Abstract:
Environmental pollution caused by organic effluents emitted by industry has become a worldwide issue and poses a serious threat to the public and the ecosystem. Metal-organic frameworks (MOFs), comprising metal-containing clusters and organic bridging ligands, are porous and crystalline materials, possessing fascinating shape and size-dependent properties such as high surface area, abundant active sites, well-defined crystal morphologies, and huge potential for surface functionalization. To date, numerous well designated MOFs have emerged as critical functional materials to solve the growing challenges associated with water environmental issues. Here we present the recent progress of MOF-based materials and their applications in the treatment of organic effluents. Firstly, several traditional and emerging synthesis strategies for MOF composites are introduced. Then, the structural and functional regulations of MOF composites are presented and analyzed. Finally, typical applications of MOF-based materials in treating organic effluents, including chemical, pharmaceutical, textile, and agricultural wastewaters are summarized. Overall, this review is anticipated to tailor design and regulation of MOF-based functional materials for boosting the performance of organic effluent remediation.
摘要:
工业排放的有机废水造成的环境污染已经成为一个世界性的问题,对公众和生态系统构成了严重威胁。金属有机骨架(MOFs),包含含金属簇和有机桥接配体,是多孔和结晶材料,拥有迷人的形状和尺寸相关的特性,如高表面积,丰富的活性位点,定义明确的晶体形态,以及表面功能化的巨大潜力。迄今为止,许多精心指定的MOF已经成为关键的功能材料,以解决与水环境问题相关的日益增长的挑战。在这里,我们介绍了MOF基材料的最新进展及其在有机废水处理中的应用。首先,介绍了MOF复合材料的几种传统和新兴的合成策略。然后,提出并分析了MOF复合材料的结构和功能规律。最后,MOF基材料在处理有机废水中的典型应用,包括化学,Pharmaceutical,纺织品,并对农业废水进行了总结。总的来说,这项审查预计将定制设计和监管基于MOF的功能材料,以提高有机废水治理的性能。