Chemical Hazard Release

  • 文章类型: Journal Article
    近年来,环境事件显著激增,包括野火和化学释放.对此类事件的反应主要集中在解决严重和直接的影响。然而,潜在的长期健康风险被忽视了。我们提出的框架首先倡导全面识别污染物,优先考虑通过基于知识和非目标和目标分析确定的持久性有机污染物。我们建议整合环境监测和建模方法,以评估这些化学物质造成的污染程度和组成。为了促进快速评估,我们提倡发展简化的化学分析技术和持久性有机化学品原位监测专用技术。此外,我们概述了传统和最新的风险评估方法,并引入了三层风险评估框架,以评估与环境事件相关的长期健康风险。我们强调原位土壤修复和协调恢复工作的重要性,包括有效的沟通,疏散,以及受影响空间的清洁计划,这对于促进从环境事件中恢复至关重要。这种全面的方法加强了备灾和恢复战略,为管理未来的环境危机提供了一个强有力的框架。
    In recent years, there has been a notable surge in environmental incidents, including wildfires and chemical releases. Responses to such events have primarily focused on addressing acute and immediate impacts. However, potential long-term health risks have been overlooked. Our proposed framework first advocates for the holistic identification of contaminants, prioritizing persistent organic contaminants determined through both knowledge-based and non-targeted and targeted analysis. We suggest integrating environmental monitoring and modeling approaches to assess the extent and composition of contamination caused by these chemicals. To facilitate swift assessments, we advocate the development of streamlined chemical analysis techniques and dedicated technologies for in situ monitoring of persistent organic chemicals. In addition, we provide an overview of both traditional and state-of-the-art approaches to risk assessment and introduce a three-tier risk assessment framework for evaluating the long-term health risks associated with environmental incidents. We emphasize the importance of in situ soil remediation and coordinated recovery efforts, including effective communication, evacuation, and cleaning plans for affected spaces, which are pivotal for facilitating recovery from environmental incidents. This comprehensive approach fortifies preparedness and recovery strategies, providing a robust framework for managing future environmental crises.
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  • 文章类型: Journal Article
    目标:Seveso事故(1976年)在米兰以北地区造成了2,3,7,8-四氯二苯并对二恶英(TCDD)的污染,意大利。我们报告了截至2013年暴露人群死亡率和癌症发病率的最新结果。
    方法:研究队列包括生活在三个TCDD土壤浓度降低的污染区(A区,B和R)以及周围未受污染的区域(参考)。泊松模型分层/调整性别,对年龄和时期进行拟合以计算比率(RR)和95%CIs。
    结果:在男性的A区中,我们发现,在事故发生后的头十年中,循环系统疾病的死亡率上升(17人死亡,RR2.00,95%CI1.24至3.23)。在女性中,糖尿病死亡率增加,各地区都有积极的趋势。在最初的十年中,男性在R区的软组织肉瘤的发病率增加(6例,RR2.62,95%CI1.01至6.83)。在B区的女性中,30年后有过多的非霍奇金淋巴瘤(6例,RR2.87,95%CI1.14至7.23)。B区女性多发性骨髓瘤在第二个十年增加(4例,RR5.09,95%CI1.82至14.2),男性在R区(11例,RR2.15,95%CI1.08至4.26)。在R区的男性中,30年后出现白血病过度(23例,RR2.02,95%CI1.04至3.93)。
    结论:尽管不同性别的模式不同,地区和时间,我们证实了先前心血管疾病增加的结果,糖尿病,软组织肉瘤,以及淋巴癌和造血肿瘤。
    OBJECTIVE: The Seveso accident (1976) caused the contamination with 2,3,7,8-tetrachlorodibenzo-para-dioxin (TCDD) in an area north of Milan, Italy. We report the results of the update of mortality and cancer incidence in the exposed population through 2013.
    METHODS: The study cohort includes subjects living in three contaminated zones with decreasing TCDD soil concentrations (zone A, B and R) and in a surrounding uncontaminated territory (reference). Poisson models stratified/adjusted for gender, age and period were fitted to calculate rate ratios (RRs) and 95% CIs.
    RESULTS: In zone A in males, we found elevated mortality from circulatory diseases in the first decade after the accident (17 deaths, RR 2.00, 95% CI 1.24 to 3.23). In females, mortality from diabetes mellitus was increased, with a positive trend across zones. Incidence of soft tissue sarcoma was increased in males in zone R in the first decade (6 cases, RR 2.62, 95% CI 1.01 to 6.83). In females in zone B, there was an excess of non-Hodgkin\'s lymphoma after 30 years (6 cases, RR 2.87, 95% CI 1.14 to 7.23). Multiple myeloma was increased in the second decade in females in zone B (4 cases, RR 5.09, 95% CI 1.82 to 14.2) and in males in zone R (11 cases, RR 2.15, 95% CI 1.08 to 4.26). In males in zone R, there was a leukaemia excess after 30 years (23 cases, RR 2.02, 95% CI 1.04 to 3.93).
    CONCLUSIONS: Although with different patterns across gender, zone and time, we confirmed previous results of increased cardiovascular diseases, diabetes, soft tissue sarcoma, and lymphatic and haematopoietic cancers.
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  • 文章类型: Journal Article
    洪水相关的有毒化学品释放对健康造成的急性和长期影响是一个重大的地方健康问题,并可能不成比例地影响弱势群体社区;需要可靠的释放数据来量化这种危害。
    在本文中,我们分析美国联邦紧急事务管理署指定的洪泛区数据和美国环境保护局有毒物质释放清单(TRI)数据,以确定地理上操纵的数据库是否符合本福德法律。
    我们研究了多种变体,发现污染释放符合本福德定律和测试,从而验证了自我报告的毒性释放数据集。
    我们发现本福德定律适用于自我报告的有毒化学品释放和处置数据,表明缺乏广泛的数据错误或操纵。
    UNASSIGNED: Acute and long-term health impacts from flooding related toxic chemical releases are a significant local health concern and can disproportionately impact communities with vulnerable populations; reliable release data are needed to quantify this hazard.
    UNASSIGNED: In this paper, we analyze US Federal Emergency Management Agency designated floodplain data and US Environmental Protection Agency Toxic Release Inventory (TRI) data to determine if geographically manipulated databases adhere to Benford\'s Law.
    UNASSIGNED: We investigated multiple variants and discovered pollution releases adhere to Benford\'s Law and tests which thereby validates the self-reported toxic release dataset.
    UNASSIGNED: We find that Benford\'s Law applies to self-reported toxic chemical release and disposal data, indicating a lack of widespread data errors or manipulation.
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    文章类型: Journal Article
    背景:文献综述强调,联合准备和培训急救人员对于应对重大化学事件是必要的。对暴露评估的了解得到改善,可以估计风险并调整即时措施。本文的目的是总结在需要应急响应的化学事故中评估暴露的建议。分析了可以更好地预测化学污染并优化健康保护的措施。
    方法:对文献进行了综述,并使用PECO方法制定了研究问题。使用PRISMA方法选择文献。
    结论:选定的论文(n=16)表明,就个人和集体防护设备而言,化学事故的准备工作,风险评估过程的知识仍然缺乏。我们建议进行培训以掌握风险评估的步骤。我们的分析还指出了化学事件发生后监测环境状况的重要性,允许采取调整措施保护受影响人群,特别是弱势群体的健康。这种监测必须准确和动态,以便在干预阶段提供现实的建议。
    结论:了解风险评估过程的所有急救人员和卫生工作者都应做出改进:在时间和空间上使用保护措施,污染暴露的界限,以及风险的表征。
    BACKGROUND: The literature review highlights that joint preparation and training of first aid responders is necessary to deal with a major chemical incident. Improved knowledge of exposure assessments makes it possible to estimate the risk and adjust immediate measures. The aim of this paper is to summarize recommendations for assessing exposure during chemical incidents that require emergency responses. Actions allowing the chemical contamination to be better anticipated and health protection to be optimized were analyzed.
    METHODS: A review of the literature was conducted, and research questions were formulated using the PECO method. The PRISMA method was used to select the literature.
    CONCLUSIONS: The selected papers (n=16) show that preparation for chemical incidents in terms of individual and collective protective equipment, and knowledge of the risk assessment process remain lacking. We propose training to master the steps of risk assessment. Our analysis also points out the importance of monitoring the state of the environment after a chemical incident, allowing adjusted measures to protect the health of the exposed population and vulnerable groups in particular. This monitoring must be accurate and dynamic to provide realistic recommendations during the intervention phase.
    CONCLUSIONS: All first-aid responders and health workers knowing the risk assessment process should result in improvements: in the use of protective measures in time and space, the delimitation of exposure to contamination, and the characterization of the risk.
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  • 文章类型: Journal Article
    地表水中的化学物质泄漏对公众健康和环境构成重大威胁。本研究调查了与有机化学物泄漏紧急情况相关的公共卫生影响,并探索了饮用水设施可及时部署的对策。使用典型的多源新英格兰饮用水处理设施及其分配网络的动态模型,这项研究评估了各种对策部署方案的影响,包括源切换,通过聚合氯化铝(PACl)增强凝结,添加粉状活性炭(PAC),暂时关闭系统。这项研究表明,部署多种对策可以最大程度地减少总的公共卫生影响,不管需求和供应的可用性。首先部署PAC与其他对策的组合被证明是最有效的策略,其次是设施关闭的组合。通过了解潜在的公共卫生影响并评估对策的有效性,当局可以制定积极的计划,获得额外资金,并增强其减轻此类事件后果的能力。这些见解有助于保护公众健康,提高饮用水系统的抵御能力,以应对日益增长的化学品泄漏威胁。
    Chemical spills in surface waters pose a significant threat to public health and the environment. This study investigates the public health impacts associated with organic chemical spill emergencies and explores timely countermeasures deployable by drinking water facilities. Using a dynamic model of a typical multi-sourced New England drinking water treatment facility and its distribution network, this study assesses the impacts of various countermeasure deployment scenarios, including source switching, enhanced coagulation via poly‑aluminum chloride (PACl), addition of powdered activated carbon (PAC), and temporary system shutdown. This study reveals that the deployment of multiple countermeasures yields the most significant reduction in total public health impacts, regardless of the demand and supply availability. With the combination PAC deployed first with other countermeasures proving to be the most effective strategies, followed by the combination of facility shutdowns. By understanding the potential public health impacts and evaluating the effectiveness of countermeasures, authorities can develop proactive plans, secure additional funding, and enhance their capacity to mitigate the consequences of such events. These insights contribute to safeguarding public health and improving the resilience of drinking water systems in the face of the ever-growing threat of chemical spills.
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  • 文章类型: Journal Article
    通过Radon赤字技术调查了最近在加油站发生的柴油泄漏(日期为2019年1月±1个月)。主要重点是量化LNAPL孔隙饱和度作为老化持续时间的函数,并提出了现场自然衰减的预测模型。对当地波动的浅层含水层进行两年一次的监测,涉及饱和区9次,和渗流区只有一次。由于现场特点,进一步阐述了通常在外部和上游井中测量的Rn背景。使用钻井测井和潜水振荡。值得注意的是,这项研究标志着Rn赤字法的首次应用,以产生整个土壤深度的详细Rn背景图。同时,对LNAPL表面样品进行测试以研究柴油老化。特别是,他们专注于LNAPL粘度的时间变化(从最初的3.90cP到8.99cP,在25°C测量,34个月后),和Rn在污染物和水之间的分配系数(从47.7到80.2,在25°C时测得,14个月后)。在25°C的空气中,还可以在不同的流体中测量Rn扩散(0.092cm2s-1、1.14×10-5cm2s-1和2.53×10-6cm2s-1,水和LNAPL,分别)直接。介绍了本研究中使用的所有参数和方程,从理论角度讨论了它们对氡缺乏技术的影响。实验结果用于减轻LNAPL老化和潜水振荡对LNAPL饱和指数(S.I.LNAPL)测定的影响。最后,对S.I.LNAPL数据集进行了讨论和阐述,以显示整个地下污染物随时间的衰减,主要是由自然过程引起的。所提出的现场自然衰减预测模型表明,半去除时间为一年零六个月。这种模型的意义在于它们能够评估特定地点对污染物的反应,从而随着时间的推移提高补救工作的有效性。这些实验发现可能为Rn赤字技术的应用和持久性有机化合物的环境修复提供了一种新颖的方法。
    A recent diesel spill (dated January 2019 ± 1 month) in a refilling station is investigated by the Radon deficit technique. The primary focus was on quantifying the LNAPL pore saturation as a function of duration of ageing, and on proposing a predictive model for on-site natural attenuation. A biennial monitoring of the local fluctuating shallow aquifer has involved the saturated zone nine times, and the vadose zone only once. Rn background generally measured in external and upstream wells is elaborated further due to the site characteristics, using drilling logs and phreatic oscillations. Notably, this study marks the first application of the Rn deficit method to produce a detailed Rn background mapping throughout the soil depth. Simultaneously, tests are performed on LNAPL surnatant samples to study diesel ageing. In particular, they are focused on temporal variations of LNAPL viscosity (from an initial 3.90 cP to 8.99 cP, measured at 25 °C, after 34 months), and Rn partition coefficient between the pollutant and water (from 47.7 to 80.2, measured at 25 °C, after 14 months). Rn diffusion is also measured in different fluids (0.092 cm2 s-1, 1.14 × 10-5 cm2 s-1, and 2.53 × 10-6 cm2 s-1 at 25 °C for air, water and LNAPL, respectively) directly. All parameters and equations utilized during this study are introduced, discussing their influence on Radon deficit technique from a theoretical point of view. Experimental findings are used to mitigate the effect of LNAPL ageing and of phreatic oscillations on determination of LNAPL saturation index (S.I.LNAPL). Finally, S.I.LNAPL dataset is discussed and elaborated to show the pollutant attenuation across subsurface over time, induced by natural processes primarily. The proposed predictive model for on-site natural attenuation suggests a half-removal time of one year and six months. The significance of such models lies in their capability to assess site-specific reactions to pollutants, thereby enhancing the effectiveness of remediation efforts over time. These experimental findings may offer a novel approach to application of Rn deficit technique and to environmental remediation of persistent organic compounds.
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  • 文章类型: Journal Article
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  • 文章类型: Journal Article
    Objectives.本研究对中国发生的两起灾难性管道事故进行了比较分析,以找出一些常见的错误和经验教训,以防止类似事故的发生。方法。本研究使用了24Model,为事故分析提供了从个人层面到组织层面的通用途径。结果。这两种情况在发生方面有相似之处,发展,不同层次的紧急情况和因果关系:两者都是由管道泄漏引起的,并在应急过程中演变成多次爆炸;两者都是由潮湿或盐雾环境的密闭空间中的管道腐蚀引起的;两者都被归类为“责任事故”,和不安全的行为,例如未能识别出事故直接原因的管道隐患,反映了个人安全习惯行为在知识方面的缺陷,意识,习惯和心理;组织管理中的弱点主要涉及危险识别,管道维护,应急处置,等。组织内部没有良好的安全氛围。Conclusions.组织应制定闭环管理体系,加强安全文化建设,政府应该监督程序的执行。
    Objectives. This study conducted a comparative analysis of two catastrophic pipeline accidents in China in order to identify some common mistakes and lessons learned to prevent similar accidents. Methods. The 24Model was used in this study, which provides a universal pathway for accident analysis from the individual level to the organizational level. Results. There were similarities between the two cases in the aspects of the occurrence, development, emergency and causation at different levels: both were caused by leaks of pipelines and evolved into multiple explosions during emergency response; both leaks were caused by the corrosion of pipelines in the confined space of a damp or salt-spray environment; both were classified as \'responsibility accidents\', and unsafe acts, such as the failure to identify hidden hazards of pipelines that were the direct cause of accidents, reflected the shortcomings of individual safety habitual behaviour in terms of knowledge, awareness, habits and psychology; weaknesses in the organizational management mainly concerned hazard identification, pipeline maintenance, emergency disposal, etc.; and there is not a good safety climate within the organization. Conclusions. Organizations should develop a closed-loop management system and strengthen the construction of safety culture, and the government should supervise the implementation of procedures.
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  • 文章类型: Editorial
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  • 文章类型: Journal Article
    背景:本文总结了我们对运输过程中意外释放氯气的情景的研究,并准备了应急响应计划,以减轻城市地区的后续危害。
    方法:为了进行研究,事件树分析(ETA),一系列的头脑风暴会议,并使用空间/时间模型(PHAST)软件的系统发育分析对事故的后果进行建模。
    结论:根据事件树的结果,32个初始发生路径和20个最终发生路径被识别为结果。疏散时间约为41秒,这是非常短的,在离释放地点140-192米的半径范围内,伤亡人数估计为99%,在202-599米半径范围内50%,和半径为758米的1%。
    结论:随着后果建模的使用,ETA的开发可以有效地做好应急准备。在氯气释放的情况下,不可能有效控制释放源。此外,结果表明,在德黑兰这样的大城市,氯气的应用和运输可能是一个严峻的挑战。
    BACKGROUND: This article summarizes our research study on the scenario of an accidental chlorine gas release during transportation and preparing emergency response plan to mitigate the subsequent hazards in urban areas.
    METHODS: To conduct the research study, the event tree analysis (ETA), a series of brain storming sessions, and a modeling of consequences of an accident using the Phylogenetic Analysis with Space/Time models (PHAST) software were employed.
    CONCLUSIONS: Based on the result of the event tree, 32 initial occurring paths and 20 eventual occurring paths are identified as the outcome. The evacuation time is about 41 seconds, which is very short, and the odds of casualties are estimated at 99 percent within a radius of 140-192 m from the release site, 50 percent within a radius of 202-599 m, and 1 percent within a radius of 758 m.
    CONCLUSIONS: Along with the use of consequence modeling, the development of the ETA can be effective in emergency preparedness. In the case of a chlorine gas release, it would not be possible to effectively control the source of release. Furthermore, the result indicates that in a major city like Tehran, the application and transport of chlorine gas can be a serious challenge.
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