Magnetic properties

磁性能
  • 文章类型: Journal Article
    在新的国际法规框架内,关于电动机在不久的将来必须实现的条件,降低能耗的问题为电动机生产商提出了重要的挑战。最重要的主题之一是与由切割技术引起的电工钢退化的影响直接相关的磁芯损耗降低。通过分析化学物质来了解这种现象是如何发生的,机械,晶体学,磁畴,当制造工艺必须改变并适应以高效电机为特征的新市场时,磁性是至关重要的。今天,机械和激光切割技术是最常用的,因为它们降低了价格和高速过程。尽管如此,不幸的是,这些方法不是最好的,因为它们会导致,在大多数情况下,磁芯损耗的高值,低电磁转矩,从而降低了效率。这篇综述论文表明,如果添加适当的修改,可以应用诸如喷水和电腐蚀之类的非常规技术。本文的主要思想是对切削技术对显微硬度和残余应力的影响进行全面的研究。晶体学纹理,磁畴结构,电机生产中使用的一些无取向电工钢的磁性能。它通过将作者的研究和发现纳入其他研究小组贡献的更广泛背景,对上述方面进行了详细分析。它还提供了宏观和微观层面上存在的机制的一般概念。读者可以找到一些最常用的分析模型,包括基于简单数学方法的切削过程对磁特性变化的损坏影响,以及在各种程序中对实际电机设计进行有限元建模的示例。最后但并非最不重要的,在本文的最后一部分中介绍了切割程序对电机工作条件的影响的一些实际实现。通过强调主题的重要性并确定必须进行补充研究的地方,它提供了有关切割方法应如何包括在高效电机生产中的最新分析。从调查的文献中,通过分析与不同表征方法相关的特定样品几何形状,可以得出结论,所有切割技术都对机械和磁量有重要贡献。当通过非常规方法生产电动机的磁芯时,切割程序的整体影响在电机效率中的百分比较低,如本文所述。
    The problem of energy consumption reduction establishes important challenges for electric motor producers in the framework of new international regulations regarding the conditions that must be accomplished by motors in the near future. One of the most important topics is related to the core loss decrease directly linked to the effect of electrical steel degradation induced by the cutting technology. Understanding exactly how this phenomenon occurs by analyzing the chemical, mechanical, crystallographic, magnetic domain, and magnetic properties is of utmost importance when manufacturing processes must be changed and adapted to a new market characterized by high-efficiency motors. Today, mechanical and laser cutting technologies are the most used because of their reduced price and high-speed process. Still, unfortunately, these methods are not the best due to the fact that they lead, in most cases, to a high value of magnetic core losses, low electromagnetic torque, and hence reduced efficiency. This review paper shows that non-conventional technologies such as water jetting and electroerosion could be applied if proper modifications are added. This paper\'s main idea is to present a comprehensive study regarding the impact of cutting technologies on microhardness and residual stresses, crystallographic texture, magnetic domain structure, and magnetic properties of some non-oriented electrical steels used in motor production. It provides a detailed analysis of the abovementioned aspects by including the authors\' research and findings in the wider context of other research group contributions. It also offers a general idea of the mechanisms present at the macro- and microscopic levels. The readers can find some of the most used analytical models, including the cutting process\'s damaged effect on the magnetic properties\' variation based on a simple mathematical approach and examples of finite element modeling performed on real motor designs implemented in various programs. Last but not least, some practical implementations of the cutting procedure\'s influence on motor working conditions are presented in the last section of the paper. It provides an up-to-date analysis regarding how the cutting method should be included in high-efficiency motor production by emphasizing the importance of the topic and identifying where supplementary research must be undertaken. From the investigated literature, by analyzing specific sample geometries associated with different characterization methods, it can be concluded that all the cutting technologies have an important contribution to the mechanical and magnetic quantities. When the magnetic core of an electric motor is produced through non-conventional methods, the overall influence of the cutting procedure has a low percentage in the motor efficiency, as presented in this paper.
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  • 文章类型: Journal Article
    磁性在许多生物系统中起着举足轻重的作用。然而,磁体之间施加的磁力强度通常较低,这需要开发用于正确感测的超灵敏度工具。在这个框架中,磁力显微镜(MFM)提供了出色的横向分辨率和进行单分子研究像其他单探针显微镜(SPM)技术的可能性。这篇全面的综述试图通过强调MFM的主要优点和内在局限性来描述磁力对生物应用的至关重要性。在深入描述工作原理的同时,本文还重点介绍了MFM提示的新型微加工和纳米加工程序,与商业纳米探针相比,这增强了测试生物材料的磁响应信号。这项工作还描述了一些相关的例子,其中MFM可以定量评估参与生物系统的纳米材料的磁性能,包括趋磁细菌,隐色素黄素蛋白,和可以与动物组织相互作用的磁性纳米粒子。此外,该领域最有希望的观点被强调,以使读者意识到即将到来的挑战,当瞄准量子技术。
    Magnetism plays a pivotal role in many biological systems. However, the intensity of the magnetic forces exerted between magnetic bodies is usually low, which demands the development of ultra-sensitivity tools for proper sensing. In this framework, magnetic force microscopy (MFM) offers excellent lateral resolution and the possibility of conducting single-molecule studies like other single-probe microscopy (SPM) techniques. This comprehensive review attempts to describe the paramount importance of magnetic forces for biological applications by highlighting MFM\'s main advantages but also intrinsic limitations. While the working principles are described in depth, the article also focuses on novel micro- and nanofabrication procedures for MFM tips, which enhance the magnetic response signal of tested biomaterials compared to commercial nanoprobes. This work also depicts some relevant examples where MFM can quantitatively assess the magnetic performance of nanomaterials involved in biological systems, including magnetotactic bacteria, cryptochrome flavoproteins, and magnetic nanoparticles that can interact with animal tissues. Additionally, the most promising perspectives in this field are highlighted to make the reader aware of upcoming challenges when aiming toward quantum technologies.
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  • 文章类型: Journal Article
    增材制造(AM)是一组有吸引力的工艺,最近被用来处理用于制造电机部件的特定材料。这是因为AM允许保持或增强它们的磁性,使用其他传统工艺制造时可能会降级或受到限制。软磁材料(SMM),如Fe-Si,Fe-Ni,Fe-Co,和软磁复合材料(SMC),由于其磁性,是适用于电机增材制造部件的材料,热,机械,和电性能。除了这些,在文献中观察到其他合金,如软铁氧体,由于它们的低磁化强度和脆性而难以加工。然而,多亏了增材制造,可以利用它们的高电阻率,使它们成为电机部件应用的替代候选者。重要的是要强调材料科学领域的重大进展,这使得新材料如高熵合金(HEAs)的开发成为可能。这些合金,由于它们复杂的化学成分,可以表现出软磁性能。本工作的目的是对通过不同AM技术制造的最先进的SMM进行严格审查。这篇综述涵盖了这些技术对微观结构变化的影响,机械强度,后处理,和磁参数,如饱和磁化强度(MS),矫顽力(HC),剩磁(Br),相对渗透率(Mr),电阻率(r),和热导率(k)。
    Additive manufacturing (AM) is an attractive set of processes that are being employed lately to process specific materials used in the fabrication of electrical machine components. This is because AM allows for the preservation or enhancement of their magnetic properties, which may be degraded or limited when manufactured using other traditional processes. Soft magnetic materials (SMMs), such as Fe-Si, Fe-Ni, Fe-Co, and soft magnetic composites (SMCs), are suitable materials for electrical machine additive manufacturing components due to their magnetic, thermal, mechanical, and electrical properties. In addition to these, it has been observed in the literature that other alloys, such as soft ferrites, are difficult to process due to their low magnetization and brittleness. However, thanks to additive manufacturing, it is possible to leverage their high electrical resistivity to make them alternative candidates for applications in electrical machine components. It is important to highlight the significant progress in the field of materials science, which has enabled the development of novel materials such as high-entropy alloys (HEAs). These alloys, due to their complex chemical composition, can exhibit soft magnetic properties. The aim of the present work is to provide a critical review of the state-of-the-art SMMs manufactured through different AM technologies. This review covers the influence of these technologies on microstructural changes, mechanical strengths, post-processing, and magnetic parameters such as saturation magnetization (MS), coercivity (HC), remanence (Br), relative permeability (Mr), electrical resistivity (r), and thermal conductivity (k).
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  • 文章类型: Journal Article
    磁性尖晶石铁氧体材料在生物医学领域提供各种应用,水处理,和工业电子设备,这引起了很多关注。这篇综述的重点是综合,表征,以及尖晶石铁氧体在各个领域的应用,特别是尖晶石铁氧体掺杂。掺杂该元素的尖晶石铁氧体纳米颗粒具有显著的电学和磁学性能,允许它们在磁场等广泛的应用中使用,微波吸收器,和生物医学。此外,尖晶石铁氧体的物理性质可以通过取代金属原子来改变,从而提高性能。本文综述和讨论了磁性铁氧体纳米粒子的最新和值得注意的应用。这篇综述回顾了综合,不同类型的金属铁氧体纳米粒子的掺杂和应用,以及如何根据预期应用选择合适的磁性铁氧体。
    Magnetic spinel ferrite materials offer various applications in biomedical, water treatment, and industrial electronic devices, which has sparked a lot of attention. This review focuses on the synthesis, characterization, and applications of spinel ferrites in a variety of fields, particularly spinel ferrites with doping. Spinel ferrites nanoparticles doped with the elements have remarkable electrical and magnetic properties, allowing them to be used in a wide range of applications such as magnetic fields, microwave absorbers, and biomedicine. Furthermore, the physical properties of spinel ferrites can be modified by substituting metallic atoms, resulting in improved performance. The most recent and noteworthy applications of magnetic ferrite nanoparticles are reviewed and discussed in this review. This review goes over the synthesis, doping and applications of different types of metal ferrite nanoparticles, as well as views on how to choose the appropriate magnetic ferrites based on the intended application.
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  • 文章类型: Journal Article
    Pure and doped iron oxide and hydroxide nanoparticles are highly potential materials for biological, environment, energy and other technological applications. On demand of the applications, single phase as well as multiple phase of different polymorphs or composites of iron oxides with compatible materials for example, zeolite, SiO2, or Au are prepared. The properties of the as-synthesized nanoparticles are predominantly dictated by the local structure and the distribution of the cations. Mössbauer spectroscopy is a perfect and efficient characterization technique to investigate the local structure of the Mössbauer-active element such as Fe, Au, and Sn. In the present review, the local structure transformation on the optimization of the magnetite coexisted with iron hydroxides, spin dynamics of the bare, caped, core-shell and the composites of iron oxide nanoparticles (IONPs), dipole-dipole interactions and the diffusion of IONPs were discussed, based on the findings using Mössbauer spectroscopy.
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  • 文章类型: Review
    从理论和实验的角度来看,低维材料都引起了极大的研究兴趣。由于在低尺寸中的限制效应,这些材料表现出新颖的物理和化学性质。石墨烯的试验不雅察开辟了一个新的平台,研讨资料的物理机能局限于二维。这篇专题文章提供了关于被称为石墨烯纳米带的准一维(1D)材料的新颖特性的评论。石墨烯纳米带可以通过解开碳纳米管(CNT)或切割石墨烯片来获得。或者,它也被称为石墨烯边缘的有限终止。它产生了不同的边缘几何形状,即之字形和扶手椅,在其他人中。有各种物理和化学技术来实现这些材料。根据边缘类型终止,这些被称为之字形和扶手椅石墨烯纳米带(ZGNR和AGNR)。这些边缘在控制石墨烯纳米带的性质中起重要作用。本评论文章概述了电子,运输,光学,石墨烯纳米带的磁性能。然而,有不同的方法来调整设备应用程序的这些属性。这里,其中一些,例如外部扰动和化学修饰,被突出显示。还简要讨论了石墨烯纳米带的一些应用。
    Low dimensional materials have attracted great research interest from both theoretical and experimental point of views. These materials exhibit novel physical and chemical properties due to the confinement effect in low dimensions. The experimental observations of graphene open a new platform to study the physical properties of materials restricted to two dimensions. This featured article provides a review on the novel properties of quasi one-dimensional (1D) material known as graphene nanoribbon. Graphene nanoribbons can be obtained by unzipping carbon nanotubes (CNT) or cutting the graphene sheet. Alternatively, it is also called the finite termination of graphene edges. It gives rise to different edge geometries, namely zigzag and armchair, among others. There are various physical and chemical techniques to realize these materials. Depending on the edge type termination, these are called the zigzag and armchair graphene nanoribbons (ZGNR and AGNR). These edges play an important role in controlling the properties of graphene nanoribbons. The present review article provides an overview of the electronic, transport, optical, and magnetic properties of graphene nanoribbons. However, there are different ways to tune these properties for device applications. Here, some of them, such as external perturbations and chemical modifications, are highlighted. Few applications of graphene nanoribbon have also been briefly discussed.
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  • 文章类型: Journal Article
    任何可持续增长的成功都代表了管理任何生态问题的新方法和新方法的进步。磁性纳米粒子由于其通用特性如可控尺寸而获得了最近的兴趣,形状,量子和表面效应,etc,以及废水处理和污染物去除的结果。在合成具有所需尺寸的磁性纳米粒子方面取得了进展,形状和形态,表面和化学成分。与常规处理技术相比,磁性纳米颗粒是靶特异性的且廉价的。本文综述了使用物理方法合成磁性纳米粒子的方法,化学,生物方法。合成磁性纳米颗粒的生物方法具有成本效益,绿色工艺,和环保的各种应用。使用TEM对合成的纳米颗粒进行表征研究,XRD,SARS,桑斯,DLS,等进行了详细讨论。磁性纳米颗粒在最近的研究中广泛用于去除有机和无机污染物。已发现,磁性纳米吸附方法与氧化还原反应一起被证明是从废物废水中去除污染物的有效而灵活的机制。
    The success of any sustainable growth represents an advancement of novel approaches and new methodologies for managing any ecological concern. Magnetic nanoparticles have gained recent interest owing to their versatile properties such as controlled size, shape, quantum and surface effect, etc, and outcome in wastewater treatment and pollutant removal. Developments have progressed in synthesizing magnetic nanoparticles with the required size, shape and morphology, surface and chemical composition. Magnetic nanoparticles are target specific and inexpensive compared to conventional treatment techniques. This review insight into the synthesis of magnetic nanoparticles using physical, chemical, and biological methods. The biological method of synthesizing magnetic nanoparticles serves to be cost-effective, green process, and eco-friendly for various applications. Characterization studies of synthesized nanoparticles using TEM, XRD, SARS, SANS, DLS, etc are discussed in detail. Magnetic nanoparticles are widely utilized in recent research for removing organic and inorganic contaminants. It was found that the magnetic nanosorption approach together with redox reactions proves to be an effective and flexible mechanism for the removal of pollutants from waste effluents.
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  • 文章类型: Journal Article
    石墨烯(GDY),二维人工合成碳材料,因其独特的物理性质引起了人们的极大兴趣。非常高的活性提供了用金属原子或轻质元素如氢和卤素等化学掺杂GDY的可能性。化学掺杂已被证实是产生具有有用物理性质的各种GDY衍生物的有效方法。因此,这篇评论旨在概述电子,光学,从理论到实验都报道了原始GDY及其衍生物的磁性。由于原始GDY及其衍生物在实际应用中的重要性,我们还总结了近年来报道的GDY及其衍生物的主要物理应用。我们相信,这项审查对所有对GDY感兴趣的人都是有价值的。
    Graphdiyne (GDY), a two-dimensional artificial-synthesis carbon material, has aroused tremendous interest because of its unique physical properties. The very high activity affords the possibility to chemically dope GDY with metal atoms or lightweight elements such as hydrogen and halogen and so on. Chemical doping has been confirmed to be an effective method to lead to various GDY derivatives with useful physical properties. Thus, this review is intended to provide an overview of the electronic, optical, and magnetic properties of pristine GDY and its derivatives reported from theories to experiments. Because of the importance of pristine GDY and its derivatives in real applications, we also summarize the main physical applications of GDY and its derivatives reported in recent years in this review. We believe that the review will be valuable to all those interested in GDY.
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  • 文章类型: Journal Article
    综述了通过催化化学气相沉积法大规模生产碳纳米材料的微波吸收能力。讨论了影响碳纳米材料生长和磁性的因素。
    The large-scale production of carbon nanomaterials by catalytic chemical vapor deposition is reviewed in context with their microwave absorbing ability. Factors that influence the growth as well as the magnetic properties of the carbon nanomaterials are discussed.
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  • 文章类型: Journal Article
    背景:氧化铁纳米颗粒(IONP)表现出非凡的性能,包括固有的磁性,生物相容性,高表面体积比,和工程的多功能性,使他们成为各种临床应用的理想人选。
    方法:该综述对最近7年与生物医学IONP相关的最新专利和发展进行了深入讨论。它涵盖了化学合成的创新,表面涂层和功能化,和生物医学应用,包括MRI和多模态成像,分子成像,细胞标记,药物输送,热疗,高磷酸盐血症,和抗菌活性。还简要概述了IONP的重要特性。
    结论:当前研究的主要重点是开发新方法,以生成在颗粒几何形状方面具有最佳性能的高质量IONP,晶体结构,表面功能,稳定性,和磁化。在化学合成方法中,热分解和水热合成过程允许精细控制颗粒性质。大量的涂层材料已成功地用作这些NP的外壳,以提供胶体稳定性,甚至可以同时进行疾病诊断和治疗。然而,在磁性纳米系统被批准用于临床之前,需要进行长期毒性和药代动力学研究。
    BACKGROUND: Iron oxide nanoparticles (IO NPs) exhibit remarkable properties, including inherent magnetism, biocompatibility, high surface to volume ratio, and versatility of engineering, making them ideal candidates for a variety of clinical applications.
    METHODS: The review provides an in-depth discussion on recent patents and developments related to IO NPs in Biomedicine from the last 7 years. It covers innovations in the chemical synthesis, surface coating and functionalization, and biomedical applications, including MRI and multimodal imaging, molecular imaging, cell labeling, drug delivery, hyperthermia, hyperphosphatemia, and antibacterial activity. A brief outline of the important properties of IO NPs is also presented.
    CONCLUSIONS: The main focus of current research is the development of new approaches to generate high-quality IO NPs with optimal properties in terms of particle geometry, crystal structure, surface functionalities, stability, and magnetization. Among chemical synthesis methods, thermal decomposition and hydrothermal synthetics processes allow fine control of the particle properties. Plenty of coating materials have been successfully used as shells for these NPs to provide colloidal stability, even enabling the formulation of nanotheranostics for simultaneous disease diagnosis and therapy. However, long-term toxicity and pharmacokinetic studies are necessary before magnetic nanosystems can be approved for clinical use.
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