In the evolving landscape of food packaging, lipid-based edible films and coatings are emerging as a sustainable and effective solution for enhancing food quality and prolonging shelf life. This critical review aims to offer a comprehensive overview of the functional properties, roles, and fabrication techniques associated with lipid-based materials in food packaging. It explores the unique advantages of lipids, including waxes, resins, and fatty acids, in providing effective water vapor, gas, and microbial barriers. When integrated with other biopolymers, such as proteins and polysaccharides, lipid-based composite films demonstrate superior thermal, mechanical, and barrier properties. The review also covers the application of these innovative coatings in preserving a wide range of fruits and vegetables, highlighting their role in reducing moisture loss, controlling respiration rates, and maintaining firmness. Furthermore, the safety aspects of lipid-based coatings are discussed to address consumer and regulatory concerns.

Energy problems have become increasingly prominent. The use of thermal insulation materials is an effective measure to save energy. As an efficient energy-saving material, nanocellulose aerogels have broad application prospects. However, nanocellulose aerogels have problems such as poor mechanical properties, high flammability, and they easily absorbs water from the environment. These defects restrict their thermal insulation performance and severely limit their application. This review analyzes the thermal insulation mechanism of nanocellulose aerogels and summarizes the methods of preparing them from biomass raw materials. In addition, aiming at the inherent defects of nanocellulose aerogels, this review focuses on the methods used to improve their mechanical properties, flame retardancy, and hydrophobicity in order to prepare high-performance thermal insulation materials in line with the concept of sustainable development, thereby promoting energy conservation, rational use, and expanding the application of nanocellulose aerogels.

Ice protection techniques have attracted significant interest, notably in aerospace and wind energy applications. However, the current solutions are mostly costly and inconvenient due to energy-intensive and environmental concerns. One of the appealing strategies is the use of passive icephobicity, in the form of coatings, which is induced by means of several material strategies, such as hydrophobicity, surface texturing, surface elasticity, and the physical infusion of ice-depressing liquids, etc. In this review, surface-roughness-related icephobicity is critically discussed to understand the challenges and the role of roughness, especially on superhydrophobic surfaces. Surface roughness as an intrinsic, independent surface property for anti-icing and de-icing performance is also debated, and their interdependence is explained using the related physical mechanisms and thermodynamics of ice nucleation. Furthermore, the role of surface roughness in the case of elastomeric or low-modulus polymeric coatings, which typically instigate an easy release of ice, is examined. In addition to material-centric approaches, the influence of surface roughness in de-icing evaluation is also explored, and a comparative assessment is conducted to understand the testing sensitivity to various surface characteristics. This review exemplifies that surface roughness plays a crucial role in incorporating and maintaining icephobic performance and is intrinsically interlinked with other surface-induced icephobicity strategies, including superhydrophobicity and elastomeric surfaces. Furthermore, the de-icing evaluation methods also appear to be roughness sensitive in a certain range, indicating a dominant role of mechanically interlocked ice.

Natural bio-material surface with hydrophobic behavior (aqueous droplet to roll off from its surface) has inspired researchers to design sustainable artificial coatings with hydrophobic or superhydrophobic behavior. The developed hydrophobic or superhydrophobic artificial coatings are highly useful in various applications such as water remediation, oil/water separation, self-cleaning, anti-fouling, anti-corrosion and also in medical fields including anti-viral, anti-bacterial efficacy. In recent years, among various coating materials, bio-based materials derived from plants and animals (cellulose, lignin, sugarcane bagasse, peanut shell, rice husk, egg cell etc.) are applied on various surfaces in order to develop fluorine free hydrophobic coatings with longer durability by lowering the surface energy and increasing the surface roughness. This review summarized recent developments in hydrophobic/superhydrophobic coating fabrication methods, properties and applications with the use of different bio-based materials and their combinations. In addition, basic mechanisms behind the coating fabrication process and their durability under different environmental conditions are also discussed. Moreover, prospects and limitations of bio-based coatings in practical applications have been highlighted.

Due to their broad-spectrum activity against Gram-negative and Gram-positive bacteria, natural antimicrobial peptides (AMPs) and their synthetic analogs have emerged as prospective therapies for treating illnesses brought on by multi-drug resistant pathogens. To overcome the limitations of AMPs, such as protease degradation, oligo-N-substituted glycines (peptoids) are a promising alternative. Despite having the same backbone atom sequence as natural peptides, peptoid structures are more stable because, unlike AMP, their functional side chains are attached to the backbone nitrogen (N)-atom rather than the alpha carbon atom. As a result, peptoid structures are less susceptible to proteolysis and enzymatic degradation. The advantages of AMPs, such as hydrophobicity, cationic character, and amphipathicity, are mimicked by peptoids. Furthermore, structure-activity relationship studies (SAR) have shown that tuning the structure of peptoids is a crucial step in developing effective antimicrobials.

Biochar is a product of the thermal treatment of biomass, and it can be used for enhancing soil health and productivity, soil carbon sequestration, absorbance of pollutants from water and soil, and promoting environmental sustainability. Extensive research has been done on applications of biochar to enhance the Water Holding Capacity (WHC) of biochar amended soil. However, a comprehensive road map of biochar optimised for enhanced WHC, and reduced hydrophobicity is not yet published. This review is the first to provide not only quantitative information on the impacts of biochar properties in WHC and hydrophobicity, but also a road map to optimise biochar for enhanced WHC when applied as a soil amendment. The review shows that straw or grass-derived biochar (at 500-600 °C) increases the WHC of soil if applied at 1 to 3 % in the soil. It is clear from the review that soil of varying texture requires different particle sizes of biochar to enhance the WHC and reduce hydrophobicity. Furthermore, the review concludes that ageing biochar for at least a year with enhanced oxidation is recommended for improving the WHC and reducing hydrophobicity compared to using biochar immediately after production. Additionally, while producing biochar a residence time of 1 to 2 h is recommended to reduce the biochar\'s hydrophobicity. Finally, a road map for optimising biochar is presented as a schematic that can be a resource for making decisions during biochar production for soil amendment.

Sulphidisation, an electrochemical process for conversion of a non-sulphide, oxide or oxidised sulphide, to a sulphide surface that facilitates efficient adsorption of thiol collectors to impart hydrophobicity, offers a way to improve the enrichment of oxide and oxidised sulphide ores by flotation. Although it has shown great potential, it has equally proved to suffer from drawbacks such as low efficiency, difficulty to sulphidise minerals that are prone to surface oxidation and the chemistry at play remains insufficiently understood. These drawbacks hinder the full potential of the sulphidisation process as a remediation strategy for flotation of oxide and oxidised sulphide ores. A holistic understanding of the process is crucial in identification of the underpinning phenomena that render the process inefficient and will be a stepping stone in the quest to modify it for an improved efficiency. Therefore, this paper seeks to review the sulphidisation reactions and products at the mineral-solution interfaces of oxide and oxidised sulphide minerals. The influence and implications of the sulphidisation conditions on adsorption of thiol collectors on mineral surfaces to impart hydrophobicity necessary for flotation are also highlighted. Finally, it makes recommendations on how to circumvent the drawbacks and provides guidelines for future research and industrial application.

An aggressive impact of the formed ice on the surface of man-made objects can ultimately lead to serious consequences in their work. When icing occurs, the quality and characteristics of equipment, instruments, and building structures deteriorate, which affects the durability of their use. Delays in the adoption of measures against icing endanger the safety of air travel and road traffic. Various methods have been developed to combat de-icing, such as mechanical de-icing, the use of salts, the application of a hydrophobic coating to the surfaces, ultrasonic treatment and electric heating. In this review, we summarize the recent advances in the field of anti-icing and analyze the role of various additives and their operating mechanisms.

Starch has received research focus due to its low cost, excellent film-forming ability, bio-compatibility, extensive sources, renewability and biodegradability. However, native starch with relatively strong hydrophilicity greatly limits its application in industries. Therefore, in this paper, the recent research advances in chemical modifications of starch for hydrophobicity, e.g., esterification, etherification, crosslinking, grafting and condensing reaction etc., were discussed. The changes of hydrophobicity and other properties due to chemical modifications were described, as well. Different applications of modified starch with better hydrophobicity, i.e., packaging industries, Pickering emulsion and pharmaceutical, are presented, too. Finally, the future research and prospects on chemical modifications of starch for hydrophobicity and their applications are proposed.

BACKGROUND: Treatment of neurological diseases using systemic and non-surgical techniques presents a significant challenge in medicine. This challenge is chiefly associated with the condensation and coherence of the brain tissue.
METHODS: The coherence structure of the brain is due to the presence of the blood-brain barrier (BBB), which consists of a continuous layer of capillary endothelial cells. The BBB prevents most drugs from entering the brain tissue and is highly selective, permitting only metabolic substances and nutrients to pass through.
RESULTS: Although this challenge has caused difficulties for the treatment of neurological diseases, it has opened up a broad research area in the field of drug delivery. Through the utilization of nanoparticles (NPs), nanotechnology can provide the ideal condition for passing through the BBB.
CONCLUSIONS: NPs with suitable dimensions and optimum hydrophobicity and charge, as well as appropriate functionalization, can accumulate in the brain. Furthermore, NPs can facilitate the targeted delivery of therapeutics into the brain areas involved in Alzheimer\'s disease, Parkinson\'s disease, stroke, glioma, migraine, and other neurological disorders. This review describes these methods of actively targeting specific areas of the brain.