Incineration

焚烧
  • 文章类型: Journal Article
    由于气候变化和人为活动,北极自生社区和环境面临前所未有的挑战。这些挑战的一个较少探索的方面是人为纳米材料在本土社区的释放和分布。这项研究开创了对北极原住民社区中人为纳米材料的性质和分散的全面调查,源于他们传统的废物燃烧做法。采用先进的纳米分析工具,我们揭示了纳米材料的性质和普遍性,包括金属氧化物(TiO2,PbO),合金(SnPb,SbPb,SnAg,SnCu,SnZn),铬化砷酸铜相关纳米材料(CuCrO2,CuCr2O4),以及废物燃烧地点附近的雪和沉积物中的纳米塑料(聚苯乙烯和聚丙烯)。这项开创性的研究阐明了偏远北极地区废物燃烧的意外后果,强调跨学科研究的迫切需要,社区参与,可持续的废物管理。这些措施对于保护脆弱的北极生态系统和当地社区的健康至关重要。
    Arctic autochthonous communities and the environment face unprecedented challenges due to climate change and anthropogenic activities. One less-explored aspect of these challenges is the release and distribution of anthropogenic nanomaterials in autochthonous communities. This study pioneers a comprehensive investigation into the nature and dispersion of anthropogenic nanomaterials within Arctic Autochthonous communities, originating from their traditional waste-burning practices. Employing advanced nanoanalytical tools, we unraveled the nature and prevalence of nanomaterials, including metal oxides (TiO2, PbO), alloys (SnPb, SbPb, SnAg, SnCu, SnZn), chromated copper arsenate-related nanomaterials (CuCrO2, CuCr2O4), and nanoplastics (polystyrene and polypropylene) in snow and sediment near waste burning sites. This groundbreaking study illuminates the unintended consequences of waste burning in remote Arctic areas, stressing the urgent need for interdisciplinary research, community engagement, and sustainable waste management. These measures are crucial to safeguard the fragile Arctic ecosystem and the health of autochthonous communities.
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  • 文章类型: Journal Article
    玻璃化是一种很有前途的处理城市固体废物焚烧飞灰(MSWI-FA);但是,高的MSWI-FA聚变温度导致的高能耗限制了该技术的发展和应用。在这项研究中,将煤气化产生的细矿渣灰(FSA)和煤矸石灰(CGA)与MSWI-FA混合以降低灰熔融温度。通过X射线衍射和热力学平衡计算检查了热处理过程中灰分中矿物的转化。使用热平台显微镜观察灰流行为,并且使用拉曼光谱对硅酸盐结构进行定量。系统地研究了混合灰的共熔机理。结果表明,混合灰分的流动温度(FT)随FSA或CGA的添加比例而表现出初始降低和随后的升高。对于添加50%FSA和50%CGA,记录到1215°C和1223°C的最低灰分FT。分别;进一步,这些温度分别降低了>285°C和>277°C,相对于MSWI-FA的FT。混合灰加热过程中矿物和硅酸盐结构的转变是灰熔融温度变化的原因。MSWI-FA中的CaO倾向于与莫来石反应,FSA和CGA中的石英和赤铁矿,形成矿物,如钙长石,Gehlenite,和熔点相对较低的andradite。FSA或CGA的添加引起混合灰的硅酸盐网络结构的变化。特别是,50%FSA掺入导致Q4和Q3转化为Q2,而50%CGA引入导致Q4和Q2分别转化为Q3和Q1+Q0。硅酸盐网络解聚,导致灰分熔融温度降低并增加熔融速率。
    Vitrification is a promising treatment for municipal solid waste incineration fly ash (MSWI-FA); however, high energy consumption due to the high MSWI-FA fusion temperature limits the development and application of this technique. In this study, fine slag ash (FSA) derived from coal gasification and coal gangue ash (CGA) were mixed with MSWI-FA to reduce the ash fusion temperature. The transformation of minerals in ash during thermal treatment was examined via X-ray diffraction and thermodynamic equilibrium calculations. The ash flow behaviour was observed using a thermal platform microscope, and the silicate structure was quantified using Raman spectra. The co-melting mechanisms for the mixed ash were systematically investigated. Results indicate that the flow temperature (FT) of the mixed ash exhibited an initial decrease and subsequent increase as a function of the addition ratio of FSA or CGA. Lowest ash FT of 1215 °C and 1223 °C were recorded for addition of 50% FSA and 50% CGA, respectively; further, these temperatures were lowered by > 285 °C and >277 °C respectively, relative to FT of the MSWI-FA. The transformation of minerals and silicate structure during mixed ash heating was responsible for the variation in the ash fusion temperature. CaO in MSWI-FA tended to react with mullite, quartz and haematite in FSA and CGA, forming minerals such as anorthite, gehlenite, and andradite with relatively low melting points. The addition of FSA or CGA caused changes in the silicate network structure of the mixed ash. In particular, 50% FSA incorporation caused the transformation of Q4 and Q3 to Q2, whereas 50% CGA introduction resulted in the conversion of Q4 and Q2 into Q3 and Q1 + Q0, respectively. The silicate network depolymerised, causing reduction in the ash fusion temperature and increasing the melting rate.
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  • 文章类型: Journal Article
    研究人员正在积极研究城市固体废物焚烧底灰(MSWIBA)和粉煤灰(MSWIFA)的解毒和利用方法,考虑到它们作为低能耗碱活化材料(AAMs)的潜力。最近的研究强调,来自MSWIFA和MSWIBA的AAM在酸性和碱性环境中均显示出显着的耐久性。本文全面概述了MSWIFA和MSWIBA的生产工艺,评估创新的工程稳定技术,如石墨烯纳米片和轻质人工冷粘结骨料,以及它们各自的优点和局限性。此外,这项审查精心纳入了相关反应。还提出了一些建议,以指导旨在完善这些方法的未来研究工作。
    Researchers are actively investigating methodologies for the detoxification and utilization of Municipal Solid Waste Incineration Bottom Ash (MSWIBA) and Fly Ash (MSWIFA), given their potential as alkali-activated materials (AAMs) with low energy consumption. Recent studies highlight that AAMs from MSWIFA and MSWIBA demonstrate significant durability in both acidic and alkaline environments. This article provides a comprehensive overview of the processes for producing MSWIFA and MSWIBA, evaluating innovative engineering stabilization techniques such as graphene nano-platelets and lightweight artificial cold-bonded aggregates, along with their respective advantages and limitations. Additionally, this review meticulously incorporates relevant reactions. Recommendations are also presented to guide future research endeavors aimed at refining these methodologies.
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  • 文章类型: Journal Article
    城市固体废物焚烧飞灰(MSWIFA)的大量生产强调了开发高效固化材料的重要性。本研究采用MgO和CaO固定MSWIFA(掺入70%粉煤灰),并与硅酸盐水泥(PC)的固定化效果进行了比较。实验结果表明,MgO对重金属(Cd,Cu,Pb,和Zn)与CaO和PC相比。XRD,FTIR,TG,和SEM分析表明,MgO固化的MSWIFA粘结剂中的主要水化产物,CaO,和PC是Mg(OH)2,CaCO3和C-S-H凝胶,分别。Mg(OH)2通过化学络合和表面吸附机制有效地固定了重金属。MgO处理的MSWIFA显示出最高的残留分数和最低的易浸出分数。此外,重金属的浸出特性受pH水平的显著影响,因此,MgO处理的MSWIFA的渗滤液pH为9.18,可实现大多数重金属的沉淀和稳定。总之,本研究为MSWIFA固定化提供了有效的材料选择,并为MSWIFA管理提供了新的策略。
    The significant production of municipal solid waste incineration fly ash (MSWI FA) underscores the importance of developing efficient solidification materials. This study employed MgO and CaO for immobilizing MSWI FA (with a 70% fly ash incorporation), and the immobilization effect was compared with that of Portland cement (PC). Experimental findings revealed that MgO exhibited the most effective stabilization for heavy metals (Cd, Cu, Pb, and Zn) compared to CaO and PC. XRD, FTIR, TG, and SEM analysis indicated that the principal hydration products in MSWI FA binders solidified with MgO, CaO, and PC were Mg(OH)2, CaCO3, and C-S-H gel, respectively. Mg(OH)2 efficiently immobilized heavy metals through chemical complexation and surface adsorption mechanisms. The MgO-treated MSWI FA demonstrated the highest residual fractions and the lowest easily leachable fractions. Moreover, the leaching characteristics of heavy metals were significantly influenced by the pH level, so MgO-treated MSWI FA with a leachate pH of 9.18 achieved the precipitation and stabilization of most heavy metals. In summary, this study provided an effective material selection for MSWI FA immobilization and presented a novel strategy for MSWI FA management.
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  • 文章类型: Journal Article
    城市固体废物(MSW)产量的增加对可持续城市发展提出了挑战。现代废物能源(EfW)设施焚烧MSW,减少质量和回收能量。在英国,MSW焚烧底灰(MSWIBA)主要用于土木工程应用。这项研究描述了英国生产的MSWIBA,检查其pH依赖性浸出行为和对环境浸出剂的响应。结果表明,主要成分包括熔融相,初级玻璃和细灰聚集体,和以SiO2为主的化学成分(30-50%),CaO(约15%),Fe2O3(~10%),和Al2O3(~8%)。X射线近边缘结构吸收(XANES)分析表明,Zn和Cu很可能与某些硫结合在一起(吸附在羟基氧化物上并作为氧化物)。多氯联苯(PCBs)和多氯二苯并二恶英/呋喃(PCDD/Fs)远低于监管限值,多环芳烃(PAHs)检测不到。浸出试验表明微量元素在pH≤6时移动。具有11.3的天然pH和高缓冲能力,需要向MSWIBA输入大量酸才能达到该pH值,在环境中是不可能的。木片添加增加渗滤液的溶解有机碳(DOC)和降低pH值,但对金属浸出行为的影响最小。合成植物渗出物溶液在现实浓度下对金属浸出的影响最小,仅在≥1500mgl-1DOC时增强浸出。这项工作支持MSWIBA在特定土木工程应用中的低风险。
    Increasing municipal solid waste (MSW) production poses challenges for sustainable urban development. Modern energy-from-waste (EfW) facilities incinerate MSW, reducing mass and recovering energy. In the UK, MSW incineration bottom ash (MSW IBA) is primarily reused in civil engineering applications. This study characterizes UK-produced MSW IBA, examining its pH-dependent leaching behaviour and response to environmental lixiviants. Results show predominant components include a melt phase, primary glass and fine ash aggregations, and a chemical composition dominated by SiO2 (30-50 %), CaO (∼15 %), Fe2O3 (∼10 %), and Al2O3 (∼8%). X-ray absorption near edge structure (XANES) analysis shows that Zn and Cu are most likely oxygen-bound (adsorbed to oxy-hydroxides and as oxides) with some sulphur bound. Polychlorinated biphenyls (PCBs) and polychlorinated dibenzodioxins/furans (PCDD/Fs) are well below regulatory limits, and polycyclic aromatic hydrocarbons (PAHs) were undetectable. Leaching tests indicate trace elements mobilize at pHs ≤ 6. With a natural pH of 11.3 and high buffering capacity, significant acid inputs to the MSW IBA are required to reach this pH, which are improbable in the environment. Wood chip additions increase leachate\'s dissolved organic carbon (DOC) and reduce pH, but had minimal impact on metal-leaching behaviour. Synthetic plant exudate solutions minimally affect metal leaching at realistic concentrations, only enhancing leaching at ≥ 1500 mg l-1 DOC. This work supports MSW IBA\'s low-risk in specified civil engineering applications.
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  • 文章类型: Journal Article
    城市固体废物(MSW)管理正在极大地促进全球温室气体(GHG)排放。分析城市生活垃圾温室气体的排放模式对于制定适当的碳减排政策至关重要。基于IPCC模型,通过填埋和焚烧作业计算了2004年至2021年中国各省城市生活垃圾的温室气体排放量,分开。从2004年到2021年,填埋和焚烧分别产生了约1271MtCO2-eq和198MtCO2-eq。从2004年到2020年,垃圾填埋产生的温室气体排放量增加,到2021年下降,而焚烧产生的温室气体排放量呈现增加趋势,有三个不同的增长阶段。然后采用面板回归模型来确定影响温室气体排放的关键因素。GDP和人口与垃圾填埋场的温室气体排放量呈正相关,而PCCE与垃圾填埋场的温室气体排放呈负相关。GDP和PCCE对焚烧产生的温室气体排放有积极影响,而人口没有显着影响。多表达式编程用于开发显式模型,到2030年预测城市生活垃圾的温室气体排放量。从2022年到2024年,垃圾填埋场的温室气体排放量将迅速减少。而焚烧产生的温室气体排放量将迅速增加。随后,焚烧的温室气体排放速率将会减慢,由于没有垃圾填埋处理,填埋产生的温室气体将缓慢减少。这些方法和结果为决策者和废物管理部门提供了深刻的信息。
    The municipal solid waste (MSW) management is significantly contributing to global greenhouse gas (GHG) emissions. Analyzing the emission pattern of GHGs from MSW is essential for formulating appropriate carbon mitigation policies. Based on IPCC Models, GHG emissions from MSW were calculated in Chinese provinces from 2004 to 2021 by landfilling and incineration operations, separately. Landfilling and incineration generated approximately 1271 MtCO2-eq and 198 MtCO2-eq from 2004 to 2021, respectively. GHG emissions from landfilling increased from 2004 to 2020 and declined in 2021, while GHG emissions from incineration demonstrated an increasing trend with three distinct growth stages. A panel regression model was then employed to identify the key factors influencing GHG emissions. GDP and population are positively related to GHG emissions from landfills, while PCCE is negatively related to GHG emissions from landfills. GDP and PCCE have a positive impact on GHG emissions from incineration, while population showed no significant impact. Multi-expression programming was used to develop an explicit model, forecasting GHG emissions from MSW by 2030. From 2022 to 2024, GHG emissions from landfills will quickly decrease, while GHG emissions from incineration will rapidly increase. Subsequently, the GHG emission rate of incineration will slow down, and GHGs from landfilling will slowly decrease due to no MSW for landfill disposal. The methods and results provide insightful information for policy-makers and waste management sector.
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  • 文章类型: Journal Article
    城市生活垃圾焚烧发电对于减少和再利用固体废物具有重要意义。该研究对中国城市生活垃圾焚烧的环境和经济进行了综合评估,从“从摇篮到坟墓”的角度来看,以1吨城市固体废物焚烧为功能单元。还计算了每个月的环境影响,以分析一年中的动态变化。结果表明,环境影响主要集中在海洋生态毒性,淡水生态毒性,人类致癌毒性,和人类非致癌毒性。烟气净化,垃圾焚烧和运输是关键流程,占65.61%,18.50%,以及整体环境影响的11.93%,分别。尿素,活性炭,螯合剂(EDTA)和柴油运输是关键因素。寿命周期成本(LCC)为132.26元/吨废物,其中初始资本造成最大的经济成本。当考虑城市生活垃圾焚烧发电以替代电网供电时,取得显著的环境效益,归一化环境影响值由0.85变为-12.19。研究结果为城市生活垃圾处理在整个生命周期内减轻环境影响和减轻经济负担提供了参考。
    Municipal solid waste incineration for power generation is significant for reducing and reusing solid waste. The study conducted an integrated assessment of environment and economy on municipal solid waste incineration in China, from a \"cradle to grave\" perspective using 1 tonne of municipal solid waste incineration as the functional unit. The environmental impacts of each month are also calculated to analyze the dynamic change throughout one year. The results indicate that the environmental impacts are mainly concentrated in marine ecotoxicity, freshwater ecotoxicity, human carcinogenic toxicity, and human non-carcinogenic toxicity. Flue gas purification, waste incineration and transportation are the key processes, which account for 65.61 %, 18.50 %, and 11.93 % of the overall environmental impact, respectively. Urea, activated carbon, chelating agent (EDTA) and diesel fuel for transportation are key factors. The life cycle cost (LCC) is 132.26 RMB/t of waste, of which the initial capital causes the largest economic cost. When considering power generated from municipal solid waste incineration to replace electricity supply from the power grid, it achieves significant environmental benefits and the normalized environmental impact value changes from 0.85 to -12.19. The findings provide references for municipal solid waste treatment to mitigate the environmental impact and reduce the economic burden across the entire life cycle.
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  • 文章类型: Journal Article
    由于全球人口增长和生活水平的提高,纺织品生产和消费增加。纺织固体废物已成为废物管理当局具有挑战性的问题。据报道,纺织材料每天都被丢弃,约占全球产生废物的1.5%。在过去的几十年里,全球所有地区的旧衣服都受到了特别关注,它可以将能源成本降低80%,并且还代表了经济上有利可图且对环境负责的原材料来源。这篇综述文章试图解决不同的主题,包括:固体纺织废物的来源,由于大量消费服装,纺织废物对环境的影响,纺织废物管理流程,如回收,纺织废料的再利用,垃圾填埋和焚烧以及从纺织废物中回收能源。通过收集最新的定量信息进行了叙事审查,以反映纺织固体废物的状况。在这篇文章中,研究并提出了从纺织废料中生产生物乙醇作为有价值的纤维素原料的可能性。结果表明,发展中国家缺乏系统的废物管理。在地球的另一边,这些天,一些国家正试图通过焚烧来回收能源。从这个过程中回收的热量和能量可以用来代替其他能源。在整个焚烧过程中,烟气(CO2,H2O,产生O2,N2),因此应适当设计以避免污染。在能量回收过程中,不同的预处理方法和不同的酶水解参数建议暗示更好的结果。
    Due to global population growth and living standards improvements, textile production and consumption are increased. Textile solid waste has become challenging issue for waste management authority. It is reported that textile materials are discarded daily, representing approximately 1.5% of the generated waste around the world. Over the past few decades, special attention has been given to the used clothes in all regions globally, which can reduce energy costs by 80% and also represent a source of raw materials economically profitable and environmentally responsible. This review article attempted to address different topics including: source of solid textile waste, environmental impact of textile waste as a result of massive consumption of clothing, textile waste management processes such as recycling, reuse of textile waste, landfill and incineration and energy recovery from textile waste. Narrative review with collection of recent quantitative information was carried to reflect the status of textile solid waste. In this article, the possibilities of bio-ethanol production from textile waste as valuable cellulosic raw material are investigated and presented. Results show that developing countries lack of systematic waste management. On another side of the globe, some countries are trying to recover energy these days by incineration. The heat and power that recovered from this process can be used instead of other energy sources. Throughout the incineration process, flue gases (CO2, H2O, O2, N2) are generated so it should be properly designed to avoid pollution. During energy recovery, different pre-treatment methods and different enzymatic hydrolysis parameters are recommended to be implied for better results.
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  • 文章类型: Journal Article
    本研究根据约旦2030年愿景,全面评估了约旦2022年至2030年的城市固体废物(MSW)管理部门。这项研究引入了新的可持续性指标和创新的废物管理替代方案,以应对快速工业化和人口增长的挑战。四个战略方案-1)回收,堆肥,和卫生填埋;2)回收,厌氧消化,和卫生填埋;3)焚烧和卫生填埋;4)仅根据业务照常进行评估。利用多准则决策分析(MCDA)和敏感性分析,这项研究评估了温室气体净排放量,年度运营费用,收入来源,和就业率来衡量环境,经济,和社会可持续性。结果表明,方案1是将材料回收设施(MRF)与堆肥厂和卫生垃圾填埋场整合在一起的最佳方案,实现最低的温室气体排放,年度成本,和就业机会。这项研究为约旦的废物管理挑战提供了实用和可持续的解决方案,通过开发的MCDA和敏感性分析提供新的见解,并为可持续性研究做出了重大贡献。
    This study comprehensively evaluates Jordan\'s municipal solid waste (MSW) management sector from 2022 to 2030, in alignment with Jordan Vision 2030. This study introduces new sustainability indicators and innovative waste management alternatives to address the challenges of rapid industrialization and population growth. Four strategic scenarios-1) recycling, composting, and sanitary landfilling; 2) recycling, anaerobic digestion, and sanitary landfilling; 3) incineration and sanitary landfilling; and 4) sanitary landfilling alone-were assessed against the business-as-usual scenario. Using multi-criteria decision analysis (MCDA) and sensitivity analysis, this study evaluates net greenhouse gas emissions, annual operating expenses, revenue streams, and employment rates to measure environmental, economic, and social sustainability. The results indicate that Scenario 1 is the optimal scenario for integrating a material recovery facility (MRF) with a composting plant and sanitary landfill, achieving the lowest greenhouse gas emissions, annual costs, and employment opportunities. This study offers practical and sustainable solutions to Jordan\'s waste management challenges, provides novel insights through the developed MCDA and sensitivity analysis, and significantly contributes to sustainability research.
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  • 文章类型: Journal Article
    城市固体废物(MSW)管理是大城市的一个关键问题,这些城市严重依赖外部材料和能源投入,但缺乏垃圾处理空间。MSW处理是碳排放的重要原因。源分类的实施改善了整个MSW管理系统,并增强了MSW的资源回收。然而,源分类对碳减排的确切贡献尚不清楚。本研究旨在分析深圳市城市生活垃圾管理中的碳排放演变,中国典型的大城市,使用2006年至2020年的数据,并采用碳足迹评估方法。结果表明,考虑到城市环境卫生管理部门的贡献,源分类将碳排放量从0.19-0.25降低到0.14-0.18tCO2-eq/tMSW。考虑到商业企业收集的可回收物,整个MSW管理系统成为碳汇。尽管来源分类使城市生活垃圾的收集和运输变得复杂,回收食品垃圾和可回收物的碳补偿效应比收集和运输的碳排放效应更显著。此外,垃圾填埋场气体回收率严重影响了垃圾填埋场管理系统的碳排放。相比之下,塑料的回收对于确定基于焚烧的MSW管理系统的碳排放至关重要。
    Municipal solid waste (MSW) management is a critical concern in megacities that depend heavily on external material and energy inputs but lack space for waste disposal. MSW treatment is a significant contributor to carbon emissions. The implementation of source classification improved the overall MSW management system and enhanced resource recovery from MSW. However, the precise contribution of source classification to carbon emissions reduction remains unclear. This study aimed to analyze the carbon emissions evolution in the MSW management of Shenzhen, a prototypical megacity in China, using data from 2006 to 2020 and employing carbon footprint assessment methodologies. The results demonstrated that source classification reduced the carbon emissions from 0.19-0.25 to 0.14-0.18 t CO2-eq/t MSW when considering the contribution of the urban environmental sanitation management department. The entire MSW management system becomes a carbon sink when considering recyclables collected by commercial enterprises. Although the source classification complicated the collection and transportation of MSW, the carbon offset effect of recycling food waste and recyclables was more significant than that of carbon emissions from collection and transport. Moreover, the landfill gas recovery rate critically influenced the carbon emissions of landfill-based MSW management systems. In contrast, the recovery of plastics was crucial for determining carbon emissions from incineration-based MSW management systems.
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