Cement industry

水泥工业
  • 文章类型: Journal Article
    提供的数据是从印度六个不同的水泥厂收集的与水泥生产有关的主要数据。这作为进行物料流分析的库存,供应链预测,以及水泥和混凝土系统的生命周期评估。数据集在三个数据表中给出,其中包含与生命周期评估(LCA)方法相关的步骤相关的信息,即,库存,表征因素和影响(这里,碳足迹和能源消耗)。数据包括原材料的数量(类型和来源),熟料和生产的其他产品中使用的电力(来源和数量),如OPC(普通波特兰水泥),PPC(波特兰火山灰水泥),PSC(波特兰矿渣水泥)和GGBS(磨碎的粒状高炉矿渣)。相关功能单元的数据(在表A和C中)。即,每个工厂生产一吨材料。表B给出了与水泥厂相关的火力发电厂中产生的电力(1kWh)相关的一种数据,也被称为圈养发电厂。由于水泥生产过程占人为二氧化碳排放量的8%,了解与之相关的环境影响很重要,和产生的原始数据对于评估影响和修改具有更高贡献的流程以减少影响至关重要。这个数据集可以,因此,作为收集来自世界任何地方的类似工厂的数据和基准的基础。
    The data provided is primary data related to cement production collected from the six different cement plants in India. This serves as the inventory for conducting material flow analysis, supply chain forecasting, and life cycle assessment of cement and concrete systems. The dataset is given in three data sheets with information relevant to the steps followed in line with the life cycle assessment (LCA) methodology, i.e., inventory, characterization factors and impacts (here, carbon footprint and energy consumed). The data includes the amounts of raw materials (type and source), the electricity (source and amount) used in the clinker and other products produced, such as OPC (Ordinary Portland Cement), PPC (Portland Pozzolana Cement), PSC (Portland Slag Cement) and GGBS (Ground Granulated Blast Furnace Slag). The data is presented (in Sheet A and C) for the relevant functional unit, i.e., one tonne of material produced in each plant. Sheet B gives one of its kind data related to electricity produced (1 kWh) in the thermal power plant associated with the cement plant, also called as captive power plant. As the cement production process contributes to 8% of the anthropogenic CO2 emissions, it is important to understand the environmental impacts associated with it, and primary data generated are essential for assessing the impacts and to modify the processes with higher contribution to reduce the impacts. This dataset can, therefore, serve as a basis to collect the data from similar plants in any part of the world and benchmarking.
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  • 文章类型: Journal Article
    水泥行业在全球碳排放中发挥着重要作用,强调迫切需要采取措施将其转变为零净碳足迹。本文为此提出了详细的计划,检查水泥行业的现状,它的碳输出,以及减排的必要性。它深入研究了各种低CO2技术和新兴创新,如碱活化水泥,钙循环,电气化,和生物启发材料。经济和政策因素,包括成本评估和政府法规,与挑战和潜在解决方案一起考虑。总结未来的前景,本文为决策者提供了建议,行业参与者,和研究人员,强调路线图在实现碳中和水泥行业中的关键作用。
    The cement industry plays a significant role in global carbon emissions, underscoring the urgent need for measures to transition it toward a net-zero carbon footprint. This paper presents a detailed plan to this end, examining the current state of the cement sector, its carbon output, and the imperative for emission reduction. It delves into various low-CO2 technologies and emerging innovations such as alkali-activated cements, calcium looping, electrification, and bio-inspired materials. Economic and policy factors, including cost assessments and governmental regulations, are considered alongside challenges and potential solutions. Concluding with future prospects, the paper offers recommendations for policymakers, industry players, and researchers, highlighting the roadmap\'s critical role in achieving a carbon-neutral cement sector.
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  • 文章类型: English Abstract
    The cement industry faces great pressure from the targets of carbon peak and carbon neutrality. CO2capture, geological utilization, and storage(CCUS) technology is crucial for CO2 mitigation in large-scale fossil-based industries. An integrated techno-economic assessment model of CCUS was improved here to assess the potential of CCUS retrofits in the cement industry in China, and the cost curve or supply curve of CCUS in the cement industry was obtained. The model set up ten scenarios from four aspects:source-sink matching distance, capture rate, CCUS technology, and technical level. The cement enterprise screening, site screening, techno-economic evaluation, and source-sink matching of CCUS were completed to answer some key problems in realizing low-carbon development via CCUS, such as enterprise inventory, storage site, emission reduction scale, and cost range. Under the scenario of 250 km matching distance, 85% net capture rate, CO2-enhanced water recovery technology, and current technical level, 44% of cement enterprises reduced carbon emission via CCUS, the cumulative capacity reached 625 million tons per year, and the levelized cost was 290-1838 yuan·t-1. The projects with a levelized cost of fewer than 600 yuan·t-1 accounted for 77% and could reduce CO2 emission by 564 million tons annually. The projects whose levelized cost was less than 400 yuan·t-1 could reduce CO2 by 199 million tons per year. When the coupling of CO2-enhanced oil recovery and CO2-enhanced water recovery technology was considered, the levelized cost was 27% lower. When the cement capacity was less than 530 million tons per year, the additional cost of cement production was 95-300 yuan·t-1. Under technological progress to 2030, the levelized cost will be reduced by 9%-15%. The regions with early demonstration advantages of full-chain CO2-enhanced water recovery technology were Xinjiang, Inner Mongolia, Ningxia, Henan, and Hebei. Additionally, the areas suitable for cement CCUS cluster included Ordos Basin, Junggar Basin, Bohai Bay Basin, and Songliao Basin. It is technically feasible for the cement industry to deploy full-chain CCUS projects, and low-cost projects have an early demonstration opportunity. These results can provide a quantitative reference for the low-carbon development of the cement industry and the commercial deployment of CCUS in cement production.
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  • 文章类型: Journal Article
    水泥行业的二氧化碳(CO2)排放量占工业总排放量的26%,水泥行业发展低碳技术的需求极为迫切。本手稿对不同地区和国家水泥行业的低碳项目和技术进行了全面审查,并分析了各县的低碳发展理念。对于中国和印度等发展中国家,节能增效是当前的重点,而对于欧洲等发达国家和地区,更多的努力集中在碳捕获上,利用率,和存储(CCUS)。全球CCUS项目以前已经进行过,大多数CCUS项目目前在欧洲执行,其中主要项目如CEMCAP,清洁工,和IEILAC项目代表了全球水泥行业在水泥生产技术和低碳技术方面的最新研究进展。低碳水泥技术的发展已经从关注终点转变为通过氢和太阳能的探索来关注来源和过程,预计将开发更具颠覆性和独创性的技术,特别是在中国的水泥行业。
    Carbon dioxide (CO2) emissions from the cement industry account for 26% of the total industrial emissions, and the need to develop low-carbon techniques within the cement industry is extremely urgent. Low-carbon projects and technologies for the cement industry in different regions and countries have been thoroughly reviewed in this manuscript, and the low-carbon development concept for each county has been analyzed. For developing countries such as China and India, energy saving and efficiency enhancement are currently the key points, while for developed countries and regions such as Europe, more efforts have been focused on carbon capture, utilization, and storage (CCUS). Global CCUS projects have been previously conducted, and the majority of CCUS projects are currently performed in Europe where major projects such as the CEMCAP, CLEANKER, and IEILAC projects represent the latest research progress in cement production technologies and low-carbon technologies for the global cement industry. The development of low-carbon cement technologies has changed from focusing on the end point to instead focusing on the source and process through the exploration of hydrogen and solar energies, and more disruptive and original technologies are expected to be developed, particularly in the cement industry in China.
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  • 文章类型: Journal Article
    目的:评估水泥生产工人的个人胸腔粉尘样品中的组成和对熟料和其他特定成分的暴露。
    方法:基于分类树开发了一种用于对水泥生产工厂中的空气传播颗粒进行分类的程序。为此,29个材料样品中27,217个颗粒的化学成分(熟料,石灰石,石膏,粘土,石英,铝土矿,铁源,粉煤灰,和煤)通过扫描电子显微镜(SEM)和能量色散X射线显微分析(EDX)自动确定。水泥中主要元素的浓度(钙,铝,硅,铁,和硫)用于分类。在材料样品中获得的分类树的分割标准用于对34个个人胸部气溶胶样品中的44,176个颗粒进行分类。对熟料和其他材料的含量进行了估算,并对熟料含量进行了统计分析,以了解工作类型和工作任务之间的差异。
    结果:材料样品中64%至88%的颗粒被归类为实际材料。具有可变成分的材料类型(粘土,粉煤灰,和煤炭)被归类为最低一致性(64%至67%),而成分变化更有限的材料(熟料,石膏,和石英)分类更一致(76%至85%)。个人样品中熟料含量的算术平均值(AM)为62.1%,中位数为55.3%,95%置信区间(CI)为42.6%至68.1%。在工作类型之间没有观察到显著差异。然而,当工人处理高熟料含量的材料时,样品中的熟料含量明显高于处理低熟料含量的材料时,85%对65%(P=0.02)。石灰石含量为14.8%,中位数13.2%(95%CI5.5至20.9),而其他材料的相对丰度中位数≤6.4%。
    结论:通过SEM-EDX进行自动颗粒分析,然后进行分类树分析,量化的熟料与预期在水泥生产工厂中空气传播的原材料一起评估时具有相当高的一致性。工作类型的熟料比例相似。按假定的熟料含量进行先验排序的任务有明显不同,并且根据预期,这支持所选方法的有效性。
    结论:水泥生产行业中矿物气溶胶的个人样品的组成可以通过使用SEM-EDX进行自动单颗粒分析并通过分类树程序进行分类来估算。熟料是水泥生产工人接触的胸腔气溶胶的主要成分。工作类型之间的差异相对较小且不显著。来自任务的熟料含量与假设一致。
    To estimate the composition and exposure to clinker and other specific components in personal thoracic dust samples of cement production workers.
    A procedure for the classification of airborne particles in cement production plants was developed based on classification trees. For this purpose, the chemical compositions of 27,217 particles in 29 material samples (clinker, limestone, gypsum, clay, quartz, bauxite, iron source, coal fly ash, and coal) were determined automatically by scanning electron microscopy (SEM) and energy-dispersive X-ray microanalysis (EDX). The concentrations of the major elements in cement (calcium, aluminium, silicon, iron, and sulphur) were used for the classifications. The split criteria of the classification trees obtained in the material samples were used to classify 44,176 particles in 34 personal thoracic aerosol samples. The contents of clinker and other materials were estimated, and the clinker contents were analysed statistically for differences between job types and job tasks.
    Between 64% and 88% of the particles from material samples were classified as actual materials. The material types with variable composition (clay, coal fly ash, and coal) were classified with the lowest consistency (64% to 67%), while materials with a more limited compositional variation (clinker, gypsum, and quartz) were classified more consistently (76% to 85%). The arithmetic mean (AM) of the clinker content in personal samples was 62.1%, the median was 55.3%, and 95% confidence interval (CI) was 42.6% to 68.1%. No significant differences were observed between job types. However, the clinker content in samples when workers handled materials with high clinker content was significantly higher than when materials with lower clinker content were handled, 85% versus 65% (P = 0.02). The limestone content was AM 14.8%, median 13.2% (95% CI 5.5 to 20.9), whereas the other materials were present with relative abundances of median ≤ 6.4%.
    Automated particle analysis by SEM-EDX followed by classification tree analysis quantified clinker with fairly high consistency when evaluated together with raw materials that are expected to be airborne in cement production plants. The clinker proportions for job types were similar. Tasks a priori ranked by assumed clinker content were significantly different and according to expectations, which supports the validity of the chosen methodology.
    The composition of personal samples of mineral aerosols in the cement production industry could be estimated by automated single particle analysis with SEM-EDX and classification by a classification tree procedure. Clinker was the major component in the thoracic aerosol that cement production workers were exposed to. Differences between job types were relatively small and not significant. The clinker content from tasks was in agreement with assumptions.
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  • 文章类型: Journal Article
    水泥行业对世界排放做出了重大贡献。全球采用可持续和循环做法来减少此类排放。像巴基斯坦这样的发展中国家缺乏对循环和可持续做法的适应。该研究提出了一种可用于水泥生产的煤炭和农作物残留物的替代混合物。该研究旨在为水泥工业中的燃烧目的寻找煤与农作物残渣的最佳混合物。生命周期评估(LCA)和生命周期成本分析(LCCA)是针对拟议材料混合物的环境和经济可行性实施的。此外,该研究旨在探索与发展中国家水泥行业实施循环实践相关的风险。本研究采用改进的安全改进风险评估(SIRA)进行风险评估。结果表明,用甘蔗渣部分替代煤是最可行的混合物,具有较低的环境排放,并且在其他替代混合物中在经济上是可行的。在风险评估方面,缺乏政府对采用循环经济(CE)做法的支持,以及这些CE做法的利润不确定性。
    The cement industry contributes substantially to world emissions. Sustainable and circular practices are adopted globally to mitigate such emissions. Developing countries like Pakistan lack adaptation to circular and sustainable practices. The study proposes an alternative mix of coal and crop residues that can be used for cement production. The study aims to find the best mixtures of coal with crop residue for combustion purposes in cement industries. The Life Cycle Assessment (LCA) and Life Cycle Cost Analysis (LCCA) are implemented for the environmental and economic viability of the proposed material mixtures. Moreover, the study seeks to explore risks associated with the implementation of circular practices in the cement industry of a developing country. The study adopts Modified Safety Improvement Risk Assessment (SIRA) for assessing the risks. The results suggest that the partial replacement of coal with bagasse is the most viable mixture with lower environmental emissions and is economically feasible among other alternate mixtures. In terms of risk assessment, there is a lack of governmental support for adopting circular economy (CE) practices and profit uncertainties of these CE practices.
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  • 文章类型: Journal Article
    水泥工业在任何国家的发展和经济增长中都起着至关重要的作用。水泥广泛用于建筑业和基础设施项目。丰富的原材料供应,基础设施需求,城市化,和最近的政府倡议-阿塔尔复兴和城市转型任务(AMRUT)项目和PradhanMantriAwasYojana(PMAY)下的所有人住房,印度在世界水泥生产国中排名第二。水泥厂将全球15%的污染物排放到各个行业的环境中。水泥行业的副产品包括粉尘/颗粒物(PM2.5和PM10),有毒气体(COX,NOx,SOx,CH4和VOC),噪音,和重金属(Cr,Ni,Co,Pb,和Hg),导致气候变化,全球变暖,和健康风险以及对动植物的负面影响。Terra,Aura,Sentinel-5P,GOSAT,和其他卫星数据集允许估计水泥行业的主要空气污染物,如颗粒物(PM),二氧化硫(SO2),二氧化氮(NO2),二氧化碳(CO2),和挥发性有机化合物(VOC)使用回归模型,基于人工神经网络的模型,机器学习模型,和对流层NO2垂直柱密度(VCD)检索算法。这篇评论文章探讨了印度水泥工业的演变,来自水泥工业的空气污染物,社会和环境影响,卫星数据集,用于评估空气污染物的模型,以及水泥行业长期可持续发展面临的挑战。
    The cement industry plays critical role in any country\'s development and economic growth. Cement is extensively used in construction sector and infrastructural projects. Abundant raw material availability, infrastructure demands, urbanization, and recent government initiatives-Atal Mission for Rejuvenation and Urban Transformation (AMRUT) project and housing for all under the Pradhan Mantri Awas Yojana (PMAY), India-stood at second place in cement-producing country in the world. Cement plants are emitting 15% of global pollutions into the environment among various industries. Cement industry byproducts include dust/particulate matter (PM2.5 and PM10), toxic gases (COx, NOx, SOx, CH4, and VOCs), noise, and heavy metals (Cr, Ni, Co, Pb, and Hg), which cause climate change, global warming, and health risks as well as negative impact on flora and fauna. The Terra, Aura, Sentinel-5P, GOSAT, and other satellite datasets allow estimation of cement industry major air pollutants such as particulate matter (PM), sulfur dioxide (SO2), nitrogen dioxide (NO2), carbon dioxide (CO2), and volatile organic compounds (VOCs) using regression models, artificial neural network-based models, machine learning models, and the tropospheric NO2 vertical column density (VCD) retrieval algorithm. This review article explores the evolution of the Indian cement industry, air pollutants from the cement industry, social and environmental implications, satellite datasets, models used for assessing air pollutants, and challenges for the long-term sustainability of the cement industry.
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  • 文章类型: Journal Article
    这项研究评估了暴露于铬(Cr)的水泥厂工人的致癌和非致癌健康风险,砷(As),镉(Cd),采用概率方法,水泥粉尘中的铅(Pb)。根据NIOSH7900和OSHAID-121方法收集空气样品,并通过石墨炉原子吸收光谱仪进行分析。利用EPA吸入风险评估模型和蒙特卡罗模拟对健康风险进行评估。采用敏感性分析确定影响健康风险的参数。As和Pb的平均浓度超过职业接触限值(OEL),达到最大3.4倍和1.7倍的OEL,分别,在水泥厂。单个金属的癌症风险按Cd This study assessed the carcinogenic and non-carcinogenic health risks of cement plant workers exposed to chromium (Cr), arsenic (As), cadmium (Cd), and lead (Pb) in cement dust using a probabilistic approach. Air samples were collected according to NIOSH 7900 and OSHA ID-121 methods and analyzed by an graphite furnace atomic absorption spectrometer. The EPA inhalation risk assessment model and Monte Carlo simulation were utilized to assess the health risks. Sensitivity analysis was used to determine the influencing parameters on health risk. The average concentrations of As and Pb exceeded the occupational exposure limit (OEL), reaching a maximum of 3.4 and 1.7 times the OEL, respectively, in the cement mill. Individual metals\' cancer risk exceeded the 1E-4 threshold in ascending order of Cd < As < Cr. The mean cancer risk of Cr ranged from 835E-4 (in raw mill) to 2870E-4 (in pre-heater and kiln). Except for Cd, the non-cancer risk of metals exceeded the standard (hazard index, HQ = 1) in the ascending order of Pb < As < Cr. The mean HQ of Cr ranged from 162.13 (in raw mill) to 558.73 (in pre-heater and kiln). After adjusting for control factors, the cancer and non-cancer risks remained over the respective recommended levels. Sensitivity analysis revealed that the concentration of Cr was the most influential parameter on both carcinogenic (78.5%) and non-carcinogenic (88.06%) risks. To protect the health of cement factory employees, it is recommended to minimize cement dust emissions, implement job rotation, and use raw materials with low levels of heavy metals.
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  • 文章类型: Journal Article
    水泥行业包括能源密集型工艺,例如,熟料回转窑和熟料炉排冷却器。熟料是在回转窑中从生料中通过化学和物理反应获得的;这些反应还涉及燃烧过程。炉排冷却器位于熟料回转窑的下游,目的是适当地冷却熟料。当熟料在炉排冷却器内运输时,通过多个冷空气风扇单元的作用冷却熟料。本工作描述了一个项目,其中先进的过程控制技术应用于熟料回转窑和熟料炉排冷却器。选择模型预测控制作为主要控制策略。通过临时工厂实验获得具有延迟的线性模型,并将其适当地包括在控制器的公式中。在窑炉和冷却器控制器之间引入了合作和协调策略。控制器的主要目标是控制回转窑和炉排冷却器的关键过程变量,同时最小化窑的燃料/煤的特定消耗和冷却器内的冷空气风扇单元的电能消耗。整个控制系统安装在真正的工厂,在服务系数、控制和节能性能方面取得显著成果。
    The cement industry includes energy-intensive processes, e.g., clinker rotary kilns and clinker grate coolers. Clinker is obtained through chemical and physical reactions in a rotary kiln from raw meal; these reactions also involve combustion processes. The grate cooler is located downstream of the clinker rotary kiln with the purpose of suitably cooling the clinker. The clinker is cooled through the action of multiple cold air fan units as it is transported within the grate cooler. The present work describes a project where Advanced Process Control techniques are applied to a clinker rotary kiln and a clinker grate cooler. Model Predictive Control was selected as the main control strategy. Linear models with delays are obtained through ad hoc plant experiments and suitably included in the controllers\' formulation. A cooperation and coordination policy is introduced between the kiln and the cooler controllers. The main objectives of the controllers are to control the rotary kiln and grate cooler critical process variables while minimizing the fuel/coal specific consumption of the kiln and the electric energy consumption of the cold air fan units within the cooler. The overall control system was installed on the real plant, obtaining significant results in terms of service factor and control and energy-saving performances.
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  • 文章类型: Journal Article
    蒂尔基耶是世界上最大的发展中国家之一和第二大水泥出口国。2021年,该国出口了约10亿美元的水泥,占全球排放量的8%以上。为了实现欧盟的规范,能源,排放,和降低成本的投资继续在该国。本文的目的是对旋转燃烧器进行详细的经济评估,以提高能量和火用性能并降低能耗。蒂尔基耶一家真正规模的水泥厂的火用成本和环境影响。在两年期间,通过对熟料生产过程的实时检测,从工厂获得了详细的数据。通过应用特定火用成本计算(SPECO)方法,能量和火用破坏,并详细计算了旋转燃烧器的成本分布。整个工厂的第一和第二定律效率,比能(SEC)和火用(SExC)消耗,熟料生产的SPECO计算为59.84%,39.04%,4786.75MJ/ton,5230.38MJ/ton,10.11美元/MJ,分别。镁尖晶石复合耐火砖的使用和支架层的形成使SPECO减少了2.71%,相当于每年节省了2,280,000美元,从而防止了13.74MtCO2的排放。
    Türkiye is one of the biggest developing countries and the second biggest cement exporter in the world. In 2021, the country exported around $1billion of cement, which is responsible for over 8% of emissions globally. In order to fulfill the EU norms, energy, emissions, and cost reduction investments continue in the country. The aim of this paper is to perform a detailed exergoeconomic assessment of a rotary burner to increase the energy and exergy performance and decrease energy consumption, exergy costs and environmental impacts of a real scale cement factory in Türkiye. During the 2-year period, detailed data has been obtained from the factory by real time detection of clinker manufacturing process. By applying the specific exergy costing (SPECO) method, energy and exergy destructions, and exergetic cost distributions for the rotary burner are calculated in detail. The 1st and 2nd law efficiencies of the overall factory, specific energy (SEC) and exergy (SExC) consumption, and SPECO for clinker production are calculated to be 59.84%, 39.04%, 4786.75 MJ/ton, 5230.38 MJ/ton, and 10.11 $/MJ, respectively. The use of magnesia-spinel composite refractory bricks and the anzast layer formation decreased the SPECO by 2.71% corresponding to a saving of $2,280,000 preventing 13.74 MtCO2 emissions yearly.
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