Polypropylene

聚丙烯
  • 文章类型: Journal Article
    本文重点介绍了聚烯烃在高压直流(HVDC)电缆和电容器中的应用。首先提供了HVDC电缆和电容器的最新发展和当前使用的简短描述,其次是电绝缘和电容器功能的基础知识。然后描述了确定介电特性的方法,包括电荷运输,空间电荷,电阻率,介电损耗,和击穿强度。描述了聚乙烯和全同立构聚丙烯的半晶体结构,并讨论了它与介电性能的关系。该综述的重要部分致力于描述考虑原子和连续方法的聚烯烃电或介电性能的建模和预测的最新技术。此外,介绍了材料纯度和纳米颗粒存在的影响,审查以这些材料的可持续性方面结束。总之,有效地利用建模结合实验工作被描述为理解和设计下一代材料在高压输电电绝缘的重要途径。本文受版权保护。保留所有权利。
    This review focuses on the use of polyolefins in high-voltage direct-current (HVDC) cables and capacitors. A short description of the latest evolution and current use of HVDC cables and capacitors is first provided, followed by the basics of electric insulation and capacitor functions. Methods to determine dielectric properties are described, including charge transport, space charges, resistivity, dielectric loss, and breakdown strength. The semicrystalline structure of polyethylene and isotactic polypropylene is described, and the way it relates to the dielectric properties is discussed. A significant part of the review is devoted to describing the state of art of the modeling and prediction of electric or dielectric properties of polyolefins with consideration of both atomistic and continuum approaches. Furthermore, the effects of the purity of the materials and the presence of nanoparticles are presented, and the review ends with the sustainability aspects of these materials. In summary, the effective use of modeling in combination with experimental work is described as an important route toward understanding and designing the next generations of materials for electrical insulation in high-voltage transmission.
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  • 文章类型: Journal Article
    本系统综述检查了由聚对苯二甲酸乙二醇酯(PeT-G)构成的正畸透明矫正器牙齿矫正器的功效和生物相容性,聚丙烯(PP),聚碳酸酯(PC),热塑性聚氨酯(TPU),和乙烯-醋酸乙烯酯(EVA)。
    为了找到到2021年9月发表的相关论文,对PubMed进行了广泛搜索。包括评估对准剂材料的有效性和生物相容性的随机临床试验(RCT)和观察性研究。数据独立提取,并使用相关程序对纳入研究的质量进行了评估。研究的可变性需要叙事综合。
    纳入5项研究进行比较。所有材料都具有生物相容性;然而,PeT-G和EVA对准器引起的组织刺激最小。患者首选TPU矫正器以获得初始舒适度,而首选PeT-G矫正器以获得透明度和耐力。
    生物相容性PET-G,PP,PC,TPU,EVA牙齿矫正器修复咬合不良。应根据患者的喜好选择校准材料,治疗目标,和材料质量。为了更有力的证明,需要进行更长期的研究。
    UNASSIGNED: This systematic review examines the efficacy and biocompatibility of orthodontic clear aligner tooth aligners constructed from polyethylene terephthalate glycol (PeT-G), polypropylene (PP), polycarbonate (PC), thermoplastic polyurethanes (TPUs), and ethylene-vinyl acetate (EVA).
    UNASSIGNED: To find relevant papers published through September 2021, PubMed was searched extensively. Randomized clinical trials (RCTs) and observational studies assessing the effectiveness and biocompatibility of the aligner materials were included. Data were extracted independently, and the quality of included research was appraised using relevant procedures. The research variability necessitated a narrative synthesis.
    UNASSIGNED: Five studies were included for comparison. All materials were biocompatible; however, PeT-G and EVA aligners caused the least tissue irritation. Patients preferred TPU aligners for initial comfort and PeT-G aligners for transparency and endurance.
    UNASSIGNED: Biocompatible PeT-G, PP, PC, TPU, and EVA tooth aligners fix malocclusions. Aligner materials should be chosen based on patient preferences, treatment goals, and material qualities. For stronger proof, a longer-term study is needed.
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  • 文章类型: Meta-Analysis
    微塑料污染是一个备受公众关注的全球性问题。非洲被标记为全球污染最严重的水体,但是关于非洲水生生态系统中微塑料污染的程度和微塑料污染的潜在风险没有足够的信息。这项荟萃分析整合了有关非洲水生生态系统中微塑料污染的已发表文章的数据。水中微塑料分布和形态特征的数据,来自非洲河流的沉积物和生物群,湖泊,从75项选定的研究中提取了海洋。多变量统计用于批判性地分析采样和检测方法的效果,生态风险,微塑料的空间分布和相似性与采样点之间的地理距离有关。这项研究发现,采样方法对微塑料的丰度和形态特征有显著影响,与全球数据相比,非洲水生生态系统受到微塑料的高度污染。最普遍的颜色是白色,透明和黑色,最普遍的形状是纤维和碎片,和最可用的聚合物是聚丙烯(PP),聚苯乙烯(PS)和聚对苯二甲酸乙二醇酯(PET)。微塑料聚合物相似性随着站点之间地理距离的增加而降低。非洲水生生态系统中微塑料的风险水平相对较高,超过40%的水和沉积物表现出最高的生态风险水平。这篇综述提供了关于患病率的最新信息,微塑料在非洲水生生态系统中的分布和风险。
    Microplastic pollution is a global issue of great public concern. Africa is flagged to host some of the most polluted water bodies globally, but there is no enough information on the extent of microplastic contamination and the potential risks of microplastic pollution in African aquatic ecosystems. This meta-analysis has integrated data from published articles about microplastic pollution in African aquatic ecosystems. The data on the microplastic distribution and morphological characteristics in water, sediments and biota from African rivers, lakes, oceans and seas were extracted from 75 selected studies. Multivariate statistics were used to critically analyze the effects of sampling and detection methods, ecological risks, spatial distribution and similarity of microplastics in relation to the geographical distance between sampling sites. This study found that sampling methods have significant effect on abundance and morphological characteristics of microplastics and that African aquatic ecosystems are highly contaminated with microplastics compared to global data. The most prevalent colors were white, transparent and black, the most prevalent shapes were fibres and fragments, and the most available polymers were polypropylene (PP), polystyrene (PS) and polyethene terephthalate (PET). Microplastic polymers similarity decreased with an increase in geographical distance between sites. Risk levels of microplastics in African aquatic ecosystems were comparatively high, and more than 40 % of water and sediments showed highest level of ecological risk. This review provides recent information on the prevalence, distribution and risks of microplastics in African aquatic ecosystems.
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  • 文章类型: Journal Article
    在这个现代环境中,微塑料(MPs)是一个重要的问题,海洋环境现在对他们来说是一个水槽。研究人员最近对海洋微塑料研究产生了兴趣,这为大型藻类和微藻的研究打开了大门。大型藻类是海洋生态系统中的主要生产者,具有重要的经济意义。这篇综述旨在根据现有文献确定微塑料与海洋大型藻类的相互作用以及微塑料对大型藻类的影响,同时也认识到知识差距。MPs主要是纤维和聚合物,具有显着的生产和应用水平;它们的丰度因物种而异。与其他类型相比,在丝状物种中发现了更多的MP。这项研究的结果表明,在海洋环境中,大型藻类有助于MP生物放大和生物积累。需要进行足够的研究来填补MPs在大型藻类及其影响方面的研究空白。
    Microplastics (MPs) are a significant concern in this modern environment, and the marine environment is a sink for them now. Researchers have taken an interest in marine microplastic studies recently, which has opened the door to research in macroalgae and microalgae. Macroalgae are the primary producers in maritime ecosystems and are economically significant. This review aimed to identify the microplastic interactions with marine macroalgae and the impacts of microplastics on macroalgae based on existing literature while also recognizing knowledge gaps. MPs were mostly fibers and polymers with notable production and application levels; their abundance differed among species. More MPs were found in filamentous species than in other types. The results of this study indicated that, in maritime environments, macroalgae contribute to MP biomagnification and bioaccumulation. Adequate studies are needed to fill the research gaps in this area of MPs in macroalgae and their effects.
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  • 文章类型: Journal Article
    鉴于近年来塑料回收的快速发展,对取样和材料表征指南的需求正在稳步出现。然而,仍然存在相当稀缺的方法,使适当的材料数据采集。本文由两部分组成。第一部分对可用于塑料回收领域的可用采样技术进行了严格审查。审查中与著名的标准化机构一起涵盖了几项抽样研究。研究发现,无论是文献还是标准,都没有提供综合实践,考虑到塑料废物的独特特征,并将其应用于价值链上的不同情况。在第二部分,根据所审查方法中的选定信息,概念化了对经过预处理的硬质塑料废物进行采样计划的建议。根据薄片尺寸分布和四种不同的预处理聚烯烃(PO)废料的表观密度,对拟议计划的两种变体进行了评估。研究结果表明,将分层随机抽样与复合抽样相结合,可为刚性PO废物提供良好的抽样技术。此外,复合样品的分析充分传达了一个子批次或批次的真实材料特性。
    Given the rapid development of plastics recycling in recent years, the need for guidelines for sampling and material characterization is steadily emerging. However, there still exists a considerable scarcity of methods that enable proper material data acquisition. This paper consists of two parts. The first part provides a critical review of the available sampling techniques that can be utilized in the field of plastics recycling. Several sampling studies were covered in the review alongside the prominent standardization institutions. It was found that neither the literature nor the standards provide a comprehensive practice that considers the distinctive characteristics of plastic waste and applies it to different situations along the value chain. In the second part, a proposal of a sampling plan for pretreated rigid plastic waste is conceptualized based on selected information from the reviewed methods. Two variants of the proposed plan were evaluated based on the flake size distribution and the apparent density of four different pretreated polyolefin (PO) waste materials. The results of the study showed that combining stratified random sampling with composite sampling yields a good sampling technique for rigid PO waste. Moreover, the analysis of a composite sample adequately conveys the true material properties of a sublot or lot.
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  • 文章类型: Journal Article
    The inherent resistance of synthetic plastics to degradation has led to an increasing challenge of waste accumulation problem and created a pollution issue that can only be addressed with novel complementary methods such as biodegradation. Since biocontrol is a promising eco-friendly option to address this challenge, the identification of suitable biological agents is a crucial requirement. Among the existing options, organisms of the Streptomyces genus have been reported to biodegrade several complex polymeric macromolecules such as chitin, lignin, and cellulose. Therefore, this systematic review aimed to evaluate the potential of Streptomyces strains for the biodegradation of synthetic plastics. The results showed that although Streptomyces strains are widely distributed in different ecosystems in nature, few studies have explored their capacity as degraders of synthetic polymers. Moreover, most of the research in this field has focused on Streptomyces strains with promising biotransforming potential against polyethylene-like polymers. Our findings suggest that this field of study is still in the early stages of development. Moreover, considering the diverse ecological niches associated with Streptomyces, these actinobacteria could serve as complementary agents for plastic waste management and thereby enhance carbon cycle dynamics.
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  • 文章类型: Journal Article
    The launch of Roadmap towards Zero Single-use Plastics in 2018 demands baseline data on the management of marine debris in Malaysia. In 2021, Malaysia is placed 28th top plastic polluter in the world with plastic consumption at 56 kg/capita/year, therefore data on mismanaged plastic is imperative. This paper reviews the abundance and distribution of marine debris in selected Malaysian beaches over the last decade (2010-2020) and discusses issue on its management. Plastic debris on beaches in Malaysia, was reported to range from 64 items/m2, to as high as 1930 items/m2, contributing 30-45% of total waste collected. Plastics film was the most dominant, mainly originated from packaging materials. Therefore, appropriate action including improved marine waste management system is crucial to tackle the problem, together with effective governance mechanisms. Various suggestions were proposed based on the statistical-environmental data to reduce the occurrence of marine debris in the country.
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  • 文章类型: Journal Article
    Stress urinary incontinence (SUI) was managed with techniques such as colposuspension, autologous fascia sling and urethral bulking agents. The introduction of the mid-urethral polypropylene (PP) sling in the 1990s led to a significant and rapid global change in SUI surgery. The synthetic non-degradable PP sling had superior results to traditional SUI procedures but its use has now declined due to significant complications such as pain and mesh erosion. These complications are attributed to its poor biocompatibility and integration into vaginal tissues. The efficacy of PP was extrapolated from studies on abdominal wall repair and it is now clear that integration of implanted materials in the pelvic floor differs from the abdominal wall. With PP prohibited in some jurisdictions, female patients with SUI have few management options. In the present review we summarise recent advances in SUI surgery and evaluate potential alternatives to PP slings with a particular focus on degradable materials. Allograft and xenograft materials demonstrate good biocompatibility but have yielded suboptimal cure rates. Tissue engineered synthetic degradable materials outperform unmodified synthetic degradable materials in terms of biomechanics and cell support. Synthetic tissue engineered degradable materials show promising results from in vitro studies and future research should focus on animal and human trials in this field.
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  • 文章类型: Journal Article
    BACKGROUND: The aim of this study is to systematically compare rates of erosion and chronic pain after mesh insertion for pelvic organ prolapse (POP) and stress urinary incontinence (SUI) surgery.
    METHODS: A systematic electronic search was performed on studies that evaluated the incidence of erosion and chronic pain after mesh insertion for POP or SUI. The primary outcome measurement was to compare mesh erosion rates for POP and SUI surgery. Secondary outcome measurements were incidence of de novo pain and a comparison of patient demographics for both surgeries.
    RESULTS: Twenty-six studies on 292,606 patients (n = 9077 for POP surgery and n = 283,529 for SUI surgery) met the inclusion criteria. Median follow-up was 26.38 ± 22.17 months for POP surgery and 39.33 ± 27.68 months for SUI surgery. Overall, the POP group were older (p < 0.0001) and had a lower BMI (p < 0.0001). Mesh erosion rates were significantly greater in the POP group compared to the SUI group (4% versus 1.9%) (OR 2.13; 95% CI 1.91-2.37; p < 0.0001). The duration from surgery to onset of mesh erosion was 306.84 ± 183.98 days. There was no difference in erosion rates between abdominal and transvaginal mesh for POP. There was no difference in erosion rates between the transobturator and retropubic approach for SUI. The incidence of chronic pain was significantly greater in the POP group compared to the SUI group (6.7% versus 0.6%) (OR 11.02; 95% CI 8.15-14.9; p < 0.0001). The duration from surgery to onset of chronic pain was 325.88 ± 226.31 days.
    CONCLUSIONS: The risk of mesh erosion and chronic pain is significantly higher after surgery for POP compared to SUI. These significant complications occur within the first year after surgery.
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  • 文章类型: Journal Article
    Polypropylene (PP) is a commodity plastic known for high rigidity and crystallinity, which is suitable for a wide range of applications. However, high flammability of PP has always been noticed by users as a constraint; therefore, a variety of additives has been examined to make PP flame-retardant. In this work, research papers on the flame retardancy of PP have been comprehensively reviewed, classified in terms of flame retardancy, and evaluated based on the universal dimensionless criterion of Flame Retardancy Index (FRI). The classification of additives of well-known families, i.e., phosphorus-based, nitrogen-based, mineral, carbon-based, bio-based, and hybrid flame retardants composed of two or more additives, was reflected in FRI mirror calculated from cone calorimetry data, whatever heat flux and sample thickness in a given series of samples. PP composites were categorized in terms of flame retardancy performance as Poor, Good, or Excellent cases. It also attempted to correlate other criteria like UL-94 and limiting oxygen index (LOI) with FRI values, giving a broad view of flame retardancy performance of PP composites. The collected data and the conclusions presented in this survey should help researchers working in the field to select the best additives among possibilities for making the PP sufficiently flame-retardant for advanced applications.
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