Following the Fukushima Daiichi Nuclear Power Plant disaster in March 2011, the Japanese government initiated an unprecedented decontamination programme to remediate 137Cs-contaminated soils and allow population return. This programme involved the removal of topsoil under farmland and residential land, and its replacement with \"fresh soil\" composed of granitic saprolite. However, decontamination was limited to these two land uses, without remediating forests, which cover 70 % of the surface area in the affected region. In this unprecedented context, the specific impact of this unique decontamination programme on 137Cs transfers in river systems remains to be quantified at the catchment scale. In this study, based on the analysis of a sediment core collected in June 2021 in the Mano Dam reservoir draining a decontaminated catchment, the effects of soil decontamination on particle-bound 137Cs dynamics and sediment source contributions in response to a succession of extreme precipitation events were retrospectively assessed. The sequence of sediment layer deposition and its chronology were reconstructed through the analysis of several diagnostic properties (organic matter, elemental geochemistry, visible colourimetry, granulometry) and contextual information. During abandonment (2011-2016), cropland contribution decreased (31 %). Concurrently, 137Cs activity and deposition flux decreased (19 and 29%year-1, respectively). Following decontamination (2017), sediment transfer increased (270 %) in response to increased contributions from decontaminated cropland and \"fresh soil\" (625 % and 180 % respectively). Meanwhile, forest contributions remained stable. In contrast, 137Cs activity dropped (65 %), although 137Cs deposition flux remained constant. Forests acted as a stable source of 137Cs. Accordingly, 137Cs deposition flux after decontamination (2016-2021) was similar to that observed during the 5-years period of land abandonment (2011-2016), as a result of the regrowth of spontaneous vegetation over farmland, protecting soil against erosion. Future research should further investigate the impact of longer land abandonment that prevailed in some regions decontaminated lately on the 137Cs fluxes in the rivers.

Floating anthropogenic litter occurs in all ocean basins, yet little is known about their distribution and abundance in the coastal waters off east Africa. Neuston net and bulk water sampling shows that meso- and micro-litter (8567 ± 19,684 items∙km-2, 44 ± 195 g∙km-2) and microfibres (2.4 ± 2.6 fibres∙L-1) are pervasive pollutants off the coasts of Tanzania and northern Mozambique, with higher litter loads off Tanzania. Densities of meso- and micro-litter at the start of the rainy season were greater close to the coast and to major river mouths, suggesting that much litter likely originates on land. However, the mass of litter increased with distance from the six major coastal cities. By number, 95% of meso- and micro-litter was plastic, but only 6% of microfibres. Our results highlight the need to reduce plastic use and improve solid waste management in the region.

UNASSIGNED: Identifying best practices for sediment fingerprinting or tracing is important to allow the quantification of sediment contributions from catchment sources. Although sediment fingerprinting has been applied with reasonable success, the deployment of this method remains associated with many issues and limitations.
UNASSIGNED: Seminars and debates were organised during a 4-day Thematic School in October 2021 to come up with concrete suggestions to improve the design and implementation of tracing methods.
UNASSIGNED: First, we suggest a better use of geomorphological information to improve study design. Researchers are invited to scrutinise all the knowledge available on the catchment of interest, and to obtain multiple lines of evidence regarding sediment source contributions. Second, we think that scientific knowledge could be improved with local knowledge and we propose a scale of participation describing different levels of involvement of locals in research. Third, we recommend the use of state-of-the-art sediment tracing protocols to conduct sampling, deal with particle size, and examine data before modelling and accounting for the hydro-meteorological context under investigation. Fourth, we promote best practices in modelling, including the importance of running multiple models, selecting appropriate tracers, and reporting on model errors and uncertainty. Fifth, we suggest best practices to share tracing data and samples, which will increase the visibility of the fingerprinting technique in geoscience. Sixth, we suggest that a better formulation of hypotheses could improve our knowledge about erosion and sediment transport processes in a more unified way.
UNASSIGNED: With the suggested improvements, sediment fingerprinting, which is interdisciplinary in nature, could play a major role to meet the current and future challenges associated with global change.
UNASSIGNED: The online version contains supplementary material available at 10.1007/s11368-022-03203-1.

Based on the Cr, Pb, Zn, Cd, and As content and grain data from the surface sediments of 56 sampling sites in the coastal waters off the northern Shandong Peninsula, the distribution characteristics of heavy metals in sediments were analyzed, and the sources of these elements were discussed. The results show that the distributions of Cr, Pb, and Zn were similar to each other, while the distributions of As and Cd differed from the other three, with Cr, Pb, Cd, and As all showing high concentrations in the Dengzhou shoal. Cr, Pb, and Zn, which are controlled by fine-grained components of surface sediments, mainly originated from natural processes, As mainly originated from aquaculture, and Cd originated from both natural and human sources. The high concentrations of heavy metals were mostly in areas of residual current convergence and coastal current action, and the distribution of heavy metals can be well correlated to the sedimentary dynamic environment. Human activities, grain size and hydrodynamic conditions are therefore important factors that influence the distribution of heavy metals in this study area.

Most monitoring studies of marine anthropogenic debris have focused on sandy beaches, so little is known about litter on rocky shorelines. We surveyed litter trapped on a rocky intertidal shore in False Bay, South Africa, between May 2015 and March 2018. An exceptional upwelling of seabed litter occurred in November 2017 (70 items∙m-1). Excluding this event, monthly clean-ups at spring low tide collected 2 (1.3-3.1) items∙m-1∙month-1 and 31 (19.4-49.4) g∙m-1∙month-1 of which 74% was plastic (31% by mass). Litter loads peaked in autumn when seasonal rains washed litter into False Bay, suggesting that most litter comes from local land-based sources. Litter composition differed from that on a nearby sandy beach, with more glass and other dense items on the rocky shore, but 60% of plastic items floated in water. Sand inundation and biotic interactions helped to trap buoyant plastics in the intertidal zone.

Sustainable management of insular beaches, that are critical to tourism-based economies, depends on sound understanding of coastal evolution drivers. However, interconnections among geological, oceanographical, biological and human key-drivers of coastal change, operating at relevant spatial and temporal scales, remains poorly understood. This work aims at understanding and quantifying the main drivers of insular beaches evolution using a past-to-future sediment budget approach, and to address future coastal impacts raised by anthropogenic interventions and climate change. This approach was developed in Porto Santo\'s beach from the early 20th century to the middle 21st century. Results show that anthropic activities undertaken during the late 20th century perturbed the existing long-term (natural) coastal stability. They caused significant reduction of the main sediment source (river sediment yield) and increased sediment sinks (e.g. sediment extraction from beach, harbour sedimentation). Altogether, this resulted in the onset of an erosive trend that persists until present. Projecting patterns of coastal change into the forthcoming decades strongly depends on sediment management strategies. We show that the adoption of a neutral strategy (i.e. compensating for anthropogenic-induced losses with beach nourishment) will not be enough to cease beach erosion, given the negative impacts related to acceleration of future sea level rise. Still, maintenance of the socioeconomic values of Porto Santo\'s beach can be achieved by triggering positive anthropic influences on its sediment budget. The past-to-future sediment budget approach proposed herein provided a unified perspective on the evolution of the main drivers of coastal change and simultaneously offers foundations for adaptations strategies aiming at increasing sustainability of insular beaches.

The visualization of foliage color in plants provides immediate insight into some of the compounds that exist in the leaf. However, many non-colored compounds are also present; their cellular distributions are not readily identifiable optically. In this study we evaluate the applicability of mass spectrometry imaging (MSI) via electrospray laser desorption ionization (ELDI) to reveal the spatial distribution of metabolites. ELDI-MSI is a matrix free, atmospheric pressure ionization method that utilizes a UV laser coupled with supplemental ionization by electrospray. We specifically applied ELDI-MSI to determine the spatial distribution of metabolites in Coleus Henna half leaves that were grown with half-sections either fully illuminated or shaded. We monitored dynamic changes in the spatial distribution of metabolites in response to the change of illumination every 7 days for a 28 day period. A novel source-sink relationship was observed between the 2 halves of the experimental leaf. Furthermore, Coleus Henna leaves present visually recognizable sectors associated with the differential accumulation of flavonoids. Thus, we correlated the effect of differential illumination and presence or absence of flavonoids with metabolic changes revealed by the accumulation of carbohydrates, amino acids, and organic acids. The results show the potential of ELDI-MSI to provide spatial information for a variety of plant metabolites with little sample preparation.

To understand the source-to-sink of pollutants in the Kelantan River estuary and the adjacent shelf area in Malaysia, a total of 42 surface sediment samples were collected in the Kelantan River-estuary-shelf system to analyze for grain size, total organic carbon (TOC) content, Al and heavy metals (Cr, Ni, Cu, Zn, Cd and Pb). The surficial sediments were mainly composed of clayey silt and the TOC content in sediments decreased from the river to the shelf. The surficial sediments experienced Pb pollution; Cr only showed a certain level of pollution in the coastal area of the estuary but not in other areas, and Ni, Cu, Zn, and Cd showed no pollution. The heavy metals mainly originated from natural weathering and erosion of rocks and soils in the catchment and enriched near the river mouth. Total organic carbon can promote the enrichment of heavy metals in sediments.