Poly[[μ3-2-(benzotriazol-1-yl)acetato-κ3 O:O':N 3]chlorido-(ethanol-κO)cobalt(II)].

聚 [[μ 3 - 2 - (苯并三唑 - 1 - 基) 乙酸 - κ 3 O: O ': N 3] 氯 - (乙醇 - κ O) 钴 (II)] 。

• 发表时间: 2024 Jul
• 来源期刊: IUCrdata
• DOI: 10.1107/S2414314624006308
• PMID: 39108935
• 文章类型: Journal Article
• 作者列表: Zheng YY,Su DS,Yao QH,Huang MM

关键词: 2-(benzotriazol-1-yl) acetic acid; cobalt; coordination polymers; crystal structure

Abstract

In the title compound, [Co(C8H6N3O2)Cl(C2H5OH)] n , the CoII atoms adopt octa-hedral trans-CoN2O4 and tetra-hedral CoCl2O2 coordination geometries (site symmetries and m, respectively). The bridging μ3-O:O:N 2-(benzotriazol-1-yl)acetato ligands connect the octa-hedral cobalt nodes into (010) sheets and the CoCl2 fragments link the sheets into a tri-periodic network. The structure displays O-H⋯O hydrogen bonding and the ethanol mol-ecule is disordered over two orientations.

摘要

在标题化合物中，[Co(C8H6N3O2)Cl(C2H5OH)]n,CoII原子采用八面体反式CoN2O4和四面体CoCl2O2配位几何形状(位点对称性和m，分别)。桥接的μ3-O：O：N2-（苯并三唑-1-基）乙酸配体将八面体钴节点连接到（010）薄片中，而CoCl2片段将薄片连接到三周期网络中。该结构显示O-H-O氢键，乙醇摩尔在两个方向上无序。