除。纤维沉积是通过纤维等效空气动力学直径计算的,使用它们的性能,如尺寸,密度和动态形状因子。对于直径为1μm和10μm的圆柱形(基础)和纵横比(纤维长度与基础直径的比率)为3、10和100的细长颗粒进行场景模拟。建模结果表明,由于大颗粒(纤维圆柱直径dp>0.1μm),最高的纤维沉积发生在胸外区域,而颗粒长度(通过长径比)主要影响较小的基础直径纤维(dp<0.1μm),这些纤维主要沉积在肺泡区域。ExDoM2剂量测定模型还用于使用不同微环境中的微塑料纤维和碎片浓度的实验数据来计算HRT中的纤维沉积。在具有最高纤维浓度(17.3±2.4纤维/m3)的微环境(总线)中计算暴露24小时后的最高沉积数量剂量(220纤维)。清除后,大部分(66.4%)的平均沉积纤维通过粘膜纤毛清除从呼吸道转移到食道,32.6%保留在呼吸道,1%进入血液,少量(0.0004%)转移到淋巴结。
    Αirborne microplastics (MPs) are considered an important exposure hazard to humans, especially in the indoor environment. Deposition and clearance of MPs in the human respiratory tract (HRT) was investigated using the ExDoM2 dosimetry model, modified to incorporate the deposition and clearance of MPs fibers. Fiber deposition was calculated via the fiber equivalent aerodynamic diameter determined using their properties such as size, density and dynamic shape factor. Scenario simulations were performed for elongated particles of cylindrical (base) diameters 1 μm and 10 μm and aspect ratios (ratio of fiber length to base diameter) 3, 10 and 100. Modelling results showed that the highest fiber deposition occurred in the extra-thoracic region due to large particles (fiber cylindrical diameter dp > 0.1 μm), whereas particle length (via the aspect ratio) had an influence mainly on smaller base-diameter fibers (dp < 0.1 μm) that deposited predominantly in the alveolar region. The ExDoM2 dosimetry model was also used to calculate fiber deposition in the HRT using experimental data for microplastic fiber and fragment concentrations in different microenvironments. The highest deposited number dose (220 fibers) after a 24-hour exposure was calculated in the microenvironment (bus) that had the highest fiber concentration (17.3 ± 2.4 fibers/m3). After clearance, the majority (66.4 %) of the average deposited fiber mass was transferred from the respiratory tract to the esophagus via mucociliary clearance, 32.6 % was retained in the respiratory tract, 1 % passed into the blood, and a very small amount (0.0004 %) was transferred to the lymph nodes.
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  • 文章类型: Journal Article
    纤维素层压板代表了天然材料和现代工程的显着融合,在可持续包装中提供广泛的多功能应用,建筑,和先进的材料。在这项研究中,使用环保方法开发了新型全纤维素层压板,在不需要溶剂(用于浸渍和/或部分溶解)的情况下堆叠新鲜再生的纤维素II薄膜,化学修饰,或树脂。彻底研究了这些全纤维素层压材料的结构和机械性能。这种简单且可扩展的过程导致透明层压板具有与普通塑料相当甚至优于普通塑料的卓越机械性能,单层的E模量高于9GPa,层压材料的E模量高于7GPa。这些层压材料是可延展的并且可以容易地图案化。根据层数,它们可以是薄的和柔性的(只有一层)或厚的和刚性的(有三层)。层压材料还掺杂有10重量%的不溶解的纤维而不损害其特性。这些创新的全纤维素层压板呈现出强大的,传统合成材料的环保替代品,从而弥合环境责任和高性能功能之间的差距。
    Cellulose laminates represent a remarkable convergence of natural materials and modern engineering, offering a wide range of versatile applications in sustainable packaging, construction, and advanced materials. In this study, novel all-cellulose laminates are developed using an environmentally friendly approach, where freshly regenerated cellulose II films are stacked without the need for solvents (for impregnation and/or partial dissolution), chemical modifications, or resins. The structural and mechanical properties of these all-cellulose laminates were thoroughly investigated. This simple and scalable procedure results in transparent laminates with exceptional mechanical properties comparable to or even superior to common plastics, with E-modulus higher than 9 GPa for a single layer and 7 GPa for the laminates. These laminates are malleable and can be easily patterned. Depending on the number of layers, they can be thin and flexible (with just one layer) or thick and rigid (with three layers). Laminates were also doped with 10 wt% undissolved fibers without compromising their characteristics. These innovative all-cellulose laminates present a robust, eco-friendly alternative to traditional synthetic materials, thus bridging the gap between environmental responsibility and high-performance functionality.
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  • 文章类型: Journal Article
    由于更好的可持续性和环保性能,基于生物聚合物的材料的应用正在增加。明胶纤维具有比表面积和高孔隙率,这就是为什么它们在医学和食品工业中的应用正在被研究。本文探讨了离心纺丝生产明胶纤维的潜力。用于纤维制备的明胶使用独特的酶方法从胶原蛋白(鸡副产品)的非传统来源获得。将纤维质量与由传统胶原蛋白组织产生的明胶制备的纤维质量进行了比较(猪,牛)。结果表明,与戊二醛蒸气交联的纤维即使与水接触也能保持其结构。使用交联剂控制溶胀能力和溶解度,同时保持纤维结构。相反,未交联的明胶纤维是水溶性的,由于高的表面体积比,促进水的渗透和溶解。扫描电子显微镜(SEM)提供了通过离心纺丝获得的明胶纤维的更清晰的形态图片。使用傅里叶变换红外光谱法(FTIR)分析取决于所用原料和交联剂的存在的结合量的差异。总体结果表明,鸡肉明胶是传统来源明胶的合适替代品,可用于制备食品和药品包装和涂层,纤维,或3D矩阵的生物打印。
    The application of biopolymer-based materials is increasing due to better sustainability and environmental protection properties. Gelatin fibers have a specific surface and high porosity, which is why their use in medicine and the food industry is being researched. This article explores the potential of centrifugal spinning to produce gelatin fibers. Gelatin for fiber preparation was obtained from a non-traditional source of collagen (chicken by-products) using a unique enzymatic process. The fiber quality was compared with those prepared from gelatins produced from traditional collagen tissues (porcine, bovine). The results showed that fibers cross-linked with glutaraldehyde vapor preserved their structure even in contact with water. Using a cross-linker controlled swelling ability and solubility while maintaining the fiber structure. On the contrary, uncross-linked gelatin fibers were water soluble due to a high surface-to-volume ratio, facilitating water penetration and dissolution. Scanning electron microscopy (SEM) provided a clearer picture of the morphology of gelatin fibers obtained by centrifugal spinning. Differences in the amount of bonding depending on the raw material used and the presence of a cross-linker were analyzed using Fourier transform infrared spectroscopy (FTIR). The overall results showed that chicken gelatin is a suitable alternative to gelatins from traditional sources and can be used for preparing food and pharmaceutical packaging and coatings, fibers, or bioprinting of 3D matrices.
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  • 文章类型: Journal Article
    流行病学和公共卫生问题主要依赖于对气体污染物的准确控制,需要高效的气体传感器设备检测有害气体。尽管在这个时代付出了许多努力,精确的,对气体的持续审查对于适当的气体选择性仍然难以捉摸,迅速响应和恢复时间,适当的可重复性,以及低成本。因此,纳米结构的建筑传感线索已经得到了广泛的关注,以通用的检测和传感程序。作为一种代表性的纳米结构,MXene系列已被广泛引入,通过提供大表面积来定制和增强传感器模式,可调表面化学,优越的导电性,化学稳定性,与柔性基板的兼容性,和多功能性的潜力。此外,它们可以以各种薄膜和分层设计的形式合成,纤维膜,和凝胶状结构,创造协同效应,可以提供卓越的气体传感性能。在这里,MXene纳米片作为气敏材料的合成和好处,与MXene基气体传感器在薄膜形成方面的过去到现在的进展相一致,纤维状,和凝胶状结构,全面审查。作为一个深入的参考,本概述可以阐明进一步推进基于MXene结构开发的气体传感器架构。
    Epidemiology and public health concerns have primarily relied on the accurate control of gas pollutants, requiring highly efficient gas sensor devices for detecting hazardous gases. Despite the dedication of many efforts in this era, the precise, continuous scrutiny of gases remains elusive for appropriate gas selectivity, prompt response and recovery time, proper repeatability, as well as low cost. Accordingly, nanostructured architectural sensing cues have received enormous attention toward versatile detection and sensing procedures. As a representational nanostructure, the MXene family has been widely introduced to tailor and augment sensor patterns by providing large surface area, tunable surface chemistry, superior electrical conductivity, chemical stability, compatibility with flexible substrates, and potential for multifunctionality. Additionally, they could be synthesized in various formations of film and layered designs, fibrous membranes, and gel-like structures, creating synergetic effects that can provide superior gas-sensing performance. Herein, the synthesis and benefits of MXene nanosheets as gas-sensitive materials, in tandem with the past-to-present progress of MXene-based gas sensors in the formation of films, fibrous, and gel-like configurations, are comprehensively reviewed. As an in-depth reference, the present overview could shed light on further advancing gas sensor architectures developed based on MXene structures.
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  • 文章类型: Journal Article
    塑料污染已成为全球面临的重大环境挑战,对生态系统和人类健康构成严重威胁。本研究旨在探索循环性之间的相互作用,可持续性以及位于黑海西部沿岸的淡水生态系统中的微塑料释放-杜兹斯,蒂尔基耶.采用整合环境科学的多学科方法,经济学,和政策分析,该研究调查了该地区塑料污染的现状,考虑到不同的土地利用和社会经济生活方式。在四个不同的季节进行,目前的研究确定了该地区微塑料的主要类型。纤维占主导地位,每个季节占86.7%,其次是电影和碎片,分别占7.7%和7.0%,分别。值得注意的是,聚乙烯(PE)和聚丙烯(PP)作为主要的聚合物类型出现。聚合物类型的分布在该地区不同的土地用途上有所不同,强调土地利用在塑造丰度聚合物组成方面的影响作用。污染综合评价,这反映在梅伦河的整体污染负荷指数(PLI)中,表明污染水平令人担忧(PLI>1)。最后,这项研究揭示了社会经济活动与季节性降水模式之间的关系,以及该地区的微塑料污染。这强调了针对特定地点的缓解措施对减少微塑料数量的重要性。最后,将可持续的做法纳入循环经济框架,促进蒂尔基耶经济发展与环境保护之间的和谐平衡。
    Plastic pollution has emerged as a significant environmental challenge worldwide, posing serious threats to ecosystems and human health. This study seeks to explore the interplay among circularity, sustainability, and the release of microplastics within the freshwater ecosystems situated along the western Black Sea coast- Düzce, Türkiye. Employing a multidisciplinary approach that integrates environmental science, economics, and policy analysis, the research examines the current state of plastic pollution in the region, considering diverse land uses and socio-economic lifestyles. Conducted over four different seasons, the current study identifies the prevailing types of microplastics in the region. Fibers dominate, comprising 86.7% in each season, followed by film and fragments at 7.7% and 7.0%, respectively. Notably, polyethylene (PE) and polypropylene (PP) emerges as the primary polymer types. The distribution of polymer types varies across different land uses within the region, emphasizing the influential role of land use in shaping the abundance polymer composition. The comprehensive assessment of pollution, as reflected in the overall pollution load index (PLI) of the Melen River indicating a concerning level of pollution (PLI>1). Finally, the study unveiled the relationship between socio-economic activities as well as the seasonal precipitation patterns, and microplastic contamination in the region. This underscored the importance of site-specific mitigation measures on reducing the amount of microplastics. Lastly, incorporating sustainable practices within the circular economy framework fosters a harmonious balance between economic development and environmental protection in Türkiye.
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  • 文章类型: Journal Article
    目的:木材包含不同的细胞类型,如纤维,气管和血管,定义其属性。研究细胞的形状,尺寸,和安排在显微镜图像是至关重要的理解木材的特点。通常,这涉及将样品浸渍(浸泡)在溶液中以分离细胞,然后将它们铺在载玻片上,用覆盖广阔区域的显微镜成像,捕获成千上万的细胞。然而,这些细胞经常在图像中聚集和重叠,使用标准的图像处理方法使分割变得困难和耗时。
    结果:在这项工作中,我们开发了一种自动深度学习分割方法,该方法利用一阶段YOLOv8模型对显微镜图像中浸渍的纤维和血管形式的白杨树进行快速准确的分割和表征。该模型可以分析32,640x25,920像素的图像,并展示了有效的细胞检测和分割,实现78%的MAP0.5-0.95。为了评估模型的稳健性,我们检查了已知较长纤维的转基因树系的纤维。结果与以前的手动测量相当。此外,我们创建了一个用于图像分析的用户友好的Web应用程序,并提供了在GoogleColab上使用的代码。
    结论:通过利用YOLOv8的进步,这项工作提供了一种深度学习解决方案,可以对适合实际应用的木材细胞进行有效的量化和分析。
    OBJECTIVE: Wood comprises different cell types, such as fibers, tracheids and vessels, defining its properties. Studying cells\' shape, size, and arrangement in microscopy images is crucial for understanding wood characteristics. Typically, this involves macerating (soaking) samples in a solution to separate cells, then spreading them on slides for imaging with a microscope that covers a wide area, capturing thousands of cells. However, these cells often cluster and overlap in images, making the segmentation difficult and time-consuming using standard image-processing methods.
    RESULTS: In this work, we developed an automatic deep learning segmentation approach that utilizes the one-stage YOLOv8 model for fast and accurate segmentation and characterization of macerated fiber and vessel form aspen trees in microscopy images. The model can analyze 32,640 x 25,920 pixels images and demonstrate effective cell detection and segmentation, achieving a mAP 0.5 - 0.95 of 78 %. To assess the model\'s robustness, we examined fibers from a genetically modified tree line known for longer fibers. The outcomes were comparable to previous manual measurements. Additionally, we created a user-friendly web application for image analysis and provided the code for use on Google Colab.
    CONCLUSIONS: By leveraging YOLOv8\'s advances, this work provides a deep learning solution to enable efficient quantification and analysis of wood cells suitable for practical applications.
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  • 文章类型: Journal Article
    骨缺损和损伤很常见,需要更好的解决方案来改善再生和骨整合。生物可吸收膜由于其高表面积和多功能性而在骨组织工程中具有巨大的潜力。在这种情况下,聚合物如聚(乳酸-羟基乙酸共聚物)(PLGA)可以与骨传导材料如羟基磷灰石(HA)纳米颗粒(NP)组合以产生具有增强的生物活性和骨再生的膜。旋转喷射纺丝(RJS)是生产这些复合膜的强大技术。这项研究提出了一种创新和有效的方法来获得具有连续纤维的PLGA-HA(NP)膜,该连续纤维含有均匀的HA(NP)分布。膜表现出稳定的热降解,允许HA(NP)定量。此外,PLGA-HA(NPs)呈现骨传导性,没有细胞毒性,与前成骨细胞培养时具有较高的细胞粘附性。这些发现证明了RJS产生PLGA-HA(NPs)膜的潜力,可轻松有效地应用于骨骼再生。
    Bone defects and injuries are common, and better solutions are needed for improved regeneration and osseointegration. Bioresorbable membranes hold great potential in bone tissue engineering due to their high surface area and versatility. In this context, polymers such as poly(lactic-co-glycolic acid) (PLGA) can be combined with osteoconductive materials like hydroxyapatite (HA) nanoparticles (NPs) to create membranes with enhanced bioactivity and bone regeneration. Rotary Jet spinning (RJS) is a powerful technique to produce these composite membranes. This study presents an innovative and efficient method to obtain PLGA-HA(NPs) membranes with continuous fibers containing homogeneous HA(NPs) distribution. The membranes demonstrated stable thermal degradation, allowing HA(NPs) quantification. In addition, the PLGA-HA(NPs) presented osteoconductivity, were not cytotoxic, and had high cell adhesion when cultured with pre-osteoblastic cells. These findings demonstrate the potential of RJS to produce PLGA-HA(NPs) membranes for easy and effective application in bone regeneration.
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  • 文章类型: Journal Article
    到目前为止,机织织物表面的粗糙度主要被研究为与皮肤接触时舒适度的关键特征。粗糙度的分析可以扩展到各种环境和应用,成为了解纺织材料如何与不同整理剂相互作用的重要工具,以及深入了解治疗的持久性和有效性。本研究全面研究了碱水解和壳聚糖涂层对涤纶机织物粗糙度的影响,利用新颖和适应的方法。该研究采用接触和光学方法来分析织物和纤维表面特性,强调粗糙度轮廓参数在理解材料变化后处理中的重要性。调查显示,机械作用,碱性介质,洗涤温度,和洗涤剂残留物有助于织物侵蚀和改性在洗涤过程中,壳聚糖涂层产生明显的表面不规则。对比分析表明,洗涤后织物粗糙度变化显著,而纤维粗糙度的变化是治疗特异性的。尽管由于处理而导致纤维粗糙度最初增加,它们的耐久性在洗涤后下降。这些发现强调了粗糙度分析在优化纺织品整理过程和洗涤周期中的重要性。影响舒适性和治疗效果。
    The roughness of woven fabric surface has so far been mainly investigated as a key characteristic of comfort in contact with the skin. The analysis of roughness can be extended to various contexts and applications, becoming an important tool for understanding how textile materials react in interaction with different finishing agents, as well as for gaining insight into the durability and effectiveness of treatments. This research presents a comprehensive study on the impact of alkaline hydrolysis and chitosan coating on the roughness of polyester woven fabric, utilizing both novel and adapted methods. The study employed contact and optical methods to analyze fabric and fiber surface characteristics, highlighting the significance of roughness profile parameters in understanding material changes post-treatment. The investigation revealed that mechanical action, alkaline medium, washing temperature, and detergent residues contribute to fabric erosion and modification during washing, with chitosan coatings creating pronounced surface irregularities. Comparative analysis showed significant fabric roughness changes post-washing, while fiber roughness changes were treatment specific. Despite initial increases in fiber roughness due to treatments, their durability decreased after washing. These findings emphasize the importance of roughness analysis in optimizing textile finishing processes and washing cycles, impacting both comfort and treatment efficacy.
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  • 文章类型: Journal Article
    微塑料污染已成为全球威胁,和水,作为污染物的主要“汇”,代表了人类暴露的重要来源。本研究旨在评估BirninKebbi钻孔水的安全性,尼日利亚,特别是关于微塑料污染。从选定区域的钻孔中收集水样,包括BayanKara,Malali,RafinAtiku,AlieroQuarters,GwadanGaji,FUBK起飞地点,Kalgo市场,还有Tarasa.使用玻璃纤维滤纸通过过滤从水样中提取微塑料,并随后进行光谱学和显微镜检查以确定浓度,形状,和聚合物类型。还计算了与微塑料相关的健康风险。结果表明,来自Tarasa的样品显示出最高的微塑料浓度(96.967颗粒/L),其次是BayanKara(92.70粒子/L),拉芬·阿提库(92.33粒子/升),GwadanGwaji(92.30颗粒/升),FUBK起飞现场(91.07颗粒/升),AlieroQuarters(90.43粒子/L),卡尔戈市场(88.00颗粒/升),和Malali(86.40颗粒/升)。最主要的形状是纤维(73%),其次是碎片(16%),泡沫(6%),和长丝(5%)。聚乙烯和聚酰胺,按照这个顺序,是最主要的聚合物,而聚苯乙烯是最不常见的。大多数风险评分被归类为III。从结果可以推断,钻孔水中的微塑料污染对城市的健康构成了危害。建议研究区域的钻孔水消费者在饮用前处理水,以减轻潜在的健康风险。
    Microplastic pollution has become a global menace, and water, being a major \"sink\" for pollutants, represents a significant source of human exposure. This study aimed to assess the safety of borehole water in Birnin Kebbi, Nigeria, specifically concerning microplastic pollution. Water samples were collected from boreholes in selected areas, including Bayan Kara, Malali, Rafin Atiku, Aliero Quarters, GwadanGaji, FUBK Takeoff Site, Kalgo Market, and Tarasa. Microplastics were extracted from the water samples through filtration using glass fiber filter papers, and were subsequently subjected to spectroscopy and microscopy to determine concentrations, shapes, and polymer types. Health risks associated with the microplastics were also calculated. The results revealed that the samples from Tarasa exhibited the highest concentrations of microplastics (96.967 particles/L), followed by Bayan Kara (92.70 particles/L), Rafin Atiku (92.33 particles/L), GwadanGwaji (92.30 particles/L), FUBK Takeoff Site (91.07 particles/L), Aliero Quarters (90.43 particles/L), Kalgo Market (88.00 particles/L), and Malali (86.40 particles/L). The most dominant shape was fibers (73 %), followed by fragments (16 %), foams (6 %), and filaments (5 %). Polyethylene and polyamide, in that order, were the most dominant polymers, while polystyrene was the least common. The majority of risk scores were classified as III. It can be inferred from the results that microplastic pollution in borehole water poses a health hazard in the city. Consumers of borehole water in the studied areas are advised to treat the water before consumption to mitigate potential health risks.
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  • 文章类型: Journal Article
    已检测到微塑料(MP)和人造纤维(AF)悬浮在大气中,然而,关于它们的经验数据仍然很少。本研究旨在调查两种丰富鸟类的消化系统和呼吸系统中MPs和AFs的存在。共同的房子马丁(DelichonUbicum)和共同的斯威夫特(Apusapus),在马德里社区内,西班牙。鉴于这些鸟的大部分时间都在空中飞行,在飞行过程中从事交配和睡眠等活动,该研究试图评估将这些鸟类用作悬浮大气MPs和AFs的生物指标的潜力。样品是从主要在2021年至2023年春季和夏季之间收集的鸟类尸体(N=24)中获得的。仅选择在最初的24小时内死亡且未喂食的个体进行检查以避免污染。MPs和AFS通过微型FTIR鉴定,表征和量化。结果显示,75%的鸟类在其呼吸和/或消化系统中表现出至少一种MP。所有确定的国会议员都是纤维,聚酯(PES)是最主要的(48%),其次是丙烯酸纤维(ACR;28%),和聚乙烯(PE;18%)。对于普通Swift,呼吸系统中的平均浓度为1.12±0.45MPs/样本和2.78±1.04AFs/样本,对于HouseMartin,为0.75±0.30MPs/样本和0.75±0.36AFs/样本。在消化系统中,对于普通雨燕,这些是1.92±0.72MPs/样本和3.42±0.69AFs/样本,豪斯马丁1.34±0.50MPs/标本和1.39±0.47AFs/标本。位于盛行风方向的人口密度高的鸟类收集区域显示,消化系统中的MP浓度明显更高。一起来看,这些发现证实了这些鸟类可能用作监测悬浮大气MPs和AFs的生物指标.
    Microplastics (MPs) and artificial fibers (AFs) have been detected suspended tens of meters above ground level in the atmosphere, yet empirical data on them remain scarce. This study aimed to investigate the presence of MPs and AFs in the digestive and respiratory systems of two abundant bird species, the Common House Martin (Delichon urbicum) and the Common Swift (Apus apus), within the Community of Madrid, Spain. Given that these birds spend the majority of their lives airborne, engaging in activities such as mating and sleeping during flight, the research sought to assess the potential of using these bird species as bioindicators for suspended atmospheric MPs and AFs. Samples were obtained from necropsies of birds (N = 24) collected primarily between spring and summer from 2021 to 2023. Only individuals that died within the initial 24-hour period and had not been fed were selected for examination to avoid contamination. MPs and AFS were identified by micro-FTIR, characterized and quantified. Results revealed that 75 % of the sampled birds exhibited at least one MPs in their respiratory and/or digestive system. All identified MPs were fibers, with polyester (PES) being the most predominant (48 %), followed by acrylic fibers (ACR; 28 %), and polyethylene (PE; 18 %). The average concentrations in the respiratory system were 1.12 ± 0.45 MPs/specimen and 2.78 ± 1.04 AFs/specimen for Common Swift and 0.75 ± 0.30 MPs/specimen and 0.75 ± 0.36 AFs/specimen for House Martin. In the digestive system, these were 1.92 ± 0.72 MPs/specimen and 3.42 ± 0.69 AFs/specimen for Common Swift, and 1.34 ± 0.50 MPs/specimen and 1.39 ± 0.47 AFs/specimen for House Martin. Birds collected areas with high population density located in the direction of the prevailing winds showed a concentration of MPs significantly higher in the digestive system. Taken together, these findings confirmed the potential use of these birds as bioindicators for monitoring of suspended atmospheric MPs and AFs.
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