关键词: Ag−ZnO nanoparticles Young’s modulus antibacterial activity biocomposite degradable film tensile strength

Mesh : Zinc Oxide / chemistry pharmacology Escherichia coli / drug effects Anti-Bacterial Agents / chemistry pharmacology chemical synthesis Materials Testing Biocompatible Materials / chemistry pharmacology chemical synthesis Silver / chemistry pharmacology Particle Size Antioxidants / chemistry pharmacology chemical synthesis Microbial Sensitivity Tests Curcuma / chemistry Food Packaging Metal Nanoparticles / chemistry Green Chemistry Technology Citrus / chemistry

来  源:   DOI:10.1021/acsabm.4c00225

Abstract:
Nanotechnology offers an innovative application as an eco-friendly food packaging film fabricated along with a degradable active mixture (AM). The AM is an assortment of alloyed metal oxide nanoparticles (Ag-ZnO), citron powder (AA), and Curcuma peel powder (CPP). Alloyed nanoparticles (NPs) were observed to exhibit a hexagonal structure from the experimental X-ray diffraction. Compositional and morphological study of the NPs (22.69 nm) and AM (32 nm) was done using energy-dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and ζ- potential was observed to be -14.7 mV, indicating the stability of NPs. The prepared film was observed to be more effective with antibacterial analysis against Escherichia coli, exhibiting 72% of inhibition and antioxidant activity with IC50: 51.56% using the 2,2 diphenyl-1-picrylhydrazyl (DPPH) assay. Film 1, Film 2, Film 3, and Film 4 were fabricated with the AM and observed to be perfectly encapsulated by PVA using XRD. FESEM images of the film exhibit the aggregation of NPs with biocomposites in perfect distribution. The mechanical properties such as Young\'s modulus, elongation at break, tensile strength, and ultimate tensile strength (UTS- 5.37 MPa) were experimented for the films. The degradation rate was observed to be 6.12% for film 1 using the soil burial method. The study emphasizes that NPs along with biocomposite upgrade the sustainability of the packaging film with improved mechanical and physicochemical properties. The synthesized film with biomaterials could be used as a \"green\" food package to store fruits, vegetables, and sweets in the food industry.
摘要:
纳米技术提供了一种创新的应用,作为一种环保的食品包装膜,与可降解的活性混合物(AM)一起制造。AM是各种合金化的金属氧化物纳米颗粒(Ag-ZnO),柚子粉(AA),和姜黄皮粉(CPP)。从实验X射线衍射观察到合金纳米颗粒(NP)表现出六方结构。NPs(22.69nm)和AM(32nm)的组成和形态研究使用能量色散X射线光谱(EDX),扫描电子显微镜(SEM),傅里叶变换红外(FTIR)光谱,ζ-电位为-14.7mV,表明NP的稳定性。通过对大肠杆菌的抗菌分析,观察到制备的薄膜更有效,表现出72%的抑制和抗氧化活性,IC50:使用2,2二苯基-1-吡啶酰肼(DPPH)测定为51.56%。用AM制造膜1、膜2、膜3和膜4,并使用XRD观察到被PVA完全包封。薄膜的FESEM图像显示出NP与生物复合材料的聚集在完美的分布中。机械性能,如杨氏模量,断裂伸长率,抗拉强度,和极限拉伸强度(UTS-5.37MPa)的薄膜进行了实验。采用土埋法观察到膜1的降解率为6.12%。该研究强调,NP与生物复合材料一起提高了包装膜的可持续性,并改善了机械和物理化学性能。合成的生物材料膜可用作“绿色”食品包装来储存水果,蔬菜,食品行业的糖果。
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