High internal phase Pickering emulsion (HIPPE) is renowned for its exceptionally high-volume fraction of internal phase, leading to flocculated yet deformed emulsion droplets and unique rheological behaviors such as shear-thinning property, viscoelasticity, and thixotropic recovery. Alongside the inherent features of regular emulsion systems, such as large interfacial area and well-mixture of two immiscible liquids, the HIPPEs have been emerging as building blocks to construct three-dimensional (3D) scaffolds with customized structures and programmable functions using an extrusion-based 3D printing technique, making 3D-printed HIPPE-based scaffolds attract widespread interest from various fields such as food science, biotechnology, environmental science, and energy transfer. Herein, the recent advances in preparing suitable HIPPEs as 3D printing inks for various applied fields are reviewed. This work begins with the stabilization mechanism of HIPPEs, followed by introducing the origin of their distinctive rheological behaviors and strategies to adjust the rheological behaviors to prepare more eligible HIPPEs as printing inks. Then, the compatibility between extrusion-based 3D printing and HIPPEs as building blocks was discussed, followed by a summary of the potential applications using 3D-printed HIPPE-based scaffolds. Finally, limitations and future perspectives on preparing HIPPE-based materials using extrusion-based 3D printing were presented.

Self-assembly coatings are used to functionalize the surface structures of protein. Herein, emulsion-templated approach was adopted to obtain oleogels using metal-phenolic network coatings-decorated zein nanoparticles. Two self-assembly strategies were used to decorate zein nanoparticles: 1) adding (-)-epigallocatechin-3-gallate (EGCG) first and then calcium ions (Ca2+) (zein/EGCG/Ca2+ nanoparticles). 2) adding Ca2+ first and then EGCG (zein/Ca2+/EGCG nanoparticles). The formation of nanoparticles, the stability of emulsions and the rheological behaviors of oleogels were modulated by using different adding sequences of EGCG and Ca2+. Nanoparticles prepared by two self-assembly strategies exhibited increasing diameter (340-360 nm). More Ca2+ participated in the formation of zein/EGCG/Ca2+ nanoparticles, as described by X-ray photoelectron spectroscopy analysis. Metal-phenolic network coatings facilitated the formation of well-structured emulsions and oleogels, which were candidates for fat substitutes and stable carriers. Findings confirmed metal-phenolic network coatings-decorated zein nanoparticles were effective stabilizers for emulsions and oleogels, further expanding the selectivity of oleogelators.

The rheological behaviors of low-density polyethylene doped with additives (PEDA) determine the dynamic extrusion molding and structure of high-voltage cable insulation. However, the coupling effect of additives and molecular chain structure of LDPE on the rheological behaviors of PEDA is still unclear. Here, for the first time, the rheological behaviors of PEDA under uncross-linked conditions are revealed by experiment and simulation analysis, as well as rheology models. The rheology experiment and molecular simulation results indicate that additives can reduce the shear viscosity of PEDA, but the effect degree of different additives on rheological behaviors is determined by both chemical composition and topological structure. Combined with experiment analysis and the Doi-Edwards model, it demonstrates that the zero-shear viscosity is only determined by LDPE molecular chain structure. Nevertheless, different molecular chain structures of LDPE have different coupling effects with additives on the shear viscosity and non-Newtonian feature. Given this, the rheological behaviors of PEDA are predominant by the molecular chain structure of LDPE and are also affected by additives. This work can provide an important theoretical basis for the optimization and regulation of rheological behaviors of PEDA materials used for high-voltage cable insulation.

Rice husk biochar (RHB) is a renewable agricultural waste, and its fixation on pavements helps develop environmentally friendly, economical, and sustainable asphalt pavements. This paper used RHB to replace part of styrene-butadiene-styrene (SBS) for the composite modification study of matrix asphalt. The high- and low-temperature properties and microscopic mechanisms of the composite-modified asphalt were studied through a series of tests. The results showed that, compared with SBS-modified asphalt, the softening point, viscosity, complex shear modulus, stiffness modulus, and rutting factors of RHB-SBS composite-modified asphalt were improved. In contrast, the ductility and creep rate were slightly decreased, indicating an improvement in the high-temperature performance of composite-modified asphalt, but a slight decrease in its low-temperature performance. The process of RHB and SBS composite modification was mainly physical blending, with only a small number of chemical reactions, and no new functional groups were generated. The porous structure of RHB enables it to adhere better to the network crosslinked continuous phase system formed by SBS and matrix asphalt. This results in composite-modified asphalt with good high-temperature storage stability and rheological properties. Therefore, RHB-SBS composite-modified asphalt can be applied to high-temperature areas and rice-producing areas, and the optimal content of RHB is suggested to be 15%.

Research on the rheological performance and mechanism of polymer nanocomposites (PNCs), mainly focuses on non-polar polymer matrices, but rarely on strongly polar ones. To fill this gap, this paper explores the influence of nanofillers on the rheological properties of poly (vinylidene difluoride) (PVDF). The effects of particle diameter and content on the microstructure, rheology, crystallization, and mechanical properties of PVDF/SiO2 were analyzed, by TEM, DLS, DMA, and DSC. The results show that nanoparticles can greatly reduce the entanglement degree and viscosity of PVDF (up to 76%), without affecting the hydrogen bonds of the matrix, which can be explained by selective adsorption theory. Moreover, uniformly dispersed nanoparticles can promote the crystallization and mechanical properties of PVDF. In summary, the viscosity regulation mechanism of nanoparticles for non-polar polymers, is also applicable to PVDF, with strong polarity, which is of great value for exploring the rheological behavior of PNCs and guiding the process of polymers.

Polymer melt strength (MS) is strongly correlated with its molecular structure, while their relationship is not very clear yet. In this work, designable long-chain branched polylactide (LCB-PLA) is prepared in situ by using a tailor-made (methyl methacrylate)-co-(glycidyl methacrylate) copolymer (MG) with accurate number of reactive sites. A new concept of branching density (φ) in the LCB-PLA system is defined to quantitively study their relationship. Importantly, a critical point of φc  = 5.5 mol/104  mol C is revealed for the first time, below which the zero-shear viscosity (η0 ) corresponding to MS increases slowly with a slope of Δη0 /Δφ = 1400, while it increases sharply above this critical point due to entanglement of neighboring LCB-PLA chains. Consequently, the MS of PLA increased by >100 times by optimizing the LCB structures while maintaining processibility. Therefore, this work provides a deeper understanding and feasible route in quantitative design of polymers with high(er) melt strength for some specialty applications.

Asphalt binder plays an important role in the overall resistance of asphalt mixture to the moisture damage induced by a dynamic pore water pressure environment. This study evaluates the moisture sensitivity of asphalt binder from the perspective of rheological behaviors using the dynamic shear rheometer (DSR) and the bending beam rheometer (BBR) methods at high, medium, and low temperatures. The damage mechanism is further discussed quantitatively based on the Fourier transform infrared spectroscopy (FTIR) method. The results indicate that a longer conditioning duration is beneficial for asphalt binder to recover its adhesion at 60 °C in multiple stress creep recover (MSCR) tests, but the increasing pore water pressure magnitude of 60 psi held an opposite effect in this study. The asphalt binder\'s fatigue life at 20 °C in linear amplitude sweep (LAS) tests decreased obviously with conditioning duration and environmental severity, but the reducing rate gradually slowed down, while the groups of 50 psi-4000 cycles and 60 psi-4000 cycles held a comparable erosion effect. Both the stiffness and relaxation moduli at -12 °C in the BBR tests exhibited an obvious decreasing trend with conditioning duration and environmental severity. The erosion effect on the asphalt binder was gradually enhanced, but it also exhibited a slightly more viscous performance. Water conditioning induced several obvious characteristic peaks in the FTIR absorbance spectra of the asphalt binder. The functional group indexes presented a trend of non-monotonic change with conditioning duration and environmental severity, which made the asphalt binder show complicated rheological behaviors, such as non-monotonic variations in performance and the abnormal improving effect induced by dynamic pore water pressure conditioning.

Silver paste is widely used for low-temperature co-fired ceramic (LTCC) electrodes. In this work, a kind of LTCC silver paste for fine-line screen-printing was developed by considering the effect of the organic vehicle on rheological behavior and screen-printing properties. A step-by-step volatilization mode was applied to screen the mixed organic solvent of α-terpineol, 2-(2-butoxyethoxy) ethyl acetate (BCA) and dibutyl phthalate (DBP). The α-terpineol:BCA:DBP ratio of 5:2:3 is selected by considering the volatility, viscosity, and pseudoplasticity of the organic vehicle. Both viscosity and pseudoplasticity of shear-thinning increase with the increase of ethyl cellulose (EC) organic binder content. Three interval thixotropy test (3ITT) was conducted to discuss the thixotropy of silver paste. The minimum printing line width of 13.27 µm is obtained using silver paste with 10 wt% EC, confirming that the homemade paste has good printability.

PBT and PET are subjected to thermal-oxidative degradation and thermomechanical degradation during the process of melt blending, which affect the polymer structure and properties. The effect of feed properties of PET and the addition of modified nanoparticles on blends are a question worthy of discussion. This work describes the melting and thermal stability, the crystallization behavior and non-isothermal crystallization kinetic, the rheological behaviors and mechanical properties of several PBT/PET blends prepared by twin-screw melt extrusion. Results show that the molecular chain of the polyester blends obtained by stable extrusion are not significantly degraded, there is only one obvious melting peak and crystallization peak on the thermal analysis curves, and the melting point is lower than either of the two polyesters. An appropriate amount of SD can effectively reduce the crystallization rate of the PBT material and extend the crystallization time. The rheological behavior of PBT/PET blends is complicated than PET raw materials and SD, as well as the melt processing temperature and shear rate will all affect the rheological behavior of the blends. For example, at low shear rate, polyester blends with SD exhibit strong shear thinning behavior. In general, the SD content affects the rheological property of blends in a way similar to the law of influence on crystallization behavior. When SD content is 0.3 wt%, a polyester product with higher elongation at break than pure PBT can be obtained. This can provide a useful reference for preparing commercialized polyester blend products with good melt processability and elongation by simple blending.

Biochar has been utilized as a renewable biomass resource to develop sustainable and eco-friendly pavements. This study focuses on the influence of biochar as an asphalt modifier on the improvement of high-temperature performance of asphalt. A series of tests were performed to comprehensively evaluate the high-temperature performance of the biochar modified binder. The interaction mechanism between the biochar and the binder was explored using scanning electron microscopy and Fourier-transform infrared spectroscopy (FTIR). The results indicated that the complex modulus and penetration of the biochar-modified asphalt binder could be increased by up to 35% and 36.5%, respectively, compared with those in case of the matrix asphalt, thereby improving the deformation resistance. In addition, the observed increase in the complex modulus, rutting factor, and viscosity-temperature index contributed to the improvement of temperature sensitivity and anti-rutting properties. These relationships are attributed to the fact that biochar has a fibrous porous structure and forms a skeleton and stiffening zone in the binder. Although biochar has a negative effect on the low-temperature properties of the binder, this can be alleviated by controlling the biochar content. Moreover, the FTIR results showed that no new chemical functional groups appeared after the incorporation of biochar into the binder. The internal chemical environment of the biochar-modified asphalt binder was different from that of the matrix asphalt. In conclusion, biochar is feasible as a modifier for binders owing to its high-temperature properties.