Internet of Things

物联网
  • 文章类型: Journal Article
    各种深度学习技术,包括基于区块链的方法,已经被探索以释放边缘数据处理和由此产生的情报的潜力。然而,现有研究往往忽视了典型物联网(IoT)边缘网络设置中区块链共识处理的资源需求。本文介绍了我们的FLCoin方法。具体来说,我们提出了一种新颖的基于委员会的共识处理方法,在该方法中,委员会成员通过FL流程选举产生。此外,我们采用了两层区块链架构进行联合学习(FL)处理,以促进区块链和FL技术的无缝集成。我们的分析表明,随着网络规模的增加,通信开销保持稳定,确保我们基于区块链的FL系统的可扩展性。为了评估所提出方法的性能,实验是使用MNIST数据集进行的,以训练标准的五层CNN模型。我们的评估证明了FLCoin的效率。随着越来越多的节点参与模型训练,共识延迟保持在3s以下,导致总训练时间低。值得注意的是,与使用PBFT作为共识协议的基于区块链的FL系统相比,我们的方法实现了90%的通信开销和35%的培训时间成本的减少。我们的方法可确保高效且可扩展的解决方案,实现区块链和FL到物联网边缘网络的集成。所提出的架构为构建智能物联网服务提供了坚实的基础。
    Various deep learning techniques, including blockchain-based approaches, have been explored to unlock the potential of edge data processing and resultant intelligence. However, existing studies often overlook the resource requirements of blockchain consensus processing in typical Internet of Things (IoT) edge network settings. This paper presents our FLCoin approach. Specifically, we propose a novel committee-based method for consensus processing in which committee members are elected via the FL process. Additionally, we employed a two-layer blockchain architecture for federated learning (FL) processing to facilitate the seamless integration of blockchain and FL techniques. Our analysis reveals that the communication overhead remains stable as the network size increases, ensuring the scalability of our blockchain-based FL system. To assess the performance of the proposed method, experiments were conducted using the MNIST dataset to train a standard five-layer CNN model. Our evaluation demonstrated the efficiency of FLCoin. With an increasing number of nodes participating in the model training, the consensus latency remained below 3 s, resulting in a low total training time. Notably, compared with a blockchain-based FL system utilizing PBFT as the consensus protocol, our approach achieved a 90% improvement in communication overhead and a 35% reduction in training time cost. Our approach ensures an efficient and scalable solution, enabling the integration of blockchain and FL into IoT edge networks. The proposed architecture provides a solid foundation for building intelligent IoT services.
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  • 文章类型: Journal Article
    物联网(IoT)在我们的日常生活中变得越来越普遍。最近的一份行业报告预测,到2032年,全球物联网市场的价值将超过4万亿美元。为了应对使用中不断增加的物联网设备,识别和保护物联网设备对于网络管理员来说变得至关重要。在这方面,网络流量分类通过精确识别物联网设备以增强网络可见性,提供了一个有前途的解决方案,更好的网络安全。目前,大多数物联网设备识别解决方案都围绕机器学习,优于以前的解决方案,如港口和基于行为的解决方案。虽然表现良好,由于数据的统计变化,这些解决方案通常会随着时间的推移而出现性能下降。因此,他们需要频繁的再培训,这在计算上是昂贵的。因此,本文旨在通过一个健壮的替代特征集来提高模型性能。改进的功能集利用有效载荷长度来模拟物联网设备的独特特征,并随着时间的推移保持稳定。除此之外,本文利用随机森林和OneVSRest提出的特征集来优化学习过程,特别是关于更容易添加新的物联网设备。另一方面,本文介绍了每周数据集分割,以确保在不同的时间范围内进行公平的评估。对两个数据集的评估,一个公共数据集,IoT交通轨迹,和一个自收集的数据集,IoT-FSCIT,显示建议的功能集在物联网交通跟踪数据集上的所有周保持80%以上的准确性,优于选定的基准研究,同时在IoT-FSCIT数据集上提高了10.13%的准确性。
    The Internet of Things (IoT) is becoming more prevalent in our daily lives. A recent industry report projected the global IoT market to be worth more than USD 4 trillion by 2032. To cope with the ever-increasing IoT devices in use, identifying and securing IoT devices has become highly crucial for network administrators. In that regard, network traffic classification offers a promising solution by precisely identifying IoT devices to enhance network visibility, allowing better network security. Currently, most IoT device identification solutions revolve around machine learning, outperforming prior solutions like port and behavioural-based. Although performant, these solutions often experience performance degradation over time due to statistical changes in the data. As a result, they require frequent retraining, which is computationally expensive. Therefore, this article aims to improve the model performance through a robust alternative feature set. The improved feature set leverages payload lengths to model the unique characteristics of IoT devices and remains stable over time. Besides that, this article utilizes the proposed feature set with Random Forest and OneVSRest to optimize the learning process, particularly concerning the easier addition of new IoT devices. On the other hand, this article introduces weekly dataset segmentation to ensure fair evaluation over different time frames. Evaluation on two datasets, a public dataset, IoT Traffic Traces, and a self-collected dataset, IoT-FSCIT, show that the proposed feature set maintained above 80% accuracy throughout all weeks on the IoT Traffic Traces dataset, outperforming selected benchmark studies while improving accuracy over time by +10.13% on the IoT-FSCIT dataset.
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  • 文章类型: Journal Article
    物联网(IoT)的快速发展广泛地推动了无线传感器网络(WSNs)的发展,用于显示从物理世界收集的感知和数据的系列的基本技术。在密集分布的地区,传感器节点分布不均匀,这导致了网络覆盖的建立以及随之而来的WSN的效率和有效性。为了解决这个问题,提出了一种基于爬行动物搜索算法(RSA)的无线传感器网络覆盖优化方法。在过去,爬行动物搜索算法已用于解决优化问题,这意味着它可以改进不同的过程。然而,RSA需要跟踪每次迭代中最优个体的轨迹,这将忽略非最优个体的生物经济特征。因此,本文将分布估计策略引入到RSA框架中,它可以充分挖掘隐藏在整个人群中的所有位置信息。我们选择了几个函数作为优化测试基准函数来评估所提出方法的可行性。本文将提出的改进RSA与标准RSA和一些传统的优化算法进行了比较。通过一系列网络覆盖优化实验,参数的变化也决定了RSA在网络覆盖优化中的作用。3个相似网络覆盖优化实验的仿真结果表明,改进的RSA在不同场景下都能有效使用。
    The rapid development of the Internet of Things (IoT) has extensively promoted the development of Wireless Sensor Networks (WSNs), an essential technology for series displaying perception and data collected from the physical world. In densely distributed areas, sensor nodes are unevenly distributed, which leads to the network coverage build-up and the consequent efficiency and effectiveness of WSNs. To address this issue, this paper proposes a new method for WSN coverage optimization based on the Reptile Search Algorithm (RSA). In the past, the Reptile Search algorithm has been used to solve optimization problems, which means it can improve different processes. However, the RSA needs to track the trajectory of optimal individuals in each iteration, which will ignore non-optimal individuals\' bioeconomic characteristics. Therefore, the paper introduces a distribution estimation strategy into the RSA framework, which can fully mine all the positional information hidden in the entire population. We selected several functions as optimization test benchmark functions to evaluate the feasibility of the proposed method. This paper compares the proposed improved RSA with the standard RSA and some traditional optimization algorithms. The result has been calculated through a series of experiments on network coverage optimization, and the change of parameters also determines the effect of the RSA in the optimization of network coverage. The simulated results of the three similar network coverage optimization experiments show that the improved RSA can be used efficiently within different scenarios.
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  • 文章类型: Journal Article
    本文提出了一种用于患者跟踪应用的新型多频带纺织单极天线。设计的天线具有紧凑的占地面积(0.13λ02),可在窄带物联网(NB-IoT)1.8GHz中工作,射频识别(RFID),工业,科学,和医疗(ISM)2.45GHz和5.8GHz频段。天线在1.8GHz时的阻抗带宽和增益,2.45GHz,5.8GHz是310MHz,960MHz,和1140兆赫;3.7dBi,5.3dBi,和9.6dBi,分别。此外,在各种弯曲情况下,在人体的不同身体部位检查天线的行为。根据评估的链路预算,设计的天线可以很容易地通信达100米的距离。根据(FCC/ICNIRP)标准,在所报告的频带处,所设计的天线的比吸收率值也在可接受的限度内。与传统的刚性天线不同,拟议的纺织天线是非侵入式的,提高用户的安全性和舒适性。牛仔布材料使其适合长时间穿着,降低皮肤刺激的风险。它也能承受经常的磨损,包括拉伸和弯曲。所呈现的基于牛仔布的天线可以无缝集成到服装和配饰中,使它不那么引人注目,更美观。
    This paper proposes a novel multi-band textile monopole antenna for patient tracking applications. The designed antenna has compact footprints (0.13λ02) and works in the narrow band-internet of things (NB-IoT) 1.8 GHz, radio frequency identification (RFID), and industrial, scientific, and medical (ISM) 2.45 GHz and 5.8 GHz bands. The impedance bandwidths and gain of the antenna at 1.8 GHz, 2.45 GHz, and 5.8 GHz are 310 MHz, 960 MHz, and 1140 MHz; 3.7 dBi, 5.3 dBi, and 9.6 dBi, respectively. Also, the antenna\'s behavior is checked on different body parts of the human body in various bending scenarios. As per the evaluated link budget, the designed antenna can easily communicate up to 100 m of distance. The specific absorption rate values of the designed antenna are also within acceptable limits as per the (FCC/ICNIRP) standards at the reported frequency bands. Unlike traditional rigid antennas, the proposed textile antenna is non-intrusive, enhancing user safety and comfort. The denim material makes it comfortable for extended wear, reducing the risk of skin irritation. It can also withstand regular wear and tear, including stretching and bending. The presented denim-based antenna can be seamlessly integrated into clothing and accessories, making it less obtrusive and more aesthetically pleasing.
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  • 文章类型: Journal Article
    有效的空气质量监测和预报对保障公众健康至关重要,保护环境,促进智慧城市的可持续发展。传统的系统是基于云的,产生高昂的成本,缺乏用于多步预测的准确的深度学习(DL)模型,并且无法优化雾节点的DL模型。为了应对这些挑战,本文通过集成物联网(IoT),提出了一种基于雾的空气质量监测和预测(FAQMP)系统,雾计算(FC),低功耗广域网(LPWAN),和深度学习(DL),以提高监测和预测空气质量水平的准确性和效率。三层FAQMP系统包括一个低成本的空气质量监测(AQM)节点,该节点通过LoRa将数据传输到雾计算层,然后再到云层进行复杂处理。FC层中的智能雾环境网关(SFEG)通过采用优化的轻量级基于DL的序列到序列(Seq2Seq)门控递归单元(GRU)注意力模型,引入了有效的雾智能,实现实时处理,准确的预测,并在优化雾资源使用的同时及时警告危险的AQI水平。最初,Seq2SeqGRU注意力模型,验证了多步预测,优于最先进的DL方法,平均RMSE为5.5576,MAE为3.4975,MAPE为19.1991%,R2为0.6926,泰尔的U1为0.1325。然后使用训练后量化(PTQ)使该模型轻量化并进行优化,特别是动态范围量化,将模型尺寸缩小到原来的不到四分之一,在保持预测准确性的同时,将执行时间提高了81.53%。这种优化通过平衡性能和计算效率,实现了在SFEG等资源受限的雾节点上的高效部署。从而通过高效的雾情报提高FAQMP系统的有效性。FAQMP系统,由EnviroWeb应用程序支持,提供实时AQI更新,预测,和警报,协助政府积极解决污染问题,维持空气质量标准,培养更健康、更可持续的环境。
    Effective air quality monitoring and forecasting are essential for safeguarding public health, protecting the environment, and promoting sustainable development in smart cities. Conventional systems are cloud-based, incur high costs, lack accurate Deep Learning (DL)models for multi-step forecasting, and fail to optimize DL models for fog nodes. To address these challenges, this paper proposes a Fog-enabled Air Quality Monitoring and Prediction (FAQMP) system by integrating the Internet of Things (IoT), Fog Computing (FC), Low-Power Wide-Area Networks (LPWANs), and Deep Learning (DL) for improved accuracy and efficiency in monitoring and forecasting air quality levels. The three-layered FAQMP system includes a low-cost Air Quality Monitoring (AQM) node transmitting data via LoRa to the Fog Computing layer and then the cloud layer for complex processing. The Smart Fog Environmental Gateway (SFEG) in the FC layer introduces efficient Fog Intelligence by employing an optimized lightweight DL-based Sequence-to-Sequence (Seq2Seq) Gated Recurrent Unit (GRU) attention model, enabling real-time processing, accurate forecasting, and timely warnings of dangerous AQI levels while optimizing fog resource usage. Initially, the Seq2Seq GRU Attention model, validated for multi-step forecasting, outperformed the state-of-the-art DL methods with an average RMSE of 5.5576, MAE of 3.4975, MAPE of 19.1991%, R2 of 0.6926, and Theil\'s U1 of 0.1325. This model is then made lightweight and optimized using post-training quantization (PTQ), specifically dynamic range quantization, which reduced the model size to less than a quarter of the original, improved execution time by 81.53% while maintaining forecast accuracy. This optimization enables efficient deployment on resource-constrained fog nodes like SFEG by balancing performance and computational efficiency, thereby enhancing the effectiveness of the FAQMP system through efficient Fog Intelligence. The FAQMP system, supported by the EnviroWeb application, provides real-time AQI updates, forecasts, and alerts, aiding the government in proactively addressing pollution concerns, maintaining air quality standards, and fostering a healthier and more sustainable environment.
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  • 文章类型: Journal Article
    连接的设备或物联网(IoT)设备的数量已经迅速增加。根据最新的统计数据,到2023年,大约有172亿个连接的物联网设备;预计到2030年将达到254亿个IoT设备,并在可预见的未来逐年增长。IoT设备共享,收集,通过互联网交换数据,无线网络,或其他网络。物联网互连技术改善和便利了人们的生活,但是,同时,对他们的安全构成了真正的威胁。拒绝服务(DoS)和分布式拒绝服务(DDoS)攻击被认为是最常见的威胁物联网设备安全的攻击。这些被认为是一种增加的趋势,降低风险将是一个重大挑战,尤其是在未来。在这种情况下,本文提出了一种改进的框架(SDN-ML-IoT),该框架可用作入侵和防御检测系统(IDPS),可以帮助更高效地检测DDoS攻击并实时减轻它们。该SDN-ML-IoT在软件定义网络(SDN)环境中使用机器学习(ML)方法,以保护智能家居IoT设备免受DDoS攻击。我们采用了一种基于随机森林(RF)的ML方法,逻辑回归(LR),k-最近邻居(kNN),和朴素贝叶斯(NB)与一个对休息(OvR)策略,然后将我们的工作与其他相关工作进行比较。根据性能指标,如混淆矩阵,培训时间,预测时间,准确度,和接收器工作特性曲线下面积(AUC-ROC),已经确定SDN-ML-IoT,当应用于RF时,优于其他ML算法,以及与我们工作相关的类似方法。它有一个令人印象深刻的99.99%的准确率,它可以在不到3s的时间内缓解DDoS攻击。我们对相关工作中使用的各种模型和算法进行了比较分析。结果表明,我们提出的方法优于其他方法,展示其在检测和减轻SDN内DDoS攻击方面的有效性。基于这些有希望的结果,我们选择在SDN中部署SDN-ML-IoT。此实施可确保智能家居中的物联网设备免受网络流量中的DDoS攻击。
    The number of connected devices or Internet of Things (IoT) devices has rapidly increased. According to the latest available statistics, in 2023, there were approximately 17.2 billion connected IoT devices; this is expected to reach 25.4 billion IoT devices by 2030 and grow year over year for the foreseeable future. IoT devices share, collect, and exchange data via the internet, wireless networks, or other networks with one another. IoT interconnection technology improves and facilitates people\'s lives but, at the same time, poses a real threat to their security. Denial-of-Service (DoS) and Distributed Denial-of-Service (DDoS) attacks are considered the most common and threatening attacks that strike IoT devices\' security. These are considered to be an increasing trend, and it will be a major challenge to reduce risk, especially in the future. In this context, this paper presents an improved framework (SDN-ML-IoT) that works as an Intrusion and Prevention Detection System (IDPS) that could help to detect DDoS attacks with more efficiency and mitigate them in real time. This SDN-ML-IoT uses a Machine Learning (ML) method in a Software-Defined Networking (SDN) environment in order to protect smart home IoT devices from DDoS attacks. We employed an ML method based on Random Forest (RF), Logistic Regression (LR), k-Nearest Neighbors (kNN), and Naive Bayes (NB) with a One-versus-Rest (OvR) strategy and then compared our work to other related works. Based on the performance metrics, such as confusion matrix, training time, prediction time, accuracy, and Area Under the Receiver Operating Characteristic curve (AUC-ROC), it was established that SDN-ML-IoT, when applied to RF, outperforms other ML algorithms, as well as similar approaches related to our work. It had an impressive accuracy of 99.99%, and it could mitigate DDoS attacks in less than 3 s. We conducted a comparative analysis of various models and algorithms used in the related works. The results indicated that our proposed approach outperforms others, showcasing its effectiveness in both detecting and mitigating DDoS attacks within SDNs. Based on these promising results, we have opted to deploy SDN-ML-IoT within the SDN. This implementation ensures the safeguarding of IoT devices in smart homes against DDoS attacks within the network traffic.
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  • 文章类型: Journal Article
    个人防护设备(PPE)在保护工人免受伤害和疾病方面的作用已得到普遍认可。智能PPE集成了物联网(IoT)技术,以实现对工人及其周围环境的持续监控,防止不良事件,促进快速应急响应,并告知救援人员潜在的危险。这项工作提出了一种具有传感器节点体系结构的智能PPE系统,旨在监视工人及其周围环境。传感器节点配备了各种传感器和通信功能,能够监测特定气体(VOC,CO2、CO、O2),颗粒物(PM),温度,湿度,湿度位置信息,音频信号,和身体手势。该系统利用人工智能算法来识别工人活动中可能导致危险情况的模式。气体测试是在一个特殊的房间里进行的,在室内和室外测试了定位能力,其余传感器在模拟实验室环境中进行了测试。本文介绍了传感器节点的体系结构和目标风险场景的测试结果。传感器节点在所有情况下都表现良好,正确地发出所有可能导致危险情况的信号。
    Personal protective equipment (PPE) has been universally recognized for its role in protecting workers from injuries and illnesses. Smart PPE integrates Internet of Things (IoT) technologies to enable continuous monitoring of workers and their surrounding environment, preventing undesirable events, facilitating rapid emergency response, and informing rescuers of potential hazards. This work presents a smart PPE system with a sensor node architecture designed to monitor workers and their surroundings. The sensor node is equipped with various sensors and communication capabilities, enabling the monitoring of specific gases (VOC, CO2, CO, O2), particulate matter (PM), temperature, humidity, positional information, audio signals, and body gestures. The system utilizes artificial intelligence algorithms to recognize patterns in worker activity that could lead to risky situations. Gas tests were conducted in a special chamber, positioning capabilities were tested indoors and outdoors, and the remaining sensors were tested in a simulated laboratory environment. This paper presents the sensor node architecture and the results of tests on target risky scenarios. The sensor node performed well in all situations, correctly signaling all cases that could lead to risky situations.
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  • 文章类型: Journal Article
    物联网(IoT)的广泛应用表明,它有可能彻底改变工业,改善日常生活,克服全球挑战。本研究旨在评估成熟的工业无线传感器网络(IWSN)的性能可扩展性。基于多个因素,提出了一种新的工业领域物联网分类方法,并介绍了6LoWPAN(低功耗无线个人局域网上的IPv6)的集成,传感器网络的消息队列遥测传输(MQTT-SN),和ContikiMAC协议,用于工业物联网系统中的传感器节点,以提高节能连接。ContikiCOOJAWSN模拟器用于在两个静态和移动场景中对协议的性能进行建模和仿真,并评估针对网络入侵的新颖性检测系统(NDS),以便实时识别某些事件以进行真实的数据集分析。仿真结果表明,我们的方法是确定IWSN中实现特定可靠性目标所需的传输次数的重要措施。尽管对低功耗运行的需求不断增长,确定性沟通,和端到端可靠性,我们使用激光诱导的选择性表面激活(SSAIL)技术的创新传感器设计方法被开发并部署在FTMC场所,以证明其长期功能和可靠性。通过仿真对所提出的框架进行了实验验证和测试,以证明所提出方法的适用性和适用性。优化的WSN的能源效率提高了50%,电池寿命延长了350%,重复的数据包减少了80%,数据冲突减少了80%,结果表明,所提出的方法和工具可以有效地用于新工业项目中遥测节点网络的开发,以便准确地检测物联网网络中的事件和漏洞。测量了所开发的传感器节点的能耗。总的来说,这项研究对工业过程的挑战进行了全面评估,如遥测通道的可靠性和稳定性,自治节点的能效,以及IWSN中重复信息传输的最小化。
    The wide-ranging applications of the Internet of Things (IoT) show that it has the potential to revolutionise industry, improve daily life, and overcome global challenges. This study aims to evaluate the performance scalability of mature industrial wireless sensor networks (IWSNs). A new classification approach for IoT in the industrial sector is proposed based on multiple factors and we introduce the integration of 6LoWPAN (IPv6 over low-power wireless personal area networks), message queuing telemetry transport for sensor networks (MQTT-SN), and ContikiMAC protocols for sensor nodes in an industrial IoT system to improve energy-efficient connectivity. The Contiki COOJA WSN simulator was applied to model and simulate the performance of the protocols in two static and moving scenarios and evaluate the proposed novelty detection system (NDS) for network intrusions in order to identify certain events in real time for realistic dataset analysis. The simulation results show that our method is an essential measure in determining the number of transmissions required to achieve a certain reliability target in an IWSNs. Despite the growing demand for low-power operation, deterministic communication, and end-to-end reliability, our methodology of an innovative sensor design using selective surface activation induced by laser (SSAIL) technology was developed and deployed in the FTMC premises to demonstrate its long-term functionality and reliability. The proposed framework was experimentally validated and tested through simulations to demonstrate the applicability and suitability of the proposed approach. The energy efficiency in the optimised WSN was increased by 50%, battery life was extended by 350%, duplicated packets were reduced by 80%, data collisions were reduced by 80%, and it was shown that the proposed methodology and tools could be used effectively in the development of telemetry node networks in new industrial projects in order to detect events and breaches in IoT networks accurately. The energy consumption of the developed sensor nodes was measured. Overall, this study performed a comprehensive assessment of the challenges of industrial processes, such as the reliability and stability of telemetry channels, the energy efficiency of autonomous nodes, and the minimisation of duplicate information transmission in IWSNs.
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  • 文章类型: Journal Article
    在过去的几年中,低功耗广域网(LPWAN)的应用数量一直在大幅增长,协议栈的数量也在大幅增长。尽管如此,仍然没有完全开放的LPWAN协议栈提供给公众,这限制了现有集成的灵活性和易用性。最接近完全开放的是LoRa;然而,只有它的媒体访问控制(MAC)层,被称为LoRaWAN,是开放的,其物理和逻辑链路控制层,也被称为LoRaPHY,仍然只是部分理解。在本文中,LoRaPHY的基本缺失方面不仅是逆向工程,而且,使用GNURadio以模块化和灵活的方式提出并实现了收发器及其子组件的新设计。最后,收发器及其组件的一些应用示例,通过使用廉价且广泛可用的现成硬件,可以在简单的设置中运行,给出了如何使用和扩展库。
    The number of applications of low-power wide-area networks (LPWANs) has been growing quite considerably in the past few years and so has the number of protocol stacks. Despite this fact, there is still no fully open LPWAN protocol stack available to the public, which limits the flexibility and ease of integration of the existing ones. The closest to being fully open is LoRa; however, only its medium access control (MAC) layer, known as LoRaWAN, is open and its physical and logical link control layers, also known as LoRa PHY, are still only partially understood. In this paper, the essential missing aspects of LoRa PHY are not only reverse engineered, but also, a new design of the transceiver and its sub-components are proposed and implemented in a modular and flexible way using GNU Radio. Finally, some examples of applications of both the transceiver and its components, which are made to be run in a simple setup by using cheap and widely available off-the-shelf hardware, are given to show how the library can be used and extended.
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  • 文章类型: Journal Article
    用熵介导的策略来降低反应活化能的多金属纳米催化剂被认为是促进高效多相催化的创新和有效方法。因此,构象熵驱动的高熵合金(HEAs)正在成为解决纳米酶催化效率限制的有希望的候选者,归因于它们的多功能活性位点组成和协同效应。作为高熵纳米酶(HEzymes)概念的证明,精心制作具有丰富活性位点和调谐电子结构的PdMoPtCoNiHEA纳米线(NWs),据报道,表现出与天然辣根过氧化物酶相当的过氧化物酶模拟活性。密度泛函理论计算表明,费米能级(EF)附近HEANWs的电子丰度增强是通过各种过渡金属位点之间的自互补作用而促进的,从而通过混合物效应提高催化界面处的电子转移效率。随后,HEzmes与便携式电子设备集成,该设备利用物联网驱动的信号转换和无线传输功能进行即时诊断,以验证其在尿液生物标志物的数字生物传感中的适用性。所提出的酶强调了通过可调电子结构和协同效应增强纳米酶催化的巨大潜力,为纳米生物分析的改革发展铺平了道路。
    Engineering multimetallic nanocatalysts with the entropy-mediated strategy to reduce reaction activation energy is regarded as an innovative and effective approach to facilitate efficient heterogeneous catalysis. Accordingly, conformational entropy-driven high-entropy alloys (HEAs) are emerging as a promising candidate to settle the catalytic efficiency limitations of nanozymes, attributed to their versatile active site compositions and synergistic effects. As proof of the high-entropy nanozymes (HEzymes) concept, elaborate PdMoPtCoNi HEA nanowires (NWs) with abundant active sites and tuned electronic structures, exhibiting peroxidase-mimicking activity comparable to that of natural horseradish peroxidase are reported. Density functional theory calculations demonstrate that the enhanced electron abundance of HEA NWs near the Fermi level (EF) is facilitated via the self-complementation effect among the diverse transition metal sites, thereby boosting the electron transfer efficiency at the catalytic interface through the cocktail effect. Subsequently, the HEzymes are integrated with a portable electronic device that utilizes Internet of Things-driven signal conversion and wireless transmission functions for point-of-care diagnosis to validate their applicability in digital biosensing of urinary biomarkers. The proposed HEzymes underscore significant potential in enhancing nanozymes catalysis through tunable electronic structures and synergistic effects, paving the way for reformative advancements in nano-bio analysis.
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