Catalyzed reduction processes have been recognized as important and supplementary technologies for water treatment, with the specific aims of resource recovery, enhancement of bio/chemical-treatability of persistent organic pollutants, and safe handling of oxygenate ions. Palladium (Pd) has been widely used as a catalyst/electrocatalyst in these reduction processes. However, due to the limited reserves and high cost of Pd, it is essential to gain a better understanding of the Pd-catalyzed decontamination process to design affordable and sustainable Pd catalysts. This review provides a systematic summary of recent advances in understanding Pd-catalyzed reductive decontamination processes and designing Pd-based nanocatalysts for the reductive treatment of water-borne pollutants, with special focus on the interactions and transformation mechanisms of pollutant molecules on Pd catalysts at the atomic scale. The discussion begins by examining the adsorption of pollutants onto Pd sites from a thermodynamic viewpoint. This is followed by an explanation of the molecular-level reaction mechanism, demonstrating how electron-donors participate in the reductive transformation of pollutants. Next, the influence of the Pd reactive site structure on catalytic performance is explored. Additionally, the process of Pd-catalyzed reduction in facilitating the oxidation of pollutants is briefly discussed. The longevity of Pd catalysts, a crucial factor in determining their practicality, is also examined. Finally, we argue for increased attention to mechanism study, as well as precise construction of Pd sites under batch synthesis conditions, and the use of Pd-based catalysts/electrocatalysts in the treatment of concentrated pollutants to facilitate resource recovery.

Volatile organic compounds (VOCs) pose a serious threat to human health and the ecological environment. Thermal catalytic oxidation based on cerium dioxide based (CeO2-based) catalysts is widely used in the degradation of toluene. However, new problems and challenges such as how to reduce the energy consumption during catalytic oxidation, improve the anti-poisoning performance of catalysts, and enhance the multi-species synergistic catalytic ability of catalysts continue to emerge. On this basis, we systematically summarize the current status of research progress on the thermocatalytic oxidation of toluene based on CeO2-based catalysts. Firstly, we summarized the rules on how to improve the catalytic performance and anti-poisoning performance of CeO2-based catalysts; Secondly, we discussed the effect of light reaction conditions on the thermal coupled catalytic oxidation of toluene; In addition to this, we explored the current status of synergistic multi-pollutant degradation, mainly of toluene; Finally, we summarized the mechanism of catalytic oxidation of toluene by combining theoretical simulation calculations, in-situ infrared analyses, and other means. We present the promising applications of CeO2-based catalysts in the catalytic oxidation of toluene, and hope that these summaries will provide an important reference for the catalytic treatment of VOCs.

The thermocatalytic conversion of carbon dioxide (CO2) into high value-added chemicals provides a strategy to address the environmental problems caused by excessive carbon emissions and the sustainable production of chemicals. Significant progress has been made in the CO2 hydrogenation to long chain α-olefins, but controlling C-O activation and C-C coupling remains a great challenge. This review focuses on the recent advances in catalyst design concepts for the synthesis of long chain α-olefins from CO2 hydrogenation. We have systematically summarized and analyzed the ingenious design of catalysts, reaction mechanisms, the interaction between active sites and supports, structure-activity relationship, influence of reaction process parameters on catalyst performance, and catalyst stability, as well as the regeneration methods. Meanwhile, the challenges in the development of the long chain α-olefins synthesis from CO2 hydrogenation are proposed, and the future development opportunities are prospected. The aim of this review is to provide a comprehensive perspective on long chain α-olefins synthesis from CO2 hydrogenation to inspire the invention of novel catalysts and accelerate the development of this process.

Mn-based catalysts have attracted significant attention in the field of catalytic research, particularly in NOx catalytic reductions and CO catalytic oxidation, owing to their good catalytic activity at low temperatures. In this review, we summarize the recent progress of Mn-based catalysts for the removal of NOx and CO. The effects of crystallinity, valence states, morphology, and active component dispersion on the catalytic performance of Mn-based catalysts are thoroughly reviewed. This review delves into the reaction mechanisms of Mn-based catalysts for NOx reduction, CO oxidation, and the simultaneous removal of NOx and CO. Finally, according to the catalytic performance of Mn-based catalysts and the challenges faced, a possible perspective and direction for Mn-based catalysts for abating NOx and CO is proposed. And we expect that this review can serve as a reference for the catalytic treatment of NOx and CO in future studies and applications.

This review provides an analysis of experimental results on the study of alkaline heterogeneous deacetylation of chitin obtained by the authors and also published in the literature. A detailed analysis of the reaction kinetics was carried out considering the influence of numerous factors: reaction reversibility, crystallinity and porosity of chitin, changes in chitin morphology during washing, alkali concentration, diffusion of hydroxide ions, and hydration of reacting particles. A mechanism for the chitin deacetylation reaction is proposed, taking into account its kinetic features in which the decisive role is assigned to the effects of hydration. It has been shown that the rate of chitin deacetylation increases with a decrease in the degree of hydration of hydroxide ions in a concentrated alkali solution. When the alkali concentration is less than the limit of complete hydration, the reaction practically does not occur. Hypotheses have been put forward to explain the decrease in the rate of the reaction in the second flat portion of the kinetic curve. The first hypothesis is the formation of \"free\" water, leading to the hydration of chitin molecules and a decrease in the reaction rate. The second hypothesis postulates the formation of a stable amide anion of chitosan, which prevents the nucleophilic attack of the chitin macromolecule by hydroxide ions.

Hydrothermal carbonization has gained attention in converting wet organic solid waste into hydrochar with many applications such as solid fuel, energy storage material precursor, fertilizer or soil conditioner. Recently, various catalysts such as organic and inorganic catalysts are employed to guide the properties of the hydrochar. This review presents a summarize and a critical discussion on types of catalysts, process parameters and catalytic mechanisms. The catalytic impact of carboxylic acids is related to their acidity level and the number of carboxylic groups. The catalysis level with strong mineral acids is likely related to the number of hydronium ions liberated from their hydrolysis. The impact of inorganic salts is determined by the Lewis acidity of the cation. The metallic ions in metallic salts may incorporate into the hydrochar and increase the ash of the hydrochar. The selection of catalysts for various applications of hydrochars and the environmental and the techno-economic aspects of the process are also presented. Although some catalysts might enhance the characteristics of hydrochar for various applications, these catalysts may also result in considerable carbon loss, particularly in the case of organic acid catalysts, which may potentially ruin the overall advantage of the process. Overall, depending on the expected application of the hydrochar, the type of catalyst and the amount of catalyst loading requires careful consideration. Some recommendations are made for future investigations to improve laboratory-scale process comprehension and understanding of pathways as well as to encourage widespread industrial adoption.

Water-gas shift (WGS) reaction offers a dominating path to hydrogen generation from fossil fuel, in which heterogeneous metal catalysts play a crucial part in this course. This review highlights and summarizes recent developments on theoretical calculations of metal catalysts developed to date, including surface structure (e. g., monometallic and polymetallic systems) and interface structure (e. g., supported catalysts and metal oxide composites), with special emphasis on the characteristics of crystal-face effect, alloying strategy, and metal-support interaction. A systematic summarization on reaction mechanism was performed, including redox mechanism, associative mechanism as well as hybrid mechanism; the development on chemical kinetics (e. g., molecular dynamics, kinetic Monte Carlo and microkinetic simulation) was then introduced. At the end, challenges associated with theoretical calculations on metal catalysts toward WGS reaction are discussed and some perspectives on the future advance of this field are provided.

As the main contributor of the formation of particulate matter as well as ozone, volatile organic compounds (VOCs) greatly affect human health and the environmental quality. Catalytic combustion/oxidation has been viewed as an efficient, economically feasible and environmentally friendly way for the elimination of VOCs. Supported metal catalyst is the preferred type of catalysts applied for VOCs catalytic combustion because of the synergy between active components and support as well as its flexibility in the composition. The presence of support not only plays the role of keeping the catalyst with good stability and mechanical strength, but also provides a large specific surface for the good dispersion of active components, which could effectively improve the performance of catalyst as well as decrease the usage of active components, especially the noble metal amount. Mesoporous molecular sieves, owing to their large surface area, unique porous structures, large pore size as well as uniform pore-size distribution, were viewed as superior support for dispersing active components. This review focuses on the recent development of mesoporous molecular sieve supported metal catalysts and their application in catalytic oxidation of VOCs. The effect of active component types, support structure, preparation method, precursors, etc. on the valence state, dispersion as well as the loading of active species were also discussed and summarized. Moreover, the corresponding conversion route of VOCs was also addressed. This review aims to provide some enlightment for designing the supported metal catalysts with superior activity and stability for VOCs removal.

Aluminosilicate phosphate (ASP) geopolymers are a new kind of green cementitious materials synthesized from aluminosilicate precursors and acidic activators (phosphoric acid or phosphate), which have received extensive attention from researchers because of their excellent and unique characteristics. The current investigation indicates that ASP geopolymers have the characteristics of a low-carbon synthesis process, high mechanical properties (e.g., the highest compressive strength can reach 146 MPa), a strong heat resistance (e.g., withstanding a high temperature of 1500 °C), and excellent dielectric properties. These excellent properties make them have broad application prospects in the fields of new building materials, coating materials, insulating materials, and heavy metal curing. Based on the research findings of approximately 85 relevant literatures on ASP geopolymers in past decades, this paper focuses on the latest research progress of ASP geopolymers from the perspectives of synthesis processes, performances, modifications, and application developments. In addition, this study summarizes the key problems existing in the current research of ASP geopolymers and suggests their possible applications in the future, which will help to provide directions for further research activities of relevant researchers.

PER: and polyfluoroalkyl substances (PFAS) are a concerning and unique class of environmentally persistent contaminants with biotoxic effects. Decades of PFAS discharge into water and soil resulted in PFAS bioaccumulation in plants, animals, and humans. PFAS are very stable, and their treatment has become a global environmental challenge. Significant efforts have been made to achieve efficient and complete PFAS mineralization using existing and emerging technologies. Hydrothermal treatments in subcritical and supercritical water have emerged as promising end-of-life PFAS destruction technologies, attracting the attention of scholars, industry, and key stakeholders. This paper reviews the state-of-the-art research on the behavior of PFAS, PFAS precursors, PFAS alternatives, and PFAS-containing waste in hydrothermal processes, including the destruction and defluorination efficiency, the proposed reaction mechanisms, and the environmental impact of these treatments. Scientific literature shows that >99% degradation and >60% defluorination of PFAS can be achieved through subcritical and supercritical water processing. The limitations of current research are evaluated, special considerations are given to the challenges of technology maturation and scale-up from laboratory studies to large-scale industrial application, and potential future technological developments are proposed.