Super absorbent polymer (SAP)

高吸水性聚合物 (SAP)
  • 文章类型: Journal Article
    随着印度社会和医学对月经卫生的认识不断提高,对卫生巾的需求显着增加。利用高质量和环保的原材料来生产这些垫进一步支持了市场的增长。然而,随着需求和使用的改善,对适当处置技术的需求变得更加相关,因为所有这些垫子都被人体血液污染,这使得它们具有生物危害,并可能对人类健康和环境造成重大损害。一个卫生垫需要大约800年才能自然降解,而卫生垫中的塑料和超吸收聚合物(SAP)是不可生物降解的,可能需要几十年才能降解。废物管理技术,如热解,气化,可以采用资源回收来管理吨卫生废物。目前,卫生废物处理主要集中在填埋,焚化,堆肥,生物危害废物与数吨固体废物混合在一起。一次性卫生垫具有每年约5.3kgCO2当量的高碳足迹。手稿中讨论了用于卫生垫处理的创新解决方案,其中包括将衍生的废纤维素和塑料部分重新用于增值产品。系统讨论了消毒策略的未来方面以及从餐巾纸中回收的废纤维素的增值,以促进循环经济。
    With ever-improving social and medical awareness about menstrual hygiene in India, the demand for sanitary napkins has increased significantly. The utilization of high-quality and environment-friendly raw materials to produce these pads is further supporting the growth of the market. However, with improving demand and usage, the need for proper disposal techniques becomes more relevant, since all of these pads get contaminated with human blood which makes them a biohazard and can cause significant damage to human health and the environment. One sanitary pad takes around 800 years to degrade naturally and the plastic and super absorbent polymers (SAPs) in sanitary pads are non-biodegradable and can take multiple decades to degrade. Waste management technologies such as pyrolysis, gasification, and resource recovery can be adopted to manage tons of sanitary waste. Currently, sanitary waste treatment mainly focuses on landfilling, incineration, and composting, where biohazard wastes are mixed with tons of solid waste. Disposable sanitary pads have a high carbon footprint of about 5.3 kg CO2 equivalent every year. Innovative solutions for sanitary pad disposal are discussed in the manuscript which includes repurposing of derived waste cellulose and plastic fraction into value-added products. Future aspects of disinfection strategies and value addition to waste cellulose recovered from napkins were systematically discussed to promote a circular economy.
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  • 文章类型: Journal Article
    本文旨在解决北方冬季在路面混凝土上喷洒除冰盐引起的材料耐久性问题。采用高吸水性聚合物(SAP)作为内固化剂,以增强路面混凝土的耐久性。在砂浆试验的基础上,采用灰靶决策法优化了固化参数,包括SAP的粒径和用量以及固化条件。通过快速冻融试验,探讨了盐冻融循环后不同SAP用量内养护路面混凝土耐久性能和力学性能的劣化规律。结合孔隙结构特征,水化和微观结构,揭示了SAP对路面混凝土耐盐冻融性能的影响机理。实验结果表明:(i)采用中剂量的SAP内固化显著提高了质量损失率和相对动态模量的降低;(ii)试样经历的冻融循环次数越多,强度增加越大;(iii)经过75个循环后,氯离子侵蚀深度可减少约23.18%。此外,SAP的加入可以细化孔径,抑制收缩微裂纹的产生,促进后期水泥水化程度,提高了水泥混凝土结构的内密度。因此,降低了盐冻融耦合作用下路面的劣化。
    This paper aims at solving the material durability problem caused by spraying deicing salt on pavement concrete in the northern winter. Super absorbent polymer (SAP) was adopted as an internal curing agent to enhance the durability of pavement concrete. Curing parameters including particle size and dosage of SAP and curing condition were optimized based on mortar tests by means of the grey target decision method. The deterioration rule of durability and mechanical properties of pavement concrete internally cured by different SAP dosages after salt freeze-thaw cycles were explored through rapid freeze-thaw test. Combined with the characteristics of pore structure, hydration and microstructure, the influence mechanism of SAP on the salt freeze-thaw resistance of pavement concrete was revealed. The experimental results showed that: (i) The reduction in mass loss rate and relative dynamic modulus was significantly improved by SAP internal curing with moderate dosage; (ii) The more freeze-thaw cycles the specimen underwent, the greater the increase in strength; (iii) After 75 cycles, the chloride ion erosion depth could be decreased by approximately 23.18%. Moreover, the addition of SAP could refine the pore size, inhibit the generation of shrinkage microcracks, and promote the degree of cement hydration in the late stage, which improved the internal density of the cement concrete structure. Therefore, the deterioration of pavement under the coupling effect of salt freeze-thaw was reduced.
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  • 文章类型: Journal Article
    水资源短缺和季节性干旱是全球农业发展的主要制约因素。高吸水性聚合物(SAP)是一种很好的改良剂,可以改善土壤结构,增加土壤保水性,即使土壤水分较少,也能促进作物生长。我们假设长期施用SAP对土壤有机碳的影响更好,土壤酶活性,光合特性,产量,和水和氮的使用比短期应用。
    未经批准:具有不同施用量的长期田间试验(0(CK),15(L),30(M),2011年至2019年在河南省农业科学院禹州节水农业基地进行了45(H)kgha-1)的SAP。
    UNASSIGNED:结果表明,施用SAP在施用一年(2011年)和9年(2019年)后,土壤中增加了>0.25毫米的聚集体,减少了<0.25毫米的聚集体。此外,土壤有机碳,土壤微生物生物量碳,土壤蔗糖酶和纤维素酶活性,土壤水分消耗,用水量,净光合速率(Pn),小麦叶片水分利用效率(LWUE)和产量,应用SAP后全部增加。SAP还提高了水的利用效率和氮的利用效率。相关分析表明,SAP促进了小麦的生长,并通过改善土壤结构,提高土壤有机碳和微生物酶活性,提高土壤水分和养分的利用率。
    未经授权:根据我们的研究,以45kgha-1的剂量进行SAP治疗是最有效的,因此是推荐的。
    UNASSIGNED: Water scarcity and seasonal drought are major constraints on agricultural development globally. Super absorbent polymer (SAP) is a good amendment that can improve soil structure, increase soil water retention, and promote crop growth even with less soil moisture. We hypothesize that long term application of SAP has a better effect on soil organic carbon, soil enzyme activity, photosynthetic characteristics, yield, and water and nitrogen use than short term application.
    UNASSIGNED: A long term field experiment with different application rates (0 (CK), 15 (L), 30 (M), 45 (H) kg ha-1) of SAP was conducted at the Yuzhou water conservation agriculture base of the Henan Academy of Agricultural Sciences from 2011 to 2019.
    UNASSIGNED: The results indicate that applying SAP increases > 0.25 mm aggregates and decreased<0.25 mm aggregates in the soil after one year (2011) and 9 years (2019) of application. In addition, soil organic carbon, soil microbial biomass carbon, soil sucrase and cellulase activities, soil water consumption, water consumption, net photosynthetic rate (Pn), leaf water use efficiency (LWUE) of wheat and yield, all increased after SAP application. SAP also boosts water use efficiency and nitrogen use efficiency. Correlation analyses show that SAP promotes the growth of wheat, and improves the utilization rate of soil water and nutrients by improving the soil structure and increasing soil organic carbon and microbial enzyme activity.
    UNASSIGNED: Based on our research, SAP treatment at a dosage of 45 kg ha-1 is most effective and is thus recommended.
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  • 文章类型: Journal Article
    典型的一次性尿布通常由无纺布组成,高吸水性聚合物(SAP),有机材料,即蓬松的纸浆,尿液和/或排泄物。目前,这些废物流正被处理到垃圾填埋场,导致许多环境问题。另一种管理方法可能是通过厌氧消化使生物可降解材料增值,以及塑料和SAP的回收利用。必须对尿布进行预处理,以将SAP和塑料与有机材料分离。这项工作的目的是开发一个过程来最小化SAP的体积,因为这种成分可以通过吸水膨胀到其自身质量的1500倍,从而阻碍任何进一步的生物过程。测试了CaCl2,MgCl2和一系列CaCl2/MgCl2组合对SAP的去溶胀效率,残留试剂浓度和试剂成本。20%CaCl2和50%MgCl2(w/w)的SAP的混合物被推断为盐的合适组合,实现92.7%的最终SAP体积减少,具有低残留阳离子浓度和最小成本。尿布水解产物的物理化学表征是为了估计其作为厌氧消化底物的充足性,导致COD:N比率在随后的厌氧消化处理的可接受范围内。
    Typical used disposable nappies usually consist of nonwoven fabrics, Super Absorbent Polymer (SAP), and organic material, namely fluffy pulp, urine and/or excreta. Currently, this waste stream is being disposed to landfills causing many environmental issues. An alternative management method could be the valorisation of the biodegradable material through anaerobic digestion, and the recycling of plastics and SAP. Pretreatment of nappies is mandatory to separate SAP and plastics from the organic material. The aim of this work was the development of a process to minimize SAP\'s volume, as this component can swell up to 1500 times its own mass by water absorbance, thus hindering any further biological process. CaCl2, MgCl2, and a range of CaCl2/MgCl2 combinations were tested against their deswelling efficiency on SAP, residual reagent concentration and reagent cost. The mixture of 20% CaCl2 and 50% MgCl2 (w/w) of SAP was concluded as the suitable combination of salts achieving a final SAP volume reduction of 92.7% with low residual cation concentrations and minimum cost. The physicochemical characterization of nappies\' hydrolysate that took place to estimate its adequacy as substrate for anaerobic digestion resulted to a COD:N ratio within the acceptable range for a subsequent anaerobic digestion processing.
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