Nanozyme activity is greatly weakened by the microenvironment and multidrug resistance of tumor cells. Hence, a bi-catalytic nanoplatform, which promotes the anti-tumor activity through \"charging empowerment\" and \"mutual complementation\" processes involved in enzymatic and pyroelectric catalysis, by loading ultra-small nanoparticles (USNPs) of pyroelectric ZnSnO3 onto MXene nanozyme (V2CTx nanosheets), is developed. Here, the V2CTx nanosheets exhibit enhanced peroxidase activity by reacting V3+ with H2O2 to generate toxic ·OH, accelerated by the near-infrared (NIR) light mediated heat effect. The resulting V4+ is then converted to V3+ by oxidizing endogenous glutathione (GSH), realizing an enzyme-catalyzed cycle. However, the cycle will lose its persistence once GSH is insufficient; nevertheless, the pyroelectric charges generated by ZnSnO3 USNPs continuously support the V4+/V3+ conversion and ensure nanoenzyme durability. Moreover, the hyperthermia arising from the V2CTx nanosheets by NIR irradiation results in an ideal local temperature gradient for the ZnSnO3 USNPs, giving rise to an excellent pyroelectric catalytic effect by promoting band bending. Furthermore, polarized charges increase the tumor cell membrane permeability and facilitate nanodrug accumulation, thereby resolving the multidrug resistance issue. Thus, the combination of pyroelectric and enzyme catalysis together with the photothermal effect solves the dilemma of nanozymes and improves the antitumor efficiency.

Sono-photodynamic therapy is hindered by the limited tissue penetration depth of the external light source and the quick recombination of electron-hole owing to the random movement of charge carriers. In this study, orthorhombic ZnSnO3 quantum dots (QDs) with piezo-photoelectronic effects are successfully encapsulated in hexagonal upconversion nanoparticles (UCNPs) using a one-pot thermal decomposition method to form an all-in-one watermelon-like structured sono-photosensitizer (ZnSnO3 @UCNPs). The excited near-infrared light has high penetration depth, and the watermelon-like structure allows for full contact between the UCNPs and ZnSnO3 QDs, achieving ultrahigh Förster resonance energy transfer efficiency of up to 80.30%. Upon ultrasonic and near-infrared laser co-activation, the high temperature and pressure generated lead to the deformation of the UCNPs, thereby driving the deformation of all ZnSnO3 QDs inside the UCNPs, forming many small internal electric fields similar to isotropic electric domains. This piezoelectric effect not only increases the internal electric field intensity of the entire material but also prevents random movement and rapid recombination of charge carriers, thereby achieving satisfactory piezocatalytic performance. By combining the photodynamic effect arising from the energy transfer from UCNPs to ZnSnO3 , synergistic efficacy is realized. This study proposes a novel strategy for designing highly efficient sono-photosensitizers through structural design.

In this study, pure zinc stannate (ZnSnO3) and bismuth (Bi)-doped ZnSnO3 composites (Bi-ZnSnO3) were synthesized via the in situ precipitation method, and their microstructures, morphologies, chemical components, sizes, and specific surface areas were characterized, followed by testing their gas sensing properties. The results revealed that Bi-ZnSnO3 showed superior gas sensing properties to n-butanol gas, with an optimal operating temperature of 300 °C, which was 50 °C lower than that of pure ZnSnO3. At this temperature, moreover, the sensitivity of Bi-ZnSnO3 to n-butanol gas at the concentration of 100 ppm reached as high as 1450.65, which was 35.57 times that (41.01) of ammonia gas, 2.93 times that (495.09) of acetone gas, 6.02 times that (241.05) of methanol gas, 2.54 times that (571.48) of formaldehyde gas, and 2.98 times that (486.58) of ethanol gas. Bi-ZnSnO3 had a highly repeatable performance. The total proportion of oxygen vacancies and chemi-adsorbed oxygen in Bi-ZnSnO3 (4 wt%) was 27.72% to 32.68% higher than that of pure ZnSnO3. Therefore, Bi-ZnSnO3 has considerable potential in detecting n-butanol gas by virtue of its excellent gas-sensing properties.

In this work, the gas-sensing functionality of porous ceramic bodies formed by the slip casting technique was studied using perovskite nanoparticles of an MSnO3 system (M = Ba, Ca, Zn) synthesized by a chemical route. The performance and reliability of the sensitive materials in the presence of different volatile organic compounds (acetone, ethanol, and toluene), and other gases (CO, H2 and NO2) were analysed. The ZnSnO3, BaSnO3, and CaSnO3 sensors showed sensitivities of 40, 16, and 8% ppm-1 towards acetone, ethanol, and toluene vapours, respectively. Good repeatability and selectivity were also observed for these gaseous analytes, as well as excellent stability for a period of 120 days. The shortest response times were recorded for the ZnSnO3 sensors (e.g., 4 s for 80 ppm acetone) with marked responses to low concentrations of acetone (1000 ppb). These results are attributed to the porosity of the sensitive materials, which favours the diffusion of gases, induces surface defects, and provides greater surface area and good sensitivity to acetone, as is seen in the case of ZnSnO3.

The current trend for smart, self-sustainable, and multifunctional technology demands for the development of energy harvesters based on widely available and environmentally friendly materials. In this context, ZnSnO3 nanostructures show promising potential because of their high polarization, which can be explored in piezoelectric devices. Nevertheless, a pure phase of ZnSnO3 is hard to achieve because of its metastability, and obtaining it in the form of nanowires is even more challenging. Although some groups have already reported the mixing of ZnSnO3 nanostructures with polydimethylsiloxane (PDMS) to produce a nanogenerator, the resultant polymeric film is usually flat and does not take advantage of an enhanced piezoelectric contribution achieved through its microstructuration. Herein, a microstructured composite of nanowires synthesized by a seed-layer free hydrothermal route mixed with PDMS (ZnSnO3@PDMS) is proposed to produce nanogenerators. PFM measurements show a clear enhancement of d33 for single ZnSnO3 versus ZnO nanowires (23 ± 4 pm/V vs 9 ± 2 pm/V). The microstructuration introduced herein results in an enhancement of the piezoelectric effect of the ZnSnO3 nanowires, enabling nanogenerators with an output voltage, current, and instantaneous power density of 120 V, 13 μA, and 230 μW·cm-2, respectively. Even using an active area smaller than 1 cm2, the performance of this nanogenerator enables lighting up multiple LEDs and other small electronic devices, thus proving great potential for wearables and portable electronics.

The trade-off between performance and stability in amorphous oxide semiconductor-based thin-film transistors (TFTs) has been a critical challenge, meaning that it is difficult to simultaneously achieve high mobility and stability under bias and light stresses. Here, an amorphous mixture of two indium-free BaSnO3 and ZnSnO3 compounds, a-(Zn,Ba)SnO3, is proposed as a feasible strategy to achieve high mobility and stability at the same time. The choice of BaSnO3 as a counterpart to ZnSnO3, a well-known In-free candidate in amorphous oxide semiconductors, is to improve structural order and oxygen stoichiometry due to the large heat of formation and to preserve electron mobility due to the same kind of octahedral Sn-O network. Our first-principles calculations indeed show that compared to pure a-ZnSnO3, BaSnO3 plays a crucial role in restoring structural order in both stoichiometric and O-deficient supercells without seriously damaging the conduction band minimum. The resulting features of a-(Zn,Ba)SnO3 reduce O-deficiency and the valence band tail states, which are known to be critically associated with instability. It is experimentally demonstrated that a-(Zn,Ba)SnO3-based TFTs simultaneously exhibit high mobility (>20 cm2 V-1 s-1) and remarkable stability against negative bias illumination stress (ΔVth: <0.9 V). Our results suggest that a-(Zn,Ba)SnO3 would be a strong In-free candidate for next-generation TFT display, replacing the conventional a-InGaZnO4.

ZnSnO3 semiconductor nanostructures have several applications as photocatalysis, gas sensors, and energy harvesting. However, due to its multicomponent nature, the synthesis is far more complex than its binary counter parts. The complexity increases even more when aiming for low-cost and low-temperature processes as in hydrothermal methods. Knowing in detail the influence of all the parameters involved in these processes is imperative, in order to properly control the synthesis to achieve the desired final product. Thus, this paper presents a study of the influence of the physical parameters involved in the hydrothermal synthesis of ZnSnO3 nanowires, namely volume, reaction time, and process temperature. Based on this study a growth mechanism for the complex Zn:Sn:O system is proposed. Two zinc precursors, zinc chloride and zinc acetate, were studied, showing that although the growth mechanism is inherent to the material itself, the chemical reactions for different conditions need to be considered.

A self-powered device for human activity monitoring and energy harvesting for Internet of Things (IoT) devices is proposed. The self-powered device utilizes flexible Nano-generators (NGs), flexible diodes and off-the-shelf capacitors. During footsteps the NGs generate an AC voltage then it is converted into DC using rectifiers and the DC power is stored in a capacitor for powering the IoT devices. Polydimethylsiloxane (PDMS) and zinc stannate (ZnSnO₃) composite is utilized for the NG active layer, indium tin oxide (ITO) and aluminum (Al) are used as the bottom and top electrodes, respectively. Four diodes are fabricated on the bottom electrode of the NG and connected in bridge rectifier configuration. A generated voltage of 18 Vpeak was achieved with a human footstep. The self-powered smart device also showed excellent robustness and stable energy scavenger from human footsteps. As an application we demonstrate human activity detection and energy harvesting for IoT devices.

Polarization and conduction loss play fundamentally important roles in the nonmagnetic microwave absorption process. In this paper, a uniform and monodisperse hollow ZnSnO3 cube wrapped by multiwalled carbon nanotubes (ZSO@CNTs) was successfully synthesized via facile hydrothermal treatment. A reasonable mechanism related to Ostwald ripening was proposed to design the varied ZSO@CNTs for the special hollow conductive network. Scanning electron microscopy images clearly indicate that reaction temperature is the key factor for the composite structure, which has a significant effect on its electromagnetic properties. Electron holography proves the inhomogeneous distribution of charge density in the ZSO@CNT system, leading to the occurrence of interface polarization. Complex permittivity properties of ZSO@CNT composites under different reaction temperatures were investigated to optimize the morphology that can distinctly enhance microwave absorption performance. The maximum reflection loss that the ZSO@CNT-130 °C composite can reach is -52.1 dB at 13.5 GHz, and the absorption bandwidths range from 11.9 to 15.8 GHz with a thickness as thin as 1.6 mm. Adjusting the simulation thicknesses from 1 to 5 mm, the efficient absorption bandwidth (RL < -10 dB) that the ZSO@CNT composite could reach was 14.16 GHz (88.8% of 2-18 GHz). The excellent microwave absorption performance may be attributed to the synergistic effects of polarization, conduction loss, and special hollow cage structure. It is proposed that the specially controlled structure could provide an effective path for achieving a high-performance microwave absorber.