Halogenated benzoquinones (HBQs) are frequently detected in tap water. HBQ levels are correlated with water age. As the water-transmission distance (water age) increases, the levels of bromo-benzoquinones (Br-BQs) decreased and those of chloro-benzoquinones (Cl-BQs) remained relatively stable in drinking water-distribution system in the presence of residual chlorine. 2,3,5,6-Tetrachloro-1,4-benzoquinone (TCBQ) and 2,6-dibromo-1,4-benzoquinone (DBBQ) were the most abundant Cl-BQ and Br-BQ, with maximum concentrations of 60.2 and 181.4 ng/L, respectively. TCBQ and DBBQ were chosen as representatives of HBQs to investigate their reactions with chlorine, including kinetics, pathways, and changes in toxicity. The hydrolysis and chlorination rates of HBQs were significantly pH-dependent, and the kinetic rates of DBBQ were faster than TCBQ in the pH range of 5-10. Chlorination converted highly toxic TCBQ and DBBQ to less-toxic chlorinated/brominated aliphatic disinfection by-products (DBPs), thereby reducing the overall toxicity of water bodies. This study provides comprehensive insights into the distinct life cycles of TCBQ and DBBQ in drinking water, covering formation, transformation, and toxicity. These findings provide a nuanced understanding of the risks posed by HBQs at various locations within the drinking water distribution system, offering valuable guidance for improving the control of DBPs in drinking water.

Groundwater recharge reduces due to high transpiration from shallow-rooted to deep-rooted afforestation. However, reaching a steady state in recharge process is challenging and no methods are available for assessing potential groundwater recharge under unsteady state. Hence, this study developed a new method to quantify groundwater recharge in the unsteady state by (1) calculating the water age (A2) at maximum root depth (D2) for deep-rooted afforestation using the chloride accumulative age method; (2) determining the soil depth (D1) corresponding to A2 under shallow-rooted vegetation using the multi-year average pore water velocity multiplied by A2; (3) calculating the reduction in groundwater recharge (∆R) from shallow- to deep-rooted afforestation as the depth difference multiplied by the average water content between D1 and D2, divided by stand age. The average groundwater recharge for deep-rooted afforestation is equal to the average annual groundwater recharge under shallow-rooted vegetation minus ∆R. Soil cores with >25 m soil profiles below four land-use types of Hippophae rhamnoides Linn. (H. rhamnoides), Platycladus orientalis (L.) Franco (P. orientalis), Robinia pseudoacacia L. (R. pseudoacacia), and grassland were collected to measure soil water content, root distribution, and chloride and tritium contents. The results revealed that: (1) maximum root depths were 11.0 ± 0.5, 20.2 ± 1.2, and 22.6 ± 0.8 m, with soil water deficits of 373.48, 823.65, and 1847.92 mm under H. rhamnoides, P. orientalis, and R. pseudoacacia, respectively; (2) groundwater recharge following land-use change has not reached a steady state; (3) an average annual groundwater recharge was 89.12 mm yr-1 under grassland, amounting to 16 % of the average annual precipitation; deep-rooted afforestation did not significantly differ, with 83.55, 84.91, and 85.65 mm yr-1 under H. rhamnoides, P. orientalis, and R. pseudoacacia, respectively. This study contributes to a rational assessment of groundwater resources under unsteady state during land-use change.

97% of residential buildings are installed with secondary water supply system (SWSS) in China. In order to meet the water pressure demand, the SWSS has become a key solution to store and transport drinking water. The water age of the SWSS directly determines the quality of tap water, while total chlorine is a key indicator to evaluate the quality and safety of the water supply network. This study revealed the relationship between total chlorine and water age controlled by adjusting the liquid level of the secondary water supply tank. Models governing water age and the total chlorine concentration were developed based on the variation of the liquid level and the attenuation rate of the total chlorine in the SWSS. Furthermore, the validation was performed through case studies. The developed models can gain effective insights for determining the longest water age while guaranteeing the concentration of total chlorine meets the demand of the lower standard in SWSS. The secondary chlorine dosage would be quantified and added to the pipe network. The integration of the SWSS would be guided by water age in some old communities. The taste of tap water for direct drinking water could be improved by adjusting of water age using this model. The optimization method is easy to use for identifying efficient solutions for SWSS operation.

Due to the lack of outlets, inflowing pollutants are often deposited in an endorheic lake, posing potential pressure on the environment. With climate change, extreme weather is expected to be more frequent and will contribute to the release of carbon and nutrients buried in the lakebeds. However, the distribution of sedimentary organic carbon and nutrients and the mechanisms that control the distribution are not fully understood, despite their significance to environmental development in endorheic lakes being widely recognized. In this study, the mechanisms controlling the sedimentary organic carbon and nutrient distributions in endorheic lakes were examined based on the analysis of an endorheic lake in the semiarid area of the Mongolian Plateau. The field survey results indicate that the concentrations of sedimentary organic carbon (TOC) and nutrients (NH3-N and TP) on the lakebed have significant correlations and present spatial heterogeneities. To further study the distribution mechanisms, numerical models were established to calculate the age of the water discharged from the rivers around the lake, and satellite remote sensing data were applied to examine the external source of organic carbon and nutrients and the factors influencing their movements to the lake. Based on the distribution of the water age, the water flow and mass transport trends in Lake Hulun were determined, and the time scales of the environmental processes were compared with those of water circulation. Further analysis indicates that the water circulation in the lake favors the accumulation of sedimentary organic carbon and nutrients in the northwestern part of the lake, and the organic carbon produced in the lake is transported to this region within an ice-free period. Satellite remote sensing data indicate that the region on the northwest bank of the lake experiences a larger terrestrial slope and better vegetation coverage than that on the southeast bank, which corresponds to a higher concentration of sedimentary organic carbon and nutrients in the northwest of the lake. This suggests that the sediment quality is closely related to the environment around the endorheic lake, and the larger slope and better vegetation coverage are significant factors for the high concentration of sedimentary organic carbon and nutrients on the lakebed under the conditions of scarce precipitation and low temperature. This study provides a theoretical basis and direction for further protection and management of the ecological environment of endorheic lakes.

In recent years, problems such as water quality deterioration, saltwater invasion, and low oxygen have appeared in estuaries all over the world. The Minjiang River in Fujian, as a typical tidal estuary area, is facing these thorny problems. In this paper, the effects of topography and hydrologic evolution on the water age and water quality of the lower reaches of the Minjiang River were simulated by building a hydrodynamic and water quality model. The results show that: (1) It was found that the riverbed incision of the lower reaches of the Minjiang River led to the overall decline of river water level, the increase of river volume, and the increase of downstream water age, which eventually led to the decrease of dissolved oxygen (DO) and the deterioration of water quality in the downstream from Shuikou to Baiyantan. However, the decline of topography led to the increase of tidal volume in the estuary, the enhancement of the dilution effect of oxygen-rich water bodies in the open sea, and the increase of DO in the lower reaches of Baiyantan. (2) Under no tidal action, the concentration of pollutants in the water of the North Channel increased, the DO decreased, and the DO decreased from Baiyantan to the offshore water. After the enhancement of tidal action, the dilution of oxygen-enriched water from the offshore water increased, and the DO increased. (3) The hydrological and water quality characteristics of the upper part of the lower reaches of the Minjiang River were mainly controlled by topography, runoff, and pollutant discharge, which were more affected by the tidal current transport operation and pollutant discharge near the open sea. In recent decades, the deterioration of water quality and the aggravation of saltwater intrusion in the Minjiang River were closely related to the serious topographic downcutting. The results provide a scientific basis for revealing the deterioration of estuary water quality and long-term management of the estuary.

As a key component of the global water cycle, river flow transports both freshwater and biotic/abiotic matters from land to sea, while in recent decades its rhythm has been strongly disturbed by human activities, especially damming. Yet little is known about the long-distance transport processes along the world\'s major fluvial systems and the impact of large dams on their timescales. Here, taking the Changjiang River (Yangtze River) as an example, we built a hydrodynamics-based model to investigate the water age and residence time in the mainstream from the upper reach ~700 km upstream of the Three Gorges Dam (TGD) to the estuary ~1900 km downstream of the TGD. We find that since the mainstream was dammed by the TGD, the water age increases significantly by approximately 2 to 5 times from the estuary to the dam. Downstream of the dam the longitudinal ageing rate of water becomes discordant in an annual cycle, and the replenished discharge in dry season accelerates the water transport. Due to the stationary assumption, the widely applied hydraulic residence time of water is substantially larger and smaller than the age-based dynamic residence time in the large reservoir during the impounding and releasing periods, respectively.

Estuaries are a special transition zone subject to both riverine and marine processes, where environmental issues, e.g. water pollution, eutrophication and hypoxia, have become an increasing cause of concern in recent decades. The vertical transport of water and material is an intrinsic process in estuarine environments, with the atmosphere and seabed being the upper and lower boundaries. However, vertical water renewal in estuaries is not fully understood despite its significance to the estuarine environment being widely recognized. In the present study, the vertical water renewal process in a large estuary is investigated using the concept of water age. A three-dimensional water age model is built based on a hydrodynamic model, in which the age of a water parcel is defined as the time interval since it last touched the air-water interface, and thus indicates the renewal duration from the free surface. Water renewal durations, especially when relatively long, can provide insight into environmental and water quality issues, e.g. a low dissolved oxygen (DO), that can have a significant impact on ecosystem functioning. Results showed that the water age in the Pearl River Estuary (PRE) was characterized by significant spatial distributions and seasonal variations, which depends heavily on the water density stratification, as indicated by the Richardson number. During the wet season, the bottom water age was large at the lower reach of the estuary, up to 8 days, whereas the maximum bottom age during the dry season was ~1 day at the upper reach. Based on the quantification of vertical renewal, a new approach was proposed, and used to successfully evaluating DO depletion. The data and method would benefit for future environmental management, eco-biological restoration and related policy-making, especially when oxygen-based pollution is considered.

Submarine groundwater discharge (SGD) has been recognized as an important source of dissolved heavy metals to the coastal ocean. Bohai Bay, the second largest bay of Bohai Sea in China, is subjected to serious environmental problems. However, SGD and SGD-derived heavy metal fluxes in the bay are seldom reported. In this study, we present mass balance models considering the radium losses caused by recirculated seawater to estimate water age, SGD and SGD-derived heavy metal fluxes in Bohai Bay during May 2017. The water age is estimated to be 56.7-85.0 days based on tidal prism model. By combining water and salt mass balance models, submarine fresh groundwater discharge (SFGD) is estimated to be (3.5-9.3) × 107 m3 d-1. The SGD flux estimated by the radium mass balance models is (3.2-7.7) × 108 m3 d-1, an order of magnitude larger than the discharge of the Yellow River during the sampling period. SGD-derived heavy metal fluxes were estimated to be (0.2-6.0) × 107 mol d-1 for Fe, (1.2-2.7) × 107 mol d-1 for Mn, (3.0-8.2) × 105 mol d-1 for Zn, (2.7-7.4) × 104 mol d-1 for Cr and (0.6-1.8) × 103 mol d-1 for Cd, which are significantly higher than those from local rivers. This study reveals that SGD is a significant source of heavy metals (Mn, Zn and Fe) into Bohai Bay, which may have important influences on the metal budgets and ecological environments in coastal areas.

Anthropogenic activities such as land reclamation are threatening tidal marshes worldwide. This study\'s hypothesis is that land reclamation in a semi-enclosed bay alters the seasonal dynamics of intertidal benthic infauna, which is a key component in the tidal marsh ecosystem. Mai Po Tidal Marsh, Deep Bay, Pearl River Estuary, China was used as a case study to evaluate the hypothesis. Ecological models that simulate benthic biomass dynamics with governing environmental factors were developed, and various scenario experiments were conducted to evaluate the impact of reclamations. Environmental variables, selected from the areas of hydrodynamics, meteorology, and water quality based on correlation analysis, were used to generate Bayesian regression models for biomass prediction. The best-performing model, which considered average water age (i.e., a hydrodynamic indicator of estuarine circulation) in the previous month, salinity variation (i.e., standard deviation of salinity), and the total sunny period in the current month, captured well both seasonal and yearly trends in the benthic infauna observations from 2002 to 2008. This model was then used to simulate biomass dynamics with varying inputs of water age and salinity variation from coastal numerical models of different reclamation scenarios. The simulation results suggest that the reclamation in 2007 decreased the spatial and annual average benthic infauna biomass in the tidal marsh by 20%, which agreed with the 28% biomass decrease recorded by field survey. The range of biomass seasonal variation also decreased significantly from 2.1 to 230.5g/m2 (without any reclamation) to 1.2 to 131.1g/m2 (after the 2007 reclamation), which further demonstrates the substantial ecological impact of reclamation. The ecological model developed in this study could simulate seasonal biomass dynamics and evaluate the ecological impact of reclamation projects. It can therefore be applied to evaluate the ecological impact of coastal engineering projects for tidal marsh management, conservation, and restoration.

The water quality in Poyang Lake, the largest freshwater lake in China, has deteriorated steadily in recent years and local governments have made efforts to manage the potential eutrophication. In order to investigate the transport and retention processes of dissolved substances, the hydrodynamic model, Environmental Fluid Dynamics Code (EFDC) was applied by using the concept of water age. The simulated results showed agreement with the measured water level, discharge, and inundation area. The water age in Poyang Lake was significantly influenced by the variations of hydrological conditions. The annual analysis revealed that the largest averaged water age was observed during the wet year (2010) with 28.4 days at Hukou, the junction of the Yangtze River and Poyang Lake. In the normal season (April), the youngest age with 9.1 days was found. The spatial distribution of water quality derived from the remote sensing images suggested that a higher chlorophyll-a concentration, lower turbidity, and smaller water age in the eastern area of Poyang Lake might threaten the regional aquatic health. The particle tracking simulation reproduced the trajectories of the dissolved substances, indicating that the water mass with greater nutrient loading would further lead to potential environmental problems in the east lake. Moreover, the water transfer ability would be weakened due to dam (Poyang Project) construction resulting in the rising water levels in periods of regulation. Generally, this study quantified an indicative transport timescale, which could help to better understand the complex hydrodynamic processes and manage wetland ecosystems similar to Poyang Lake.