%0 Journal Article %T Synthesis and application of thiocarbamates via thiol-dioxazolone modified Lossen rearrangement. %A Jiang Y %A Li M %A Liu S %A Li R %A Zheng Y %A Song W %A Zheng N %J Chem Commun (Camb) %V 58 %N 88 %D Nov 2022 3 %M 36263456 %F 6.065 %R 10.1039/d2cc05198b %X Thiocarbamates could be synthesized in green solvents via thiol-dioxazolone modified Lossen rearrangement under transition-metal free, additive free, and mild conditions. Polythiocarbamates were further prepared with excellent self-healing and shape-memory properties, showing great potential in the development of functional materials.