Microplastic release

  • 文章类型: Journal Article
    每年,来自陆地河流的近115-241万吨塑料在一定条件下经历了破碎,并定居在河口三角洲和浅海陆架地区,使这个地区成为陆基微塑料的“汇”。由于其快速沉积速率,相对较软的沉积物床,和浅水深度,河口三角洲地区在高风浪条件下容易液化。这可能会在液化过程中释放深埋的微塑料颗粒,对海洋生态和人类健康构成进一步威胁。为了研究这种现象,使用水箱进行了实验室实验,以模拟波浪引起的沉积物床液化。结果表明,在波浪液化的影响下,56.2%的微塑料颗粒被释放回沉积物表面,更大的颗粒被更大程度地释放。根据这些实验结果,本研究还分析和讨论了波浪诱导液化过程中沉积物微塑料颗粒的释放速率和机理,估计在实验条件下微塑料颗粒的最大释放速率可以达到0.34mm/min。
    Every year, almost 1.15-2.41 million tons of plastic from terrestrial rivers undergo fragmentation under certain conditions and settle in the estuarine delta and shallow marine shelf areas, making this region a \"sink\" for land-based microplastics. Owing to its fast deposition rate, relatively soft sediment bed, and shallow water depth, the estuarine delta region is prone to liquefaction under high wind and wave conditions. This could potentially release deeply buried microplastic particles during the liquefaction process, posing further threats to marine ecology and human health. To investigate this phenomenon, laboratory experiments were conducted using a water tank to simulate wave-induced liquefaction of sediment beds. The results showed that under the influence of wave-induced liquefaction, 56.2 % of microplastic particles were released back into the sediment surface, with larger particles being released to a greater extent. Based on these experimental results, this study also analyzed and discussed the release rate and mechanisms of microplastic particles from sediment during wave-induced liquefaction, estimating that the maximum release rate of microplastic particles under the experimental conditions could reach 0.34 mm/min.
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  • 文章类型: Journal Article
    全球对微塑料(MPs)的关注正在增加,因为这些物质对生态系统和人类健康构成潜在威胁。一次性杯子,经常用作饮料的容器,通常由塑料或涂塑纸制成。在使用期间从一次性杯子释放MP可以为人类提供直接暴露途径。在这项研究中,90批商用一次性杯子的MP释放能力,包括聚乙烯(PE)涂层纸杯,聚丙烯(PP)杯,和聚苯乙烯(PS)杯,在日常使用条件下进行了调查,释放的MP颗粒的性质用拉曼光谱表征,扫描电子显微镜(SEM),和原子力显微镜(AFM)。在本研究中,对于每个测试的杯子,检测释放到含有饮料中的MP。释放的MPs颗粒呈不规则形状并且主要小于20μm。对于PE涂层纸杯,释放的MP的数量在675-5984、781-4951和838-5215颗粒/L的范围内,PP杯和PS杯,分别,当在95°C下含有纯水20分钟时。在实验条件下,在三种类型的杯子中没有观察到MP释放量的显著差异。发现高温促进MP从一次性杯子中的释放。当杯子第二次使用时,MP释放是值得注意的,虽然比第一次使用略低。与超纯水相比,酸性碳酸饮料明显增强了PE涂层杯子中MP的释放。
    Global concern over microplastics (MPs) is increasing because of the potential threat these substances pose to ecosystem and human health. Disposable cups, frequently used as containers of beverages, are typically made of plastic or plastic-coated paper. The release of MPs from disposable cups during use may provide a direct exposure pathway for humans. In this study, the MP release capacities of 90 batches of commercial disposable cups, including polyethylene (PE)-coated paper cups, polypropylene (PP) cups, and polystyrene (PS) cups, were investigated under daily use conditions, and the properties of released MP particles are characterized with Raman spectroscopy, scanning electron microscopy (SEM), and atomic force microscopy (AFM). The MPs release into containing beverages is detected for each of the tested cups in this study. The released MPs particles are in irregular shapes and dominantly smaller than 20 μm. The quantities of released MPs are in the range of 675-5984, 781-4951, and 838-5215 particles/L for PE-coated paper cups, PP cups and PS cups, respectively, when containing pure water at 95 °C for 20 min. No significant difference in the quantity of MP released is observed among the three types of the cups in the experimental conditions. High temperature is found to promote the release of MPs from disposable cups. The MP release is notable when the cups are used for a second time, although at a slightly lower level than the first use. Acidic carbonated beverages obviously enhance MP release from PE-coated cups over that of ultrapure water.
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  • 文章类型: Journal Article
    Microplastic particles and fibers are increasingly being detected in our surface and ground waters as well as within a wide range of aquatic species. Their presence in the environment is largely due to in situ generation from physical and chemical weathering of larger plastics, and thus has left environmental community concerned in the post-banned era of microbead use in personal care products through the passage of Microbead-Free Waters Act in the United States. To improve understanding of secondary microplastic formation, accelerated weathering has been conducted on four materials (high-density polyethylene, high impact polystyrene, nylon 6, and polypropylene) under ultraviolet radiation (equivalent to 44 days in full sun) in simulated seawater. Physical and chemical characterization of the plastics were completed following ultraviolet exposure. This simulated weathering generated microfibers from high-density polyethylene and nylon 6, while high impact polystyrene and polypropylene did not physically degrade. The techniques used were applied to sediment samples containing plastic pellets collected from Cox Creek in Port Comfort, TX (near a large plastics manufacturer), which were purified for analysis and were found to contain microplastics composed of polypropylene and polyethylene. These findings can be used to determine degradation pathways and plastic source tracking, which can facilitate risk assessment and environmental management.
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