Conventional oil-water separation membranes are difficult to establish a trade-off between membrane flux and separation efficiency, and often result in serious secondary contamination due to their fouling issue and non-degradability. Herein, a double drying strategy was introduced through a combination of oven-drying and freeze-drying to create a super-wettable and eco-friendly oil-water separating aerogel membrane (TMAdf). Due to the regular nacre-like structures developed in the drying process and the pores formed by freeze-drying, TMAdf aerogel membrane finally develops regularly arranged porous structures. In addition, the aerogel membrane possesses excellent underwater superoleophobicity with a contact angle above 168° and antifouling properties. TMAdf aerogel membrane can effectively separate different kinds of oil-water mixtures and highly emulsified oil-water dispersions under gravity alone, achieving exceptionally high flux (3693 L·m-2·h-1) and efficiency (99 %), while being recyclable. The aerogel membrane also displays stability and universality, making it effective in removing oil droplets from water in corrosive environments such as acids, salts and alkalis. Furthermore, TMAdf aerogel membrane shows long-lasting antibacterial properties (photothermal sterilization up to 6 times) and biodegradability (completely degraded after 50 days in soil). This study presents new ideas and insights for the fabrication of multifunctional membranes for oil-water separation.

With the rapid development of urbanization, the discharge of industrial wastewater has led to increasingly critical water pollution issues. Additionally, heavy metals, organic dyes, microorganisms and oil pollution often coexist and have persistence and harmfulness. Developing materials that can treat these complex pollutants simultaneously has important practical significance. In this study, a calcium alginate-based aerogel membrane (PANI@CA membrane) was prepared by spraying, polymerization, Ca2+ cross-linking and freeze-drying using aniline and sodium alginate as raw materials. Oil-water emulsion can be separated by PANI@CA membrane only under gravity, and the separation efficiency was as high as 99 %. At the same time, the membrane can effectively intercept or adsorb organic dyes and heavy metal ions. The removal rates of methylene blue and Congo red were above 92 % and 63 % respectively even after ten times of cyclic filtration. The removal rate of Pb2+ was up to 95 %. In addition, PANI@CA membrane shows excellent photothermal conversion ability, and it can effectively kill Staphylococcus aureus under 808 nm laser irradiation. PANI@CA membrane has the advantages of low cost, simple preparation, good stability and high recycling ability, and has potential application prospects in wastewater treatment.

In recent years, frequent oil spills and increasing industrial wastewater discharge have caused serious water pollution problems. In addition, there are often microbial and dye pollutants in oil-containing wastewater. The development of materials that can simultaneously treat these three pollutants is very important for the safe treatment and recovery of wastewater. In this work, a modified calcium alginate-based aerogel membrane (CTW) was prepared through sol spraying, Ca2+ crosslinking and freeze drying by using tetrabutylammonium hydroxide (TBA) quaternary ammonium salt modified sodium alginate (SA) as raw material and waterborne polyurethane (WPU) as adhesive. The results show that CTW membrane has super hydrophilic and underwater super-oleophobic properties, and can realize the separation oil-water emulsions under gravity, with the separation efficiency of >99 %. CTW membrane can also remove bacteria and dye such as Congo red from water by filtration, with removal rates of 100 % and 99 % respectively. The filtration results of mixed wastewater show that CTW membrane can realize one-step separation of oil, bacteria and dye in wastewater, and can also be recycled, having potential application prospect.

The present work demonstrates an innovative strategy for robust water purification using an engineered aerogel membrane fabricated from biopolymers and task-specific Fe-Al-based nanocomposites. The as-prepared ethylenediaminetetraacetate dianhydride cross-linked chitosan- and agarose (7:3 weight ratio)-based aerogel membrane decorated with α-FeOOH- and γ-AlOOH-based nanocomposites was characterized using various analytical tools, which suggested formation of a highly stable network interconnected through covalent and electrostatic interactions. The optimized bionanocomposite-based aerogel (BNC-AG-0.1) membrane showed macroporous and partial unidirectional short-range channels with an ultralow density of 0.021 g·m-2, a high swelling ratio of 1974%, and a remarkable pure water flux of 19,228 L·m-2·h-1 (>6-fold higher flux compared to the reported aerogel membranes). The aerogel membranes were successfully utilized for purification of diverse pollutants such as dyes, emerging pollutants (EPs), arsenate, and fluoride in a continuous flow method under gravitational force. The BNC-AG-0.1 membrane exhibits high rejection (95-98.6%) for both cationic and anionic dyes with a flux rate of 1150-1375 L·m-2·h-1 and a rejection of 89-92% for EPs with a flux rate of 1098-1165 L·m-2·h-1. Moreover, the BNC-AG-0.1 membrane showed a qmax of 102.45 mg·g-1 (at pH 6.5) for As(V) with >93% rejection at a flow rate of 1000 L·m-2·h-1. Furthermore, the aerogel membrane showed an excellent removal efficiency (92%) of arsenic up to the 10th cycle and hence demonstrated as a potential adsorption-based membrane for arsenic-free potable water. On the other hand, the BNC-AG-0.1 membrane showed a qmax of 81.56 mg·g-1 (at pH 6.5) for F- removal with >99% rejection at a flow rate of 250 L·m-2·h-1. When applied for real-water purification, approximately 4734 L of safe drinking water (the F- concentration is less than the WHO permissible limit) per square meter of the aerogel membrane can be obtained with a flux rate of 250 L·m-2·h-1. Overall, the prepared aerogel membrane showed robust removal of a variety of contaminants with ultrafast water permeation and established excellent recyclability.

Owing to highly porous and low density attributes, aerogels have been actively utilized in catalysis and adsorption processes, but their great potential in filtration requires exploitation. In this study, an asymmetric aerogel membrane is fabricated via one-pot hydrothermal reaction-induced self-cross-linking of poly(vinyl alcohol) (PVA), which exhibits ultrafast permeation for the separation of oil-in-water emulsion. Meanwhile, carbon nanotubes are added to improve the mechanical strength of the aerogel membranes. The self-cross-linking of PVA forms the supporting layer, and the exchange of water and vapor at the interface of PVA solution and air generates the separating layer as well as abundant hydroxyl groups on the membrane surface. The density, porosity, pore size, and wettability of the aerogel membrane can be tuned by the PVA concentration. Owing to high porosity (>95%) and suitable pore size (<85 nm), the aerogel membrane exhibits high rejection (99.0%) for surfactant-stabilized oil-in-water emulsion with an ultrahigh permeation flux of 135.5 × 103 L m-2 h-1 bar-1 under gravity-driven flow, which is 2 orders of magnitude higher than commercial filtration membranes with similar rejection. Meanwhile, the aerogel membrane exhibits superhydrophilicity, superoleophobicity underwater, and excellent antifouling properties for various surfactant-stabilized oil-in-water emulsions, as indicated by the fact that the flux recovery ratio maintains more than 93% after five cycles of the filtration experiment. The findings in this study may offer a novel idea to fabricate high-throughput filtration membranes.

Here, we demonstrate direct recovery of water from stable emulsion waste using aerogel membrane. Chitosan-based gel was transformed into highly porous aerogel membrane using bio-origin genipin as cross-linking agent. Aerogel membranes were characterized for their morphology using SEM, chemical composition by FTIR and solid-UV. Further, aerogel was tested for recovery of high quality water from oil spill sample collected from ship breaking yard. High quality (with >99% purity) water was recovered with a flux rate of >600 L·m(-2)·h(-1)·bar(-1). After repeated use, aerogel membranes were tested for greener disposal possibilities by biodegrading membrane in soil.

With growing public interest in portable electronics such as micro fuel cells, micro gas total analysis systems, and portable medical devices, the need for miniaturized air pumps with minimal electrical power consumption is on the rise. Thus, the development and downsizing of next-generation thermal transpiration gas pumps has been investigated intensively during the last decades. Such a system relies on a mesoporous membrane that generates a thermomolecular pressure gradient under the action of an applied temperature bias. However, the development of highly miniaturized active membrane materials with tailored porosity and optimized pumping performance remains a major challenge. Here we report a systematic study on the manufacturing of aerogel membranes using an optimized, minimal-shrinkage sol-gel process, leading to low thermal conductivity and high air conductance. This combination of properties results in superior performance for miniaturized thermomolecular air pump applications. The engineering of such aerogel membranes, which implies pore structure control and chemical surface modification, requires both chemical processing know-how and a detailed understanding of the influence of the material properties on the spatial flow rate density. Optimal pumping performance was found for devices with integrated membranes with a density of 0.062 g cm(-3) and an average pore size of 142.0 nm. Benchmarking of such low-density hydrophobic active aerogel membranes gave an air flow rate density of 3.85 sccm·cm(-2) at an operating temperature of 400 °C. Such a silica aerogel membrane based system has shown more than 50% higher pumping performance when compared to conventional transpiration pump membrane materials as well as the ability to withstand higher operating temperatures (up to 440 °C). This study highlights new perspectives for the development of miniaturized thermal transpiration air pumps while offering insights into the fundamentals of molecular pumping in three-dimensional open-mesoporous materials.