{Reference Type}: Journal Article
{Title}: Dual-Strategy of Cation-Doping and Nanoengineering Enables Fast and Stable Sodium-Ion Storage in a Novel Fe/Mn-Based Layered Oxide Cathode.
{Author}: Shen Q;Zhao X;Liu Y;Li Y;Zhang J;Zhang N;Yang C;Chen J;
{Journal}: Adv Sci (Weinh)
{Volume}: 7
{Issue}: 21
{Year}: Nov 2020
{Factor}: 17.521
{DOI}: 10.1002/advs.202002199
{Abstract}: Iron/manganese-based layered transition metal oxides have risen to prominence as prospective cathodes for sodium-ion batteries (SIBs) owing to their abundant resources and high theoretical specific capacities, yet they still suffer from rapid capacity fading. Herein, a dual-strategy is developed to boost the Na-storage performance of the Fe/Mn-based layered oxide cathode by copper (Cu) doping and nanoengineering. The P2-Na0.76Cu0.22Fe0.30Mn0.48O2 cathode material synthesized by electrospinning exhibits the pearl necklace-like hierarchical nanostructures assembled by nanograins with sizes of 50-150 nm. The synergistic effects of Cu doping and nanotechnology enable high Na+ coefficients and low ionic migration energy barrier, as well as highly reversible structure evolution and Cu/Fe/Mn valence variation upon repeated sodium insertion/extraction; thus, the P2-Na0.76Cu0.22Fe0.30Mn0.48O2 nano-necklaces yield fabulous rate capability (125.4 mA h g-1 at 0.1 C with 56.5 mA h g-1 at 20 C) and excellent cyclic stability (≈79% capacity retention after 300 cycles). Additionally, a promising energy density of 177.4 Wh kg-1 is demonstrated in a prototype soft-package Na-ion full battery constructed by the tailored nano-necklaces cathode and hard carbon anode. This work symbolizes a step forward in the development of Fe/Mn-based layered oxides as high-performance cathodes for SIBs.