Abstract:
Seventeen polycyclic aromatic hydrocarbons (PAHs) and eight nitrated PAHs (NPAHs) in PM2.5 and conventional gaseous pollutants exhausted from 54 in-use gasoline vehicles encompassing different emission standards (China 1 to China 5) were tested on the chassis and engine dynamometric test bench. With the increase of emission standards, a decrease in the emissions of PM2.5-bound PAHs and NPAHs was detected. The emission factors (EFs) of total PAHs and NPAHs in PM2.5 emitted by the vehicles with a mileage of >100,000 km were greater than that emitted by the vehicles with driving mileage of <100,000 km under all the five emission standards. The EFs of PM2.5-bound PAHs and NPAHs emitted from port fuel injection engines were larger than that from gasoline direct injection engines. The emissions of PM2.5-bound PAHs and NPAHs were less correlated with the exhaust of CO, while the hydrocarbon (HC) emissions were strongly correlated with the PM2.5-bound PAHs emissions. The emissions of NPAHs and NOx had an inverse correlation. The toxic (TEQs) of total PAHs and NPAHs in China 3, China 4 and China 5 were significantly reduced compared to China 1 and China 2, which may be related to exhaust technology improvements. Although the EFs of NPAHs were significantly lower than those of PAHs, the TEQs of NPAHs were higher, which indicates that the toxic effect of NPAHs emitted by gasoline vehicles were stronger than PAHs.