Abstract：
Organic-inorganic hybrid manganese(II) halides (OIMnHs) have garnered tremendous interest across a wide array of research fields owing to their outstanding optical properties, abundant structural diversity, low-cost solution processibility, and low toxicity, which make them extremely suitable for use as a new class of luminescent materials for various optoelectronic applications. Over the past years, a plethora of OIMnHs with different structural dimensionalities and multifunctionalities such as efficient photoluminescence (PL), radioluminescence, circularly polarized luminescence, and mechanoluminescence have been newly created by judicious screening of the organic cations and inorganic Mn(II) polyhedra. Specifically, through precise molecular and structural engineering, a series of OIMnHs with near-unity PL quantum yields, high anti-thermal quenching properties, and excellent stability in harsh conditions have been devised and explored for applications in light-emitting diodes (LEDs), X-ray scintillators, multimodal anti-counterfeiting, and fluorescent sensing. In this review, the latest advancements in the development of OIMnHs as efficient light-emitting materials are summarized, which covers from their fundamental physicochemical properties to advanced optoelectronic applications, with an emphasis on the structural and functionality design especially for LEDs and X-ray detection and imaging. Current challenges and future efforts to unlock the potentials of these promising materials are also envisioned.
摘要：
有机-无机杂化卤化锰（II）（OIMnHs）由于其出色的光学性能而在广泛的研究领域引起了极大的兴趣，丰富的结构多样性，低成本的解决方案可加工性，低毒性,这使得它们非常适合用作各种光电应用的新型发光材料。在过去的几年里,大量具有不同结构维度和多功能的OIMnH，如高效光致发光(PL)，放射性发光，圆偏振发光，机械发光是通过对有机阳离子和无机Mn（II）多面体的明智筛选而新产生的。具体来说,通过精确的分子和结构工程，一系列具有接近统一的PL量子产率的OIMnHs，高抗热淬火性能，以及在恶劣条件下的出色稳定性已被设计和探索用于发光二极管（LED）的应用，X射线闪烁体,多模式防伪，和荧光传感。在这次审查中,总结了OIMnHs作为高效发光材料发展的最新进展，从基本的物理化学特性到先进的光电应用，重点是结构和功能设计，特别是LED和X射线检测和成像。还设想了当前挑战和未来努力来释放这些有前途的材料的潜力。
