Oxidative stability

氧化稳定性
  • 文章类型: Journal Article
    这项研究探讨了姜黄副产品的潜力,称为姜黄素去除姜黄油树脂(CRTO),延长花生酱的保质期。CRTO,富含姜黄素,添加到花生酱配方中以评估其防腐效果,风味影响,和营养益处。结果表明,CRTO油和姜黄素通过延缓酸败有效延长了花生酱的保质期。该研究还比较了使用氧清除剂膜(OSF)包装的结果。随着时间的推移,水活度和油分离增加,但CRTO石油和OSF帮助减轻了这些影响。感官评估有利于CRTO油和姜黄素,虽然微生物分析证实了对照和OSF样品在27°C和65%RH下六个月的安全性,并在37°C和95%RH下持续四个月。这项研究提出了一种自然和可持续的方法来延长花生酱的保质期,同时丰富姜黄素,对食品工业有重大影响。
    This study explores the potential of Curcuma longa byproducts, called Curcuminoid removed turmeric oleoresin (CRTO), to extend the shelf life of peanut butter. CRTO, rich in curcuminoids, was added to peanut butter formulations to assess its preservative effects, flavour impact, and nutritional benefits. Results demonstrated that CRTO oil and curcuminoids effectively prolonged peanut butter shelf life by delaying rancidity. The study also compared results using oxygen scavenger film (OSF) packaging. Over time, water activity and oil separation increased, but CRTO oil and OSF helped to mitigate these effects. Sensory evaluations favored CRTO oil and curcuminoids, while microbial analysis confirmed safety of both the control and OSF samples for six months at 27 °C and 65% RH, and for four months at 37 °C and 95% RH. This study proposes a natural and sustainable method for extending peanut butter shelf life while enriching it with curcuminoids, with significant implications for the food industry.
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  • 文章类型: Journal Article
    本研究旨在评估小球藻补充对肉鸡日粮的影响,单独或与维生素E联合使用,关于肉质参数,营养价值,和氧化稳定性在储存时间。在180COBB500肉鸡(14日龄)上进行了实验,被分配到六种治疗中,遵循2×3阶乘排列。玉米-豆粕日粮补充了三个水平的普通梭菌(C1组0%,E1组1%,E2组2%),两种水平的维生素E(C1中0%,C2中250ppm),和它们的组合(1%C.vulgaris+250ppm维生素(E3),2%的普通念珠菌+250ppm维生素(E4))。普通梭菌的饮食掺入,包括那些补充了维生素E的,导致肉类蛋白质含量显着增加。在2%普通梭菌+维生素E组中,DPA和DHA水平分别增加2.01倍和1.60倍。PUFA/SFA比率在所有饮食处理中均增加(p<0.0001)。HPI和h/H记录的最高值是补充2%普通梭菌的结果,与降低胆固醇水平的积极作用有关。与对照组相比,补充2%普通梭菌和维生素E显示大腿肉中维生素E浓度增加了1.45倍,是这个实验中大腿肉中记录的最高水平。实验组大腿肉中的肌红蛋白浓度较低,而与对照组相比,同组的脱氧肌红蛋白增加。在肉鸡日粮中加入普通梭菌(1%和2%)与维生素E(250mg/kg)的组合,在冷藏7天后表现出对脂质氧化的最佳预防。由二次氧化产物评估的最高效率因子定义。
    This study aimed to assess the impact of Chlorella vulgaris supplementation in broilers\' diet, alone or in combination with vitamin E, on meat quality parameters, nutritional value, and oxidative stability during storage time. An experiment was conducted on 180 COBB 500 broiler chickens (14 days old), assigned into six treatments, following a 2 × 3 factorial arrangement. A corn-soybean meal diet was supplemented with three levels of C. vulgaris (0% in group C1, 1% in E1, 2% in E2), two levels of vitamin E (0% in C1, 250 ppm in C2), and a combination of them (1% C. vulgaris + 250 ppm vitamin (E3), 2% C. vulgaris + 250 ppm vitamin (E4)). Dietary incorporation of C. vulgaris, including those supplemented with vitamin E, resulted in a significant increase in meat protein content. DPA and DHA levels increased by 2.01-fold and 1.60-fold in the 2% C. vulgaris + vitamin E group. The PUFA/SFA ratio was increased across all dietary treatments (p < 0.0001). HPI and h/H registered the highest values as a result of 2% C. vulgaris supplementation, being linked with a positive effect in lowering cholesterol levels. Supplementation with 2% C. vulgaris and vitamin E exhibited a 1.45-fold increase in vitamin E concentration in thigh meat compared to the control group, being the highest level registered in thigh meat in this experiment. Metmyoglobin concentrations registered lower values in the thigh meat of the experimental groups, while deoxymyoglobin increased in the same groups when compared to the control group. The inclusion of C. vulgaris (1% and 2%) in combination with vitamin E (250 mg/kg) in broiler diets exhibited the best prevention of lipid oxidation after 7 days of refrigerated storage, defined by the highest efficiency factors assessed in terms of secondary oxidation products.
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  • 文章类型: Journal Article
    在本文中,以虎子油(TNO)为芯材,采用喷雾干燥法,以大豆分离蛋白(SPI)和麦芽糊精(MD)为壁材,并对其理化性质和稳定性进行了表征和分析。在最佳条件下,TNOM的包封率(EE)可达91.23%。值得注意的是,在60°C下储存60天后,TNO的过氧化值(PV)几乎是包封TNO的21.8倍。此外,TNOM在200°C以下具有良好的热稳定性,并且足以满足一般的食品加工需求。通过拟合阿伦尼乌斯氧化动力学模型,据预测,产品在25°C下储存的保质期为352.48d。因此,有望在未来应用于高油酸食品的开发。这项研究为TNO在食品工业中的利用和应用范围提供了理论框架。
    In this paper, tiger nut oil-loaded microcapsules (TNOMs) were prepared by complexation soybean protein isolate (SPI) and maltodextrin (MD) as wall materials using the spray drying method with tiger nut oil (TNO) as the core material, and its physicochemical properties and stabilities were characterized and analyzed. Under the optimum conditions, the encapsulation efficiency (EE) of TNOMs could reach up to 91.23%. Of note, after 60 days of storage at 60 °C, the peroxide value (PV) of TNO was almost 21.8 times as much as that of TNO encapsulated. Furthermore, TNOMs had good thermal stability below 200 °C and are sufficient for the general food processing needs. By fitting Arrhenius oxidation kinetics model, it was predicted that the shelf life of the product stored at 25 °C was 352.48 d. Therefore, it is promised to be applied to the development of high oleic acid food in the future. This study offered a theoretical framework for utilization and broadening the range of applications of TNO in the food industry.
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  • 文章类型: Journal Article
    本研究调查了甘氨酸(Gly)和戊糖片(Pp)的应用效果,单独或组合,关于物理化学性质,氧化稳定性,哈尔滨干香肠的口感品质。结果表明,经过9天的发酵,Gly+Pp组水分含量(19.04%)显著降低(P<0.05),水活度(0.686),和pH值(4.78),值得注意的是(P<0.05)更高的乳酸菌计数(8.11logCFU/g香肠)和红度值(17.2),与其他三组相比(P<0.05)。此外,Gly+Pp组的干香肠表现出最低的过氧化值(0.34meq/kg香肠),硫代巴比妥酸反应性物质(0.46MAD/kg香肠),发酵过程中的蛋白质羰基含量(1.26nmol/kg蛋白质),紧随其后的是Gly集团,PP组,和对照组。电子舌(e-舌)和感官评价显示,与戊糖P.pososacusR1和Gly的组合处理导致优异的味道特征。此外,偏最小二乘回归(PLSR)分析表明,使用电子舌表征的味道品质与感官评价结果一致,和总游离氨基酸(FAA)和有机酸有助于干香肠的味道特性。总之,Gly和PentosaceusR1的联合应用增强了理化性质,氧化稳定性,哈尔滨干香肠的味道。
    This study investigated the effects of the application of glycine (Gly) and Pediococcus pentosaceus R1(Pp), alone or in combination, on the physicochemical properties, oxidative stability, and taste quality of Harbin dry sausages. The results demonstrated that after nine days of fermentation, the Gly + Pp group exhibited significantly (P < 0.05) lower moisture content (19.04%), water activity (0.686), and pH (4.78) values, alongside notably (P < 0.05) higher lactic acid bacteria count (8.11 log CFU/g sausage) and redness value (17.2), compared to the other three groups (P < 0.05). In addition, the dry sausages in the Gly + Pp group exhibited the lowest peroxide value (0.34 meq/kg sausage), thiobarbituric acid reactive substances (0.46 MAD/kg sausage), and protein carbonyl content (1.26 nmol/kg protein) during fermentation, followed by the Gly group, Pp group, and control group. Electronic tongue (e-tongue) and sensory evaluations revealed that the combined treatment with P. pentosaceus R1 and Gly resulted in superior taste characteristics. Besides, partial least squares regression (PLSR) analysis illustrated that the taste qualities characterized using the e-tongue were accordant with the sensory evaluation consequences, and total free amino acids (FAAs) and organic acids contributed to the dry sausages\' taste properties. In conclusion, the combined application of Gly and P. pentosaceus R1 enhanced the physicochemical properties, oxidative stability, and taste profile of Harbin dry sausages.
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  • 文章类型: Journal Article
    本研究探索了介质研磨对玉米淀粉(CS)和槲皮素(QC)络合的影响,玉米-槲皮素(CS-QC)复合物的相互作用机制及Pickering乳化能力。QC/CS比为1:24的CS-QC具有76.00±1.30%的最高包封效率。平均体积-平均直径,CS-QC的平均全分子大小(Rh)和去支链淀粉链长度在研磨后显着降低。衰减全反射-傅里叶变换红外光谱(ATR-FTIR)和X射线光电子能谱(XPS)光谱证实了CS和QC之间的络合。经5%CS-QC复合粒子稳定的Pickering乳液经120min研磨后的乳化能力和乳化稳定性分别达到100.00%和100.00%。由这些复合颗粒稳定的Pickering乳液表现出优异的氧化稳定性。这些结果表明,通过增强非共价相互作用,介质研磨可能是获得淀粉-多酚复合物的有效物理方法。它不仅可以用作食品级皮克林乳化剂,还能延缓脂质氧化。
    This research explored the effect of media milling on complexation of corn starch (CS) and quercetin (QC), interaction mechanism and Pickering emulsifying ability of corn-quercetin (CS-QC) complex. CS-QC with QC/CS ratio of 1:24 had the highest encapsulation efficiency of 76.00 ± 1.30 %. Average volume-mean diameter, average whole molecular size (Rh) and debranchedamylopectinchain length of CS-QC were significantly decreased after milling. Attenuated Total Reflectance-Fourier Transform Infrared spectroscopy (ATR-FTIR) and X-ray photoelectron spectroscopy (XPS) spectra confirmed the complexation between CS and QC. Emulsifying capacity and emulsion stability of Pickering emulsion stabilized by 5 % CS-QC complex particles after 120 min milling reached 100.00 % and 100.00. Pickering emulsions stabilized by these complex particles demonstrated superior oxidative stability. These results demonstrated that media milling could be an efficient physical approach to obtain starch-polyphenol complex by enhancing non-covalent interactions, which could not only be used as food-grade Pickering emulsifiers, but also retard lipid oxidation.
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  • 文章类型: Journal Article
    生物柴油有几个缺点,比如容易氧化,具有降低的稳定性,储存时间有限。与生物柴油相容的抗氧化剂被用于解决其缺点。抗氧化剂的使用有效地提高了生物柴油的质量。提高用作清洁能源的生物柴油的质量有利于全球经济和生态。因此,我们相信,我们的工作将有助于全球生物柴油行业的发展。这项研究使用了由20%生物柴油和80%柴油组成的混合物。使用oxifast装置以3000ppm(ppm)的浓度测试了在共混物中的Isatin-氨基硫脲作为添加剂,并与化学抗氧化剂Trolox进行了比较。FT-IR,DSC,和TGA用于表征这些样品。DSC测量样品结晶温度(Tc)。与非抗氧化剂柴油样品D100相比,具有抗氧化剂的样品显示出降低的值。进行若干DSC测试以确定各种样品的抗氧化剂强度。结果表明,随着抗氧化剂的加入,FT-IR光谱的抗氧化作用区域变得更加清晰。额外的抗氧化剂是有效的。生物柴油的氧化稳定性可在不同浓度下改善。使用Kissinger确定了在非等温条件下Isatin-硫代氨基脲的热分解动力学,小泽,和Boswell技术。化合物1和2的活化能分别计算为137-147kJmol-1和173-183kJmol-1。
    Biodiesel has several drawbacks, such as being prone to oxidation, having reduced stability, and having limited storage time. Antioxidants compatible with biodiesel are being used to address its drawbacks. Utilizing antioxidants effectively improves the quality of biodiesel. Enhancing the quality of biodiesel for use as a clean energy source benefits both the global economy and ecology. Therefore, we believe that our work will contribute to the advancement of the biodiesel industry worldwide. This study used blends consisting of 20% biodiesel and 80% diesel fuel. Isatin-thiosemicarbazones were tested as additives in blends at a concentration of 3000 parts per million (ppm) using an oxifast device and were compared with the chemical antioxidant Trolox. FT-IR, DSC, and TGA were used to characterize these samples. DSC measured sample crystallization temperatures (Tc). Samples with antioxidants showed decreased values compared to the non-antioxidant diesel sample D100. Several DSC tests were conducted to determine the antioxidant strengths of various samples. The results show that the FT-IR spectrum\'s antioxidant effect regions grow clearer with antioxidants. The extra antioxidant is effective. Biodiesel\'s oxidative stability improves with isatin-thiosemicarbazones at varying concentrations. The kinetics of thermal decomposition of isatin-thiosemicarbazones under non-isothermal conditions were determined using the Kissinger, Ozawa, and Boswell techniques. The activation energies of compounds 1 and 2 were calculated as 137-147 kJ mol-1 and 173-183 kJ mol-1, respectively.
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  • 文章类型: Journal Article
    烤核桃仁显著提高了其油脂的氧化稳定性和感官特性。然而,焙烧温度对核桃油主要成分和微量营养素分子变化的影响尚不清楚。在这里,整合脂质组学和代谢组学,以全面描述在不同烘烤温度(30°C,120°C,140°C,160°C,和180°C)。脂质组学显示,甘油脂的含量,鞘脂,甘油磷脂随着焙烧温度而降低,而氧化脂肪酸和甘油三酯增加。亚油酸和亚麻酸的比例随焙烧温度而变化,在140°C时最接近4-6:1,160°C,180°C主要种类的微量营养素在120°C和140°C的焙烧温度下显示出增加的趋势,然后在160°C和180°C时降低。核桃油中首次发现的脂溶性氨基酸随烘烤温度的变化而变化。相关分析表明,较高的脂溶性氨基酸和酚类物质含量与在140°C下获得的核桃油的氧化稳定性增强呈正相关。此外,谷氨酰胺和5-氧代-D-脯氨酸有望成为区分新鲜和烤核桃油的潜在生物标志物。该研究有望为核桃油在焙烧过程中主要脂质和微量营养素的变化机理提供新的见解。
    Roasting walnut kernel significantly improves the oxidative stability and sensory properties of its oil. However, the effect of roasting temperatures on the molecular change of main components and micronutrients in walnut oil is still unclear. Herein, lipidomics and metabolomics were integrated to comprehensively profile the walnut oil obtained at different roasting temperatures (30 °C, 120 °C, 140 °C, 160 °C, and 180 °C). Lipidomics showed that the content of glycerolipids, sphingolipids, and glycerophospholipids decreased with roasting temperatures, while the oxidized fatty acids and triglycerides increased. Ratios of linoleic acid and linolenic acid varied with roasting temperatures and were most close to 4-6:1 at 140 °C, 160 °C, and 180 °C. Major classes of micronutrients showed a tendency to increase at the roasting temperature of 120 °C and 140 °C, then decrease at 160 °C and 180 °C. Liposoluble amino acids identified for the first time in walnut oil varied with roasting temperatures. Correlation analysis demonstrated that the higher contents of liposoluble amino acids and phenolics are positively associated with enhanced oxidative stability of walnut oil obtained at 140 °C. Furthermore, glutamine and 5-oxo-D-proline were expected to be potential biomarkers to differentiate the fresh and roasted walnut oil. The study is expected to provide new insight into the change mechanism of both major lipids and micronutrients in walnut oil during the roasting process.
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  • 文章类型: Journal Article
    从金银花花蕾中提取的精油(LJEO)用于向日葵油的高温(65℃)加速保存。在目前的调查中,以800ppm的浓度添加精油可显着抑制向日葵油氧化稳定性的降低。这种积极的效果是通过显著阻碍酸度值(AV)的降低来实现的,过氧化值(PV),ρ-茴香胺值(AnV),总氧化值(TOTOX)(p<0.01),和硫代巴比妥酸反应性物质(TBARS)的水平,在232/268nm处的吸光度(K232/K268)和总极性化合物(TPC)(p<0.01)。此外,它也显著增强了Maye的感官属性,包括味道,风味,和外观,通过添加某些潜在的香料分子(p<0.01)来提高其总体可接受性。此外,LJEO的主要化合物之一,丁香酚,在产品的传统油炸过程中表现出显著的天然抗氧化性能,梅耶.因此,与丁香酚一起,精油LJEO可以用作典型的长期保存甚至传统的油炸程序的可能有效的抗氧化剂,并开发为整个食品工业从植物中提取的有效抗氧化剂。
    The essential oil extracted from the flower buds of Lonicerae japonicae (LJEO) was employed in the high-temperature (65℃) accelerated preservation of sunflower oil. In the present investigation, the addition of the essential oil at a concentration of 800 ppm significantly inhibited the decrease in the oxidative stability of sunflower oil. This positive effect was achieved by significantly hindering the reduction in acidity value (AV), peroxide value (PV), p-anisidine value (AnV), the total oxidation value (TOTOX) (p < 0.01), and the levels of thiobarbituric acid reactive substance (TBARS), the absorbance at 232/268 nm (K232/K268) and total polar compounds (TPC) (p < 0.01). Besides, it also significantly enhances the sensory attributes of Maye, including taste, flavor, and appearance, improving its overall acceptability through the addition of certain potential fragrance molecules (p < 0.01). Furthermore, one of the primary chemical compounds in LJEO, eugenol, has demonstrated significant natural antioxidant properties in the traditional deep-frying procedure for the product, Maye. Consequently, together with eugenol, the essential oil LJEO could be employed as a possible effective antioxidant for the typical long-term preservation and even the traditional deep-frying procedures, and developed as effective antioxidant extracted from plants for the whole food industry.
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  • 文章类型: Journal Article
    具有高离子电导率和良好化学稳定性的质子交换膜对于实现直接甲醇电池(DMFC)的高功率密度和长寿命是关键的。在这里,将两性离子分子接枝到聚偏氟乙烯(PVDF)纳米纤维表面,得到功能化PVDF多孔基材(SBMA-PDA@PVDF)。然后,磺化聚醚醚酮(SPEEK)填充到SBMA-PDA@PVDF的孔中,并通过H2SO4进一步离子交联制备复合膜(SBMA-PDA@PVDF/SPEEK)。两性离子界面上的碱性基团不仅可以与SPEEK建立离子交联,增加化学稳定性,减少溶胀,但也用作随后H2SO4交联的吸附位点,以显着增强质子电导率。膜实现了超高质子传导率(165.34mScm-1,80°C),是纯SPEEK的2.12倍。此外,SBMA-PDA@PVDF/SPEEK膜在Fenton试剂中浸泡12h后,氧化稳定性显着提高,质量保留率为91.6%,而纯SPEEK完全分解。满意,用SBMA-PDA@PVDF/SPEEK组装的DMFC的峰值功率密度为99.01mWcm-2,是商用Nafion212(48.88mWcm-2)的两倍。235h耐久试验后,仅观察到11%的电压损失。
    Proton exchange membranes with high ionic conductivity and good chemical stability are critical for achieving high power density and long lifespan of direct methanol cells (DMFCs). Herein, a zwitterionic molecule was grafted onto the surface of polyvinylidene fluoride (PVDF) nanofibers to obtain functionalized PVDF porous substrate (SBMA-PDA@PVDF). Then, sulfonated poly(ether ether ketone) (SPEEK) was filled into the pores of SBMA-PDA@PVDF, and further ionic cross-linked via H2SO4 to prepare the composite membrane (SBMA-PDA@PVDF/SPEEK). The basic groups on the zwitterionic interface could not only establish ionic cross-linking with SPEEK to increase chemical stability and reduce swelling, but also serve as the adsorption sites for subsequent H2SO4 cross-linking to significantly enhance proton conductivity. Super-high proton conductivity (165.34 mS cm-1, 80 °C) was achieved for the membrane, which was 2.12 times higher than that of the pure SPEEK. Moreover, the SBMA-PDA@PVDF/SPEEK membrane exhibited remarkably improved oxidative stability of 91.6 % mass retention after soaking in Fenton\'s agent for 12 h, while pure SPEEK completely decomposed. Satisfactorily, the DMFC assembled with SBMA-PDA@PVDF/SPEEK exhibited a peak power density of 99.01 mW cm-2, which was twice as much as that of commercial Nafion 212 (48.88 mW cm-2). After 235 h durability test, only 11 % voltage loss was observed.
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  • 文章类型: Journal Article
    锌是动物必需的,在酶系统和各种生化反应中起着至关重要的作用。确保通过饮食摄入足够的锌以保持有效的体内平衡是至关重要的。只有少数关于奶牛泌乳日粮中锌效应的研究评估了对牛奶和奶酪质量的影响,矛盾的发现。将24头Friesian品种的母牛分成两组(CTR:对照和TRT:处理组)。选择奶牛的年龄,体重,产卵和泌乳期(泌乳中期,140-160天)。CTR日粮含有38mg/kg的Zn,TRT日粮用120mg/kg的完全饲料供给60天。当前调查的目的是评估泌乳弗利西亚奶牛的膳食氧化锌(ZnO)整合对化学成分的影响,锌含量,脂肪酸和蛋白质谱,氨含量,pH值,aw,纹理,和奶酪的感官特征,并提高牛奶和奶酪的化学营养质量。结果表明,添加ZnO可以减少嗜温好氧菌和假定的假单胞菌。增长,蛋白水解,生物胺含量,脂质氧化,气味强度和酸味和增加的硬度,发胶,耐嚼,奶酪的弹性。生物胺被认为是食品安全的重要方面。ZnO在奶牛日粮中的整合可以代表一种有希望的提高质量策略,Caciotta奶酪的安全性和保质期。
    Zinc is essential for animals, playing a vital role in enzyme systems and various biochemical reactions. It is crucial to ensure a sufficient intake of zinc through the diet to maintain efficient homeostasis. Only few studies on zinc effect in cow lactating diet evaluated the effects on milk and cheese quality, with conflicting findings. 24 cows of the Friesian breed were divided into two groups (CTR: control and TRT: treated group). Cows were selected for age, body weight, parity and phase of lactations (mid lactation, 140-160 days). CTR diet contained 38 mg/kg of Zn and TRT diet was supplied with 120 mg/kg of complete feed for 60 days. The objective of current investigation was to evaluate the impact of a dietary Zinc Oxide (ZnO) integration of lactating Friesian cows on chemical composition, zinc content, fatty acid and proteic profile, ammine content, pH, aw, texture, and sensory profile of cheese and to improve the chemical-nutritional quality of milk and cheese. The results showed that ZnO supplementation reduced mesophilic aerobic bacteria and Presumptive Pseudomonas spp. growth, proteolysis, biogenic amines content, lipid oxidation, odour intensity and sour and increased hardness, gumminess, chewiness, elasticity of cheese. Biogenic amines are considered an important aspect of food safety. ZnO integration in cow diet could represent a promising strategy for improving the quality, the safety and shelf-life of caciotta cheese.
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