Abstract:
A family of inorganic-organic hybrid crystalline materials made up of organic ligands and metal cations or clusters is known as metal-organic frameworks (MOFs). Because of their unique stability, intriguing characteristics, and structural diversity, zirconium-based MOFs (Zr-MOFs) are regarded as one of the most interesting families of MOF materials for real-world applications. Zr-MOFs that have the ligands, metal nodes, and guest molecules enclosed show distinct electrochemical reactions. They can successfully and sensitively identify a wide range of substances, which is important for both environmental preservation and human health. The rational design and synthesis of Zr-MOF electrochemical sensors and biosensors, as well as their applications in the detection of drugs, biomarkers, pesticides, food additives, hydrogen peroxide, and other materials, are the main topics of this comprehensive review. We also touch on the current issues and potential future paths for Zr-MOF electrochemical sensor research.
摘要:
由有机配体和金属阳离子或簇组成的无机-有机杂化晶体材料家族被称为金属-有机骨架(MOF)。由于其独特的稳定性,耐人寻味的特点,和结构多样性,锆基MOFs(Zr-MOFs)被认为是最有趣的MOF材料家族之一,用于现实世界的应用。具有配体的Zr-MOFs,金属节点,和封闭的客体分子显示出不同的电化学反应。他们可以成功而灵敏地识别各种物质,这对环境保护和人类健康都很重要。合理设计合成了Zr-MOF电化学传感器和生物传感器,以及它们在药物检测中的应用,生物标志物,杀虫剂,食品添加剂,过氧化氢,和其他材料,是这次全面审查的主要议题。我们还谈到了Zr-MOF电化学传感器研究的当前问题和潜在的未来路径。