Monoterpenoids

单萜
  • 文章类型: Comparative Study
    从醚提取物中获得的挥发性化合物,通过GC/MS分析了高良姜和小豆豆的顶部空间气体和蒸汽馏出物。这两个物种都是天然稀有的fenchane型单萜的丰富来源,芬妮,Fenchone,芬基醇及其乙酸酯,和1,8-桉树脑一起.挥发性倍半萜的分布在这两个物种中都非常差。A.japonica和E.cardamomum中的Fenchone的手性占(1S,4R)-(+)形式。A.japonica中的樟脑由(1R,4R)-(+)-形式(94.3%)和(1S,4S)-(-)-形式(5.7%)。另一方面,仅生产的E.豆蔻(1R,4R)-(+)-樟脑(99%)。
    The volatile compounds obtained from the ether extracts, headspace gases and steam distillates of Alpinia japonica and Elettaria cardamomum were analyzed by GC/MS. Both species were rich sources of naturally rare fenchane-type monoterpenoids, fenchene, fenchone, fenchyl alcohol and its acetate, together with 1,8-cineole. The distributions of volatile sesquiterpenoids were very poor in both species. Chiralities of fenchone in A. japonica and E. cardamomum were 99% of (1S,4R)-(+)-form. Camphor in A. japonica is composed of a mixture of (1R,4R)-(+)-form (94.3%) and (1S,4S)-(-)-form (5.7%). On the other hand, E. cardamomum produced only (1R,4R)-(+)-camphor (99%).
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