Remediation

补救
  • 文章类型: Journal Article
    背景:在荷兰,2~10%的住院医师过早终止培训。很少,终止培训是由解雇。顺便说一句,居民可能不同意,对计划主任的这些决定提出异议和质疑。解雇居民总是一个艰难的决定,最常见的是之后,反复评估,以及所得评估数据的三角测量和一个或多个补救尝试。然而,培训计划之间解雇的根本原因以及补救和解雇政策可能有所不同。然而,这种差异可能会影响补救成功的机会,解雇和随后的居民上诉的机会。
    方法:在10年的上诉中,我们共纳入了来自两组(社区和医院专科)的70名居民。随后,我们就可能与调解委员会关于居民解雇的决定结果相关的因素对这些群体进行了比较。我们在此专注于应用的补救策略,以及报告解雇居民的原因。
    结果:在两组中,最据称解雇居民的原因是缺乏培训能力,>97%。这分别与社区实践中的专业素养和医院专业中的医学专业素养不足有关。一个不太常见的原因是危及患者护理,<26%。然而,这些居民都没有被指控危害他人,实际上危害了病人的健康,可能是由于他们主管的警惕。两组的补救策略各不相同,与以社区为基础的实践相比,以医院为基础的专业更喜欢正式的补救计划。每个能力都有多种补救策略(医学专业知识,敬业精神,通信,管理)在这些法律案件中被应用和描述。
    结论:与以医院为基础的专业相比,以社区为基础的实践中居民的上诉成功的可能性要小得多。这些差异背后的假设的解释因素包括基于社区的实践,更突出地关注专业的纵向评估,定期举行季度进度会议,对缺陷的精确记录,与解雇医院专科的时间相反,解雇时间的自由裁量权只有在预定的正式总结性评估会议期间才能正式进行。
    BACKGROUND: In the Netherlands, 2 to 10% of the residents terminate training prematurely. Infrequently, termination of training is by dismissal. Incidentally, residents may disagree, dispute and challenge these decisions from the programme directors. Resident dismissal is always a difficult decision, most commonly made after, repeated assessments, and triangulation of the resulting assessment data and one or more remediation attempts. Nevertheless, the underlying reasons for dismissal and the policies for remediation and dismissal may differ between training programmes. Such differences may however impact the chance of remediation success, the chance of dismissal and subsequent residents\' appeals.
    METHODS: We included a total of 70 residents from two groups (community-based and hospital-based specialties) during 10 years of appeals. Subsequently, we compared these groups on factors potentially associated with the outcome of the conciliation board decision regarding the residents\' dismissal. We focused herein on remediation strategies applied, and reasons reported to dismiss residents.
    RESULTS: In both groups, the most alleged reason to dismiss residents was lack of trainability, > 97%. This was related to deficiencies in professionalism in community-based practice and medical expertise in hospital-based specialties respectively. A reason less frequently mentioned was endangerment of patient care, < 26%. However, none of these residents accused of endangerment, actually jeopardized the patients\' health, probably due to the vigilance of their supervisors. Remediation strategies varied between the two groups, whereas hospital-based specialties preferred formal remediation plans in contrast to community-based practice. A multitude of remediation strategies per competency (medical expertise, professionalism, communication, management) were applied and described in these law cases.
    CONCLUSIONS: Residents\' appeals in community-based practice were significantly less likely to succeed compared to hospital-based specialties. Hypothesised explanatory factors underlying these differences include community-based practices\' more prominent attention to the longitudinal assessment of professionalism, the presence of regular quarterly progress meetings, precise documentation of deficiencies, and discretion over the timing of dismissal in contrast to dismissal in the hospital-based specialties which is only formally possible during scheduled formal summative assessment meetings.
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  • 文章类型: Journal Article
    人口增长的压力导致需要保护,填海,恢复受损土地的生产力,有益的健康用途。这项调查的目的是1)将能源部(DOE)橡树岭保护区(ORR)的土地覆盖与周边地区进行比较,2)选择评价ORR生态资源保护的指标,3)开发和实施一种方法,使用国家土地覆盖数据库(NLCD)将ORR指标的数量与区域进行比较。数据表明,ORR的森林占比较高(落叶,针叶树,混合)比ORR周围的10公里和30公里区域,表明正在履行保护生态和环境的义务。研究结果还表明,ORR的内部森林比30公里缓冲区的内部森林更分散,建议DOE和其他土地的管理者在开发土地或规划道路时需要考虑完整的内部森林的重要性。该研究描述了特定生态参数的基础,例如内部森林,在规划和执行修复时需要考虑的重要因素。restoration,和其他管理行动。
    Pressure from expanding populations has resulted in a need for protection, reclamation, and restoration of damaged land to productive, beneficial health uses. The objective of this investigation was to 1) compare land cover on the Department of Energy (DOE) Oak Ridge Reservation (ORR) with the surrounding region, 2) select an indicator to evaluate ORR\'s protection of ecological resources, and 3) develop and implement a method to compare the amount of the indicator on ORR with the regions using National Land Cover Database (NLCD). Data demonstrated that ORR has a higher % of forests (deciduous, coniferous, mixed) than the 10 km and 30 km areas surrounding ORR, suggesting that obligations are being met to protect the ecology and environment. The findings also indicate that the interior forest at ORR is fragmented more than is the interior forest in the 30 km buffer zone, suggesting a need for DOE and managers of other lands to take into consideration the importance of intact interior forest when developing land or planning roads. The study describes the basis for specific ecological parameters such as interior forest that are important to consider when planning and executing remediation, restoration, and other management actions.
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  • 文章类型: Journal Article
    顽固的地下水污染是全球危险废物场所的常见问题。尽管在许多地点进行了数十年的补救工作,但地下水污染仍然存在,因为在低电导率区域内吸附或溶解的污染物可能会扩散到高电导率区域,因此成为流动地下水的持续污染源。对由于反向扩散而导致的羽流持久性修复的现有文献进行了综述,并选择了四个地点作为案例研究。现场的修复包括泵和治疗,强化生物修复,和热处理。我们的审查强调,已经对相对较少的站点进行了足够详细的研究,以全面评估反扩散的补救;但是,根据审查,可以得出三个一般性结论。首先,如果没有足够的数据来区分导致污染物反弹和羽流持久性的多个因素,很难评估反向扩散的重要性。第二,高分辨率垂直样品对于反向扩散评估无疑是有价值的,但通常缺乏后处理评估。第三,从反向扩散源完全去除污染物质量可能并不总是可能的。尽管如此,部分污染物质量去除可能会有潜在的好处,类似于主要DNAPL源区的部分质量去除。
    Recalcitrant groundwater contamination is a common problem at hazardous waste sites worldwide. Groundwater contamination persists despite decades of remediation efforts at many sites because contaminants sorbed or dissolved within low-conductivity zones can back diffuse into high-conductivity zones, and therefore act as a continuing source of contamination to flowing groundwater. A review of the available literature on remediation of plume persistence due to back diffusion was conducted, and four sites were selected as case studies. Remediation at the sites included pump and treat, enhanced bioremediation, and thermal treatment. Our review highlights that a relatively small number of sites have been studied in sufficient detail to fully evaluate remediation of back diffusion; however, three general conclusions can be made based on the review. First, it is difficult to assess the significance of back diffusion without sufficient data to distinguish between multiple factors contributing to contaminant rebound and plume persistence. Second, high-resolution vertical samples are decidedly valuable for back diffusion assessment but are generally lacking in post-treatment assessments. Third, complete contaminant mass removal from back diffusion sources may not always be possible. Partial contaminant mass removal may nonetheless have potential benefits, similar to partial mass removal from primary DNAPL source zones.
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  • 文章类型: Journal Article
    风险评估为确定被天然放射性物质污染的场地或核遗留场地所需的补救行动的必要性和程度提供了关键投入。风险评估建模方法的选择,并且相应的工具集应适合评估上下文,考虑到复杂性,并明确与决策过程中要解决的问题相关。原子能机构第二辐射影响评估建模和数据方案第1工作组的目标之一是对选定地点的个案研究进行模型间比较,特别是,以帮助说明不同模型和方法作为决策过程输入的适用性。这个相互比较练习,其中包括对污染场地管理策略的潜在后果的分析,已经在两个地点进行了表演:Zapadnoe的前铀工厂尾矿设施,乌克兰,还有Tessenderlo的磷酸盐处理设施,比利时。几种模型和计算机代码已用于其中一种或两种情况:AMBER,GoldSim,NORM和Legacy网站评估,初步补救目标(PRG)-剂量依从性浓度计算器,和清洗-场外。评估探讨了使用不同评估框架和假设的影响,以及替代的建模工具,模型输出,并作为补救战略相应决策的输入。本文回顾了使用这些不同模型进行评估的结果的异同。它讨论了不同的方法如何相互补充,以帮助建立对支持决策的证据基础的信心。它还讨论了在给定的评估背景下不同建模方法的适当性。特别是在其中一个案例研究(Tessenderlo案例研究)中,修复策略基本上是由重金属污染场地驱动的,如镉。这对选择评估放射性风险并平衡其相对重要性与其他影响的最适当方法和情景具有重大影响。风险评估的整体方法的发展是,因此,突出显示。
    Risk assessment provides a key input for determining the need for and extent of remedial actions necessary for sites contaminated with naturally occurring radioactive material or nuclear legacy sites. The choice of a modelling approach for risk assessment, and the corresponding toolsets should fit the assessment context, taking account of the complexity, and be clearly related to the questions to be addressed in the decision-making process. One of the objectives of Working Group 1 of IAEA Modelling and Data for Radiological Impact Assessments II (MODARIA II) Programme is to perform intermodel comparisons for case studies of selected sites, in particular, to help illustrate the applicability of different models and approaches as inputs to decision-making processes. This intercomparison exercise, which included the analysis of potential consequences on the management strategy for contaminated sites, has been performed for two sites: The former uranium mill tailings facility at Zapadnoe, Ukraine, and the phosphate processing facility at Tessenderlo, Belgium. Several models and computer codes have been used for one or both of these cases: AMBER, GoldSim, NORM And LegacY Site Assessment, Preliminary Remediation Goals (PRG)-dose compliance concentration calculator, and RESRAD-OFFSITE. The assessments explore the implications of using differing assessment frameworks and assumptions, as well as alternative modelling tools, on model outputs and as input for corresponding decisions on remediation strategy. This paper reviews both similarities and differences in the results of assessments performed using these different models. It discusses how different approaches can complement one another to help build confidence in the evidence base underpinning decisions. It also discusses the appropriateness of the different modelling approaches in a given assessment context. In one of the case studies in particular (Tessenderlo case study), the remediation strategy is essentially driven by the contamination of the site with heavy metals, such as cadmium. This has significant consequences on the choice of the most adequate approaches and scenarios for assessing the radiological risk and balancing their relative importance with other impacts. The development of a holistic approach to risk assessment is, therefore, highlighted.
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  • 文章类型: Journal Article
    国际社会在达成共识方面取得了长足的进步,即自然发生的放射性材料和核遗留场址的补救和管理将受益于使用基于风险的决策框架。这样的框架应理想地整合风险评估和决策。本文提出的框架专门针对更广泛的社会经济和环境背景下的需求和期望,以及狭隘的人类健康环境。该框架作为国际原子能机构第二个辐射影响评估模型和数据计划的一部分进行了演示。三个案例研究,已经使用或可能使用这种综合方法,用于说明。第一个问题涉及萨斯喀彻温省北部比弗洛奇湖铀矿开采活动的补救,加拿大,让利益相关者(也称为“利益相关方”)参与进一步选择的决策过程。第二个案例研究表明,决策分析如何能够支持在兹罗夫斯基vrh选择铀矿石加工的废物处理的最佳选择,斯洛文尼亚,考虑到洪水时潜在的滑坡和废物在整个邻近山谷中的迁移。第三个案例研究介绍了Tessenderlo地区Kepkensberg污泥盆地的放射性安全评估过程和结果,比利时在处理附近温特贝克河修复材料之前和之后。它说明了此类评估如何与决策分析相结合,以支持与未来批准废物处置方案有关的监管决策。结果表明,正式的利益相关者参与决策分析为客观,健壮,和透明的决策,不仅适用于辐射保护区,而且适用于健康和环境影响受到关注的其他地区。还对今后的工作提出了一些建议。
    The international community has come a long way in developing a consensus that the remediation and management of naturally occurring radioactive materials and nuclear legacy sites will benefit from the use of the framework for risk-informed decision-making. Such a framework should ideally integrate risk assessment and decision-making. The framework presented in this paper specifically addresses the needs and expectations in the wider socio-economic and environmental context, as well as a narrower human health context. The framework was demonstrated as part of the International Atomic Energy Agency\'s second Modelling and Data for Radiological Impact Assessments Programme. Three case studies, which have used or could use this integrative approach, are used for illustration. The first concerns remediation from uranium mining activities at Beaverlodge Lake in northern Saskatchewan, Canada, engaging stakeholders (also called \'interested parties\') in the decision-making process on further options. The second case study suggests how decision analysis could support the selection of the best option for waste disposal for uranium ore processing at Žirovski vrh, Slovenia, taking into account a potential landslide and migration of waste throughout the adjacent valley in the event of flooding. The third case study presents the process and results of radiological safety assessment of the Kepkensberg sludge basin in Tessenderlo area, Belgium both before and after the disposal of material from remediation of the nearby Winterbeek River. It illustrates how such assessments could interface with decision analysis for the purpose of supporting the regulatory decisions related to future approval of a waste disposal option. Results show that formal stakeholder engagement in decision analysis provides a strong contribution to objective, robust, and transparent decision-making not only for radiation protection area but also in others where health and environmental impacts are of concern. A number of recommendations for future work have also been made.
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  • 文章类型: Journal Article
    尽管在30年前洛特河流域上游的冶金活动结束后进行了有效的补救工作,来自吉伦特下游河口的野生牡蛎中积累的镉(Cd)水平仍然超过了当今允许的人类消费限值(5mg/kg,d.w.)。这项工作的主要目标是量化沉积物作为Cd的长期河口内源或汇的作用,以及这种污染物向河口的运输,以高度浑浊的吉伦特河口为例。这项工作在1990年至2020年之间对悬浮颗粒物([公式:见正文]和颗粒Cd([公式:见正文])的年度净通量的原始估算表明,排放到海洋中的Cd的80%处于溶解形式(Cdd)。[公式:见正文]的值与[公式:见正文]的值成正比变化,范围在0.1至1.4t/y之间,在过去的30年里,十年平均水平从0.8吨/年下降到0.6吨/年。十年总通量(CdpCdd)和净通量之间的差异表明,Cd已有效地存储在河口沉积物中。1990年代,这种Cd的存储量约为43、22和13吨,2000年代和2010年代,分别。然而,在低总通量的年份,河口沉积物作为额外的,生物可利用/溶解的Cd进入水柱的次级来源,可能与河口野生牡蛎中Cd浓度高的持续观察有关。除了沿河口盐度和浊度梯度的Cdp的天然溶解度外,底部沉积物颗粒的自然和人为再动员进一步有助于其从颗粒相动员,以及其他许多无机/有机污染物。这项工作中提出的质量平衡可以支持新的沉积物管理政策,这可能对河口生态系统更有利。
    Despite the effective remediation efforts following the end of the metallurgic activity thirty years ago upstream the Lot River watershed, the levels of cadmium (Cd) accumulated in wild oysters from the downstream Gironde Estuary still exceed nowadays the admissible human consumption limit (5 mg/kg, d.w.). The main goal of this work is to quantify the role of sediments as long-term intra-estuarine sources or sinks of Cd and the transport of this contaminant towards the estuary mouth taking as case study the example of the highly turbid Gironde Estuary. The original estimation for the annual net fluxes of the suspended particulate matter ( [Formula: see text] and particulate Cd ( [Formula: see text] ) presented in this work between 1990 and 2020 indicates that 80% of the Cd discharged into the ocean is in dissolved form (Cdd). The values of [Formula: see text] vary proportionally to those of [Formula: see text] and ranged between 0.1 and 1.4 t/y, with a ten-year average decreasing from 0.8 to 0.6 t/y for the past 30 years. The differences between ten-year total (Cdp + Cdd) gross and net fluxes show that Cd has effectively been stored in estuarine sediments. This Cd storage was of about 43, 22 and 13 t for the 1990s, 2000s and 2010s, respectively. However, during years of low gross fluxes, estuarine sediments act as additional, secondary sources of bio-available/dissolved Cd into the water column, potentially relating to the continued observations of high Cd concentrations in wild oysters at the estuary mouth. In addition to the natural solubility of Cdp along the salinity and turbidity gradients of the estuary, natural and anthropogenic remobilization of bottom sediment particles further contribute to its mobilization from the particle phase, along with other numerous inorganic/organic pollutants. The mass balances presented in this work could support a new sediment management policy potentially more beneficial to the estuarine ecosystem.
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  • 文章类型: Journal Article
    To better protect public health from third-hand exposure to methamphetamine, it is important to understand the techniques and current practices used within the methamphetamine testing and decontamination industry in Australia. A survey was conducted focusing on business owners that advertised testing and/or remediation services online. They were also invited to participate in a follow-up phone interview upon completion. The survey demonstrated that testing and decontamination methods were highly varied, which was expected for an industry with no regulation. Most companies offered methamphetamine testing and remediation which could be a conflict of interest. Participants also shared personal experiences, including the conduct of other industry members, demonstrating both poor practice and/or the competitive nature of the business. Participating business owners were following Australian guidelines to the best of their ability, and many are advocates for regulation to be implemented within the industry. This would address the inconsistencies between companies and establish trust for industry members and the public. It would also provide significant public health protection, which is currently lacking. A more consistent approach to the testing and remediation of methamphetamine contamination, aided by regulation, would address the significant risk to public health caused by third-hand exposure to methamphetamine.
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  • 文章类型: Journal Article
    应用农药的不确定命运和运输途径是孟加拉国食品安全性和质量评估的主要隐患。由于监管体系薄弱,对施用农药的风险评估和不确定性探索不足,农民无知,集约化农业实践,缺乏关于植物检疫管理不善的农田上农药处理不当的可用研究数据。然而,越来越多的证据表明,农药在普通食品中的流行是由于作物对农药的吸收和对作物保护实践的不当管理。此外,人们对孟加拉国普通食品中农药的生物转化知之甚少。一些研究报告说,孟加拉国食品中的农药浓度高于欧盟准则所允许的浓度。然而,到目前为止,没有对当前研究结果和关于命运的知识差距进行批判性讨论的系统回顾,不确定性,并公布了孟加拉国食品中农药的健康风险。因此,这篇综述总结了有关食品中农药残留的现有文献的发现,并指出了监管体系和风险评估方面的弱点,以突出与全球食品政策相比,孟加拉国食品安全面临的严峻挑战.此外,还讨论了残留农药的可持续管理策略。
    The uncertain fate and transport pathways of applied pesticides are the key hidden threats with respect to the safety and quality evaluation of foodstuffs in Bangladesh. The risk assessment of and uncertainty about applied pesticides are poorly explored due to weak regulatory systems, farmer ignorance, intensive agricultural practices, and lack of available research data on improper handling of pesticides on farming lands with poor phytosanitary management. However, increasing evidence suggests that the prevalence of pesticides in common foodstuffs is due to their uptake by crops and improper management of crop protection practices. Besides, the biotransformation of pesticides in common Bangladeshi food products is poorly understood. Several studies have reported higher concentrations of pesticides than allowed by European Union guidelines in Bangladeshi foodstuffs. However, to date, no systematic review with critical discussion on current research findings and knowledge gaps concerning fate, uncertainty, and health risks of pesticides in the foodstuffs of Bangladesh is published. Therefore, this review summarizes the findings of existing literature on pesticide residue in foodstuffs and points out the weaknesses in the regulatory system and risk assessments for highlighting the critical challenges to food safety in Bangladesh as compared to global food policy. In addition, strategies for the sustainable management of residual pesticides are also discussed.
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  • 文章类型: Journal Article
    通过直接推进式气动压裂结合水力输送由研磨铁组成的修复悬浮液,在中试规模上处理了一个主要被部分存在于不饱和区自由相中的四氯乙烯(PCE)污染的非均质地质的低渗透性地区,在瓜尔胶溶液中硫化纳米零价铁和沙子。之后,将乳清溶液注入裂缝作为细菌的碳源。处理不饱和区和饱和区。对地下水的长期监测表明,注射后几个月,PCE和三氯乙烯的非生物还原是主要的修复过程。开发了一个复杂的微生物联盟,能够有效地,长期氯化乙烯(ClE)脱氯。该财团主要由Dehalococcoides组成,也由其他能够部分脱氯ClE的厌氧细菌菌株组成,包括硫酸盐还原细菌;Geobacter和脱硫杆菌。注入后2.5年内,地下水中的平均氯数从3.65降至1.38,而ClE的平均浓度从13.5增加到31.5mgL-1,这是因为处理引起的ClE向地下水的传质显着加速。修复过程充分活跃了2.5年。
    A low-permeability locality with heterogeneous geology contaminated primarily by tetrachloroethene (PCE) present partially in the free phase in the unsaturated zone was treated on a pilot scale via direct push pneumatic fracturing combined with the hydraulic delivery of a remediation suspension consisting of milled iron, sulphidated nanosized zerovalent iron and sand in guar gum solution. Afterwards, a whey solution was injected into the fractures as a carbon source for bacteria. The unsaturated and saturated zones were treated. Long-term monitoring of the groundwater revealed that the abiotic reduction of PCE and trichloroethene was the dominant remediation processes for several months after the injections. A complex microbial consortium was developed that was capable of effective, long-term chlorinated ethenes (ClE) dechlorination. The consortium consisted mainly of Dehalococcoides but also of other anaerobic bacterial strains capable of partial dechlorination of ClE, including the sulphate-reducing bacteria; Geobacter and Desulfitobacterium. The average chlorine number in the groundwater decreased from 3.65 to 1.38 within 2.5 years after the injections, while the average ClE concentration increased from 13.5 to 31.5 mgL-1 because of the substantial acceleration of the ClE mass-transfer to the groundwater caused by the treatment. The remediation processes remained fully active for 2.5 years.
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  • 文章类型: Journal Article
    Many nations are faced with the need to remediate large contaminated sites following World War II, the Cold War, and abandoned industrial sites, and to return them to productive land uses. In the United States, the Department of Energy (DOE) has the largest cleanup challenge, and its Hanford Site in the state of Washington has the most extensive and most expensive cleanup task. Ideally, the risk to ecological resources on remediation sites is evaluated before, during, and after remediation, and the risk from, or damage to, ecological resources from contaminants should be lower following remediation. In this paper, we report the risk to ecological resources before, during, and as a consequence of remediation on contaminated units requiring cleanup, and then examine the causes for changes in risk by evaluating 56 cleanup evaluation units (EUs) at the Hanford Site. In this case, remediation includes a restoration phase. In general, the risk to ecological and eco-cultural resources is currently not discernible or low at most contaminated units, increases during remediation, and decreases thereafter. Remediation often causes physical disruption to ecosystems as it reduces the risk from exposure to contaminants. Most new remediation projects at the Hanford Site include ecological restoration. Ecological restoration results in the potential for the presence of higher quality resources after remediation than currently exists on these contaminated lands and facilities. Although counter-intuitive, our evaluation of the risk to ecological resources following remediation indicated that a significant percentage of units (61%) will be at increased risk in the post-remediation period. This increased risk is due to DOE\'s successful remediation and restoration that results in a higher percent of native vegetation and higher ecological value on the sites in the post-remediation period than before. These newly-created resources can then be at risk from post-remediation activities. Risks to these new higher quality resources include the potential for spread of invasive species and of noxious grasses used in previous cleanup actions, disruption of ecosystems (including those with state or federally listed species and unique ecosystems), compaction of soil, use of pesticides to control invasive species, and the eventual need for continued monitoring activities. Thus, by greatly improving the existing habitat and health of eco-receptors, and maintaining habitat corridors between high quality habitats, the ecological resources in the post-remediated units are at risk unless care is taken to protect them. Many of the negative effects of both remediation and future monitoring (or other future land uses) can be avoided by planning and management early in the remediation process. We suggest DOE and other agencies convene a panel of managers, remediation scientists, regulators, environmental and ecological scientists, Native Americans, economists, and the public to develop a generic list of performance metrics for the restoration phase of remediation, including evaluation of success, which could be applied across the DOE complex.
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