Mechanochemistry is an emerging research field at the interface of physics, mechanics, materials science, and chemistry. Complementary to traditional activation methods in chemistry, such as heat, electricity, and light, mechanochemistry focuses on the activation of chemical reactions by directly or indirectly applying mechanical forces. It has evolved as a powerful tool for controlling chemical reactions in solid state systems, sensing and responding to stresses in polymer materials, regulating interfacial adhesions, and stimulating biological processes. By combining theoretical approaches, simulations and experimental techniques, researchers have gained intricate insights into the mechanisms underlying mechanochemistry. In this review, the physical chemistry principles underpinning mechanochemistry are elucidated and a comprehensive overview of recent significant achievements in the discovery of mechanically responsive chemical processes is provided, with a particular emphasis on their applications in materials science. Additionally, The perspectives and insights into potential future directions for this exciting research field are offered.

Data on the strength ratio between agonist and antagonist muscles are frequently examined in sports testing, given its correlation with athletic performance. The purpose of this study was to determine the agonist-to-antagonist ratio of upper body strength in female and male elite Swedish track and field throwers using a new push (bench press) and pull (supine bench row) test device, and to determine its reliability. The study involved eight female and nine male athletes, aged 19-29 years, engaging, respectively, in discus, hammer, and shot put competitions at both national and international levels. The athletes\' maximum isometric force was assessed during the bench press (push) and supine bench row (pull) exercises, respectively, using a custom-built test device. The test-retest reliability of the device was also examined. The total push-to-pull strength ratio for the female throwers was 1.15, whereas male throwers demonstrated a ratio of 1.22. Total push and pull force for the female throwers was significantly less than for the male throwers (5511 N vs. 8970 N, p < 0.001). Intraclass correlation coefficients ranged from 0.93 to 0.96 for the bench press and supine bench row exercise, indicating that the push and pull test device was highly reliable. The main findings of this study were that elite female and male discus, hammer, and shot put throwers exhibited 15% and 22% more pushing (bench press) than pulling (supine bench row) strength. Push and pull strength in the female throwers ranged from 47% to 71% of that of the male throwers. The push and pull test device is a reliable tool in establishing the agonist-to-antagonist ratio of upper body strength of athletes. Coaches and athletes may benefit from examining upper body push and pull strength ratios for training planning and prescription.

Sleep has been recognized as one of the most essential recovery methods necessary for achieving optimal performance. However, there is still a lack of scientific literature focused on examining its impact on one of the most prevalent skills in the game of basketball, the countermovement vertical jump (CVJ). Therefore, the purpose of the present study was to examine the relationship between sleep quality and quantity, and lower-body neuromuscular performance characteristics within a cohort of semi-professional male basketball players. Twenty-eight athletes competing in a first-tier regional league in Serbia volunteered to participate in this investigation. Upon arrival at the gym, all athletes completed the Pittsburgh Sleep Quality Index (PSQI) self-rated questionnaire. Immediately after completion of the PSQI, each athlete stepped on a force plate system and performed three maximum-effort CVJs with no arm swing. The following force-time metrics were obtained for the analysis: eccentric and concentric absolute and relative mean and peak force and power, vertical jump height, and reactive strength index-modified. Pearson product-moment correlation coefficients were used to examine the strength of the linear relationships between sleep quality and quantity and lower-body neuromuscular performance characteristics (p < 0.05). The results indicated that sleep quality appears to have a greater impact on the concentric than the eccentric phase of the CVJ (e.g., concentric mean force [r = -0.830; p < 0.001], relative concentric peak force [r = -0.466; p = 0.013, eccentric mean power (r = -0.162; p = 0.409)], while no significant relationship was found between sleep quantity and lower-body neuromuscular performance (e.g., concentric peak force [r = -0.055; p = 0.782], relative eccentric mean power [r = -0.301; p = 0.107]). Overall, these findings offer valuable insights into the importance of good sleep hygiene (e.g., efficiency, duration) in an athletic population, and can help practitioners develop more effective training and recovery programs.

One of the reoccurring questions that arises during the countermovement vertical jump (CVJ) assessment is whether the learning effect has an impact on the accuracy of the results obtained. Thus, the purpose of the present investigation was to examine the impact of the short-term learning effect on the assessment of lower-body neuromuscular performance characteristics when performed on a portable one-dimensional force plate system. Sixteen recreationally active college-age males volunteered to participate in the present study. Each participant completed four sets of three non-consecutive CVJs with no arm swing throughout a single day. Besides strong verbal encouragement, participants were constantly instructed to focus on pushing the ground as explosively as possible. Fourteen force-time metrics were selected for CVJ performance analysis purposes: eccentric and concentric peak and mean force and power, eccentric and concentric duration, contraction time, jump height, reactive strength index-modified, and countermovement depth. Repeated measures multivariate analysis of variance was used to examine statistically significant differences across four testing time points (p < 0.05). The results indicate an absence of any meaningful differences across four testing time points in force-time metrics of interest during both eccentric and concentric phases of the CVJ. Moreover, no differences were observed in CVJ outcome metrics such as countermovement depth, suggesting that the movement strategy tends to remain consistent. Overall, these findings reveal that CVJ test repeatability is not affected by the short-term learning effect and that data are stable at least within the scope of this study and within this population.

UNASSIGNED: To evaluate the stress distribution of calculated standardized force on maxillary and mandibular jaw bones with proclined maxillary anterior teeth with and without the use of a mouthguard.
UNASSIGNED: It\'s a finite element analysis (FEA) study. Maxillary and mandibular jaw models with and without mouthguard (4 mm) were created using a cone-beam computed tomography (CBCT) scan of a 13-year-old male patient with proclined maxillary anterior teeth. Calculated standardized forces were applied on the maxillary central incisors in the horizontal direction of the created model. The von Mises stresses (MPa) were analyzed on the maxillary and mandibular jaw.
UNASSIGNED: Higher von Mises stresses were analyzed in the maxillary and mandibular jaw model without a mouthguard compared to the model with a mouthguard. Forces were more evenly distributed in the maxillary and mandibular jaw models with a mouthguard.
UNASSIGNED: A mouthguard can be used to reduce and evenly distribute the stress on the maxillary and mandibular jaw with proclined maxillary anterior teeth when exposed to real-life situation forces.
UNASSIGNED: The force of injury is influenced by the size of the object or the velocity at which the athlete hits the object/individual. There is a need to evaluate the force at which the individual athlete hits the object/surface based on average height, weight, and velocity/performance at that particular age. As the age of the athlete\'s advances, there is a change in the height, weight as well as performance. This factor will influence the impact and severity of the trauma caused during sports activities. So, these parameters should be considered while designing the mouthguard for its better effectiveness.
UNASSIGNED: Doiphode AR, Kalaskar R. Stress Distribution Pattern of a Calculated Standardized Force on Maxillary and Mandibular Jaws with Proclined Maxillary Anterior Teeth with and without the Use of Mouthguard: A 3D Finite Element Analysis. Int J Clin Pediatr Dent 2024;17(S-1):S61-S66.

UNASSIGNED: Elastic cushioning materials protect human tissue from injury by absorbing impact energy and delaying its transfer. However, the potential compromise in force delivery to the hitting target remains unknown.
UNASSIGNED: To examine if silicone cushioning compromises punch force delivery to a hitting target, a double-blind crossover trial with 12 elite boxers was conducted following material tests. Each boxer delivered five maximal punches under two conditions: silicone-hand wrapping and gauze-hand wrapping, in counterbalanced order, with a 3-day interval between sessions. Force distribution along the Z-axis indicated the punch\'s intended direction, while forces along the X and Y axes represented force dissipation toward unwanted direction.
UNASSIGNED: The material tests (based on ASTM International, West Conshohocken, PA, USA) demonstrated substantially higher compression to disruption for silicone than gauze of similar thickness. During the punching trials, the silicon-based hand wrapping exhibited slightly higher total force production (436 ± 33 N vs. 372 ± 12 N, p < 0.001) than the gauze-based hand wrapping. Moreover, force wastage, calculated as the sum of forces along the X and Y axes vs. the total force produced in percentage, was notably lower for silicone material (2.0% wastage) compared to gauze (3.8% wastage) (p < 0.001). The use of silicone materials lengthened the contact time between the punching fist and the hitting target from 35 ms to 50 ms (p < 0.001).
UNASSIGNED: The elastic cushion does not compromise the force delivery of the boxing glove to the hitting target. Instead, it appears to allow for additional maneuvering time for alignment during the fist-target contact with higher impact.

OBJECTIVE: Ischemic pre-conditioning (IPC) offers protection against future ischemic events and may improve sports performance due to several mechanisms at local and systemic levels. This study investigates the local effects on muscle contractility in electrically induced muscle contractions, thus effectively excluding any uncontrolled change in the motor drive.
METHODS: Twenty-one subjects were divided into two groups: 12 subjects in the IPC group (3 × 5/5 min right arm ischemia/reperfusion; cuff pressure 250 mmHg) and 9 subjects in the SHAM group (same treatment at 20 mmHg). The adductor pollicis was contracted by supramaximal stimulation of the ulnar nerve with single pulses, trains of stimuli (5, 8, 10 and 12 Hz, 1-s duration) and bursts (4 pulses, 25 Hz), all separated by 5-s intervals. The stimulation sequence was delivered before and 15 and 30 min after IPC/SHAM treatment. The isometric contraction force, the superficial electromyographic signal, and tissue oxygenation were continuously monitored.
RESULTS: A significant force decrease in time was observed at 8, 10 (p < 0.01) and 12 Hz (p < 0.05) along with a decrease in half-relaxation time in single twitches and bursts (p = 0.01), regardless of treatment. This general time-related weakening was more marked in IPC than SHAM at 5-Hz stimulation. No effects were observed on the magnitude of the superficial electromyographic signal.
CONCLUSIONS: Data indicate that IPC does not increase muscle force during electrically stimulated contractions, supporting the idea that IPC\'s ergogenic effects are not due to increased muscle contractility.

Interlimb asymmetry (ILA) refers to an anatomical or physiological imbalance between contralateral limbs, which can influence neuromuscular function. Investigating the influence of neuromuscular fatigue on ILA may be critical for optimizing training programs, injury rehabilitation, and sport-specific performance. The purpose of this study was to determine if a single bout of ice hockey-specific exercise creates or exacerbates lower-limb ILA. Before and after an on-ice training session, 33 youth ice-hockey athletes (14.9 [1.7] y; 11 females) performed 3 repetitions of a maximal vertical countermovement jump (CMJ), an eccentric hamstring contraction, and maximal isometric hip adduction and abduction contractions. Force- and power-related variables were analyzed to determine limb-specific neuromuscular function. The on-ice session reduced maximal isometric hip adduction (left: 7.3% [10.3%]; right: 9.5% [9.6%]) and abduction (left: 4.9% [6.9%]; right: 5.0% [8.1%]) force, but did not impair (P ≥ .10) CMJ performance (jump height, relative peak power, braking duration, and total duration). After the on-ice session, ILA was greater for CMJ propulsive impulse (6.3% [2.9%] vs 5.1% [2.6%]), CMJ braking rate of force development (19.3% [7.6%] vs 15.2% [6.4%]), and peak isometric hip adduction force (6.7% [5.5%] vs 6.1% [4.1%]). In conclusion, hockey-specific exercise leads to increased ILA for multiple force-related metrics, which may be a compensatory mechanism to maintain bilateral task performance when fatigued.

Nanoparticle manipulation requires careful analysis of the forces at play. Unfortunately, traditional force measurement techniques based on the particle velocity do not provide sufficient resolution, while balancing approaches involving counteracting forces are often cumbersome. Here, we demonstrate that a nanoparticle dielectrophoretic response can be quantitatively studied by a straightforward visual delineation of the dielectrophoretic trapping volume. We reveal this volume by detecting the width of the region depleted of gold nanoparticles by the dielectrophoretic force. Comparison of the measured widths for various nanoparticle sizes with numerical simulations obtained by solving the particle-conservation equation shows excellent agreement, thus providing access to the particle physical properties, such as polarizability and size. These findings can be further extended to investigate various types of nano-objects, including bio- and molecular aggregates, and offer a robust characterization tool that can enhance the control of matter at the nanoscale.

Cervicocephalic proprioception (CCP) is an important assessment item for people with a range of clinical conditions, where reduced CCP is associated with neck pain and imbalance. Reliability has been established for a range of positional and movements tests, but there is limited data regarding sense of force, particularly across three planes of movement. The current test-retest study assessed reliability when evaluating sense of force in healthy adults (8 males, 6 females, mean age 31.50 years [SD 10.14]) over two sessions, 4-7 days apart. A force matching protocol was used to evaluate reliability of absolute error (AE), constant error (CE), and variable error (VE) for 10 % and 25 % maximal voluntary contraction (MVC) target forces for flexion, extension, lateral flexion, and rotation. Participants were strapped to a chair to limit trunk movement and data was captured using a compressive force transducer fixed to an adjustable wall mount. Six trials were performed for each contraction-type, totaling 72 submaximal MVCs per session. ICC estimates for AE (0.15-0.77), CE (0.01-0.85), and VE (0.00-0.83) were varied and confidence intervals were mostly wide. Considering lower limits of confidence intervals, CE had best reliability values generally, but more specifically the most reliable contraction type and movement was 25 % MVC flexion (ICC 0.85, confidence interval 0.54-0.95). This study found that reliability for sense of force testing was dependent upon contraction, type of error, and target force utilized. Further reliability analysis should be performed when applying this test to measure validity outcomes in clinical populations.