GFRP laminates

  • 文章类型: Journal Article
    在过去的几十年里,设计多功能材料和将各种功能集成到没有缺陷的单个组件结构中已经有了增长的趋势。这项研究解决了将多种功能无缝集成到热塑性层压结构中的当代需求。专注于NiTi基形状记忆合金(SMA),以其在引入应变测量和形状变化等功能方面的潜力而闻名,这项研究探索了SMA线的各种表面处理。技术,如热氧化,等离子体处理,化学活化,硅烷化,和附着力促进剂涂层进行了研究。追求将NiTiSMA集成到玻璃纤维增强聚合物(GFRP)层压板中以实现多功能性能。主要目的是评估这些表面处理对表面特性的影响,包括粗糙度,相位变化,和机械性能。微观结构,分析,并对原始和处理后的SMA线进行原位力学表征。随后在表征后将SMA线合并到GFRP层压板中,利用热压技术,允许通过拉出拉伸试验确定界面粘合强度。
    Over the past few decades, there has been a growing trend in designing multifunctional materials and integrating various functions into a single component structure without defects. This research addresses the contemporary demand for integrating multiple functions seamlessly into thermoplastic laminate structures. Focusing on NiTi-based shape memory alloys (SMAs), renowned for their potential in introducing functionalities like strain measurement and shape change, this study explores diverse surface treatments for SMA wires. Techniques such as thermal oxidation, plasma treatment, chemical activation, silanization, and adhesion promoter coatings are investigated. The integration of NiTi SMA into Glass Fiber-Reinforced Polymer (GFRP) laminates is pursued to enable multifunctional properties. The primary objective is to evaluate the influence of these surface treatments on surface characteristics, including roughness, phase changes, and mechanical properties. Microstructural, analytical, and in situ mechanical characterizations are conducted on both raw and treated SMA wires. The subsequent incorporation of SMA wires after characterization into GFRP laminates, utilizing hot-press technology, allows for the determination of interfacial adhesion strength through pull-out tensile tests.
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  • 文章类型: Journal Article
    玻璃纤维增强聚合物(GFRP)层压板由于其可用性而在许多应用中使用,高机械性能,和成本效益。在多层层压材料的生产过程中会出现波纹或褶皱形式的纤维缺陷。当生产具有显著厚度的弯曲层压板时,这种缺陷的可能性增加。研究已经证实,制造过程中的纤维变形导致层压材料的机械性能降低。因此,这些缺陷的早期检测是至关重要的。本文的主要部分涉及使用主动红外热成像技术检测弯曲多层GFRP层压板中皱纹的可能性的研究。通过分析扫描和显微图像来评估人工皱纹的大小。通过将样品与模具和假定的标称形状进行比较来评估样品的形状变形。在这项工作中提出了高压釜外制造工艺对减少形成的褶皱而不会显着影响层压板的内部结构的影响。这项研究证明了使用主动红外热成像技术检测厚弯曲层压板中皱纹的能力。然而,它还显示了热成像结果的解释如何受到结构曲率的影响,缺乏均匀的加热,和热成像装置的配置。
    Glass fiber-reinforced polymer (GFRP) laminates are used in many applications because of their availability, high mechanical properties, and cost-effectiveness. Fiber defects in the form of waviness or wrinkles can occur during the production of multilayered laminates. When curved laminates of significant thickness are produced, the likelihood of such defects increases. Studies have confirmed that fiber deformation during manufacture leads to a reduction in the mechanical properties of laminates. Therefore, early detection of such defects is essential. The main part of this paper deals with research into the possibility of using active infrared thermography to detect wrinkles in curved multilayered GFRP laminates. The size of the artificial wrinkles was assessed by analyzing scans and microimages. The shape deformations of the samples were evaluated by comparing the samples with the mold and the assumed nominal shape. The influence of the out-of-autoclave manufacturing process on the reduction in wrinkles formed without significantly affecting the internal structure of the laminate is presented in this work. This research demonstrated the ability to detect wrinkles in thick curved laminates using active infrared thermography. However, it also showed how the interpretation of the thermographic results is affected by the curvature of the structure, the lack of uniform heating, and the configuration of the thermographic setup.
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  • 文章类型: Journal Article
    聚合物复合材料的降解是许多工程方面的重要问题。由于复合材料开发过程中各种降解因素的相互作用,观察到破坏的协同效应。本文介绍了在水生环境中,在紫外线辐射(UV)的影响下,玻璃纤维增强聚酯层压板中发生的现象。将层压板暴露于UV-A,UV-B和UV-C辐射1000小时在自由空气和水下条件。在测试过程中,材料浸入1毫米和10毫米的稳定深度,分别。在暴露于紫外线后对样品进行的三点弯曲测试显示复合材料的挠曲强度增加。同时,观察到外表面层的降解。降解将树脂薄膜从表面上除去,这导致增强纤维直接暴露于环境中。由于由辐射产生的能量激发的附加交联反应,在复合材料的较深层中发生的转变增加了机械强度。此外,还观察到工艺过程后残留的游离苯乙烯形成聚合物结构,以及由于笼状效应而发生的自由基反应。
    Degradation of polymer composites is a significant problem in many engineering aspects. Due to the interaction of various degradation factors during the exploitation of composites, a synergistic effect of destruction is observed. The article describes the phenomena occurring in glass fiber reinforced polyester laminates under the influence of ultraviolet radiation (UV) in an aquatic environment. The laminates were exposed to UV-A, UV-B and UV-C radiation for 1000 h in free-air and underwater conditions. During the test, the materials were immersed at stable depth of 1 mm and 10 mm, respectively. The three-point bending tests performed on the samples after being exposed to UV showed an increase in the flexural strength of the composites. Simultaneously, degradation of the outer surface layer was observed. The degradation removed the thin resin film from the surface which resulted in a direct exposure of the reinforcing fibers to the environment. The transformations taking place in the deeper layers of the composite increased the mechanical strength due to the additional cross-linking reactions excited by the energy arising from the radiation. Moreover, the formation of polymer structures from free styrene remaining after the technological process and the occurrence of free radical reactions as a result of the cage effect was also observed.
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  • 文章类型: Journal Article
    这项研究提出了一种有效的低冲击能量耗散材料的选择,该材料应用于GFRP(玻璃纤维增强塑料)复合材料层压板,在使用相同的高速轻型材料反复撞击水面的情况下,使用辅助技术航行时,产生撞击现象。研究表明,用辅助层修改层压板的选择保护层压板免受损坏。这项工作提出了耗散层的制造,引入由聚合物基体和玻璃纤维增强材料制成的层压板中,在不同的冲击能量下通过重量下降试验进行评估。数据由给出冲击器加速度值的单向重力计收集和处理。测试比较了未经修改的面板与经修改的面板,表明未经修改的面板在相同的能量水平下吸收的能量更大。返回的能量比较曲线如图所示,并介绍了其使用的好处。
    This study presents the option of an effective low-impact energy dissipating material applied to GFRP (glass fiber reinforced plastic) composite laminates using auxectic technology in the case of planing hull vessels that use the same high-speed light materials that repeatedly impact the surface of the water when sailing, producing a slamming phenomenon. Research shows that the option to modify the laminate with an auxectic layer protects the laminate from damage. This work proposes the manufacturing of dissipative layers, introduced in laminates made with a polymeric matrix and fiberglass reinforcement, which are evaluated with weight drop tests under different impact energies. The data are collected and processed by a unidirectional gravitometer that gives the acceleration values of the impactor. The tests compare unmodified panels with modified panels, showing that the energy absorbed by the unmodified panel is greater at equal energy levels. The returned energy comparison curve is shown, and the benefits of its use are presented.
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