We obtained historical and observational data on phytoplankton communities from 1959 to 2023 to explore the responses of the phytoplankton community structure to long-term environmental changes in the southern Yellow Sea (SYS), China. The results revealed a decrease in the proportions of diatom cell abundance within the phytoplankton community by 8 %, accompanied by a corresponding increase in that of dinoflagellates. Dominant phytoplankton species were mainly chain-forming diatoms before 2000, and large dinoflagellate species from the genera Tripos and Noctiluca increased their dominance after 2000. Warm-water phytoplankton species have increased in dominance over the study period. Correlation analysis revealed that the ocean warming and alterations in nutrient structure (N/P and Si/N ratios) were mostly responsible for the long-term evolution trend, and these changes may result in an increase in dinoflagellate harmful algal blooms, reduced efficiency of the biological carbon pump, and heightened hypoxia in the future, which should draw our attention.

In 2019, South Korea launched the Geostationary Environment Monitoring Spectrometer (GEMS) to observe trace gases with an hourly temporal resolution. Compared to previous payloads on polar-orbiting satellites, the GEMS payload has significant advantages in detecting the diurnal variation characteristics of NO2. However, there is still a lack of ground-based validations regarding the overall accuracy of GEMS in the Chinese region. In this study, we conducted a systematic ground validation of GEMS NO2 data in China for the first time. We validated the accuracy of GEMS NO2 data in four typical pollution regions in China, namely the Beijing-Tianjin-Hebei region (JJJ), the Yangtze River Delta region (YRD), the Pearl River Delta region (PRD), and the Sichuan Basin region (SCB), based on MAX-DOAS and CNEMC data. The averaged correlations using the two datasets for validation were 0.81 and 0.57, respectively, indicating a high level of accuracy for the data in China. Using the GEMS seasonal averaged NO2 data, we studied the distribution of NO2 levels in the four regions. We found that the highest NO2 in all four regions occurred during winter with concentrations of 1.84 × 1016 molecules cm-2, 1.59 × 1016 molecules cm-2, 1.58 × 1016 molecules cm-2 and 9.47 × 1015 molecules cm-2, respectively. The distribution of NO2 was closely related to the terrain. Additionally, we observed a significant underestimation issue with TROPOMI, exceeding 30 % in many regions. Based on MAX-DOAS, we investigated the vertical distribution of NO2 in the four regions and found that NO2 was mainly concentrated below 0.5 km. with the HNU station having the lowest concentration, averaging only 2.12 ppb, which was approximately 41 % of the highest concentration recorded at the CQ station. Furthermore, we conducted a study on regional and cross-regional transport using a combination of MAX-DOAS and GEMS data. We found that the transport flux of NO2 could increase by over 500 % within 1 h, making a significant contribution to local NO2 concentrations. The joint observations of GEMS and MAX-DOAS will provide reliable data support for NO2 research and control in China, making a substantial contribution to environmental protection and sustainable development.

Marine biological activities make a non-negligible contribution to atmospheric aerosols, leading to potential impacts on the regional atmospheric environment and climate. The eastern China seas are highly productive with significant emissions of biogenic substances, but the spatiotemporal variations of marine biogenic aerosols are not well known. Air mass exposure to chlorophyll a (AEC) can be used to indicate the influence of biogenic sources on the atmosphere to a certain degree. In this study, the 12 year (2009-2020) daily AEC were calculated over the eastern China seas, showing the spatial and seasonal patterns of marine biogenic influence intensity which were co-controlled by surface phytoplankton biomass and boundary layer height. By combining the AEC values, relevant meteorological parameters, and extensive observations of a typical biogenic secondary aerosol component, methanesulfonate (MSA), a parameterization scheme for MSA simulation was successfully constructed. This AEC-based approach with observation constraints provides a new insight into the distribution of marine biogenic aerosols. Meanwhile, the wintertime air mass retention over land exhibited a significant decrease, showing a decadal weakening trend of terrestrial transport, which is probably related to the weakening of the East Asian winter monsoon. Thus, marine biogenic aerosols may play an increasingly important role in the studied region.

Nitrate (NO3-) is a major component of atmospheric fine particles. Recent studies in eastern China have shown the increasing trend of NO3- in contrast to the ongoing control of nitrogen oxide (NOx). Here, we elucidate the effects of reduced sulfur dioxide (SO2) on the enhancement of NO3- formation based on field measurements at the summit of Mt. Tai (1534 m a.s.l.) and present detailed modelling analyses. From 2007 to 2018, the measured springtime concentrations of various primary pollutants and fine sulfate (SO42-) decreased sharply (-16.4 % to -89.7 %), whereas fine NO3- concentration increased by 22.8 %. The elevated NO3- levels cannot be explained by the changes in meteorological conditions or other related parameters but were primarily attributed to the considerable reduction in SO42- concentrations (-73.4 %). Results from a multi-phase chemical box model indicated that the reduced SO42- levels decreased the aerosol acidity and prompted the partitioning of HNO3 into the aerosol phase. WRF-Chem model analyses suggest that such a negative effect is a regional phenomenon throughout the planetary boundary layer over eastern China in spring. This study provides new insights into the worsening situation of NO3- aerosol pollution and has important implications for controlling haze pollution in China.

Study of Air Quality Objectives (AQOs) and long-term changes of air pollution plays a decisive role in formulating and refining pollution control strategies. In this study, 10-year variations of six major air pollutants were analyzed at seven monitoring sites in Hong Kong. The continuous decrease of annual averaged concentrations of NO2, SO2, CO, PM2.5 and PM10 and numbers of days with severe pollution conditions validated the efficiency of the series of air pollution control schemes implemented by the Hong Kong government. However, there is still a big gap to meet the ultimate targets described by the World Health Organization. Besides, the concentration of O3 at roadside and urban stations increased by 135% ± 25% and 37% ± 18% from 2011 to 2020, respectively, meanwhile the highest 8 hr averaged O3 concentration was observed as 294 µg/m3 at background station in 2020, which pointed out the increasing ozone pollution in Hong Kong. There was a great decrease in the annual times of air quality health index (AQHI) laying in \"high\", \"very high\" and \"serious\" categories from 2011 to 2020 with the decrease rate of 89.70%, 91.30% and 89.74% at roadside stations, and 79.03%, 95.98% and 72.73% at urban stations, respectively. Nevertheless, the number of days categorized as \"high\" or above at roadside station was twice more than that in the urban station during the past ten years. Thus, more policies and attentions should be given to the roadside air quality and its adverse health effect to pedestrians on street.

In the Pearl River Delta (PRD), population growth and economic development have steadily increased the anthropogenic nutrient discharge into coastal waters. In this study, we employed the observed concentration and model reproduced runoff to quantify the interannual variation and the long-term (1985-2021) trends in riverine chemical oxygen demand (CODMn), biochemical oxygen demand (BOD), and nutrient fluxes. The annual CODMn and BOD fluxes increased slightly between 1999 and 2021. In comparison, the mean annual dissolved inorganic nitrogen (DIN) fluxes of the four eastern outlets increased significantly from 2.05 × 105 t/a in 1985-1995 to 3.11 × 105 t/a in 1999-2011 and then to 3.91 × 105 t/a in 2014-2021. The outlets with the largest contributions to the CODMn, BOD, and DIN fluxes were Humen and Modaomen, which are both located near large cities. By calculating the CODMn fluxes upstream of the PRD, we found that the CODMn fluxes from downstream in the PRD increased faster than the fluxes from upstream. It follows that the increase in CODMn at outlets was mostly driven by the contributions of downstream major cities. In addition, the proportion of ammonia nitrogen flux in the DIN flux decreased from over 50 % to under 10 % at most outlets. This indicates that the toxicity of DIN fluxes has been mitigated. The DIN fluxes also showed a positive correlation with surface chlorophyll a and a negative correlation with bottom dissolved oxygen outside the Pearl River Estuary (PRE). This implies that the changes in phytoplankton growth and oxygen levels outside the PRE are closely linked to the variation in river-delivered nutrients, and the increasing riverine nutrient input may result in the expansion of intensified low-oxygen conditions outside the PRE.

This paper analyzed the long-term variations in nutrients in Liaodong Bay and their potential influencing factors based on historical data from 1978 to 2019. Under the influence of both human activities and natural changes, the concentration of DIN increased approximately 4-fold from the end of the 1990s to the mid-2010s, while DIP and DSi concentrations decreased from the beginning to the end of the 1980s and have since increased again. Asynchronous changes in nutrient levels have led to changes in the nutrient composition, which has caused a series of ecological effects. The total phytoplankton abundance decreased from the 1980s to the end of the 1990s and then increased again. Additionally, the phytoplankton composition shifted from a diatom-dominated to a dinoflagellate-dominated system, and the dominant species of zooplankton changed. Harmful algal blooms (HABs) rarely occurred before the 1980s but have frequently occurred since the end of the 1990s.

Continuous measurements of ozone (O3) and nitrogen oxides (NOx = NO + NO2) were conducted from 2007 to 2019 in Hong Kong in order to evaluate the effectiveness of control strategies for NOx emission from diesel commercial vehicles (DCV). DCV control programs were periodically applied in three phases starting from 2007, 2010 and 2014. It was found that NO and NO2 levels decreased during the study period but more dramatically after the implementation of DCV Phase III than pre-DCV Phase III. Source apportionment analysis confirmed that the ambient NO and NO2 in Hong Kong attributed to the regulated DCV emissions in Phase III reduced at rates of 5.1-14.4 ppbv/yr in roadside environment and 1.6-3.1 ppbv/yr in suburban area. Despite overall NOx reduction, increased NO2/NOx ratios were recorded during the study period possibly due to the application of diesel particulate filter (DPF) in DCVs. However, after introducing DCV Phase III, observed O3 values experienced more dramatic increasing trends in most areas of Hong Kong than pre-DCV Phase III. Model simulations revealed that O3 production rate kept increasing and turned to be less sensitive to NOx from 2014 to 2019. On the roadside, net O3 production rate was more than doubled during 2014-2019 owing to NOx reduction. Moreover, the levels of oxidants (OH, HO2 and RO2) were 1.5-5 times those before 2014. In suburban environment, NOx reduction also facilitated O3 production and radical cycling, but made smaller contributions than those on the roadside during 2014-2019. This study unraveled that NOx reductions benefited from DCV regulations caused increase in surface O3 and fueled O3 photochemistry in various environments. More stringent control measures on emissions of VOCs, especially those with high OH reactivity, might help to better mitigate O3 pollution.

Long-term variation of nitrate in the East Sea was monitored in order to investigate impact of Three Gorges Dam (TGD) in the Changjiang River\'s upstream, China and Nakdong River\'s estuary dam, Korea. Tracing source of nitrate was another objective in this study. For this study, nutrient data were collected for 20 years from 1999 to 2018 in the East Sea, and divided into 4 sections, and evaluated whether a significant difference exists among the averages of nitrate concentrations. The concentrations of nitrate were affected by the major rivers (the Nakdong and the Taehwa Rivers) and Tsushima Warm Current (TWC) which diverged from the Kuroshio Current passing through East China Sea (ECS). Our results also indicated that long-term nitrate concentrations decreased and its reasons. First, the construction of TGD in the upstream of the Changjiang River may have resulted in the decrease of the nitrate supply in the river and ECS which is carried by TWC, toward the East Sea. Second, decrease in the nitrate flux of the Nakdong River\'s estuary due to the construction of the estuary dam and sewer treatment plant could also be a factor for the nitrate decrease in the East Sea. Therefore, anthropogenic activities from the Nakdong River and Changjiang River had a long-term effect on the East Sea\'s nitrate concentrations. The amount of nitrate runoff reduced by the anthropogenic activities influenced the nitrate levels over a long period by the flow of currents in the East Sea.

90Sr is useful for tracing water mass movement in oceans. We collected a suit of seawater samples from the East China Sea (ECS) in the May 2011 to investigate the spatial and vertical distribution of 90Sr and to understand its transportation and fate. To understand the sources and transportation of 90Sr more clearly, published 137Cs data from the same cruise were used to obtain the 90Sr/137Cs activity ratios. The results showed that 90Sr activities were controlled by the circulation system of the ECS, with high values in coastal regions and low values in oceanic waters. The plume with a high 90Sr/137Cs ratio showed that in late spring, the Changjiang Diluted Water could flow southeastward and extend to 126-127° E, which is farther than the previously known value of 124° E. The high 90Sr/137Cs ratios (1.35 ± 0.62) and a long effective half-life of 90Sr (20.0 ± 0.3 y) in the ECS surface water revealed that 90Sr is surplus in comparison with 137Cs. However, historical variations in the 90Sr/137Cs ratio seem to preclude the simple explanation that riverine input causes a 90Sr surplus in the ECS. Groundwater discharge with a high 90Sr but very low 137Cs may be a new potential source. However, it is difficult to quantify the contribution of groundwater discharge at present, and more detailed studies are required in this regard. Additionally, we compiled 90Sr and 137Cs water column inventory data in the western North Pacific and found that the cumulative fallout onto the ocean was different from that on land in the 20-40° N band.