Prosopis juliflora

  • 文章类型: Journal Article
    基于ProsopisJuliflora(PJ)树皮和不同长度的苎麻纤维的混合复合样品,重量百分比,和固化温度是第一次在这项工作中创建。完全正确,在这项研究中测试了120个混合复合材料样品。有五种不同的纤维长度:10毫米,15毫米,20毫米,25毫米,和30毫米,重量百分比10%,20%,30%,40%,50%,和不同的固化温度80°C,90°C,100°C,110°C,和120°C用于生产杂化复合材料样品。由于与环氧基体的交联能力,混合复合材料试样显示出高达98肖氏D硬度的高电阻。环氧基体的高极性和氢键加强感化,复合材料试样的抗弯强度提高了12%。固化温度为100°C,20毫米纤维长度,和30%的混合复合材料样品获得了最高的拉伸强度28.76MPa,抗弯强度46.54MPa,冲击强度4.5J,和硬度强度(98shoreD)。热重分析(TGA)显示复合样品的初始分解温度(Ti)发生在98°C,最大分解温度(Tmax)在320°C,最终分解温度(Tf)为466℃。
    The hybrid composite sample based on Prosopis Juliflora (PJ) bark and ramie fibre with different length, weight percentage, and curing temperature were created for the first time in this work. Totally, 120 hybrid composite samples were tested in this study. There were five different fibre lengths: 10 mm, 15 mm, 20 mm, 25 mm, and 30 mm, weight percentages 10 %, 20 %, 30 %, 40 %, and 50 %, and different curing temperatures 80 °C, 90 °C, 100 °C, 110 °C, and 120 °C used to produce the hybrid composite samples. Due to the cross-linking ability with the epoxy matrix, the hybrid composite specimen shows high resistance up to 98 Shore D hardness. The high polarity of the epoxy matrix and the hydrogen bond strengthening effect, increased the composite sample flexural strength by 12 %. The curing temperature of 100 °C, 20 mm fibre length, and 30 % of the hybrid composite sample achieved the highest tensile strength (28.76 MPa), flexural strength (46.54 MPa), impact strength (4.5 J), and hardness strength properties (98 shore D). Thermo gravimetric analysis (TGA) revealed the composite samples initial decomposition temperature (Ti) at 98 °C, maximum decomposition temperature (Tmax) at 320 °C, and the final decomposition temperature (Tf) at 466 °C.
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  • 文章类型: Journal Article
    重金属来自各种人为活动,这些活动附近的表层土壤充当直接的汇,并促进重金属扩散到食物链中。在印度的半干旱平原,Juliflora是高速公路和包括工业环境在内的贫瘠土地上最常见和最主要的杂草。这项调查假设了富含金属的土壤中Prosopisjuliflora的适应性,并试图了解除生物转化/解毒能力外,其金属的超积累潜力。朱立花原木样品(根,茎,叶子,和豆荚)来自人类活动(车辆排放和工业操作)周围100个地点的重金属浓度(Cu,Fe,Cr,Cd,Ni,Pb)。Juliflora以0.138mg/kg/天DW的铜(Cu)积累金属,Fe:0.142mg/kg/天DW,Cr:0.114mg/kg/天DW,镍:0.048毫克/千克/天DW,Pb:0.052mg/kg/天DW,Cd:0.009mg/kg/天DW。此外,X射线光电子能谱(XPS)金属氧化态分析显示,在Prosopisjuliflora的豆荚中,重金属(Fe,Cr,Pb)主要以无毒形式存在(有毒:无毒-3:6),在树冠下的土壤中,金属主要以有毒形式存在(有毒:无毒-7:2);最终XPS结果确定了植物的重金属生物转化/解毒潜力。这些发现表明,在运输走廊和金属基工业区的贫瘠景观中,Prosopisjuliflora的存在可能理想地有利于重金属的植物修复。
    Heavy metals emanate from diverse anthropogenic activities and the top soil in the vicinity of these activities acts as an immediate sink and facilitates diffusion of heavy metals into the food chain. In the semi-arid plains of India, Prosopis juliflora is the most common and dominant weed along the motorways and barren lands including industrial environs. This investigation hypothesizes the adaptive nature of Prosopis juliflora in the metal enriched soils and attempts to understand its hyper-accumulating potential of metals besides bioconversion/detoxification capability. Prosopis juliflora samples (root, stem, leaves, and pods) from 100 sites in the environs of anthropogenic activities (vehicular emissions and industrial operations) were analyzed for heavy metal concentrations (Cu, Fe, Cr, Cd, Ni, Pb). Prosopis juliflora accumulate metals at the rate of 0.138 mg/kg/day DW for Copper (Cu), Fe: 0.142 mg/kg/day DW, Cr: 0.114 mg/kg/day DW, Ni: 0.048 mg/kg/day DW, Pb: 0.052 mg/kg/day DW, Cd: 0.009 mg/kg/day DW. Furthermore, X-ray Photoelectron Spectroscopy (XPS) metal oxidation state analysis revealed that in the pods of Prosopis juliflora heavy metals (Fe, Cr, Pb) largely existed in non-toxic form (toxic:non-toxic - 3:6), while in the under canopy soil, metals predominantly existed in toxic form (toxic:non-toxic - 7:2); conclusively XPS results ascertains the heavy metal bioconversion/detoxification potential of the plant. These findings suggest that presence of Prosopis juliflora coppice in the barren landscapes across the transportation corridors and metal based industrial zones may ideally favor phyto-remediation of heavy metals.
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  • 文章类型: Journal Article
    Juliflora的显着适应性和快速增殖导致其在肯尼亚牧场的入侵状态,对原生植被和生物多样性产生不利影响。过度放牧等人类活动加剧,森林砍伐,土地退化,这些条件使得该物种的传播和管理成为一个关键的生态问题。这项研究评估了人工智能(AI)和遥感在监测Baringo县Prosopisjuliflora入侵中的有效性,肯尼亚。我们调查了环境驱动因素,包括天气条件,土地覆盖,和生物物理属性,这影响了它与原生植被的区别。通过分析是否存在Juliflora的数据,加上天气数据集,土地覆盖,和海拔,我们确定了促进其检测的关键因素。我们的发现强调决策树/随机森林分类器是最有效的,实例分类准确率达到95%。关键变量,如2月份归一化植被指数(NDVI),降水,土地覆盖类型,和海拔高度对朱草的准确鉴定具有重要意义。社区见解揭示了对Prosopisjuliflora影响的不同观点,根据该物种的专业经验,有不同的观点。将这些技术进步与当地知识相结合,这项研究有助于开发针对这种入侵物种带来的独特生态和社会挑战的可持续管理实践。我们的结果强调了先进技术对牧场生态系统中环境管理和保护的贡献。
    The remarkable adaptability and rapid proliferation of Prosopis juliflora have led to its invasive status in the rangelands of Kenya, detrimentally impacting native vegetation and biodiversity. Exacerbated by human activities such as overgrazing, deforestation, and land degradation, these conditions make the spread and management of this species a critical ecological concern. This study assesses the effectiveness of artificial intelligence (AI) and remote sensing in monitoring the invasion of Prosopis juliflora in Baringo County, Kenya. We investigated the environmental drivers, including weather conditions, land cover, and biophysical attributes, that influence its distinction from native vegetation. By analyzing data on the presence and absence of Prosopis juliflora, coupled with datasets on weather, land cover, and elevation, we identified key factors facilitating its detection. Our findings highlight the Decision Tree/Random Forest classifier as the most effective, achieving a 95% accuracy rate in instance classification. Key variables such as the Normalized Difference Vegetation Index (NDVI) for February, precipitation, land cover type, and elevation were significant in the accurate identification of Prosopis juliflora. Community insights reveal varied perspectives on the impact of Prosopis juliflora, with differing views based on professional experiences with the species. Integrating these technological advancements with local knowledge, this research contributes to developing sustainable management practices tailored to the unique ecological and social challenges posed by this invasive species. Our results highlight the contribution of advanced technologies for environmental management and conservation within rangeland ecosystems.
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  • 文章类型: Journal Article
    该研究的重点是通过热解和化学活化的方法从PJAC木材中制备活性炭。目的是评估其作为合成复合吸附剂涂层(CAC)以从水溶液中去除镉(Cd2)的吸附剂的有效性。评估了与Cd2去除效率相关的制备因素的影响。使用响应面方法(RSM)的Box-Behnken设计(BBD)(DesignExpert软件版本11)进行了在PJAC上吸附Cd2的实验设计(DoE)。浸渍比(IR)的影响,碳化时间(t),和碳化温度(T)对Cd(II)去除率(%)进行了评价。还为响应变量生成了3D响应面图,并且较高的R2系数值被拟合到多项式二次模型中。结果表明,所有可变的制备因素对PJAC去除Cd2+的影响都很显著,其中碳化温度最显著。在最佳条件下,即浸渍比(1.8),碳化温度(595°C)和碳化时间(174分钟),该模型预测Cd2+的去除效率为99.9%,而吸附实验获得了96.7%的去除效率,分别。稍后,用不同的表征技术,包括SBET,分析了用最佳参数制备的PJAC的形态和化学性质,SEM-EDX,pHPZC,FTIR和XRD。SEM图像显示了粗糙和多孔的形态表面,SBET为600.4m2/g,接近中性的pHPZC为6.92。XRD图表明所制备的吸附剂的结晶性质。PJAC的吸附前后FTIR光谱显示出明显的差异,后者显示出峰强度和高度的降低。这些结果支撑了利用ProsopisJuliflora等入侵植物作为重金属去除吸附剂的潜力。
    The study focuses on the preparation of activated carbon from Prosopis juliflora (PJAC) wood by pyrolysis and chemical activation. The objective is to assess its effectiveness as an adsorbent for synthesizing a composite adsorbent coating (CAC) for Cadmium (Cd2+) removal from aqueous solution. The effect of preparation factors related to Cd2+ removal efficiency was assessed. The Design of Experiments (DoE) for the adsorption of Cd2+ on the PJAC were done using the Box-Behnken Design (BBD) of the Response Surface Methodology (RSM) (Design Expert software version 11). The influence of impregnation ratio (IR), carbonization time (t), and carbonization temperature (T) on the Cd (II) percent (%) removal was evaluated. The response surface graphs in 3D were also generated for the response variable, and the higher R2 coefficient values were fitted into the polynomial quadric model. The results indicated that all the variable preparation factors were significant in the Cd2+ removal by PJAC with carbonization temperature being the most significant. At the optimum conditions i.e. impregnation ratio (1.8), carbonization temperature (595 °C) and carbonization time (174 min), the model predicted a 99.9 % Cd2+ removal efficiency while the adsorption experiment obtained a 96.7 % removal efficiency, respectively. Later, the morphological and chemical properties of the PJAC prepared with optimal parameters were analyzed using different characterization techniques including SBET, SEM-EDX, pHPZC, FTIR and XRD. The SEM images revealed a rough and porous morphological surface with an SBET of 600.4 m2/g and a near neutral pHPZC of 6.92. The XRD pattern indicated the crystalline nature of the prepared adsorbent. The pre and post adsorption FTIR spectrum of the PJAC demonstrated a distinct difference with the latter showing a reduction in peak intensity and height. These results underpin the potential of utilizing invasive plants like Prosopis Juliflora as adsorbents for heavy metal removal.
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  • 文章类型: Journal Article
    木本物种已在世界许多地方引入,以提供经济效益,但是其中一些物种现在是最严重的入侵者之一,造成广泛的经济和环境破坏。管理木本物种以恢复原始的生态系统服务,例如可以提供饲料和固碳的生物多样性草地,需要限制外来物种的影响。然而,最好的管理方法,即,最经济高效和有效的清除树木的方法,以及恢复或恢复被清除土地的最有效方法,不是为许多物种开发的。在东非,prosopis(Prosopisjulifora)入侵了稀树草原和草原的大片地区,从而影响,除其他外,牲畜的饲料和水,进入旱季牧场,最终获得牧区生计。我们测试了三种prosopis治疗方法(手动连根拔起,切割残端和基础树皮除草剂的应用)与三种增量恢复干预措施(divots,分块+覆盖,分块+覆盖+草种播种)。这项为期三年的研究在埃塞俄比亚(阿法尔国家地区州)进行了复制,肯尼亚(Baringo县)和坦桑尼亚(Moshi区)。Prosopis的生存和植被的发展,多样性和生物量,被记录下来。prosopis治疗都非常有效(在几乎所有情况下,树木死亡率在85%至100%之间),但是,与杀死站立的树木(基础树皮)的处理相比,涉及完全去除地上生物量的两种处理(手动和切割的树桩)产生了更多产,更多样化的植被。与去除假体的效果相比,恢复干预对植被组成的影响很小,表明大多数物种是从土壤种子库中重新建立的。结果表明,有可能恢复先前被prosopis入侵的土地。尽管植被建立的速度和物种组成的变化不同,恢复干预措施导致植被,在某些情况下,植被中含有大部分多年生草。选择控制假体的方法取决于资源的可用性,包括除草剂,如果打算种植农作物,则需要去除砧木。
    在线版本包含补充材料,可在10.1186/s43170-023-00163-5获得。
    Woody species have been introduced in many parts of the world to provide economic benefits, but some of those species are now among the worst invaders, causing widespread economic and environmental damage. Management of woody species to restore original ecosystem services, such as biodiverse grassland that can provide fodder and sequester carbon, are needed to limit the impacts of alien species. However, the best management methods, i.e., the most economically efficient and effective way to remove trees and the most effective way to restore or rehabilitate the cleared land, are not developed for many species. In Eastern Africa, prosopis (Prosopis julifora) has invaded large areas of savanna and grassland, thereby affecting, among other things, fodder and water for livestock, access to dry season grazing lands and ultimately pastoral livelihoods. We tested three prosopis treatments (manual uprooting and cut stump and basal bark herbicide application) in combination with three incremental restoration interventions (divots, divots + mulching, divots + mulching + grass seed sowing). The three-year study was replicated in Ethiopia (Afar National Regional State), Kenya (Baringo county) and Tanzania (Moshi district). Prosopis survival and vegetation development, both diversity and biomass, were recorded. The prosopis treatments were all highly effective (between 85 and 100% tree mortality in almost all cases), but the two treatments that involved the complete removal of the aboveground biomass (manual and cut stump) yielded a more productive and more diverse vegetation than the treatment that killed the trees standing (basal bark). Compared to the effect of prosopis removal, the effect of restoration interventions on vegetation composition was small, indicating that most species re-established from the soil seed bank. The results show that it is possible to restore land previously invaded by prosopis. Despite the different rates of vegetation establishment and variation in species composition, the restoration interventions resulted in vegetation that in some cases contained a substantial fraction of perennial grasses. The method chosen to control prosopis depends on the availability of resources, including herbicides, and the need to remove rootstocks if the intention is to plant crops.
    UNASSIGNED: The online version contains supplementary material available at 10.1186/s43170-023-00163-5.
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  • 文章类型: Journal Article
    由于其在传播和生长方面的优势,入侵物种已被确定为对全球本地生物多样性和生态系统功能的主要威胁。这种优越性可以用侵入性熔毁现象来解释,这表明入侵物种通过修改植物-土壤反馈(PSF)来促进建立更多的入侵物种而不是本地物种。
    我们使用阿曼的本地Prosopiscineraria和入侵的Prosopisjuliflora进行了两阶段植物-土壤反馈实验。首先,我们通过种植本地物种的幼苗来调节土壤,入侵物种,本地和入侵物种“混合”,无条件土壤作为对照。其次,我们通过测量生产力(总生物量)和植物功能性状(植物高度,比叶面积(SLA),叶片氮含量(Nmass),本地和入侵物种的叶片碳含量(Cmass)和比根长度(SRL)以及土壤中的养分有效性(土壤有机碳(SOC)和土壤全氮(STN))。
    我们发现本地物种产生更多的生物量,最佳性能,和更高的SOC和STN,当生长在受本地物种调节的土壤中时,此外,它提供了较低的生物量,降低性能,和较低的SOC和STN,当生长在受入侵和混合物种条件的土壤中时。这些结果表明,在受入侵物种影响的土壤中,本地物种的PSF为负,而入侵物种的PSF为正。这可以被认为是关于恢复作为阿曼重要本地物种的苦瓜的危险信号,因为这种阳性PSF的入侵物种将抑制苦瓜的再生。
    UNASSIGNED: Invasive species have been identified as a major threat to native biodiversity and ecosystem functioning worldwide due to their superiority in spread and growth. Such superiority is explained by the invasional meltdown phenomena, which suggests that invasive species facilitate the establishment of more invasive species rather than native species by modifying the plant-soil feedback (PSF).
    UNASSIGNED: We conducted a two-phase plant-soil feedback experiment using the native Prosopis cineraria and the invasive Prosopis juliflora in Oman. Firstly, we conditioned the soil by planting seedlings of native species, invasive species, native and invasive species \"mixed\", and unconditioned soil served as a control. Secondly, we tested the feedback of these four conditioned soil on the two species separately by measuring the productivity (total biomass) and the performance in the form of plant functional traits (plant height, specific leaf area (SLA), leaf nitrogen content (Nmass), leaf carbon content (Cmass) and specific root length (SRL) of native and invasive species as well as the nutrient availability in soil (soil organic carbon (SOC) and soil total nitrogen (STN)).
    UNASSIGNED: We found that the native species produced more biomass, best performance, and higher SOC and STN when grown in soil conditioned by native species, additionally, it gave lower biomass, reduced performance, and lower SOC and STN when grown in the soil conditioned by invasive and mixed species. These results suggest negative PSF for native species and positive PSF for invasive species in the soil conditioned by invasive species, which can be considered as red flag concerning the restoration of P. cineraria as an important native species in Oman, as such positive PSF of the invasive species P. juliflora will inhibit the regeneration of P. cineraria.
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  • 文章类型: Journal Article
    斯里兰卡的森林生态系统受到人类活动和气候变化的压力。入侵物种是对本土物种和生态系统的最大威胁之一。在斯里兰卡邦达拉国家公园,我们正在努力控制和限制有害的侵袭性紫苏的传播(Sw。)DC。和仙人掌(Ker-Gawl。)呼噜。,这对自然生态系统的保护构成了重大风险。使用了9种不同的处理变体(4次重复)来测试哪种管理方法可以控制Prosopisjuliflora。这项研究基于2017年至2021年对36个永久性研究地块(每个625平方米)进行的9次重复测量,观察到27种植物物种,总共记录了90,651种植物个体。结果证实了物种丰富度的动态,异质性,和均匀度在五年的动态过程中显示出处理之间的显着差异。在对照变体中发现了最低的物种多样性,其次是基于Prosopisjuliflora树的硬修剪和稀疏的处理。相比之下,强调Prosopisjuliflora树完全连根拔起的策略,重新种植,对本地物种自然再生的支持显示出高度的物种多样性和较高的植物物种总数。一般来说,处理对朱草的物种多样性和个体数量有显著影响,而植物物种总数的变化受时间和演替的影响更大。造林治疗包括修剪,连根拔起,变薄已被证明是各种地点自然保护的重要工具,旨在面对持续的气候变化,增强栖息地的多样性。
    Forest ecosystems in Sri Lanka are under pressure from intensive human activity and climate change. Invasive species are one of the greatest threats to autochthonous species and ecosystems. In Bundala National Park of Sri Lanka, there are efforts to control and limit the spreading of unwanted invasive Prosopis juliflora (Sw.) DC. and Opuntia dillenii (Ker-Gawl.) Haw., which poses a significant risk to natural ecosystem conservation. Nine different treatment variants (four replications) were used to test which management approach provides the control of Prosopis juliflora. This research is based on nine repeated measurements from 2017 to 2021 on 36 permanent research plots (each 625 m2) with 27 observed plant species and a total of 90,651 recorded plant individuals. The results confirmed that the dynamics of species richness, heterogeneity, and evenness showed significant differences between treatments during the five years of dynamics. The lowest species diversity was found in the control variant, followed by treatments based on the hard pruning and thinning of Prosopis juliflora trees. In contrast, strategies emphasizing the complete uprooting of Prosopis juliflora trees, replanting, and support of the natural regeneration of native species showed high species diversity and a high overall number of plant species. Generally, treatments had a significant effect on species diversity and the number of individuals of Prosopis juliflora, while changes in the overall number of plant species were more affected by time and succession. Silvicultural treatments including pruning, uprooting, and thinning have proven to be essential tools for nature conservation across various sites, aimed at enhancing habitat diversity in the face of ongoing climate change.
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  • 文章类型: Journal Article
    利什曼病在60多个国家流行,死亡人数众多。目前用于治疗利什曼病的化疗方法与严重的副作用有关。因此,有必要制定有效的,安全,和成本负担得起的抗利什曼原药候选药物。
    本研究旨在评估Prosopisjuliflora叶提取物(PJLME)对利什曼原虫的体外抗利什曼原虫活性。
    评价了PJLME对多尼乳杆菌寄生虫和小鼠巨噬细胞的细胞毒性。Further,各种体外实验,如ROS测定,线粒体膜电位测定,膜联蛋白v测定,细胞周期测定,和caspase3/7测定以了解细胞死亡的机制。通过利用HPTLC和GC-MS分析进行朱花假单胞菌的植物化学谱分析。
    PJLME在IC50为6.5μg/mL的显着较低的浓度下显示出抗石灰质活性。值得注意的是,有趣的是,PJLME的IC50浓度未显示出对小鼠巨噬细胞系的细胞毒性。所进行的实验证实了ROS诱导PJLME的电位,其不利地影响线粒体膜电位并引起线粒体膜电位的损失,从而引起ATP水平的损失。PJLME还在PJLME处理的多诺瓦尼乳杆菌中阻滞细胞周期并诱导凋亡样细胞死亡。
    结果清楚地确定了Prosopisjuliflora作为管理内脏利什曼病的有效和安全的自然资源的重要性。该发现可用作开发用于有效治疗内脏利什曼病的新型导联/制剂的基线参考。
    UNASSIGNED: Leishmaniasis is endemic in more than 60 countries with a large number of mortality cases. The current chemotherapy approaches employed for managing the leishmaniasis is associated with severe side effects. Therefore there is a need to develop effective, safe, and cost affordable antileishmanial drug candidates.
    UNASSIGNED: This study was designed to evaluate the in vitro antileishmanial activity of a Prosopis juliflora leaves extract (PJLME) towards the Leishmania donovani parasites.
    UNASSIGNED: PJLME was evaluated for its cytotoxicity against the L. donovani parasites and the mouse macrophage cells. Further, various in vitro experiments like ROS assay, mitochondrial membrane potential assay, annexin v assay, cell cycle assay, and caspase 3/7 assay were performed to understand the mechanism of cell death. Phytochemical profiling of P. juliflorawas performed by utilizing HPTLC and GC-MS analysis.
    UNASSIGNED: PJLME demonstrated antileishmanial activity at a remarkably lower concentration of IC50 6.5 μg/mL. Of note, interestingly PJLME IC50 concentration has not demonstrated cytotoxicity against the mouse macrophage cell line. Performed experiments confirmed ROS inducing potential of PJLME which adversely affected the mitochondrial membrane potential and caused loss of mitochondrial membrane potential and thereby ATP levels. PJLME also arrested the cell cycle and induced apoptotic-like cell death in PJLME treated L. donovani promastigotes.
    UNASSIGNED: The results clearly established the significance of Prosopis juliflora as an effective and safe natural resource for managing visceral leishmaniasis. The findings can be used as a baseline reference for developing novel leads/formulations for effective management of visceral leishmaniasis.
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  • 文章类型: Journal Article
    由于其毒性作用,处理纺织废水排放的有毒污染物对生物来说是一项挑战。在本研究中,研究了基于咪唑的离子液体处理的Prosopisjuliflora(ILPJS)和未经处理的P.juliflora(PJS)的比较生物吸附潜力,孔雀石绿(MG)从水溶液。纹理,表面形态,使用BET(Brunauer-Emmett-Teller)分析检查ILPJS和PJS的功能分析,SEM(扫描电子显微镜)分析,和FTIR(傅里叶变换红外光谱)分析。ILPJS的纹理性质(BET表面积)和含有不规则异质表面的表面形态比PJS显著改善,从而促进MG的显著生物吸附。在常规优化研究的基础上,发现使用ILPJS去除MG的基本生物吸附参数为:初始pH(9.0),接触时间(30分钟),和生物吸附剂用量(0.2g)。在40°C下,PJS和ILPJS的最大生物吸附能力分别为6.91和13.64mg/g,分别。通过热力学分析证实了MG的自发和吸热生物吸附。再生研究表明,直到第五个循环,ILPJS和PJS对MG的去除具有更大的可重用性。在以往文献的基础上,这是第一份比较使用ILPJS和PJS去除有毒污染物MG的报告。
    Prosopisjuliflora是一种入侵杂草,由于全年持续消耗水,对生态多样性和农村生计造成严峻挑战,导致地下水储量枯竭。为了控制它的入侵和增长,杂草已被用作去除有毒污染物的生物吸附剂,孔雀石绿(MG)。这是第一份报告,比较了使用基于咪唑鎓的离子液体(ILPJS)和原始朱立草(PJS)对朱立草进行生物吸附的方法。ILPJS对MG的生物吸附能力是PJS的1.97倍。生物吸附能力的增强可能是化学处理的朱草更好的质地和表面形态的可能性。热力学研究揭示了MG在PJS上生物吸附的吸热和自发性质。随着这种杂草在印度数千公顷土地上的入侵,PJS是去除有毒化学污染物和保持地下水位的理想生物吸附剂。
    Due to its toxicity effect, treating toxic pollutants discharged from textile effluent is challenging for living beings. In the present study, the comparative biosorption potential of imidazolium-based ionic liquid-treated Prosopis juliflora (ILPJS) and untreated P. juliflora (PJS) was investigated for the removal of toxic pollutant, malachite green (MG) from aqueous solution. The textural, surface morphology, and functional analysis of ILPJS and PJS were examined using BET (Brunauer-Emmett-Teller) analysis, SEM (Scanning electron microscopy) analysis, and FTIR (Fourier-transform infrared spectroscopy) analysis. Textural property (BET surface area) and surface morphology containing irregular heterogeneous surface for ILPJS were significantly improved than PJS, thereby facilitating significant biosorption of MG. Based on the conventional optimization studies, the essential biosorption parameters for the removal of MG using ILPJS were found to be: initial pH (9.0), contact time (30 min), and biosorbent dosage (0.2 g). The maximum biosorption capacity of PJS and ILPJS were obtained to be 6.91 and 13.64 mg/g at 40 °C, respectively. The spontaneous and endothermic biosorption of MG was confirmed by thermodynamic analysis. The regeneration study indicated the greater reusability of ILPJS and PJS for MG removal till the fifth cycle. Based on the previous literature, this is the first report comparing the removal of toxic pollutant MG using ILPJS and PJS.
    Prosopis juliflora is an invasive weed that causes a severe challenge to ecological diversity and rural livelihoods due to the continuous consumption of water throughout the year, leading to the depletion of groundwater reserves. To control its invasion and growth, weed has been applied as biosorbents to remove toxic pollutant, malachite green (MG). This is the first report comparing the pretreatment of P. juliflora using imidazolium-based ionic liquid (ILPJS) with raw P. juliflora (PJS) for the biosorption of MG. The biosorption capacity of ILPJS for MG removal was 1.97 times higher than PJS. The enhancement in biosorption capacity might be the possibility of better textural and surface morphology of chemically treated P. juliflora. Thermodynamic studies revealed the endothermic and spontaneous nature of the biosorption of MG on PJS. With the invasion of this weed over thousands of hectares of land in India, PJS is the ideal biosorbent for removing toxic chemical pollutants and preserving the groundwater level.
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  • 文章类型: Journal Article
    考虑到需要从非食用油来源生产生物柴油,并考虑到ProsopisJuliflora(JF)被确定为埃塞俄比亚的高度入侵物种,这项研究的重点是生物柴油生产从一个可能的和有前途的替代原料。本研究的目的是通过酯交换分析埃塞俄比亚变体Juliflora基于生物柴油(JFB)的生产,通过探索各种工艺参数和官能团表征的影响进行优化(用GC-MS,FT-IR和NMR)包括流变行为,之前还没有报道。根据ASTM协议测试,已发现Juliflora的甲酯具有以下主要燃料性质:运动粘度(mm2/s)3.395,十六烷值52.9,酸值(mgkoh/g)0.28,密度(gm/ml)0.880,热值(MJ/kg)44.4,甲酯含量(%)99.8和闪点(°C)128,铜带腐蚀值1a,%FFA(游离脂肪酸)0.14。与柴油相比,粘度,密度,JFB的闪点高于柴油,虽然它具有相似的热值,但更重要的是高于大多数其他生物柴油。基于使用响应面方法的评估,甲醇浓度与催化剂负载量,温度,和反应时间被确定为最重要的影响工艺参数。观察到甲醇分解的最佳摩尔比为6:1,催化剂浓度为0.5wt%,在55°C下持续60分钟,生物柴油收率为65%。JFB在70分钟时的最大产量为130ml,在10分钟时的最小产量为40ml,这表明随着混合时间的增加,JFB产量倾向于增加到一定的时间限制。从2.5kg压碎的种子,观察到用己烷溶剂压碎的种子的最大粗油产量在3天内为480ml。傅里叶变换红外分析(FT-IR)揭示了在OH自由基上存在生物柴油所需的所有所需官能团,波数为3314.40cm-1,脂肪族甲基C-H在2942.48cm-1具有官能团(CH-3,-CH2-),和在2832.59cm-1处的亚甲基C-H。气相色谱-质谱仪(GC-MS)研究证实JFB中存在较高的酯含量,具有68.81%的较高不饱和度。脂肪酸,油酸的饱和度较低,为4.5%,而棕榈酸的阈值水平较低,为2.08%。流变试验表明,在生物柴油要求的范围内,剪切应力和粘度随温度的升高而降低,牛顿行为得到证实。JFB在低温下具有相当高的粘度和剪切速率。1HNMR(核磁共振)研究确定JFB具有必要的成分;并且脂肪族共振发生在1.5-3.0ppm的化学位移区域中。重要区域表明质子与杂芳族化合物结合,醛类,如13CNMR光谱所示。FT-IR的发现,GC-MS,1HNMR,和13CNMR是一致的,因此验证了JFB中大量官能团的存在。由于JFB拥有必要的生物柴油燃料属性,ProsopisJuliflora需要作为埃塞俄比亚有前途的生物柴油原料,以减轻进口燃料的负担,同时解决化石燃料燃烧释放的排放困难。
    Considering the need for biodiesel production from non-edible oil sources and taking into account the fact that Prosopis Juliflora (JF) is identified as a highly invasive species in Ethiopia, this research focuses on biodiesel production from a possible and promising alternative feedstock. The objective of this study is to analyze Ethiopian variant Juliflora based biodiesel (JFB) production through transesterification, carry out optimization by exploring the effects of various process parameters and characterization of functional groups (with GC-MS,FT-IR and NMR) including rheological behavior, not yet been reported earlier. As per ASTM protocol testing, the methyl ester of Juliflora has been found to have the following main fuel properties: kinematic viscosity (mm2/s) 3.395, cetane number 52.9, acid number (mgkoh/g) 0.28, density (gm/ml) 0.880, calorific value (MJ/kg) 44.4, methyl ester content (%) 99.8, and flashpoint (°C) 128, copper strip corrosion value 1a,%FFA (free fatty acid) 0.14. When compared with those of diesel, the viscosity, density, and flash point of JFB are seen to be higher than those of diesel, although it has a similar calorific value but more importantly higher than most of the other biodiesels. Based on an assessment using response surface methodology, methanol concentration together with catalyst loading, temperature, and reaction time are determined to be the most important influencing process parameters. The best molar ratio for methanolysis was observed to be 6:1 with a catalyst concentration of 0.5 wt% at 55 °C for 60 min for biodiesel yield at 65%. The JFB maximum yield of 130 ml at 70 min and the minimum yield of 40 ml at 10 min demonstrate that as mixing time increases, JFB yield tend to increase up to a certain time limit. The maximum raw oil yield rom crushed seed with hexane solvent was observed to be 480 ml within 3 days from 2.5 kg of crushed seed. The Fourier transform infrared analysis (FT-IR) revealed the presence of all desired functional groups necessary for biodiesel on OH radicals at wave numbers of 3314.40 cm-1, Aliphatic methyl C-H at 2942.48 cm- 1 with a functional group (CH-3-,-CH2-), and methylene C-H at 2832.59 cm-1. The gas chromatography-mass spectrometer (GC-MS) study confirmed the higher ester content present in the JFB with a higher unsaturation level of 68.81%. The fatty acid, oleic acid has a lower saturation level of 4.5%, while palmitic acid has a lower threshold level of 2.08%. The Rheometer test showed that shear stress and viscosity reduced with increasing temperature within the range of biodiesel requirements, and the Newtonian behavior was confirmed. The JFB has a fairly high viscosity and shear rate at low temperatures. The 1H NMR (nuclear magnetic resonance) study established that JFB has a necessary ingredient; and aliphatic resonances occur in the chemical shift region of 1.5-3.0 ppm. Significant regions indicate protons bound to heteroaromatics, aldehydes, as shown by 13C NMR spectrum. The findings from the FT-IR, GC-MS, 1H NMR, and 13C NMR are in agreement thus validating the presence of numerous functional groups in JFB as such. Since JFB possesses the requisite biodiesel fuel attributes, Prosopis Juliflora need to be pursued as a promising biodiesel feedstock in Ethiopia for alleviating the burden of imported fuels while also addressing difficulties with emissions released by the combustion of fossil fuels.
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