{Reference Type}: Journal Article
{Title}: Theoretical insights, degradation, and sub-lethal toxicity of thiamethoxam to the planarian Girardia tigrina.
{Author}: Gravato C;da Silva Barbosa R;Cavallini GS;Cruz ÁB;Pereira DH;de Souza NLGD;Carlos TD;Soares AM;Sarmento RA;
{Journal}: Environ Sci Pollut Res Int
{Volume}: 0
{Issue}: 0
{Year}: 2024 Jun 26
{Factor}: 5.19
{DOI}: 10.1007/s11356-024-34067-2
{Abstract}: Advanced oxidative processes, such as Photo-Fenton, transform organic contaminants due to the attack by radicals. In this context, the lethal and sub-lethal effects of the Cruiser® 350FS (CRZ) with the active ingredient thiamethoxam (TMX) were investigated using the planarian Girardia tigrina. Degradation of thiamethoxam by the Fenton process was also assessed by using theoretical studies and the efficiency of Solar-Fenton versus Fenton. The 48 h LC50 value of CRZ for planarians was 478.6 mg L-1. The regeneration of planarians was significantly affected for concentrations ≥ 17 mg·L-1 of TMX (24 h). The Solar-Fenton showed a high degradation percentage reaching ~70%. The theoretical model showed the atoms of the TMX molecule that will suffer attacks from the formed radicals. Current results open new perspectives concerning the treatment of TMX in the aquatic environment because the 70% degradation seems to be sufficient to reach concentrations that do not induce sub-lethal effects in planarians. Further studies should determine if the by-products generated might be toxic for planaria or other organisms.