{Reference Type}: Journal Article
{Title}: Practical Synthesis of Ethynyl(phenyl)-λ3-Iodane Using Calcium Carbide as an Ethynyl Group Source.
{Author}: Hashishin T;Osawa T;Miyamoto K;Uchiyama M;
{Journal}: Front Chem
{Volume}: 8
{Issue}: 0
{Year}: 2020
{Factor}: 5.545
{DOI}: 10.3389/fchem.2020.00012
{Abstract}: Stannylation of calcium carbide followed by Sn-hypervalent iodine(III) exchange reaction cleanly afforded the electrophilic ethynylating agent ethynyl(phenyl)-λ3-iodane in high yield. This two-step method uses very inexpensive materials and is readily operable without any special precautions.