Per- and polyfluoroalkyl substances (PFAS) are ubiquitous contaminants which are also found in drinking water. Concentration levels in drinking water vary widely and range from a very low contribution to total daily exposure for humans to being the major source of uptake of PFAS. PFAS concentrations in Norwegian drinking water has been rarely reported. We investigated concentrations of 31 PFAS in 164 water samples, representing both source water (i.e., before drinking water treatment) and finished drinking water. Samples were taken from 18 different water bodies across Norway. The 17 waterworks involved supply drinking water to 41 % of the Norwegian population. Only four of the waterworks utilised treatment involving activated carbon which was able to significantly reduce PFAS from the source water. Samples of source water from waterworks not employing activated carbon in treatment were therefore considered to represent drinking water with regards to PFAS (142 samples). All samples from one of the water bodies exceeded the environmental quality standard (EQS) for perfluorooctane sulfonic acid (PFOS) according to the water framework directive (0.65 ng/L). No concentrations exceeded the sum of (20) PFAS (100 ng/L) specified in the EU directive 2020/2184 for drinking water. Several EU countries have issued lower guidelines for the sum of the four PFAS that the European Food Safety Authority (EFSA) has established as the tolerable weekly intake (TWI) for PFOS, perfluorooctanoic acid (PFOA), perfluorononanoic acid (PFNA), and perfluorohexane sulfonic acid (PFHxS). Denmark and Sweden have guidelines specifying 2 and 4 ng/L for the sum of these PFAS. Only one of the 142 drinking water samples exceeded the Danish TWI and contained a sum of 6.6 ng/L PFAS. A population exposure model, for individuals drinking water from the investigated sources, showed that only 0.5 % of the population was receiving PFAS concentrations above the Danish limit of 2 ng/L.

This article concerns UK commercial fruit and vegetable growers\' narratives regarding the sustainability of water use for food production. In it we explore their perspectives on efforts by regulators to limit agricultural withdrawals of water from the natural environment in line with EU Water Framework Directive objectives, alongside their views on retailer sustainability commitments. Discourse analysis is used to investigate how the growers contested restrictive regulation, constructed their identities, portrayed other supply chain stakeholders, and conveyed their social relations with them. Using Erving Goffman\'s theory of frontstage and backstage performances, the implications for the growers\' water management decisions and their internalisation of sustainability agendas for water are examined. Whilst the growers gave accounts of purposely misrepresenting their water withdrawal practices and their discourse illustrated significant polarisation between environmental and agricultural interests, their underlying commitment to environmental sustainability was ambivalent, with both anti and pro-environmental attitudes expressed. The growers also frequently gave critiques of superficial sustainability in fresh produce supply chains. We argue that, given contemporary shifting definitions of agricultural identities, settings in which their construction is negotiated can provide windows of opportunity for conventional growers to engage in genuine pro-environmental performances that may deepen their assimilation of environmental goals and commitment to sustainable water use.

The deterioration of superficial water quality is a significant concern in water management. Currently, most European rivers do not achieve qualitative standards defined by Directive 2000/60/EC (Water Framework Directive, WFD), while the health status of many surface water bodies remains unknown. Within this context, we propose a new methodology to perform a semi-quantitative analysis of the pressure state of a river, starting from easily accessible data related to anthropic activities. The proposed approach aims to address the endemic scarcity of monitoring records. This study proposes a procedure to (i) evaluate the relative pressure of different human activities, (ii) identify allocation points of different pollutant sources along the river using a raster-based approach, and (iii) determine a spatial biochemical water quality index. The developed index expresses the overall biochemical state of surface water induced by pollutant sources that may simultaneously impact a single river segment. This includes establishments under the so-called Seveso Directive, activities subjected to the IPPC-IED discipline, wastewater treatment plants, and contaminated sites. The methodology has been tested over three rivers in Northern Italy, each exposed to different industrial and anthropogenic pressures: Reno, Enza, and Parma. A comparison with monitored data yielded convincing results, proving the consistency of the proposed index in reproducing the spatial variability of the river water quality. While additional investigations are necessary, the developed methodology can serve as a valuable tool to support decision-making processes and predictive studies in areas lacking or having limited water quality monitoring data.

The identification of ecologically sound thresholds represents an important step toward improving the ecological status of rivers through appropriate measures to contain nutrient loads. The aim of the present study was to estimate phosphorus and nitrogen concentrations compatible with the achievement of the \"good\" ecological status of rivers from data collected in the Po River District, the largest hydrographic system in Italy. For this purpose, relationships between the diatom index used in Italy for the national assessment of the stream ecological status, the ICMi (Intercalibration Common Metric index), and total phosphorus and nitrate concentrations were analyzed using monitoring data collected between 2009 and 2019. The Po River Basin encompasses five distinct river types, from Alpine to Mediterranean to Lowlands, characterized by different anthropogenic pressures and water quality. Through regression analysis between the ICMi and nutrient concentrations, we estimated ranges of the latter values corresponding to a \"good\" ecological status for each river type. The resulting thresholds are far more stringent than the limits set by the Italian legislation for water quality classification. This is particularly true for total phosphorus, whose threshold value should be roughly halved for all river types. For nitrates, the results are more differentiated according to river type: the estimated thresholds are much more stringent than those currently in use for siliceous Alpine and Mediterranean rivers. Moreover, the availability of such a large database allowed also to assess the influence of one nutrient over the other on the diatom community and to highlight some critical issues in the formulation of ICMi for Mediterranean rivers.

The levels of metals in the waters of the Mar Menor lagoon are higher in the southern than in the northern zone both in the dissolved (As: 1.78 μg L-1 north vs 1.86 μg L-1 south; Cd: 0.020 μg L-1 vs 0.055 μg L-1; Pb: 0. 686 μg L-1 vs 2.714 μg L-1; Zn: 3.06 μg L-1 vs 10.2 μg L-1) as in the particulate fraction (As: 13.6 μg g-1 north vs 27.3 μg g-1 south; Cd: 0.510 μg g-1 vs 2.11 μg g-1; Pb: 146 μg g-1 vs 575 μg g-1; Zn: 266 μg g-1 vs 729 μg g-1). This difference is associated to the influence of historical and recent inputs from the Sierra Minera Cartagena -La Unión located south of the lagoon. Strong winds cause sediment resuspension in this shallow lagoon, increasing metal levels in the dissolved (twofold) and especially in the particulate fraction (threefold) because the resuspended sediments are rich in metals. Distribution among dissolved and particulate fraction is determined by the chemistry of each element and salinity. This increase causes the levels to reach limits very close to those established by the Water Framework Directive, especially in the case of lead, whose annual average level of 1.23 μg L-1 is very close to the 1.3 μg L-1 established in the Directive. Therefore, slight change in environmental variables could make Pb levels to exceed legal limits. Future work should focus on investigating how unique environmental events, enhanced by global change, affect metal cycles in highly anthropised coastal areas.

Bridging applied ecology and ecotoxicology is key to protect ecosystems. These disciplines show a mismatch, especially when evaluating pressures. Contrasting to applied ecology, ecotoxicological impacts are often characterized for whole species assemblages based on Species Sensitivity Distributions (SSDs). SSDs are statistical models describing per chemical across-species sensitivity variation based on laboratory toxicity tests. To assist in the aligning of the disciplines and improve decision-support uses of SSDs, we investigate taxonomic-group-specific SSDs for algae/cyanobacteria/aquatic plants, invertebrates, and vertebrates for 180 chemicals with sufficient test data. We show that splitting improves pollution impact assessments for chemicals with a specific mode of action and, surprisingly, for narcotic chemicals. We provide a framework for splitting SSDs that can be applied to serve in environmental protection, life cycle assessment, and management of freshwater ecosystems. We illustrate that using split SSDs has potentially large implications for the decision-support of SSD-based outputs around the globe.

Eutrophication impairs lake ecosystems at a global scale. In this context, as benthic microalgae are well-established warnings for a large range of stressors, particularly nutrient enrichment, the Water Framework Directive required the development of diatom-based methods to monitor lake eutrophication. Here, we present the diatom-based index we developed for French lakes, named IBDL (Indice Biologique Diatomées en Lacs). Data were collected in 93 lakes from 2015 to 2020. A challenge arose from the discontinuous pressure gradient of our dataset, especially the low number of nutrient-impacted lakes. To analyze the data we opted for the so-called \"Threshold Indicator Taxa ANalysis\" method, which makes it possible to determine a list of \"alert taxa.\" We obtained a multimetric index based on specific pressure gradients (Kjeldahl nitrogen, suspended matter, biological oxygen demand, and total phosphorous). Considering the European intercalibration process, the very good correlation between IBDL and the common metric (R2 from 0.52 to 0.87 according to the lake alkalinity type) makes us very confident in our ability to match future IBDL quality thresholds with European standards. The IBDL proved at last to be particularly relevant as it has a twofold interest: an excellent relationship with total phosphorus (R2 from 0.63 to 0.83 according to the lake alkalinity type) and a possible application to any lake metatype. Its complementarity with macrophyte-based indices moreover justifies the use of at least two primary producer components for lake ecological status classification.

The European Water Framework Directive (WFD) is one of the most studied environmental legislations and recently turned twenty. The paper deals with a literature search and analysis of 4120 references related to this Directive. After a period of strong increase in article production (2002-2012) WFD scientific productivity is currently still high (~ 260 papers year-1), suggesting a persistent interest of the scientific community on this issue. Most research supporting the WFD was on water sciences, but contributions were also from governance and socio-economic disciplines. Studies on biological quality elements and rivers were prominent. The WFD implementation has seen a strong participation of scientists from all EU countries, and partially also from outside-EU nations. To improve the EU water policy and management, the paper suggests a greater interconnection between WFD and other EU Directives and indicates some emerging environmental issues to which the Directive should address.

The possibilities of expanding a groundwater quality monitoring scheme by passive sampling using polar organic chemical integrative sampler (POCIS) comprising HLB sorbent as the receiving phase were explored. Passive sampling and grab sampling were carried out simultaneously in the regions with vulnerable groundwater resources in Slovakia, between 2013 and 2021. For 27 pesticides and degradation products detected both in POCIS and the grab samples, in situ sampling rates were calculated and statistically evaluated. The limited effectiveness of the receiving phase in POCIS for sampling polar or ionized compounds was confirmed through a comparison of the medians of compound-specific sampling rates. For the majority of the monitored compounds the median sampling rates varied between 0.01 and 0.035 L/day. In some cases, the actual in situ values could be confirmed by parallel exposure of POCIS and silicone rubber sheet employed to obtain a benchmark for maximum attainable sampling rate. Sampling site and sampling period appear to have also some influence on the sampling rates, which was attributed in part to the groundwater velocity varying in both space and time. The influence of physico-chemical parameters (temperature, pH, electrolytic conductivity) remains mostly questionable due to the naturally limited ranges of recorded values over the entire duration of the study. Concentrations of pollutants in POCIS could be used for predicting time weighed average concentrations in water, provided the sampling rates were known and relatively constant. Generally, the compound-specific sampling rate cannot be considered constant due to a combination of naturally varying environmental factors that influence the actual in situ sampling rate. The relative standard deviation of concentration data from POCIS exposed in triplicates varied between approx. 5 %-50 %. Utilizing exploratory data analysis approach and tools enabled us to obtain a relatively complex picture of the situation and progress regarding pesticide pollution of groundwater in the monitored areas.

Ecosystem responses to increasing human pressures are complex and diverse, affecting organisms across all trophic levels. This has prompted the development of methods that integrate information across many indicators for environmental management. Legislative frameworks such as the European Water Framework Directive (WFD), specifically prescribe that integrated assessme nt (IA) of ecological status must consider indicators representing various biological and supporting quality elements. We present a general approach for an IA system based on a piece-wise linear transformation of indicator distributions to a standardized scale, allowing for integrating information from multiple and diverse indicators through a policy-dependent aggregation scheme. Uncertainties associated with monitoring data used for calculating indicators and their propagation throughout the integration scheme allow for confidence assessment at all levels of the hierarchical integration. Specific pressures leading to ecological impact can be identified through the most impaired indicators in the hierarchical and transparent aggregation scheme. The IA and its confidence are facilitated though the development of an online tool that accesses information from monitoring databases and presents the outcome at all levels of the assessment, ensuring consistency and transparency in the calculations for all potential stakeholders. We demonstrate the versality and applicability of the approach using indicators and aggregation principles from the Swedish national guidelines for assessing ecological status of rivers, lakes and coastal waters according to the WFD. Although the approach and the tool were developed specifically for the WFD ecological status assessment in Sweden, the generality of the approach implies that it can easily be adapted to the WFD assessment methods of other countries as well as other policies, where an integrated assessment is required.