Abstract：
Since the discovery of graphene, research on the family of 2D materials has been a thriving field. Metal phosphorous chalcogenides (MPX3 ) have attracted renewed attention due to their distinctive physical and chemical properties. The advantages of MPX3 , such as tunable layered structures, unique electronic properties, thermodynamically appropriate band alignments and abundant catalytic active sites on the surface, make MPX3 material great potential in electrocatalysis. In this review, the applications of MPX3 electrocatalysts in recent years, including hydrogen evolution reaction, oxygen evolution reaction, and oxygen reduction reaction, are summarized. Structural regulation, chemical doping and multi-material composite that are often effective and practical research methods to further optimize the catalytic properties of these materials, are introduced. Finally, the challenges and opportunities for electrocatalytic applications of MPX3 materials are discussed. This report aims to advance future efforts to develop MPX3 and related materials for electrocatalysis.
摘要：
自从发现石墨烯以来，二维材料家族的研究一直是一个蓬勃发展的领域。金属磷硫族化物（MPX3）由于其独特的物理和化学性质而引起了新的关注。MPX3的优点，如可调分层结构，独特的电子特性，热力学上适当的能带排列和表面上丰富的催化活性位点，使MPX3材料在电催化方面具有巨大的潜力。在这次审查中,近年来MPX3电催化剂的应用,包括析氢反应，析氧反应,和氧还原反应，是总结的。结构性调节，化学掺杂和多材料复合，通常是有效和实用的研究方法，以进一步优化这些材料的催化性能，被介绍。最后,讨论了MPX3材料电催化应用的挑战和机遇。本报告旨在推动未来开发MPX3和相关电催化材料的努力。
