Abstract:
Lipopolysaccharide was obtained from the aerobic moderately halophilic bacterium Halomonas fontilapidosi KR26. The O-polysaccharide was isolated by mild acid degradation of the lipopolysaccharide and was examined by chemical methods and by 1H and 13C NMR spectroscopy, including 1H,1H COSY, TOCSY, ROESY, and 1H,13C HSQC, and HMBC experiments. The following structure of the linear tetrasaccharide repeating unit was deduced. →2)-α-l-Rhap-(1→2)-α-l-Rhap-(1→3)-α-l-Rhap-(1→3)-β-d-Galp-(1→.
摘要:
脂多糖是从需氧中度嗜盐细菌FortilapidosiKR26中获得的。通过脂多糖的弱酸降解分离出O-多糖,并通过化学方法以及1H和13CNMR光谱进行检查,包括1H,1HCOSY,托西,罗西,和1H,13CHSQC,和HMBC实验。推导出线性四糖重复单元的以下结构。→2)-α-1-γ-(1→2)-α-1-γ-γ-(1→3)-α-1-γ-γ-(1→3)-β-d-γ-(1→。