Sodium tripolyphosphate

三磷酸钠
  • 文章类型: Journal Article
    本研究旨在研究三磷酸钠(STPP)对PSE猪肉品质和消化特性的影响。结果表明,随着STPP浓度的增加,PSE猪肉的蒸煮损失从29.11%显着降低到25.67%(P<0.05)。此外,PSE猪肉的胃消化率从52.01%显著下降至45.81%(P<0.05)。消化道消化后,消化物的粒径明显下降(P<0.05)。这些变化主要是由于通过离子相互作用增强了蛋白质的交联,氢键和疏水相互作用,并导致疏水基团和内源性荧光团的嵌入。此外,形成了更密集的网络。这些发现为考虑STPP用于增强质地和持水能力时对肉类营养的影响提供了新的见解。
    This study aimed to examine the impact of sodium tripolyphosphate (STPP) on the quality and digestive characteristics of PSE pork. The results showed a notable decrease in cooking loss of PSE pork from 29.11% to 25.67% with increasing STPP concentration (P < 0.05). Additionally, the gastric digestibility of PSE pork decreased significantly from 52.01% to 45.81% (P < 0.05). The particle size of digesta decreased significantly after gastrointestinal digestion (P < 0.05). These changes were primarily due to the enhanced cross-linking of proteins through ionic interactions, hydrogen bonds and hydrophobic interactions, and resulted in the embedding of hydrophobic groups and endogenous fluorophores. Furthermore, denser network was formed. These findings give a new insight into considering the impact of STPP on meat nutrition when used to enhance texture and water holding capacity.
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  • 文章类型: Journal Article
    我们先前的实验发现,菜籽蛋白(RP)适用于低水分纹理蛋白。RP的添加量限制在<20%,但20%RP的添加仍然带来一些负面影响。因此,为了提高20%RP蛋白的质量,为了提高产品质量,并对产物的理化性质和分子结构变化进行了研究,探讨了可能的改性机理。STPP不仅改善了挤出物的膨胀特性,而且还增加了挤出物的亮度,补液率。此外,STPP在挤出过程中增加了比机械能,降低了材料质量流量。此外,STPP降低了淀粉的消化率,增加了慢消化淀粉和抗性淀粉的含量。STPP增加了挤出物蛋白质的变性程度,蛋白质二级结构中β-折叠的比例,以及分子间氢键相互作用。淀粉分子的糊化降解程度也随着STPP的加入而降低。STPP还增加了蛋白质-淀粉相互作用并增强了挤出物的热稳定性。所有这些表明STPP可以改善挤出物的物理化学性能。
    Our previous experiments found that rapeseed protein (RP) has applicability in low-moisture textured proteins. The amount of RP added is limited to <20 %, but the addition of 20 % RP still brings some negative effects. Therefore, in order to improve the quality of 20%RP textured protein, this experiment added different proportions of sodium tripolyphosphate (STPP) to improve the quality of the product, and studied the physical-chemical properties and molecular structure changes of the product to explore the possible modification mechanism. The STPP not only improved the expansion characteristics of extrudates, but also increased the brightness of the extrudates, the rehydration rate. In addition, STPP increased the specific mechanical energy during extrusion, decreased the material mass flow rate. Furthermore, STPP decreased the starch digestibility, increased the content of slow-digesting starch and resistant starch. STPP increased the degree of denaturation of extrudate proteins, the proportion of β-sheets in the secondary structure of proteins, as well as the intermolecular hydrogen bonding interactions. The gelatinization degradation degree of starch molecules also decreased with the addition of STPP. STPP also increased the protein-starch interactions and enhanced the thermal stability of the extrudate. All these indicate that STPP can improve the physical-chemical properties of extrudate.
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  • 文章类型: Journal Article
    三聚磷酸钠(STPP),一种无机无毒的聚磷酸盐,在制备可食用薄膜中作为交联剂具有潜在的应用。本研究利用STPP开发海藻酸钠-壳聚糖复合膜,专注于食品包装应用的适用性。结果表明,加入STPP导致薄膜厚度增加(从0.048±0.004到0.078±0.008mm),断裂伸长率(从11.50±1.49%到15.88±2.14%),水渗透(从0.364±0.010到0.521±0.021gmm/(m2h*kPa)),和水分含量(从25.98±0.20%到28.12±0.17%)。相比之下,抗拉强度(从30.23±2.08下降到25.60±1.22MPa)和膨胀指数(从752.9±17.1下降到533.5±8.9%)。扫描电子显微镜(SEM)分析显示,掺入STPP后形成了独特的针状微晶。傅里叶变换红外光谱(FTIR)分析表明STPP与成膜生物聚合物之间的分子间相互作用。热重分析(TGA)和差示扫描量热法(DSC)证明了STPP负载的膜在高温下的热稳定性增强。此外,随着STPP的加入,膜表现出增加的DPPH清除活性。这项研究强调了STPP作为交联剂用于开发复合可食用膜的潜力,建议在食品包装领域的应用。
    Sodium tripolyphosphate (STPP), an inorganic and non-toxic polyphosphate, has potential applications as a crosslinking agent in the fabrication of edible films. This study utilized STPP in the development of sodium alginate-chitosan composite films, with a focus on their suitability for food packaging applications. The results indicate that the incorporation of STPP led to an increase in film thickness (from 0.048 ± 0.004 to 0.078 ± 0.008 mm), elongation at break (from 11.50 ± 1.49 % to 15.88 ± 2.14 %), water permeation (from 0.364 ± 0.010 to 0.521 ± 0.021 gmm/(m2h*kPa)), and moisture content (from 25.98 ± 0.20 % to 28.12 ± 0.17 %). In contrast, there was a decrease in tensile strength (from 30.23 ± 2.08 to 25.60 ± 1.22 MPa) and swelling index (from 752.9 ± 17.1 to 533.5 ± 8.9 %). Scanning electron microscopy (SEM) analysis revealed the formation of distinctive needle-like microcrystals with the incorporation of STPP. Fourier-transform infrared spectroscopy (FTIR) analysis indicated intermolecular interactions between STPP and the film-forming biopolymers. The data obtained from Thermogravimetric analysis (TGA) and Differential Scanning Calorimetry (DSC) demonstrated enhanced thermal stability of STPP-loaded films at elevated temperatures. Furthermore, the films exhibited increased DPPH scavenging activity with the addition of STPP. This study underscores the potential of STPP as a crosslinking agent for the development of composite edible films, suggesting applications in the field of food packaging.
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  • 文章类型: Journal Article
    壳聚糖纳米颗粒由于其独特的性质而在药物递送领域引起了相当大的兴趣,包括生物相容性,生物降解性,低毒性,以及封装多种药物的能力。然而,常规方法(例如,滴法)用于合成壳聚糖纳米颗粒通常在控制粒径方面面临限制,形态学,和可扩展性,阻碍了它们在药物递送系统中的广泛应用。为了克服这些挑战,这项研究探索了使用一种新型的流动化学反应器设计来制造克林霉素负载的壳聚糖纳米颗粒。
    通过改变流动化学的两个关键操作参数,即,流量比和总流量,使用中心复合实验设计研究了这些参数对壳聚糖纳米颗粒性能的影响。
    纳米粒子制备的优化条件产生了显著的结果,壳聚糖纳米颗粒具有371.60nm的小尺寸和0.042的极低的多分散指数。此外,使用新颖设计的流动化学反应器,壳聚糖纳米颗粒的生产率估计为25,402.17mg/min,比通过分批合成获得的高〜12.71倍。
    这项研究的结果表明,使用新型设计的流动化学反应器有望用于合成克林霉素负载的壳聚糖纳米颗粒和旨在用于药物递送应用的其他聚合物纳米颗粒。这主要归因于它们产生具有显著减小的粒度分布和更小的总体尺寸的纳米颗粒的能力。这种技术的高生产率表明了工业规模纳米颗粒制造的潜力。
    UNASSIGNED: Chitosan nanoparticles have garnered considerable interest in the field of drug delivery owing to their distinctive properties, including biocompatibility, biodegradability, low toxicity, and ability to encapsulate a wide range of drugs. However, the conventional methods (eg, the drop method) for synthesizing chitosan nanoparticles often face limitations in regard to controlling the particle size, morphology, and scalability, hindering their extensive application in drug delivery systems. To overcome these challenges, this study explores using a novel flow chemistry reactor design for fabricating clindamycin-loaded chitosan nanoparticles.
    UNASSIGNED: By varying two critical operating parameters of flow chemistry, namely, the flow rate ratio and total flow rate, the impact of these parameters on the properties of chitosan nanoparticles is investigated using a central composite experimental design.
    UNASSIGNED: The optimized conditions for nanoparticle preparation yielded remarkable results, with chitosan nanoparticles exhibiting a small size of 371.60 nm and an extremely low polydispersity index of 0.042. Furthermore, using novel design flow chemistry reactor, the productivity of chitosan nanoparticles was estimated to be 25,402.17 mg/min, which was ~12.71 times higher than that obtained via batch synthesis.
    UNASSIGNED: The findings of this study indicate that the use of novel design flow chemistry reactor is promising for synthesizing clindamycin-loaded chitosan nanoparticles and other polymeric nanoparticles intended for drug delivery applications. This is primarily attributed to their ability to produce nanoparticles with a considerably reduced particle size distribution and smaller overall size. The demonstrated high productivity of this technique suggests the potential for industrial-scale nanoparticle manufacturing.
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  • 文章类型: Journal Article
    分子印迹聚合物(MIP)具有特定的识别能力,已广泛用于具有高选择性的电化学传感器。在这项研究中,通过用壳聚糖基MIP修饰丝网印刷碳电极(SPCE),开发了一种用于测定对氨基苯酚(p-AP)的电化学传感器。MIP是由p-AP作为模板,壳聚糖(CH)作为基础聚合物,戊二醛和三磷酸钠作为交联剂。基于膜表面形貌进行MIP表征,FT-IR光谱,改性SPCE的电化学性能。结果表明,MIP能够在电极表面选择性地积累分析物,其中以戊二醛作为交联剂的MIP能够增加信号。在最佳条件下,来自传感器的阳极峰值电流在0.5-35µMp-AP浓度范围内线性增加,灵敏度为(3.6±0.1)µA/µM,检测限(S/N=3)为(2.1±0.1)µM,定量限为(7.5±0.1)µM。此外,所开发的传感器具有高选择性,精度为(94.11±0.01)%。
    Molecularly Imprinted Polymers (MIPs) have specific recognition capabilities and have been widely used for electrochemical sensors with high selectivity. In this study, an electrochemical sensor was developed for the determination of p-aminophenol (p-AP) by modifying the screen-printed carbon electrode (SPCE) with chitosan-based MIP. The MIP was made from p-AP as a template, chitosan (CH) as a base polymer, and glutaraldehyde and sodium tripolyphosphate as the crosslinkers. MIP characterization was conducted based on membrane surface morphology, FT-IR spectrum, and electrochemical properties of the modified SPCE. The results showed that the MIP was able to selectively accumulate analytes on the electrode surface, in which MIP with glutaraldehyde as a crosslinker was able to increase the signal. Under optimum conditions, the anodic peak current from the sensor increased linearly in the range of 0.5-35 µM p-AP concentration, with sensitivity of (3.6 ± 0.1) µA/µM, detection limit (S/N = 3) of (2.1 ± 0.1) µM, and quantification limit of (7.5 ± 0.1) µM. In addition, the developed sensor exhibited high selectivity with an accuracy of (94.11 ± 0.01)%.
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  • 文章类型: Journal Article
    在本文中,研究了添加三聚磷酸钠(STPP)对纯铝酸钙水泥(PCAC)的分散和水化的影响,并研究了相应的作用机理。STPP对分散的影响,流变学,通过测量水泥颗粒表面的α-电位,分析了PCAC的水化过程及其在水泥颗粒表面的吸附能力,在不同的STPP添加量下,溶液中元素P和Ca2离子浓度的变化。实验结果表明,STPP很容易与Ca2+离子络合生成络合物[CaP3O10]3-吸附在水泥颗粒表面,改变水泥颗粒表面的电势,增加水泥颗粒之间的静电排斥力,从而提高水泥的分散性和流变性。同时,减少了水泥颗粒与水的接触面积,这阻碍了水合过程,并使水合过程的时间更长。综合分析表明,当STPP的添加量为0.2%时,STPP对纯铝酸钙水泥的效果最佳。该研究可为耐火浇注料中减水剂的添加以及提高耐火材料质量提供参考。
    In this paper, the effect of a sodium tripolyphosphate (STPP) addition on the dispersion and hydration of pure calcium aluminate cement (PCAC) was investigated, and the corresponding mechanism of effect was studied. The effects of STPP on the dispersion, rheology, and hydration processes of PCAC and its adsorption capacity on the surface of cement particles were analysed by measuring the 𝜁-potential on the surface of cement particles, the changes in the concentrations of elemental P and Ca2+ ions in a solution at different STPP additions. The experimental results show that STPP easily complexes with Ca2+ ions to produce the complex [CaP3O10]3- adsorbed on the surface of cement particles, which changes the potential on the surface of cement particles and increases the electrostatic repulsive force between cement particles, thus improving the dispersion and rheology of cement. At the same time, the contact area between cement particles and water is reduced, which hinders the hydration process and makes the time of hydration process longer. A comprehensive analysis shows that the best effect of STPP on pure calcium aluminate cements is achieved when the addition of STPP is 0.2%. This study can provide a reference for the addition of water-reducing agents in refractory castables as well as improving the quality of refractory materials.
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  • 文章类型: Journal Article
    研究了粉红色抑制成分(PII)在不存在或存在三聚磷酸钠(STP)的情况下消除由预先涂漆和储存的生火鸡制成的煮熟火鸡乳房中粉红色颜色缺陷的作用。将磨碎的火鸡乳房与2%氯化钠混合并真空包装。存放6d后,10个PII单独掺入,不加入或加入STP(0.5%)如下:无(对照),柠檬酸(CA;0.1%,0.2%,0.3%),氯化钙(CC;0.025%,0.05%),乙二胺四乙酸二钠盐(EDTA;0.005%,0.01%),和柠檬酸钠(SC;0.5%,1.0%)。处理以快速或缓慢的烹饪速度烹饪,冷却,并在分析前存储。与对照相比,所有测试的PII都能够降低固有的粉红色(无STP:CIEa*合并日减少23.0%,5.2%,12.6%,CA为12.6%,CC,EDTA,SC,分别;STP:减少21.5%,17.4%,6.0%,CA为18.2%,CC,EDTA,SC,分别)。对于没有STP的样品,快速的烹饪速度导致较高的CIEa*。然而,当样品包含STP时,缓慢烹饪比快速烹饪产生更多的红色产品。磨碎的火鸡的预浇筑和储存导致未固化的粉红色变色,煮熟的火鸡(CIEa*6.24和5.12,不含和含STP)。这种粉红色的变色可以通过包含CA来减少,CC,EDTA,或SC,但CA的掺入降低了蒸煮产量。特别是,例如,SC的添加可以提供一些控制而不负面影响烹饪产量。
    The effects of pink inhibiting ingredients (PII) to eliminate the pink color defect in cooked turkey breast produced from presalted and stored raw ground turkey in the absence or presence of sodium tripolyphosphate (STP) were examined. Ground turkey breast was mixed with 2% sodium chloride and vacuum packaged. After storage for 6 d, ten PII were individually incorporated without or with added STP (0.5%) as follows: none (control), citric acid (CA; 0.1%, 0.2%, 0.3%), calcium chloride (CC; 0.025%, 0.05%), ethylenediaminetetraacetic acid disodium salt (EDTA; 0.005%, 0.01%), and sodium citrate (SC; 0.5%, 1.0%). Treatments were cooked at a fast or slow cooking rate, cooled, and stored before analysis. All PII tested were capable of lowering inherent pink color compared to the control (No STP: CIE a* pooled day reduction of 23.0%, 5.2%, 12.6%, and 12.6% for CA, CC, EDTA, and SC, respectively; STP: reduction of 21.5%, 17.4%, 6.0%, and 18.2% for CA, CC, EDTA, and SC, respectively). For samples without STP, fast cooking rate resulted in higher CIE a*. However, slow cooking resulted in more red products than fast cooking when samples included STP. Presalting and storage of ground turkey caused the pink discoloration in uncured, cooked turkey (CIE a* 6.24 and 5.12 for without and with STP). This pink discoloration can be decreased by inclusion of CA, CC, EDTA, or SC, but incorporation of CA decreased cooking yield. In particular, the addition of SC may provide some control without negatively impacting the cooking yield.
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  • 文章类型: Journal Article
    The use of dressings is one of the most common methods for wound treatment. Since most single-layer dressings cannot mimic the hierarchical structure of the skin well, multi-layer dressings have been considered. In this study, a bilayer dressing was fabricated using a gelatin sponge layer cross-linked with sodium tripolyphosphate (Gel-STPP) and a layer of carrageenan nanofibers containing platelet-rich fibrin (Carr-PRF). Chemical interactions between the two layers were characterized by FTIR, and the microstructure was visualized by SEM. It was found that the presence of Carr-PRF nanofiber layer increased tensile strength by 12.96 % (from 0.216 ± 0.015 to 0.268 ± 0.036 MPa) and elastic modulus by 56.70 % (from 0.388 ± 0.072 to 0.608 ± 0.029 MPa) compared to Gel-STPP sponge. Gel-STPP/Carr-PRF wound dressing had a 45.76 ± 4.18 % degradability after 7 days of immersion in phosphate buffered saline (PBS). PRF-containing bilayer wound dressing was able to sustainably release growth factors over 7 days. The Carr-PRF nanofiber layer coated on Gel-STPP sponge was an ideal environment for adhesion and proliferation of L929 cells. Gel-STPP/Carr-PRF bilayer dressing outperformed the other tested samples in terms of angiogenic potential. Average wound closure was 94.21 ± 2.06 % in Gel-STPP/Carr-PRF dressing treated rats after 14 days, and based on the histopathological and immunohistochemical examinations, the Gel-STPP/Carr-PRF dressing group augmented full-thickness wound healing, keratin layer and skin appendages formation after 14 days.
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  • 文章类型: Journal Article
    UNASSIGNED:进行这项研究的目的是评估柑橘纤维(CF)作为腌制的肉鸡无骨鸡胸肉和内部牛肉裙中三聚磷酸钠(STPP)的天然替代品对整体保留率的影响,剪切力,和消费者感官属性。
    未经评估:五种不同的腌泡汁配方的目标是包含0.9%的盐,基于成品的0.25%或0.50%STPP或CF和水。仅将水和盐视为阴性对照(CON)。鸡胸(n=14)和牛肉裙(n=14)被随机分配到治疗中,记录原始重量,然后放入真空滚筒。记录了腌制体重,单独包装,并随机分配给任一零售展示10天保留率,剪力分析,厨师损失,或消费者感官面板。
    未经评估:接货百分比,鸡胸肉和牛肉裙的整体保留率相似。与鸡胸肉中的CON相比,柑橘纤维处理导致更高的烹饪损失;但是,CF050与内部牛肉裙中的STPP025相比导致类似的烹饪损失。鸡胸肉的感官属性没有发现差异,然而,WBSF数据显示CF025比CF050、STPP050和CON更坚韧。消费者小组总体上最不喜欢带有CF050的牛肉裙。
    UNASSIGNED:以较低的百分比率包含在腌泡汁中的柑橘纤维可以产生相似的质地特征,和感官特性与用三磷酸钠腌制的比较。
    OBJECTIVE: This research was conducted to evaluate the effects of citrus fiber (CF) as a natural alternative to sodium tripolyphosphate (STPP) in marinated broiler boneless chicken breast and inside beef skirt on overall retention rate, shear force, and consumer sensory attributes.
    METHODS: Five different marinade formulations were targeted to include 0.9% salt, either 0.25% or 0.50% STPP or CF and water on a finished product basis. Water and salt only were considered the negative control (CON). Chicken breasts (n = 14) and inside beef skirt (n = 14) were randomly assigned to a treatment, raw weights recorded and then placed in a vacuum tumbler. Marinated weights were recorded, individually packed, and randomly assigned to either retail display for 10-day retention rate, shear force analysis, cook loss, or consumer sensory panel.
    RESULTS: Pickup percentage, and overall retention was similar among treatments for chicken breast and inside beef skirt. Citrus fiber treatments resulted in higher cooking loss compared to the CON in chicken breast; though, CF050 resulted in similar cooking loss compared to STPP025 in inside beef skirt. No differences were found in sensory attributes for chicken breast, however, WBSF data showed CF025 was tougher than CF050, STPP050, and CON. Inside beef skirt with CF050 were least liked overall by the consumer panel.
    CONCLUSIONS: Citrus fiber included in marinades at a lower percentage rate can produce similar texture characteristics, and sensory properties compared with those marinated with STPP.
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  • 文章类型: Journal Article
    小麦面筋中大量疏水基团和非极性氨基酸的存在是其水溶性差的原因,极大地限制了其工业应用。结果表明:随着三磷酸钠(STP)浓度的增加,WG的溶解度和ζ电位显著提高(P<0.05),而WG的平均粒径减小。WG与TGase孵育后,磷酸化预处理显著提高了WG分散剂溶液的表观粘度,表明磷酸化处理促进了交联聚合物的生成。此外,磷酸化预处理增强了TGase诱导的WG凝胶之间的疏水相互作用和二硫键形成,从而导致凝胶更均匀和致密的三维网络结构,SEM显微照片证实了这一点。总结一下,STP可用作有效的添加剂,用于修饰WG,具有改善的TGase介导的交联程度,以获得更好的流变性和凝胶性能。
    The presence of a large number of hydrophobic groups and non-polar amino acids in the wheat gluten (WG) is responsible for its poor water solubility, greatly limiting its industrial applications. Our results showed that the solubility and zeta potential of WG were significantly (P < 0.05) improved with the increasing concentration of sodium tripolyphosphate (STP), while the average particle size of WG was decreased. After WG was incubated with TGase, phosphorylation pretreatment significantly increased apparent viscosity of WG dispersant solution, suggesting that phosphorylation treatment promoted the generation of cross-linked polymers. In addition, phosphorylation pretreatment enhanced hydrophobic interactions and disulfide bond formation between TGase-induced WG gels, thus leading to a more homogeneous and dense three-dimensional network structure of gel, which was confirmed by SEM micrographs. To summarize, STP can be used as an effective additive for the modification of WG with an improved degree of TGase-mediated cross-linking for better rheological and gel properties.
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