Abstract：
Adsorption is a promising way to remove persistent organic pollutants (POPs), a major environmental issue. With their high porosity and vast surface areas, MOFs are suited for POP removal due to their excellent adsorption capabilities. This review addresses the intricate principles of MOF-mediated adsorption and helps to future attempts to mitigate organic water pollution. This review examines the complicated concepts of MOF-mediated adsorption, including MOF synthesis methodologies, adsorption mechanisms, and material tunability and adaptability. MOFs\' ability to adsorb POPs via electrostatic forces, acid-base interactions, hydrogen bonds, and pi-pi interactions is elaborated. This review demonstrates its versatility in eliminating many types of contaminants. Functionalizing, adding metal nanoparticles, or changing MOFs after they are created can improve their performance and remove contaminants. This paper also discusses MOF-based pollutant removal issues and future prospects, including adsorption capacity, selectivity, scale-up for practical application, stability, and recovery. These obstacles can be overcome by rationally designing MOFs, developing composite materials, and improving material production and characterization. Overall, MOF technology research and innovation hold considerable promise for environmental pollution solutions and sustainable remediation. Desorption and regeneration in MOFs are also included in the review, along with methods for improving pollutant removal efficiency and sustainability. Case studies of effective MOF regeneration and scaling up for practical deployment are discussed, along with future ideas for addressing these hurdles.
摘要：
吸附是去除持久性有机污染物（POPs）的一种有前途的方法，一个重大的环境问题。它们的高孔隙率和广阔的表面积，MOF由于其优异的吸附能力而适合于POP去除。这篇综述讨论了MOF介导的吸附的复杂原理，并有助于将来减轻有机水污染的尝试。这篇综述探讨了MOF介导的吸附的复杂概念，包括MOF合成方法，吸附机制，以及材料的可调性和适应性。MOFs通过静电力吸附POPs的能力，酸碱相互作用，氢键,并详细阐述了pi-pi相互作用。这篇综述证明了它在消除许多类型的污染物方面的多功能性。Functionalizing,添加金属纳米颗粒，或在创建后更改MOF可以提高其性能并去除污染物。本文还讨论了基于MOF的污染物去除问题和未来前景，包括吸附能力，选择性,扩大实际应用，稳定性,和恢复。这些障碍可以通过合理设计MOFs来克服，开发复合材料，并改善材料的生产和表征。总的来说,MOF技术研究和创新为环境污染解决方案和可持续修复带来了巨大的希望。MOFs中的解吸和再生也包括在审查中，以及提高污染物去除效率和可持续性的方法。讨论了有效的MOF再生和扩大实际部署的案例研究，以及解决这些障碍的未来想法。
