Abstract：
Thiocarbamates could be synthesized in green solvents via thiol-dioxazolone modified Lossen rearrangement under transition-metal free, additive free, and mild conditions. Polythiocarbamates were further prepared with excellent self-healing and shape-memory properties, showing great potential in the development of functional materials.
摘要：
硫代氨基甲酸酯可以在绿色溶剂中通过硫醇-二恶唑酮修饰的Lossen重排在无过渡金属下合成，无添加剂，温和的条件。进一步制备了具有优异的自修复和形状记忆性能的聚硫代氨基甲酸酯,功能材料的开发显示出巨大的潜力。
