具有有机功能图案的无机二维(2D)材料的改性对于优化其性能具有很高的要求。但这仍然是一个艰巨的挑战。有机金属硫族化物(OMC)是一种新兴的二维材料,金属硫属化物层由长距离有序有机功能基序共价锚定,这些材料是非常理想的,但不可能通过传统方法实现。OMC的无机层和有机功能基序都是高度可设计的,因此为这类2D材料提供了结构和性能方面的巨大差异。这篇小型评论旨在回顾OMC及其散装前体的最新发展。首先,介绍了OMC本体前驱体的结构类型。第二,OMC2D材料的合成及其在光电中的应用,催化作用,传感器,并对能量转移进行了探索。最后,讨论了未来OMC研究的挑战和前景。
The modification of inorganic two-dimensional (2D) materials with organic functional motifs is in high demand for the optimization of their properties, but it is still a daunting challenge. Organic metal chalcogenides (
OMCs) are a type of newly emerging 2D materials, with metal chalcogenide layers covalently anchored by long-range ordered organic functional motifs, these materials are extremely desirable but impossible to realize by traditional methods. Both the inorganic layer and organic functional motifs of
OMCs are highly designable and thus provide this type of 2D materials with enormous variety in terms of their structure and properties. This Minireview aims to review the latest developments in
OMCs and their bulk precursors. Firstly, the structure types of the bulk precursors for
OMCs are introduced. Second, the synthesis and applications of OMC 2D materials in photoelectricity, catalysis, sensors, and energy transfer are explored. Finally, the challenges and perspectives for future research on
OMCs are discussed.