Circular economy

循环经济
  • 文章类型: Journal Article
    自然环境经常被长链烃等疏水性污染物污染,石化产品,漏油,杀虫剂,和重金属。具有毒性的疏水性污染物,缓慢的降解率,低溶解度对环境和人类健康构成严重威胁。已经发现基于常规化学表面活性剂的去污是有毒的,从而限制了其在制药和化妆品工业中的应用。相比之下,由各种微生物物种合成的生物表面活性剂由于其无毒和经济的性质而被认为优于化学对应物。一些生物表面活性剂可以承受温度和pH的宽范围波动。最近,生物表面活性剂已经成为创新的生物分子,不仅用于增溶,而且还用于环境污染物如重金属的生物降解,杀虫剂,石油碳氢化合物,和漏油。生物表面活性剂已被充分证明可以作为乳化剂,分散稳定剂,和润湿剂。生物表面活性剂的两亲性质具有通过在两个不混溶表面中分布后降低界面表面张力来增强疏水性污染物如石油烃和溢油的溶解度的潜力。然而,使用生物表面活性剂对污染物的修复受温度的影响很大,pH值,媒体组成,搅拌速率,和选择用于生物表面活性剂生产的微生物。本综述简要讨论了微生物合成生物表面活性剂的最新进展,影响生产的因素,及其在修复疏水性环境污染物中的应用。此外,从废物产生生物表面活性剂和生物表面活性剂生产的全球经济方面讨论了循环生物经济的最新方面。
    The natural environment is often contaminated with hydrophobic pollutants such as long-chain hydrocarbons, petrochemicals, oil spills, pesticides, and heavy metals. Hydrophobic pollutants with a toxic nature, slow degradation rates, and low solubility pose serious threats to the environment and human health. Decontamination based on conventional chemical surfactants has been found to be toxic, thereby limiting its application in pharmaceutical and cosmetic industries. In contrast, biosurfactants synthesized by various microbial species have been considered superior to chemical counterparts due to their non-toxic and economical nature. Some biosurfactants can withstand a wide range of fluctuations in temperature and pH. Recently, biosurfactants have emerged as innovative biomolecules not only for solubilization but also for the biodegradation of environmental pollutants such as heavy metals, pesticides, petroleum hydrocarbons, and oil spills. Biosurfactants have been well documented to function as emulsifiers, dispersion stabilizers, and wetting agents. The amphiphilic nature of biosurfactants has the potential to enhance the solubility of hydrophobic pollutants such as petroleum hydrocarbons and oil spills by reducing interfacial surface tension after distribution in two immiscible surfaces. However, the remediation of contaminants using biosurfactants is affected considerably by temperature, pH, media composition, stirring rate, and microorganisms selected for biosurfactant production. The present review has briefly discussed the current advancements in microbially synthesized biosurfactants, factors affecting production, and their application in the remediation of environmental contaminants of a hydrophobic nature. In addition, the latest aspect of the circular bioeconomy is discussed in terms of generating biosurfactants from waste and the global economic aspects of biosurfactant production.
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  • 文章类型: Journal Article
    世界面临着令人震惊的塑料垃圾问题。塑料垃圾的数量正在迅速持续增加,主要是由于一次性塑料的过度消费,而它的回收和利用还有很多不足之处。尽管塑料对环境和公众健康有负面影响,COVID-19的爆发将公众的注意力从环境问题上转移了出去,可能为利益集团和行业的长期游说提供空间,以推迟甚至阻止打击塑料污染的立法。我们的研究旨在了解媒体对一次性塑料(SUP)的讨论,在大流行过程中演变。欧盟成员国之间的差异如何?为此,我们特别分析了2019年6月至2021年6月在四个欧盟成员国发表的主要著名日报上与塑料相关的文章:德国,法国,意大利,波兰,作为具有不同可持续转型水平的国家,形成了欧洲背景下的代表性模型。此外,在2022年11月至2023年1月之间,我们通过GoogleMeet进行了一系列采访,记者同意被问及他们提出的塑料问题。我们的分析最初涵盖了1076篇文章,其中198篇因不遵守主题或重复而被拒绝,留下878篇文章组成数据库进行最终分析。具体来说,我们概述了COVID-19大流行的关键影响,然后是与塑料相关的文章数量的明显变化,关于相关利益相关者的参与,以及对特定SUP项目的关注。此外,我们解决了一个研究空白-更详细地介绍了不同类型的SUP的媒体肖像,并强调了基于单个超国家(EU)中几个文化和语言上非常不同的国家的重要性。在一次性塑料的循环经济模式中,向知情知识流通的明显趋势逆转对于开发可持续解决方案以拒绝一次性文化至关重要。停止自然资源的浪费,并减少用于塑料生产的石油或天然气的消耗,从而保护气候。
    The world faces an alarming plastic waste problem. The volume of plastic waste is rapidly and continuously increasing, mainly due to the single-use plastics overconsumption, whereas its recycling and utilization leave much to be desired. Despite the negative effects of plastic on the environment and public health, the COVID-19 outbreak shifted the public attention away from the environmental issues, potentially giving space for extended lobbyism by interest groups and industry to delay or even prevent legislation to combat plastic pollution. Our study aims to understand how the media discourse on single-use plastic (SUP) in particular, evolves in the course of the pandemic. How it vary across EU Member States? For this purpose, we specifically analyse plastic-related articles in major prestigious daily newspapers published between June 2019 and June 2021 in four EU Member States: Germany, France, Italy, and Poland, as countries with different levels of sustainable transition to form a representative model of an European context. Additionally, between November 2022 and January 2023, we conducted a series of interviews via Google Meet, with journalists who agreed to be asked on the plastic issues they upraised. Our analysis initially covered 1076 articles, out of which 198 articles were rejected due to non-compliance with the subject or repetition, leaving 878 articles forming the database for eventual analysis. Specifically, we outline a key impact of the COVID-19 pandemic followed by a clear evolution on the number of plastic-related articles, on related stakeholder engagement, and the focus on specific SUP items. Moreover, we address a research gap - presenting a media portrait of different types of SUP in more details and highlighting the significance based on several culturally and linguistically very different countries within a single supranational state (EU). A clear trend reversal towards an informed knowledge circulation across the circular economy model of single-use plastics is ultimately essential to develop sustainable solutions to reject the disposable culture, stop the waste of natural resources, and reduce the consumption of oil or gas for plastic production and thus protect the climate.
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  • 文章类型: Journal Article
    水稻秸秆是一种多功能和宝贵的资源,对养分循环具有多方面的好处,土壤健康,和气候缓解。它作为丰富的营养源和有机质的作用,在改善土壤结构和保湿性的同时,显着增强了土壤活力。水稻秸秆的影响超出了传统的农业效益,包括促进微生物活性,侵蚀控制,和碳封存,强调其在维持生态平衡方面的关键作用。此外,探索了水稻秸秆在生物能源中的潜力,包括将其转化为沼气,生物燃料,和热能。水稻秸秆的固有特性,包括它的高纤维素,半纤维素,和木质素含量,通过热解等创新工艺将其定位为生物能源生产的可行候选者,气化,厌氧消化,和燃烧。最近的研究发现了能够将稻草转化为有价值产品的最先进技术和创新技术,包括糖,乙醇,paper,和纤维,扩大其潜在的应用。本文旨在强调通过水稻秸秆创造价值的可能性,强调其在生物能源中的潜在用途,生物制品,和其他环境应用。因此,通过认识和利用稻草的价值,我们可以倡导可持续的农业实践,减少浪费,并为资源节约型循环经济铺平道路。将水稻秸秆利用纳入农业系统可以为提高资源效率和更可持续的循环经济铺平道路。
    Paddy straw is a versatile and valuable resource with multifaceted benefits for nutrient cycling, soil health, and climate mitigation. Its role as a rich nutrient source and organic matter significantly enhances soil vitality while improving soil structure and moisture retention. The impact of paddy straw extends beyond traditional agricultural benefits, encompassing the promotion of microbial activity, erosion control, and carbon sequestration, highlighting its crucial role in maintaining ecological balance. Furthermore, the potential of paddy straw in bioenergy is explored, encompassing its conversion into biogas, biofuels, and thermal energy. The inherent characteristics of paddy straw, including its high cellulose, hemicellulose, and lignin content, position it as a viable candidate for bioenergy production through innovative processes like pyrolysis, gasification, anaerobic digestion, and combustion. Recent research has uncovered state-of-the-art techniques and innovative technologies capable of converting paddy straw into valuable products, including sugar, ethanol, paper, and fiber, broadening its potential applications. This paper aims to underscore the possibilities for value creation through paddy straw, emphasizing its potential use in bioenergy, bio-products, and other environmental applications. Therefore, by recognizing and harnessing the value of paddy straw, we can advocate for sustainable farming practices, reduce waste, and pave the way for a resource-efficient circular economy. Incorporating paddy straw utilization into agricultural systems can pave the way for enhanced resource efficiency and a more sustainable circular economy.
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  • 文章类型: Journal Article
    耗尽的橄榄渣(EOP)代表橄榄渣的主要残留物。一些研究已经优化了从OleaeuropaeaL.的EOP中提取特殊代谢物的方法,但是还没有对不同的提取方法进行比较。出于这个原因,本研究旨在比较使用水和15%乙醇/水作为萃取溶剂的四种不同的萃取方法。具体来说,基于提取物的抗氧化活性,比较的方法是浸渍(MAC),微波辅助提取(MAE),超声辅助提取(阿联酋),和加速溶剂萃取(ASE)。在这些之间,UAE和ASE水醇EOP提取物被证明具有最高的抗氧化活性。随后,使用体外无细胞和基于细胞的测定法研究了这些提取物的降血糖和抗自由基活性,分别。ASE水醇EOP提取物在HepG2细胞中表现出最大的抑制α-淀粉酶的能力和与N-乙酰半胱氨酸相当的体外抗氧化活性。阿联酋和ASE提取物的植物化学表征也进行了,鉴定七种酚类化合物,包括3-羟基酪醇,酪醇,and,第一次,红景天苷.从植物化学角度来看,ASE水醇EOP提取物是最丰富的,从而证实了它的主要生物活性。因此,ASE和15%乙醇/水可能代表EOP营养保健品增值的最佳提取方法。
    Exhausted olive pomace (EOP) represents the principal residue of olive pomace. Several studies have optimized the extraction of specialized metabolites from the EOP of Olea europaea L., but a comparison between different extractive methods has not been made. For this reason, the present investigation aims to compare four different extractive methods by using water and 15% ethanol/water as extractive solvents. Specifically, based on extract antioxidant activity, the methods compared were maceration (MAC), microwave-assisted extraction (MAE), ultrasound-assisted extraction (UAE), and Accelerated Solvent Extraction (ASE). Between these, the UAE and ASE hydroalcoholic EOP extracts were demonstrated to have the highest antioxidant activity. Subsequently, these extracts were investigated for their hypoglycemic and antiradical activity using in vitro cell-free and cell-based assays, respectively. ASE hydroalcoholic EOP extract demonstrated the greatest ability to inhibit the α-amylase enzyme and an in vitro antioxidant activity comparable to N-acetyl cysteine in HepG2 cells. UAE and ASE extracts\' phytochemical characterization was also performed, identifying seven phenolic compounds, including 3-hydroxytyrosol, tyrosol, and, for the first time, salidroside. The ASE hydroalcoholic EOP extract was the richest from a phytochemical point of view, thus confirming its major biological activity. Therefore, ASE and 15% ethanol/water may represent the best extractive method for EOP nutraceutical valorization.
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  • 文章类型: Journal Article
    本文探讨了生物质聚合物组成之间的复杂关系,热化学转化路线,炭产量和特征,以提高对生物质转化过程的知识,并对其进行定制以满足特定要求。已对三种类型的生物质进行了详尽的表征:(i)云杉树皮,来自林业和木材加工的木质初级和次级残留物;(ii)小麦秸秆-来自耕地和永久性农田的农业废物收获;和(iii)藤本植物芽,由葡萄园废物产生的木质生物质。化学(近似和最终分析),生物化学,微量元素,并进行了热分析。此外,傅里叶变换红外光谱,扫描电子显微镜,进行了热重分析,以确定原料的组成和结构特征。主要聚合物组分影响焦炭的数量和质量。高的半纤维素含量建议小麦秸秆是一种很好的候选材料,尤其是用于水热碳化。纤维素是热解过程中炭形成的主要贡献者,表明与从小麦秸秆转化而来的藤本植物芽相比,藤本植物芽可能会产生更高质量的炭。已表明,可以预测炭产率,并且在很大程度上取决于聚合物组成。而在云杉树皮和小麦秸秆的情况下,木质素对焦炭的形成有重要贡献,纤维素和次生木质素是藤本植物枝条炭的主要贡献者。
    This paper explores the intricate relations between biomass polymeric composition, thermochemical conversion routes, char yields and features in order to advance the knowledge on biomass conversion processes and customize them to meet specific requirements. An exhaustive characterization has been performed for three types of biomasses: (i) spruce bark, a woody primary and secondary residue from forestry and wood processing; (ii) wheat straws-agricultural waste harvest from arable and permanent cropland; and (iii) vine shoots, a woody biomass resulting from vineyard waste. Chemical (proximate and ultimate analysis), biochemical, trace elements, and thermal analyses were performed. Also, Fourier transform infrared spectroscopy, Scanning Electron Microscopy, and thermogravimetric analysis were conducted to establish the compositional and structural characteristics of feedstock. The main polymeric components influence the amount and quality of char. The high hemicellulose content recommends wheat straws as a good candidate especially for hydrothermal carbonization. Cellulose is a primary contributor to char formation during pyrolysis, suggesting that vine shoots may yield higher-quality char compared to that converted from wheat straws. It was shown that the char yield can be predicted and is strongly dependent on the polymeric composition. While in the case of spruce bark and wheat straws, lignin has a major contribution in the char formation, cellulose and secondary lignin are main contributors for vine shoots char.
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  • 文章类型: Journal Article
    增材制造(AM)的好处得到了广泛认可,提高AM方法在工业中的使用,据预测,AM将主导全球制造业。唉,3D打印的发展受到其可持续性的阻碍。AM方法产生大量被视为浪费的残差,被处理掉了。此外,消耗的能量,使用的材料,和许多其他因素使AM不可持续。本文旨在提出文献中所有文献记载的解决方案。焦点是粉末床融合(PBF)AM的潜在解决方案,专注于选择性激光烧结(SLS),因为这些都是按行业进行大规模制造的候选人。对解决方案进行严格评估,确定关于残余材料可回收性的研究空白。只有这样,AM才能主导制造业,这是非常重要的,因为这是我们向可持续制造业过渡的一个里程碑。这种转变本身就是我们寻求成为可持续文明的复杂瓶颈。与以前的评论主要集中在特定的AM回收材料不同,本文探讨了AM回收工艺的最新技术,纳入最新的市场数据和预测。通过对AM的演变和潜力提供整体和前瞻性的观点,这项审查是研究人员和行业专业人士的宝贵资源。
    The benefits of additive manufacturing (AM) are widely recognised, boosting the AM method\'s use in industry, while it is predicted AM will dominate the global manufacturing industry. Alas, 3D printing\'s growth is hindered by its sustainability. AM methods generate vast amounts of residuals considered as waste, which are disposed of. Additionally, the energy consumed, the materials used, and numerous other factors render AM unsustainable. This paper aims to bring forward all documented solutions in the literature. The spotlight is on potential solutions for the Powder Bed Fusion (PBF) AM, focusing on Selective Laser Sintering (SLS), as these are candidates for mass manufacturing by industry. Solutions are evaluated critically, to identify research gaps regarding the recyclability of residual material. Only then can AM dominate the manufacturing industry, which is extremely important since this is a milestone for our transition into sustainable manufacturing. This transition itself is a complex bottleneck on our quest for becoming a sustainable civilisation. Unlike previous reviews that primarily concentrate on specific AM recycling materials, this paper explores the state of the art in AM recycling processes, incorporating the latest market data and projections. By offering a holistic and forward-looking perspective on the evolution and potential of AM, this review serves as a valuable resource for researchers and industry professionals alike.
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  • 文章类型: Journal Article
    该研究的目的是通过在完全控制的条件下进行研究,通过回收窗框来确定木材再利用的限制因素。这项研究涉及制造新的窗框,调味它们,然后将它们切碎成木质颗粒,以制备三层刨花板。回收中木材颗粒的比例为所制造的刨花板的0、5、10、25、50和100重量份。进行了机械性能测试:弹性模量(MOE)和断裂模量(MOR),内部键(IB),螺钉拔出阻力(SWR),和物理性质:密度分布(DP),水浸后厚度膨胀(TS),吸水率(WA),以及甲醛释放量和总挥发性有机化合物(TVOCs)测试。研究表明,利用木材工业这一部门的木材具有巨大的潜力,特别是考虑到再生木材比例较高的变体。MOR和MOE结果对于超过50重量份的再生木材的变体是最有希望的。根据获得的结果,显然,应改进生产工艺或对原材料进行改性,以增强刨花板的内部粘结性,因为这些结果是最弱的。因此,来自窗户细木工的再生木材有可能被转世为刨花板,继续广泛用于其生产中。
    The aim of the study was to identify limiting factors for reusing wood through the recycling of window frames by conducting research under fully controlled conditions. The research involved manufacturing new window frames, seasoning them, and then shredding them into wood particles to prepare a three-layer particleboard. The proportion of wood particles in recycling was 0, 5, 10, 25, 50, and 100 parts by weight of the manufactured particleboard. Mechanical property tests were conducted: modulus of elasticity (MOE) and modulus of rupture (MOR), internal bond (IB), screw withdrawal resistance (SWR), and physical properties: density profile (DP), thickness swelling (TS) after water immersion, water absorption (WA), as well as formaldehyde emission and total volatile organic compound (TVOCs) tests. The research indicates a significant potential for utilizing wood from this sector of the wood industry, particularly considering variants with a higher proportion of recycled wood. MOR and MOE results are most promising for variants above 50 parts by weight of recycled wood. Based on the results obtained, it is clear that the production process should be improved or the raw material modified to enhance the internal bonding of particleboard, as these results were the weakest. Thus, recycled wood from window joinery has the potential to be reincarnated as particleboard, which continues to be widely used in their production.
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  • 文章类型: Journal Article
    近几十年来,塑料废物管理已成为当今社会面临的主要环境挑战之一。所谓一次性塑料的过度消费对生态系统造成持续破坏,有必要找到回收这些产品的替代品。在这项工作中,对内部掺入LDPE废物的新型石膏复合材料进行了机械和湿热表征。因此,预制石膏板的设计是用回收的LDPE部分替代原始原材料,体积百分比为5-10-15%。结果表明,在所有情况下,这些新型复合材料在面板中的最小断裂载荷均超过了0.18kN,同时密度和热导率降低高达15%和21%,分别,已获得。此外,通过模拟将这些新的石膏板掺入轻质外墙中,获得了3.8%的热阻增加。这样,为回收这些废物及其在建筑业的后续应用探索了一条新途径。
    In recent decades, plastic waste management has become one of the main environmental challenges for today\'s society. The excessive consumption of so-called single-use plastics causes continuous damage to ecosystems, and it is necessary to find alternatives to recycle these products. In this work, a mechanical and hygrothermal characterisation of novel plaster composites incorporating LDPE waste in their interior was carried out. Thus, prefabricated plasterboards have been designed with a partial replacement of the original raw material with recycled LDPE in percentages of 5-10-15% by volume. The results show how these new composites exceeded the 0.18 kN minimum breaking load in panels in all cases, while decreases in density and thermal conductivity of up to 15% and 21%, respectively, were obtained. In addition, an increase of 3.8%in thermal resistance was obtained by incorporating these new gypsum boards in lightweight façade walls through simulations. In this way, a new pathway was explored for the recovery of these wastes and their subsequent application in the construction sector.
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  • 文章类型: Journal Article
    分枝杆菌蛋白是通过真菌发酵产生的替代蛋白质。然而,它通常依赖于从淀粉中提取的精制葡萄糖浆,这可能是昂贵且不可持续的。这项研究调查了大豆加工副产品(豆渣和大豆乳清)作为使用米曲霉生产分枝杆菌蛋白的替代底物的潜力。将米曲霉在30°C下在稀释的豆渣(1:50)和大豆乳清(1:1)中在搅拌或不搅拌(100rpm)下培养7天。大豆乳清产生更高的生物量产量(369.2-408.8mg干生物量/g干基质),但具有较低的生物量浓度(0.783-0.867g干重/L)。相反,豆渣产生较高的生物量浓度(2.02g干重/L),产量为114.7mg干生物量/g干底物。然而,豆渣中的生物量形成仅在静态条件下观察到,由于搅拌导致生物质与大豆浆纠缠在一起,阻碍它的生产。此外,okara倾向于将蛋白质释放到培养基中,大豆乳清在生物质中积累蛋白质,达到53%w/w蛋白质含量。这项研究的结果为解决减少大豆加工废物和粮食安全问题提供了一种有希望的方法。
    Mycoprotein is an alternative protein produced through fungal fermentation. However, it typically relies on refined glucose syrup derived from starch, which can be costly and unsustainable. This study investigates the potential of soybean processing by-products (okara and soy whey) as alternative substrates for producing mycoprotein using Aspergillus oryzae. A. oryzae was cultured for 7 days at 30 °C in diluted okara (1:50) and soy whey (1:1) with or without agitation (100 rpm). Soy whey produced higher biomass yields (369.2-408.8 mg dry biomass/g dry substrate), but had a lower biomass concentration (0.783-0.867 g dry weight/L). Conversely, okara produced a higher biomass concentration (2.02 g dry weight/L) with a yield of 114.7 mg dry biomass/g dry substrate. However, biomass formation in okara was only observed in static conditions, as agitation caused biomass to entangle with soy pulp, hampering its production. Additionally, okara tended to release protein into the media, while soy whey accumulated protein within the biomass, reaching up to 53% w/w protein content. The results of this study provide a promising approach to addressing both soybean processing waste reduction and food security concerns.
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  • 文章类型: Journal Article
    本文旨在为循环经济(CE)提供全面的定义,以支持其在建筑和建筑行业的有效引入。根据欧盟委员会(EC)到2020年,建筑业占欧盟(EU)主要能源需求的40%,占其温室气体排放量的37%。因此,该部门可以在脱碳方面发挥关键作用,从而在应对气候变化实现零排放的未来方面发挥关键作用。CE旨在使经济增长与环境保护相协调,并基于在自然生态系统中以最少的实际浪费封闭循环的概念。因此,采用CE概念被视为通过部署更可持续的建筑过程来应对气候变化的可行措施,这些过程通过最大程度地回收和再利用来大大减少对自然资源的需求。然而,尽管人们认识到行政长官在可持续性问题上的潜力,由于定义的多样性反映了广泛的方面和优先事项,导致狭窄和有限的采用,因此在建筑和建筑部门采用CE模式具有挑战性。目前,文献中有许多与建筑和施工相关的CE定义,造成混乱,阻碍有效执行。这里提出的研究旨在,以全面的文献综述为基础,定义CE的关键领域,以便在其上调整简洁准确的定义,从而在建筑和建筑行业中有效应用。该研究还旨在确定当前的研究差距和障碍,以促进建筑行业CE研究的未来,从而推动CE项目的实施,以减轻气候变化的影响,并支持联合国可持续发展目标的实现。定义和理解CEs的原则。
    The paper aims to enable a comprehensive definition for a Circular Economy (CE) that will support its effective introduction in the building and construction sectors. According to the European Commission (EC), the building sector in 2020 accounted for 40 % of the primary energy demand in the European Union (EU) and 37 % of its greenhouse gas emissions. Thus, the sector can play a crucial role in decarbonisation and hence in achieving a zero-emissions future in response to climate change. A CE aims to harmonise economic growth with environmental protection and is based on the concept of closing the loop with minimal practical waste as in a natural ecosystem. The adoption of CE concepts is therefore seen as a feasible response to climate change through the deployment of more sustainable construction processes that significantly reduce the need for natural resources by maximising recycling and reuse. However, and despite the recognition of the potential of a CE in relation to sustainability issues, the adoption of a CE model within building and construction sectors is challenging because of the wide range of aspects and priorities which are reflected in the diversity of definition resulting in a narrow and limited adoption. There are currently many definitions of CEs as related to building and construction in the literature, creating confusion and preventing effective implementation. The study presented here intends, using a comprehensive literature review as its basis, to define the key domains of a CE on which to align a concise and accurate definition that will enable effective application in the building and construction sectors. The research also aims to identify current research gaps and barriers to contribute to the future of CE research in the building sector and thus drive the implementation of CE projects to mitigate the effects of climate change and support the achievement of the UN Sustainable Development Goals (SDGs) by laying the foundations for a novel and forward-looking approach to circularity based on properly established, defined and understood principles of CEs.
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